Physical Sciences and Mathematics Commons^™

An Assessment Of The Validity Of The Kinetic Model For Liquid-Vapor Phase Change By Examining Cryogenic Propellants, Kishan Bellur

Dissertations, Master's Theses and Master's Reports

Evaporation is ubiquitous in nature and occurs even in a microgravity space envi- ronment. Long term space missions require storage of cryogenic propellents and an accurate prediction of phase change rates. Kinetic theory has been used to model and predict evaporation rates for over a century but the reported values of accommodation coefficients are highly inconsistent and no accurate data is available for cryogens. The proposed study involves a combined experimental and computational approach to ex- tract the accommodation coefficients. Neutron imaging is used as the visualization technique due to the difference in attenuation between the cryogen and the metallic …

Laboratory Measurements Of Contact Nucleation By Mineral Dusts, Bacteria, And Soluble Salts, Joseph Niehaus

Dissertations, Master's Theses and Master's Reports

We present results from experiments that emulate atmospheric ice nucleation by aerosols. We have refined experimental techniques to improve measurements of ice forming nuclei in the contact mode. Our results show that atmospherically relevant dusts such as kaolinite, feldspar, rhyolitic ash, and Arizona Test Dust have efficiencies in the contact mode that are higher than the immersion mode. Experiments with bacteria show that biological material has the potential to contribute significantly to ice concentrations, but has large variability. By choosing a soluble compound as an ice nucleus, we are able to place bounds on the timescale for contact freezing and …

Effect Of Disulfide Bond Scrambling On Protein Stability, Aggregation, And Cytotoxicity, Colina Dutta

Dissertations, Master's Theses and Master's Reports

Proteins are nano-machines that carry out majority of the cellular functions. Thermodynamically they are functional and stable within a very narrow range (1 kcal/mol). External perturbations in the form of pH change, thermal, or oxidative/reducing stress can destabilize the protein resulting in misfolding and aggregation. Prolonged environmental stress can affect the cells adaptive response resulting in loss of ability to refold or recycle proteins. This can lead to accumulation of misfolded or aggregated proteins within the cell. Such accumulation of aggregated proteins have been associated with neurodegenerative disorders such as Amyotrophic Lateral Sclerosis (ALS), Parkinson’s, Huntington’s, and Alzheimer’s disease. There …

Reservoir Characterization Through Pre-Stack Seismic Analysis And Inversion In The Thrace Basin, Northwest Turkey, Emre Doguturk

Dissertations, Master's Theses and Master's Reports

This study analyzes hydrocarbon reservoirs by using Amplitude-Versus-Offset (AVO) analysis and different inversion methods to investigate hydrocarbon reservoir in the Thrace Basin which is located in northwest Turkey.

A 3D seismic survey containing prestack data was provided by Turkish Petroleum Corporation as true amplitude NMO corrected 3D gathers.

The quality of this land data was poor for AVO applications, and steps were taken to make it useful. Radon filtering proved to be extremely useful for this purpose. Although application of this filter affected the AVO characteristics differently depending on the parameters selected for the filter, relative AVO characteristics remained useful …

Can Seismic Velocity Stacking Errors Result In The Low-Frequency Shadow?, Umit Serhan Inan

Dissertations, Master's Theses and Master's Reports

The low-frequency shadow is the area on reflection seismic data, underneath gas reservoirs, that exhibits anomalously low frequency. This phenomenon has been related to the highly attenuating nature of the gas reservoir, which could explain the low-frequency shadows observed underneath extremely thick reservoirs, but not the ones underneath thin reservoirs. There are several other mechanisms that could be responsible, however detailed analysis of these possible explanations is yet to be found in the literature.

The main focus of this research is to test the possible contribution of stacking of offset seismic data, namely, their mis-stacking, to the generation of the …

Objective Bayesian Analysis Of A Generalized Lognormal Distribution, Shengnan Li

Dissertations, Master's Theses and Master's Reports

The generalized lognormal distribution plays an important role in various aspects of life testing experiments. We examine Bayesian analysis of this distribution using objective priors (in the general sense of priors constructed using some formal rules) for the model parameters in this paper. Specifically, the derivation of explicit expressions for multiple types of the Jeffreys priors, the reference priors with different group ordering of the parameters, and the first-order matching priors. We investigate the important issue of proper posterior distributions. It is shown that only two of them lead to proper posterior distributions. Monte Carlo simulations are conducted to compare …

Representation And Analysis Of Multi-Modal, Nonuniform Time Series Data: An Application To Survival Prognosis Of Oncology Patients In An Outpatient Setting, Jennifer Winikus

Dissertations, Master's Theses and Master's Reports

The representation of nonuniform, multi-modal, time-limited time series data is complex and explored through the use of discrete representation, dimensionality reduction with segmentation based techniques, and with behavioral representation approaches. These explorations are done with a focus on an outpatient oncology setting with the classification and regression analysis being used for length of survival prognosis. Each decision of representation and analysis is not independent, with implications of each decision in method for how the data is represented and then which analysis technique is used. One unique aspect of the work is the use of outpatient clinical data for patients, which …

Dynamic Atomistic Study Of Tunnel Functions In Nanostructured Transitional Metal Oxides, Yifei Yuan

Dissertations, Master's Theses and Master's Reports

Alpha (α-) MnO₂ is a well know transitional metal oxide possessing one dimensional 2×2 (4.6 × 4.6 Ų) tunnels for accommodation of various ions. Such a characteristic tunneled structure has enabled the wide applications of α-MnO₂ in the fields of ion exchange, molecular sieves, biosensor, catalysis and energy storage. This PhD dissertation focuses on the dynamic study of ion transport functionality of α-MnO₂ at atomic level using an aberration corrected scanning transmission electron microscopy equipped with a special holder with a scanning tunneling microscopy probe.

The wide application of in situ TEM studying the dynamic …

Methodology For Analyzing Epoxy-Cnt Phononic Crystals For Wave Attenuation And Guiding, Madhu Kolati

Dissertations, Master's Theses and Master's Reports

Phononic crystals (PhnCs) control, direct and manipulate sound waves to achieve wave guiding and attenuation. This dissertation presents methodology for analyzing nanotube materials based phononic crystals to achieve control over sound, vibration and stress mitigation. Much of the analytical work presented is in identifying frequency band gaps in which sound or vibration cannot propagate through these PhnCs. Wave attenuation and mitigation analysis is demonstrated using finite element simulation. Engineering principles from current research areas of solid mechanics, solid-state physics, elasto-dynamics, mechanical vibrations and acoustics are employed for the methodology. A considerable effort is put to show that these PhnCs can …

The Role Of Amino Acids In The Nitrogen Cycle Of Peatlands, Tia Scarpelli

Dissertations, Master's Theses and Master's Reports

Future release of carbon from peatlands in response to climate change may be impacted by nitrogen limitation. The current study considers the role of amino acids as a nitrogen source in peatlands. The total free amino acid (TFAA) concentration for peats ranged from 0-2.3 µM, and leucine was the primary contributor. The dominance of sedge or ericaceous shrub plant types did not significantly impact the TFAA pool. Ammonium concentrations were much greater than TFAA and nitrate concentrations. TFAA concentrations were greatest in spring and least in fall. The springtime maxima and summer decrease in concentrations were simulated in a modeling …

Experimental Study Of The Flow Of Ferrofluid In A Porous Media Under A Magnetic Field, Muskaan Khurana

Dissertations, Master's Theses and Master's Reports

This research presents results from a laboratory-scale experimental setup that was designed to visualize the behavior of ferrofluid percolation through a porous media. Ferrofluids are colloidal suspensions made of magnetic particles of a few nanometers and stabilized in carrier liquids like water or mineral oil. Ferrofluids get magnetized and align themselves in the direction of a magnetic field when a field gradient is applied.

With the help of this experiment we investigate the viability of controlling fluid flow in porous medium by a magnetic field in vicinity. The experiments show that ferrofluids can be used as a transporting media to …

Nonlinear Inversion Strategies Applied To Source Characterization And 3d Earthquake Tomography In Volcanic Environments: A Case Study At Pacaya Volcano, Guatemala, Federica Lanza

Dissertations, Master's Theses and Master's Reports

Full-waveform moment tensor inversion of volcanic seismic signals and travel-time 3D tomography of local earthquakes have been widely used to explore source processes related to magma transport as well as to image the location and size of magma storage systems. However, the inversion solutions and the associated reliability estimates are non-unique and bear intrinsic uncertainties due to simplifying assumptions about the source, inaccuracies in the velocity models, dependence on network configuration, and other a priori constraints imposed by the modeler.

This work addresses the non-uniqueness and uncertainties of the model results by introducing non-linear inversion techniques that allow sampling the …

Diffuse Co2 Degassing And The Origin Of Volcanic Gas Variability From Rincón De La Vieja, Miravalles And Tenorio Volcanoes, Guanacaste Province, Costa Rica, Aurelia Liegler

Dissertations, Master's Theses and Master's Reports

Volcanic gas emissions are an important key component for monitoring volcanic activity and magmatic input of carbon dioxide into the atmosphere as well as the assessment of geothermal potential in volcanic regions. Diffuse soil degassing of CO₂ at Rincón de la Vieja and Miravalles volcanoes, assessed with the commonly accepted accumulation chamber method, showed the concentration of gas emissions in evident hydrothermal surface features in secondary gas emission zones of the volcanoes. Analyses of fumarolic gases were conducted to investigate similarities and differences between the volcanoes and the possibility of continued magma injection into their source(s). An output of …

Testing Lidar-Radar Derived Drop Sizes Against In Situ Measurements, Mary Amanda Shaw

Dissertations, Master's Theses and Master's Reports

How well can a co-located lidar and radar retrieve a drop size distribution in drizzling clouds? To answer, we mimic scattering from a laboratory cloud to retrieve a lidar-radar effective diameter. Using only the shape parameter of the gamma-distributed drops, the mean diameter of the drops can be estimated from lidar-radar effective diameter to within a few percent of the true mean. In practice, the shape parameter of the gamma distribution is not known. To set bounds, mean diameters were calculated from the lidar-radar effective diameter using a range of in situ measured gamma shape parameters. The estimated means varied …

Maia And Mandos: Tools For Integrity Protection On Arbitrary Files, Paul J. Bonamy

Dissertations, Master's Theses and Master's Reports

We present the results of our dissertation research, which focuses on practical means of protecting system data integrity. In particular, we present Maia, a language for describing integrity constraints on arbitrary file types, and Mandos, a Linux Security Module which uses verify-on-close to enforce mandatory integrity guarantees. We also provide details of a Maia-based verifier generator, demonstrate that Maia and Mandos introduce minimal delay in performing their tasks, and include a selection of sample Maia specifications.

Numerical Modeling Of Ambient Noise Seismic Interferometry, Simisola M. Arogundade

Dissertations, Master's Theses and Master's Reports

CO₂ sequestration involves storing CO₂ in a deep geological formation and may help to mitigate the increasing emission of carbon. To monitor the migration of injected fluid in the reservoir, seismic observations may be used to observe changes in reflection character. Conventional methods to image the subsurface, using active seismic measurements, with man-made sources, have been applied at a few test sites, and the use of passive measurements, with natural sources, has been considered as a probable cost-efficient method to monitor CO₂ migration and leakage. This numerical modeling study examines the use of seismic interferometry to retrieve …

Improved Parameter Estimation Of The Log-Logistic Distribution With Applications, Joseph Reath

Dissertations, Master's Theses and Master's Reports

In this report, we work with parameter estimation of the log-logistic distribution. We first consider one of the most common methods encountered in the literature, the maximum likelihood (ML) method. However, it is widely known that the maximum likelihood estimators (MLEs) are usually biased with a finite sample size. This motivates a study of obtaining unbiased or nearly unbiased estimators for this distribution. Specifically, we consider a certain `corrective' approach and Efron's bootstrap resampling method, which both can reduce the biases of the MLEs to the second order of magnitude. As a comparison, we also consider the generalized moments (GM) …

Assessing The Impacts Of Climate Change On The Surface Temperature Of Inland Lakes In Michigan, Kaitlin Reinl

Dissertations, Master's Theses and Master's Reports

The aim of this study was to validate and apply a lake model for predicting the susceptibility of small inland lakes in Michigan to changes in thermal regime and increased cyanobacteria growth as a result of future climate conditions. The Freshwater Lake Model was selected, tested for sensitivity to various inputs, and validated through comparison to observed conditions. The sensitivity analysis showed that the lake model was most sensitive to solar radiation, air temperature, and air humidity. Comparison of predicted climate data with observed conditions revealed highly variable climate model error. The lake model validation was conducted using 10 lakes …

Cave Detection Using Seismic Methods At Madison Blue Spring State Park, Madison County, Florida, Charles Breithaupt

Dissertations, Master's Theses and Master's Reports

Locating caves and quantifying their geometries has significant importance in aquifer characterization, sinkhole mitigation, and contaminant transport monitoring. Several geophysical methods have been used for cave detection with limited success, but no reliable solution has been found. New developments in seismic techniques, however, show promising results indicating that cave voids may be more accurately detected.

We evaluated the capability of several seismic techniques to detect caves by collecting new seismic data over a known conduit connected to Madison Blue Spring, in northern Florida. These analyses validated the abilities of diffracted surface waves to detect water-filled caves by viewing these data …

Defect-Deferred Correction Method For The Two-Domain Convection-Dominated Convection-Diffusion Problem, Dilek Erkmen

Dissertations, Master's Theses and Master's Reports

We present a method for solving a fluid-fluid interaction problem (two convection-dominated convection-diusion problems adjoined by an interface), which is a simplifed version of the atmosphere ocean coupling problem. The method resolves some of the issues that can be crucial to the fluid-fluid interaction problems: it is a partitioned time stepping method, yet it is of high order accuracy in both space and time (the two-step algorithm considered in this report provides second order accuracy); it allows for the usage of the legacy codes (which is a common requirement when resolving flows in complex geometries), yet it can be applied …

Rhyolite And Trachyte Formation At Lake City Caldera: Insight From Quantitative Textural And Geochemical Analyses, Jordan Lubbers

Dissertations, Master's Theses and Master's Reports

Lake City Caldera (22.93 ± 0.02 Ma) is the youngest of 15 Tertiary calderas found within the Southern Rocky Mountain Volcanic Field (SRMVF). Extreme topographical relief of the area reveals the three dimensional exposure of a complex, high-k calc-alkaline, magmatic system, which provides us with the opportunity to study, in detail, how large silicic magmas evolve in the subsurface. The Lake City igneous system is comprised of two major units: a resurgent syenite intrusion and the Sunshine Peak Tuff (Lower, Middle, and Upper). Bulk-rock analyses indicate that the Lower and Middle Sunshine Peak tuff are crystal poor and rhyolitic in …

Petrophysical And Empirical And Theoretical Rock Physics Modeling For The Moki Formation In Two Fields In The Taranaki Basin, New Zealand, Deniz Yener

Dissertations, Master's Theses and Master's Reports

This work consists of conventional petrophysical analysis and sonic response determination from empirical relations, rock physics modelling, and fluid substitution for six wells in the Moki formation of New Zealand’s Taranaki Basin. The project composed of three parts encompassing conventional log analysis, rock-physics modeling using empirical and theoretical approaches, and finally rock-physics modeling for shaley sands using semi-empirical adaptations to Gassmann fluid substitution. Finally, comparisons are made between results for the different wells, based on their depths and mineralogy.

The first part of this study is presented as a petrophysical analysis, including crossplot analysis, conventional 3-mineral identification approach, and determination …

Comparisons Of Seismic Interferometry By Cross Correlation, Deconvolution, And Cross Coherence, Haitao Cao

Dissertations, Master's Theses and Master's Reports

Ambient noise seismic interferometry (ANSI) has been applied widely for geophysical investigations including earthquake tomography, civil engineering and seismic exploration purposes. Comparing this approach with the traditional active seismic survey, the application of ANSI is cost effective, environmentally friendly and easily repeatable. Conventional seismic interferometry by cross correlating wavefields recorded at different receivers has already obtained fruitful results.

Even though the application of seismic interferometry (SI) by cross correlation has been successful, different methods for the processing workflow such as cross coherence and deconvolution have been conducted in an effort to improve the resolution. While these three methods have been …

Enhancement Of Margrave Deconvolution And Q Estimation In Highly Attenuating Media Using The Modified S-Transform, Adnan Djeffal

Dissertations, Master's Theses and Master's Reports

We evaluate the performance of the Margrave deconvolution and spectral ratio methods using the Gabor, S-, and modified S transforms in highly attenuating media, where the quality factor changes with depth dramatically. Our results substantiate that the modified S-transform deconvolution is more robust in terms of generating fewer artifacts and providing better estimates of reflectivities than the Gabor transform. The results also show that using the modified S-transform in the spectral ratio method produces better Q estimates than the S-transform and the Fourier transform that is conventionally used in the spectral ratio method. This improvement in the estimates of reflectivities …

Comparison Of Different Seismic Filtering Techniques On Prestack Inversion For Penobscot Area-Nova Scotia, Omer Emre Uygun

Dissertations, Master's Theses and Master's Reports

The goal of this study is to compare three different type of seismic filtering according to their inversion results and their quality of data improvements. To do this bandpass filter, Inverse Q, and Radon transform are applied to the original NMO corrected pre-stack data from Nova-Scotia offshore Canada.

The seismic data used was provided as pre-stack data of generally good quality. The test for quality of data improvement comes from the results of inversion based on different types of filtering performed on the pre-stack gathers.

Bandpass filter, Inverse Q, and Radon transform are applied to the migrated prestack data, over …

Reservoir Estimation In The Penobscot 3d Seismic Volume Using Constrained Sparse Spike Inversion, Offshore Nova Scotia, Canada, Mengchu Xiao

Dissertations, Master's Theses and Master's Reports

The Penobscot study area is located offshore Nova Scotia, Canada. There are two wells, which penetrate the highest potentially commercial bodies in the Abenaki Formation. In order to investigate the potential for locating additional hydrocarbon reservoirs, well log data was used and the Penobscot 3D seismic dataset was analyzed using Constrained Sparse Spike Inversion. From the well log data, low GR and SP values are an indication of a permeable sand layer, which provides the target zone in this study. Impedance – porosity crossplots gave the relationship between impedance and porosity, where a low impedance sand layer is correlated with …

First-Principles Studies Of Group Iv And Group V Related Two Dimensional Materials, Gaoxue Wang

Dissertations, Master's Theses and Master's Reports

Two dimensional (2D) materials have been extensively studied due to their novel properties and technologically important applications. Especially, the discovery of graphene has stimulated an avalanche of investigations to exploit its novel properties for applications at nanoscale. In the post-silicon era, graphene has been widely regarded as the most promising building blocks for the electronic devices. However, its metallic nature together with sensitivity to the environment leads to somewhat limited scope of applications. A finite band gap in a material is known to be essential for the fabrication of devices such as transistors. Such a limitation associated with graphene has …

Influence Of The Weathered Layer On Retrieving Body Wave Using Passive Siesmic Interferometry, Boming Wu

Dissertations, Master's Theses and Master's Reports

Passive seismic interferometry (SI) is an increasingly popular seismic method due to its cost-efficient advantage because it does not need an active source. Techniques in using SI to retrieve surface waves are relatively well established, but using SI to retrieve body waves is still under development by many authors. These geophysicists have proved that many factors, such as average duration of the natural sources, the number of natural sources that occurred during recording time, source distribution, etc., influence the quality of body waves retrieved. In this research, I focus on how to make use of the attenuation property of weathered …

Investigation Of The Resistance To Demagnetization In Bulk Rare-Earth Magnets Comprised Of Crystallographically-Aligned, Single-Domain Crystallites With Modified Intergranular Phase, Jie Li

Dissertations, Master's Theses and Master's Reports

The research presented in this dissertation investigates whether an increased coercivity of Neodymium-Iron-Boron (Nd2Fe14B) based bulk magnets at elevated temperature (160°C), which is now only obtainable by substituting ~7wt% dysprosium (Dy) for a portion of neodymium (Nd), can be achieved through specific microstructural modifications with decreased Dy concentrations. The approach is to reduce the size of individual crystallographically-aligned grains in the magnet so that each grain can only support a single magnetic domain and to simultaneously dilute the Nd-Fe inter-granular phase present in conventional magnets with a non-Fe-containing, Nd-rich phase (Nd-Cu alloy) in an attempt to partially magnetically isolate the …

Communication Patterns And Strategies In Software Development Communities Of Practice, Shreya Kumar

Dissertations, Master's Theses and Master's Reports

Some of the greatest challenges in the relatively new field of software development lie in the decidedly old technology of communication between humans. Software projects require sophisticated and varied communication skills because software developers work in a world of incomplete, imperfect information where teams evolve rapidly in response to evolving requirements and changing collaborators. While prescriptive models for software process such as Agile suggest ways of doing, in reality these codified practices must adapt to the complexities of a real workplace. Patterns, rather than rules of behavior within software process are more suitable to the varied and mutable nature of …