Engineering Commons^™

Ion-Implanting Modification Of Layered Manganese Dioxide And Its Electrochemical Performance, He-Ning Huang, Dong-Ping Lv, Xing-Kang Huang, Qi-Wei Zhang, Yong Yang

Journal of Electrochemistry

Layered MnO2(δ-MnO2) was prepared by thermal decomposition of potassium permanganate.Ti was ion-implanted into such δ-MnO2 by physical techniques,forming a composite(δ-MnO2-Ti).These materials were characterized by XRD,SEM,XPS techniques and their electrochemical proprieties were investigated.The results showed that the layered structure of δ-MnO2 did not been destroyed after Ti ion implantation,and the implanted Ti element was mainly Ti4+ as indicated by XPS.Both of the first and the highest discharge specific capacities of the ion-implanted layered MnO2(δ-MnO2-Ti),compared to those of δ-MnO2,were improved significantly.

Determination Of Malathion Based On Carbon Nanotubes Modified Electrode Incorporating Acetylcholinesterase, Lu Zhang, Yao-Dong Zhang, Hong-Lan Qi

Journal of Electrochemistry

A biosensor for determination of organophosphorus pesticide based on the acetylcholinesterase and multi-wall carbon nanotubes modified electrode is fabricated.Under the optimal conditions,the chronoamperometric current at +0.70V(vs.SCE) increased linearly with the concentration of malathion in the range from 6.0×10-10 to 6.0×10-9 mol·L-1 with a detection limit of 1.0×10-10 mol·L-1.The recoveries of malathion in lake water is 97% to 105% determinated by this method.

Converting Traditional Materials Labs To Project-Based Learning Experiences: Aiding Students' Development Of Higher-Order Cognitive Skills, Linda Vanasupa, Katherine C. Chen, Jonathan Stolk, Richard N. Savage, Trevor S. Harding, Blair London, William L. Hughes

Materials Engineering

Against a backdrop of compelling societal needs, graduates in science and engineering now must master their disciplines and demonstrate a sophisticated level of cognitive, affective and social development. This has lead a number of national and international commissions on science and engineering to urge educators to re-think the way in which STEM disciplines are taught. We have chosen to "repackage" a traditional undergraduate materials engineering curriculum in a form designed to promote the development of higher-order cognitive skills like self-directed learning and design. Classic metallurgy experiments have been converted to project-based learning experiences where students are put in the role …

Ultrasonic Seaming Of Pet, Pet/Cotton Blend, And Spectra Fabrics, Renuka Kadiri Reddy

Master's Theses and Doctoral Dissertations

Ultrasonic seaming offers many advantages as an alternative for joining fabrics, such as efficiency, reduced cost, conservation of energy, and recyclability of the product.

The objective of this study was to investigate the effect of ultrasonic weld parameters – weld pressure, weld time, amplitude of vibration, seam design, and material properties – on seam efficiency and stiffness of a seam. This study also compares seam efficiency and stiffness of (a) ultrasonic seam to that of sewn seam and (b) ultrasonic seam from continuous mode of operation to that of plunge mode. Regression and analytical tests were used to analyze the …

Analysis Of Three Phase Controlled Rectifier With The Same Distance Control As Compared To The Same Angle Control, Sudirman S., Sri Kurniati A.

Makara Journal of Technology

Analysis of three phase controlled rectifier with the same distance control as compared to the same angle control. This research aim to compare the firing of the same distance and the same angle control at three phase controlled rectifier with seen generated harmonic at input (AC side). Then calculate of rectifier efficiency and power factor comparison from both the control type. The rectifier use passive filter with resistance 11 ohm and is analysed with program simulation using PSPICE version 7.1. Result of research indicate that use of the same distance control generates the 5th and 7th harmonics, while the same …

Trajectory Shaping Of Surface-To-Surface Missile With Terminal Impact Angle Constraint, S. Subchan

Makara Journal of Technology

This paper presents trajectory shaping of a surface-to-surface missile attacking a fixed with terminal impact angle constraint. The missile must hit the target from above, subject to the missile dynamics and path constraints. The problem is reinterpreted using optimal control theory resulting in the formulation of minimum integrated altitude. The formulation entails nonlinear, two-dimensional missile flight dynamics, boundary conditions and path constraints. The generic shape of optimal trajectory is: level flight, climbing, diving; this combination of the three flight phases is called the bunt manoeuvre. The numerical solution of optimal control problem is solved by a direct collocation method. The …

Effect Of Contact Time On Interface Reaction Between Aluminum Silicon (7% And 11%) Alloy And Steel Dies Skd 61, Bambang Suharno, Neni Octapiani Nurhayati, Bustanul Arifin, Sri Harjanto

Makara Journal of Technology

Effect of Contact Time on Interface Reaction between Aluminum Silicon (7% and 11%) Alloy and Steel Dies SKD 61. Die soldering (die sticking) is a defect of metal casting in which molten metal “welds” to the metallic die mold surface during casting process. Die soldering is the result of an interface reaction between the molten aluminum and the die material. Aluminum alloy with 7 and 11% silicon and SKD 61 die steel are the most common melt and die material used in aluminum die casting. This research is done to study the morphology and the characteristics of the formed AlxFeySiz …

The Use Of Red Cabbage’S Anthocyanine Extract As A Photosensitizer On A Dye-Sensitized Nanocrystalline Tio2 Solar Cell, Akhiruddin Maddu, Mahfuddin Zuhri, Irmansyah Irmansyah

Makara Journal of Technology

The use of Red Cabbage’s anthocyanine extract as a photosensitizer on a Dye-Sensitized Nanocrystalline TiO2 Solar Cell. A solid-state dye-sensitized nanocrystalline TiO2 solar cell utilizing anthocyanin extract form red cabbage as photosensitizer was fabricated. The solar cell was formed in sandwich structure, which two electrodes sandwiching polymer electrolyte containing a redox couple (I-/I3 -). One of the electrodes, namely working electrode, TiO2 layer on TCO (transparent conducting oxide) coated glass substrate was sensitized with anthocyanin dye as electron donor in the system. Another electrode was a carbon sheet as a counter electrode. Gel electrolyte based on PEG (polyethylene glycol) containing …

Reverse Link Cdma System Capacity Evaluation For Stratospheric Platform Mobile Communications, Iskandar Iskandar

Makara Journal of Technology

We propose an analysis of reverse link CDMA multispot beam stratospheric platforms (SPF) in this paper. The SPF is currently proposed as a novel wireless technology for the development of the next generation fixed and mobile communications. The geometry of this technology is different from that of the terrestrial but rather similar to the satellite based cellular system. However, evaluation on the CDMA system capacity of this technology has not been much reported. This paper addresses all possible multiple access interference analyses including the effects of channel fading and shadowing in order to evaluate the system capacity. Single SPF and …

The Potency Of Fire And Explosion Hazard On Premium Oil Storage Tank At Depot X 2007, Fatma Lestari, Warid Nurdiansyah

Makara Journal of Technology

The Potency of Fire and Explosion Hazard on Premium Oil Storage Tank at Depot X 2007. Premium oil storage tanks have fire and explosion risk because Premium oil is flammable liquid. Because of that, fire and explosion risk assessment on Premium oil storage tank at Depot X is needed as foundation to fire and explosion risk management, and comply with regulations. Method of this research is Dow’s Fire and Explosion Index. This research indicate that F&EI value for Premium oil storage tank is 118,82. Based on that F&EI value, level of risk at Premium oil storage tank is intermediate risk.

Limiting Maximum Drag Reduction Asymptote For The Moment Coefficient Of An Enclosed Rotating Disk With Fine Spiral Grooves, Budiarso Budiarso, Keizo Watanabe, Satoshi Ogata

Makara Journal of Technology

In this study, the limiting maximum drag reduction asymptote for the moment coefficient of an enclosed rotating disk with fine spiral grooves in turbulent flow region were obtained analytically. Analysis which were based on an assumption for a simple parabolic velocity distribution of turbulent pipe flow to represent relative tangential velocity, was carried out using momentum integral equations of the boundary layer. For a certain K- parameter the moment coefficient results agree well with experimental results for maximum drag reduction in an enclosed rotating disk with fine spiral grooves and drag reduction ratio approximately was 15 %. Additionally, the experimental …

Co2 Absorption From Its Mixture With Ch4 Or N2 Through Hollow Fiber Membrane Contactor Using Water As Solvent, Sutrasno Kartohardjono, Anggara Anggara, Subihi Subihi, Yuliusman Yuliusman

Makara Journal of Technology

CO2 Absorption from Its Mixture with CH4 or N2 through Hollow Fiber Membrane Contactor using Water as Solvent. Hollow fiber membrane contactors have been widely used as gas-liquid contactors recently such as in the CO2 absorption process from gas stream. This research aims to evaluate the effectiveness of hollow fiber membrane contactor to absorb CO2 from its mixture with CH4 or N2 using water through mass transfer and hydrodynamic tests. There are 3 membrane modules used in this research with shell diameter of 1.9 cm, length of 40 cm, outer fiber diameter of 2.7 mm and fiber number in the …

Posterminaries: More Or Less Modern, Alexander H. King

Alexander H. King

It is yet another sign that I am aging. More and more often when young researchers hand me a written report of their research, I find myself criticizing their introductory section: “You need to start your literature survey with the original papers on this topic. Go and read…” followed by a citation to some classic of the learned literature.

High Temperature Heat Exchanger Project: Quarterly Progress Report July 1, 2007 Through September 30, 2007, Anthony Hechanova

Publications (NSTD)

• Ceramatec Sulfuric Acid Decomposer. The numerical model of a SiC ceramic coupon with two layers of microchannels was developed. Calculations of the factor of safety and probability of failure for the case of a straight channel were performed. Results for a pressure of 7.5 MPa were performed. The thermal and mechanical stress analyses of the Ceramatec HTHX and decomposer were completed.

• Bayonet Heat Exchanger. The thermal and mechanical stress analyses of the bayonet type HTHX and decomposer (Sandia design) were completed. Temperature profiles obtained from thermocouples measured from the Sandia experiments have been applied to the whole packed …

Effect Of Tip Resonances On Tunnelling Anisotropic Magnetoresistance In Ferromagnetic Break Junctions: A First-Principles Study, John D. Burton, Renat F. Sabirianov, Julian P. Velev, O. N. Mryasov, Evgeny Y. Tsymbal

Materials Research Science and Engineering Center: Faculty Publications

First-principles calculations of electron tunneling transport in nanoscale Ni and Co break-junctions reveal strong dependence of the conductance on the magnetization direction, an effect known as tunneling anisotropic magnetoresistance TAMR. An important aspect of this phenomenon stems from resonant states localized in the electrodes near the junction break. The energy and broadening of these states is strongly affected by the magnetization orientation due to spin-orbit coupling, causing TAMR to be sensitive to bias voltage on a scale of a few millivolts. Our results bear a resemblance to recent experimental data and suggest that TAMR driven by resonant states is a …

Sistema De Control De Inyección Y Movimiento Para Trayectorias En Una Máquina Inyectora De Poliuretano, Orlando Pérez Rivera

Ingeniería en Automatización

No abstract provided.

Work-In-Progress - Self-Directed Learning And Motivation In A Project-Based Learning Environment, Trevor S. Harding, Linda Vanasupa, Richard N. Savage, Jonathan D. Stolk

Materials Engineering

Self-directed learning is a key competency in life-long learning, an outcome often cited for engineering education, and is dependent on students' motivation, meta-cognition, and self-regulation with regards to a learning task. Few studies have addressed the aspects of engineering learning environments that promote the development of self-directed learning abilities. The goal of this study was to identify relationships between students' perceptions of their self-directed learning ability and their learning motivation within a project-based learning environment. Junior engineering students in a test cohort with heavy emphasis on project-based learning completed surveys on self-directed learning aptitude and learning motivation. Responses were compared …

Sub-Surface Corrosion Research On Rock Bolt System, Perforated Ss Sheets And Steel Sets For The Yucca Mountain Repository — Quarterly Technical Report No. 13, Dhanesh Chandra, Jaak J.K. Daemen

Publications (YM)

This report shows the work done for this period in accordance to cooperative agreement of University of Nevada system for the Task 019 “Subsurface Corrosion Research on Rock Bolt System, Perforated SS Sheets and Steel Sets for the Yucca Mountain Repository”, the overall objective of which is to conduct corrosion research and predict the durability of rock-bolts and other underground metallic roof supports. We are performing oxidation tests using Thermogravimetric Analyzer (TGA), and Potentiodynamic and immersion tests to determine the corrosion rates of rock bolts.

In this quarter:

Potentiodynamic tests were performed to determine corrosion rates (CR) of 4340 Steel …

Effect Of Surface Roughness On Rate-Dependent Slip In Simple Fluids, Nikolai V. Priezjev

Mechanical and Materials Engineering Faculty Publications

Molecular dynamics simulations are used to investigate the influence of molecular-scale surface roughness on the slip behavior in thin liquid films. The slip length increases almost linearly with the shear rate for atomically smooth rigid walls and incommensurate structures of the liquid/solid interface. The thermal fluctuations of the wall atoms lead to an effective surface roughness, which makes the slip length weakly dependent on the shear rate. With increasing the elastic stiffness of the wall, the surface roughness smoothes out and the strong rate dependence is restored again. Both periodically and randomly corrugated rigid surfaces reduce the slip length and …

Signaling Pathways Activated By Interleukin-2 And Interluekin-4 Receptors Mediate T Lymphocyte Clonal Expansion, Kristen K. Comfort

Chemical and Materials Engineering Faculty Publications

Cells sense and respond to chemical and physical stimuli through signal transduction pathways, which mediate cell proliferation, differentiation, migration, and survival. The cytokines interleukin-2 (IL-2) and interleukin-4 (IL-4) are key regulators of the adaptive immune system, particularly influencing the clonal expansion and differentiation of T cells. At least in culture, both synergistic and antagonistic effects of IL-2 and IL-4 co-stimulation have been reported; the antagonism, when observed, is thought to arise from the utilization of a common subunit shared by IL-2 and IL-4 receptors. We have sought to characterize IL-2 and IL-4 signaling at the level of intracellular pathways activated …

Simulación Y Diseño De Un Mecanismo Automático Para Desplazamiento De Piezas En El Área De Pre-Tratamiento Químico De Partes Metálicas, Luis Carlos Romero Bonilla, Rodrigo Quiroga Contreras

Ingeniería en Automatización

No abstract provided.

Msematters Fall 2007, Department Of Materials Science & Engineering

MSEMatters Newsletter

No abstract provided.

Platinum Nanoparticle Shape Effects On Benzene Hydrogenation Selectivity, Kaitlin M. Bratlie, Hyunjoo Lee, Kyriakos Komvopoulos, Peidong Yang, Gabor A. Somorjai

Kaitlin M. Bratlie

Benzene hydrogenation was investigated in the presence of a surface monolayer consisting of Pt nanoparticles of different shapes (cubic and cuboctahedral) and tetradecyltrimethylammonium bromide (TTAB). Infrared spectroscopy indicated that TTAB binds to the Pt surface through a weak C-HâââPt bond of the alkyl chain. The catalytic selectivity was found to be strongly affected by the nanoparticle shape. Both cyclohexane and cyclohexene product molecules were formed on cuboctahedral nanoparticles, whereas only cyclohexane was produced on cubic nanoparticles. These results are the same as the product selectivities obtained on Pt(111) and Pt(100) single crystals in earlier studies. The apparent activation energy for …

Correlation-Space Description Of The Percolation Transition In Composite Microstructures, Megan E. Frary, Christopher A. Schuh

Materials Science and Engineering Faculty Publications and Presentations

We explore the percolation threshold shift as short-range correlations are introduced and systematically varied in binary composites. Two complementary representations of the correlations are developed in terms of the distribution of phase bonds or, alternatively, using a set of appropriate short-range order parameters. In either case, systematic exploration of the correlation space reveals a boundary that separates percolating from nonpercolating structures and permits empirical equations that identify the location of the threshold for systems of arbitrary short-range correlation states. Two- and three-dimensional site lattices with two-body correlations, as well as a two-dimensional hexagonal bond network with three-body correlations, are explored. …

Simulation Of Plasticity In Nanocrystalline Silicon, M. J. Demkowicz, A. S. Argon, D. Farkas, Megan Frary

Materials Science and Engineering Faculty Publications and Presentations

Molecular dynamics investigation of plasticity in a model nanocrystalline silicon system demonstrates that inelastic deformation localizes in intergranular regions. The carriers of plasticity in these regions are atomic environments that can be described as high-density liquid-like amorphous silicon. During fully developed flow, plasticity is confined to system-spanning intergranular zones of easy flow. As an active flow zone rotates out of the plane of maximum resolved shear stress during deformation to large strain, new zones of easy flow are formed. Compatibility of the microstructure is accommodated by processes such as grain rotation and formation of new grains. Nano-scale voids or cracks …

The Urban Heat Island Mitigation Impact Screening Tool (Mist), David J. Sailor, Nikolaas Dietsch

Mechanical and Materials Engineering Faculty Publications and Presentations

A web-based software tool has been developed to assist urban planners and air quality management officials in assessing the potential of urban heat island mitigation strategies to affect the urban climate, air quality, and energy consumption within their cities. The user of the tool can select from over 170 US cities for which to conduct the analysis, and can specify city-wide changes in surface reflectivity and/or vegetative cover. The Mitigation Impact Screening Tool (MIST) then extrapolates results from a suite of simulations for 20 cities to estimate air temperature changes associated with the specified changes in surface characteristics for the …

Bulk Behavior Of Nanostructured Aluminum: Nanocrystalline Powders Compaction, Canning And Consolidation Via Intense Plastic Straining, Mohamed Mahmoud Hamed Shamma

Archived Theses and Dissertations

No abstract provided.

Dumbbell Rattling In Thermoelectric Zinc Antimony, W. Schweika, R. P. Hermann, M. Prager, J. Perßon, Veerle Keppens

Faculty Publications and Other Works -- Materials Science & Engineering

Inelastic neutron scattering measurements on thermoelectric Zn4Sb3 reveal a dominant soft local phonon mode at 5.3(1) meV. The form factor of this local mode is characteristic for dumbbells vibrating preferably along the dumbbell axis and can be related to a vibration of Sb dimers along the c axis. The Lorentzian width of the mode corresponds to short phonon lifetimes of 0.39(2) ps and yields an estimate of the thermal conductivity that agrees quantitatively with recent steady state measurements. Heat capacity measurements are consistent with an Einstein mode model describing the local Sb-dimer rattling mode with an Einstein temperature of 62(1) …

Dumbbell Rattling In Thermoelectric Zinc Antimony, W. Schweika, R. P. Hermann, M. Prager, J. Perßon, Veerle Keppens

Veerle Keppens

Inelastic neutron scattering measurements on thermoelectric Zn4Sb3 reveal a dominant soft local phonon mode at 5.3(1) meV. The form factor of this local mode is characteristic for dumbbells vibrating preferably along the dumbbell axis and can be related to a vibration of Sb dimers along the c axis. The Lorentzian width of the mode corresponds to short phonon lifetimes of 0.39(2) ps and yields an estimate of the thermal conductivity that agrees quantitatively with recent steady state measurements. Heat capacity measurements are consistent with an Einstein mode model describing the local Sb-dimer rattling mode with an Einstein temperature of 62(1) …

Light Beam Targeting And Positioning System For A Paint Or Coating Removal Blasting System, Richard J. Klein Ii, Christopher A. Lampe

Patents (University of Northern Iowa)

A blasting system for the removal of coatings or paint from an underlying surface uses an optical device to position the blasting nozzle an appropriate stand-off distance from the surface. The blasting media can use a variety of blasting media including abrasives, water, and various specialty blasting media. The preferred optical system is mounted to or integral with the blasting nozzle, and uses a diode laser, a beam splitter and a reflecting mirror to generate a reference beam and a gauge beam. Alternatively, two diode lasers can be used to generate the reference beam and gauge beam respectively. The reference …