Chemistry Commons^™

Synthesis And Physicochemical Properties Of Cationic Microgels Based On Poly(N-Isopropylmethacrylamide), Xiaobo Hu, Zhen Tong, L. Andrew Lyon

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

Surfactant-free, radical precipitation copolymerization of N-isopropylmethacrylamide and the cationic co-monomer N-(3-aminopropyl) methacrylamide hydrochloride (APMH) was carried out to prepare microgels functionalized with primary amines. The morphology and hydrodynamic diameter of the microgels were characterized by atomic force microscopy and photon correlation spectroscopy, with the effect of NaCl concentration and initiator type on the microgel size and yield being investigated. When a 2,2'-azobis (2-amidinopropane) dihydrochloride (V50)-initiated reaction was carried out in pure water, relatively small microgels (similar to 160 nm in diameter) were obtained in low yield (similar to 20%). However, both the yield and size increased if the reaction was …

Bulk Modulus Of Poly(N-Isopropylacrylamide) Microgels Through The Swelling Transition, B. Sierra-Martin, Y. Laporte, A. B. South, L. Andrew Lyon, A. Fernandez-Nieves

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

We report measurements of the bulk modulus of individual poly(N-isopropylacrylamide) microgels along their swelling transition. The modulus is determined by measuring the volume deformation of the microgel as a function of osmotic pressure using dextran solutions. We find that the modulus softens through the transition, displaying a nonmonotonous behavior with temperature. This feature is correctly reproduced by the theory of Flory for polymer gels, once the concentration dependence of the solvency parameter is properly incorporated.

Synthesis And Characterization Of Self-Healing Poly (Carbonate Urethane) Carbon-Nanotube Composites, Roger Wesley Bass

USF Tampa Graduate Theses and Dissertations

Synthesis of high molar mass polycarbonate polyurethanes using a novel polyol is described. The resulting elastomers demonstrate excellent mechanical properties as well as the capability to re-heal after rupture without the addition of additives or imbedded healing agents. The self-healing functionality is shown to greatly improve with the addition of up to 1% single and multi-walled carbon nanotubes. The interface of the carbon nanotubes and self-healing polymer are probed using Raman techniques and provide an insight into how the self-healing actions are improved with the addition of carbon nanotubes.

Synthesis of polycarbonate polyurethanes and carbon nanotube composites using a novel …

Hybrid Micro-/Nanogels For Optical Sensing And Intracellular Imaging, Weitai Wu, Shuiqin Zhou

Publications and Research

Hybrid micro-/nanogels are playing an increasing important part in a diverse range of applications, due to their tunable dimensions, large surface area, stable interior network structure, and a very short response time. We review recent advances and challenges in the developments of hybrid micro-/nanogels toward applications for optical sensing of pH, temperature, glucose, ions, and other species as well as for intracellular imaging. Due to their unique advantages, hybrid micro-/nanogels as optical probes are attracting substantial interests for continuous monitoring of chemical parameters in complex samples such as blood and bioreactor fluids, in chemical research and industry, and in food …

Two-Phase Partitioning System Using Elvax 40w Polymer For The Biodegradation Of Aqueous Phenols, Amit Suresh Ghode

Masters Theses & Specialist Projects

A solid-liquid two phase partitioning system (TPPS) is a new technology platform for destroying toxic organic compounds. TPPS have traditionally been operated by using an immiscible organic phase which partitions organic compounds into the aqueous phase. TPPS using an immiscible organic phase suffers from several limitations such as the organic phase could be biodegradable and hence only certain compatible microbial strains could be used. This therefore, eliminates the desired use of mixed microbial populations for efficient degradation. A solid-liquid two phase partitioning system, in which solid polymeric beads replace liquid organic phase, appears to have benefits over the traditional liquid-liquid …

The Influence Of Nanoporous Crystalline Structure On Low Molecular Weight Mass Transport In Syndiotactic Polystyrene, Justin Paul Brandt

Dissertations

Solid-state structure, crystalline morphology, crystallization kinetics, thermal, free volume, and gas transport properties of semicrystalline syndiotactic polystyrene (sPS) and ethylene vinyl alcohol copolymers (EVOH) have been investigated. Solid-state structure of sPS after crystallization from the melt and glassy state was examined by differential scanning calorimetry (DSC), density and wide angle x-ray diffraction analysis (WAXD). The measurements confirmed low density of syndiotactic polystyrene crystalline forms, which in the case of α and δe was smaller and in the case of β and γ crystalline forms was slightly larger than the density of the glassy amorphous sPS. Positron annihilation lifetime spectroscopy (PALS) …

Study Of 3,3' Vs. 4,4' Dds Isomer Curatives On Physical Properties And Phenyl Ring Motions Of Dgeba Epoxy Via Molecular Dynamics, Deuterium Nmr, And Dielectric Spectroscopy, Samuel James Tucker

Dissertations

The purpose of this research is to develop a multiscale understanding of crosslinked amorphous matrices, connecting molecular level events to macroscopic properties. To accomplish this goal, our methodology was to identify network architectures that influence molecular level energy dissipation through mechanisms such as bond rotations, torsions, and ring flips and then relate those molecular motions to macroscopic properties. Studies were accomplished on two aerospace grade matrices: the epoxy, diglycidyl ether of bisphenol A (DGEBA) cured with two amines, 3,3’- diaminodiphenyl sulfone (33DDS) and 4,4’-diaminodiphenyl sulfone (44DDS). The 33DDS/DGEBA and 44DDS/DGEBA served both to provide a baseline for experimental testing of …

Synthesis And Electrical Properties Of Functional Block Copolymer/Inorganic Nanocomposite Materials, Hongying Chen

Dissertations

Sulfonated poly[styrene-b-ethylene-co-butylene-b-styrene] (sSEBS) block copolymers/inorganic nanocomposite materials were synthesized via in situ formation of inorganic fillers and characterized particularly for their dielectric properties and proton conductivities.

In preparation of sSEBS/SrTiO₃ nanocomposites, titanium (IV) isopropoxide [Ti(OPrⁱ)₄] complex was diffused into sSEBS film, followed by subsequent hydrolysis of [Ti(OPr i)4], diffusion of strontium cations in sSEBS domains, and in situ formation of crystalline SrTiO₃. sSEBS with sulfonation degree of 38.1% and 65.0% were employed, and relevant sSEBS/SrTiO₃ composites contain SrTiO₃ of 10-15 wt%. Elemental composition characterization with ESEM/EDX indicated uniform distribution of …

Unusually Conductive Carbon-Inherently Conducting Polymer (Icp) Composites: Synthesis And Characterization, Shawn Edward Bourdo

Theses and Dissertations

Two groups of materials that have recently come to the forefront of research initiatives are carbon allotropes, especially nanotubes, and conducting polymers-more specifically inherently conducting polymers. The terms conducting polymers and inherently conducting polymers sometimes are used interchangeably without fully acknowledging a major difference in these terms. Conducting polymers (CPs) and inherently conducting polymers (ICPs) are both polymeric materials that conduct electricity, but the difference lies in how each of these materials conducts electricity. For CPs of the past, an electrically conductive filler such as metal particles, carbon black, or graphite would be blended into a polymer (insulator) allowing for …

On-Metal Synthesis Of Some Aryl Substituted Rhenium Η5 Cyclopenta[C] Pyridazyl Complexes, Phenahas Gandu Sriramulu

Masters Theses & Specialist Projects

Heterocyclic organic and organometallic compounds (e.g. polypyrrole) and their derivatives have been of great interest for conductive polymers due to their novel properties and environmental stability as compared to non-aromatic analogs (e.g. polyacetylene). We are interested in synthesizing organometallic pyridazines and rhenium pyridazyl complexes for polymer research. SeveraI5,6-fused ring pyridazines (1,2-CsH3(CRNH)(CRN) have been synthesized and characterized. Additionally, pyridazyl complexes of rhenium were synthesized in three steps beginning from fulvenes 1,2-CsH3(COHR)(COR). On-Metal synthesis and characterization of (Re(CO)3 {1,2- CSH3(CRN)(CRN)}] (R=C6RtOMe, C6RtCI, C4H30) and some off-metal pyridazines are reported here. Our research is focused on synthesis of a variety of 5,6- fused …

Design, Synthesis, And Polymerization Of Novel Heterocyclic Monomers As Precursors For Functional Polyester, Poly(Ester Amide)S And Polyamides, Eylem Tarkin-Tas

Dissertations

The research presented in this dissertation involves the synthesis and polymerization of heterocyclic monomers which pave the way to biodegradable polyester nanocomposites, functional polyesters or poly(ester amide)s, functional polyamides and supramolecular polymers. The key monomers are ε-caprolactone, γ-acetamido-ε- caprolactone, γ-ethylene ketal-ε-caprolactam and α-amino-ε-caprolactam.

Poly(ε-caprolactone) organo-modified montmorillonite nanocomposites were prepared by in-situ polymerization using dibutyltin dimethoxide as initiator/catalyst. The montmorillonite was first modified with 1-decyl-2-methyl-3-(11-hydroxyundecyl)- imidazolium cation. The hydroxyl functionality was used for not only initiating polymer chains from the surface of the clay platelets but also for grafting polymer chains to the surface by acting as a reversible chain transfer …

Structure-Property Correlation In Cyclopolymerization Of New Acrylate-Based Functional Monomers, Huseyin Tas

Dissertations

New ether dimer; (ED-Od) and (ED-Eh) and diester; (ODE) and (EHDE) derivatives of α-(hydroxymethyl)acrylate, each having two octadecyl and 2-ethylhexyl side chains respectively, and an amine-linked di(2-ethylhexyl)acrylate (AL-Eh), having three 2-ethylhexyl side chains, were synthesized and (co)polymerized to evaluate the effects of differences in the structures of the monomers on final (co)polymer properties, particularly glass transition temperature, Tg. The free radical polymerizations of these monomers yielded high molecular weight polymers. Cyclopolymer formation of ED-Od, ED-Eh and AL-Eh was confirmed by 13C NMR analysis and the cyclization efficiencies were found to be very high (~100%). Copolymers of ED-Od, ODE, ED-Eh, EHDE, …

Synthesis And Characterization Of Photoactive Amorphous Molecular And Polymeric Pyridinium Materials, Alexi Kamenov Nedeltchev

UNLV Theses, Dissertations, Professional Papers, and Capstones

Pyridinium materials both molecular and polymeric are interesting class of multifunctional electrolytes and polyelectrolytes, which exhibit liquid-crystalline and light-emitting properties. Moreover, their properties could be easily tuned simply by modifying the chemical structures of counterions.

In this dissertation, we described the preparation and analysis of new ionic molecular materials based on bis(pyridinium salt)s and a new class of poly(pyridinium salt)s with various heterocyclic moieties in their backbones with various organic counterions. They were prepared by either ring-transmutation reaction or by metathesis reaction. Their chemical structures were confirmed by FTIR, 1H and 13C NMR spectroscopy and elemental analysis. They had excellent …

Novel Π-Conjugated Materials Plus Their Characterizations And Applications, Xiuxian He

All Dissertations

The theme of this dissertation will focus on the syntheses and characterization of bipyridine (bipy) containing π-conjugated polymers (CPs). Specifically, poly(p-phenylene ethynylene), polyfluorene and poly(p-phenylene vinylene) derivatives have been prepared via Sonogashira coupling, Suzuki coupling and Heck coupling, respectively. Derivatives of poly(p-phenylene ethynylene), polyfluorene and poly(p-phenylene vinylene) are known to have applications in optical and electronic devices. Through this study, polymers condensed with bulky bipy-containing TAB as one of the copolymer units have shown increased solubility and diminished intrachain/interchain aggregation in solution and in film due to the effectiveness of TAB in controlling the relative orientations of individual polymer chains. …

Rational Design Of Self-Assembled Nanostructures Based On Polymers Synthesized Via Aqueous Reversible Addition-Fragmentation Chain Transfer Polymerization, Stacey Kirkland York

Dissertations

Recent advances in reversible addition-fragmentation chain transfer (RAFT) polymerization have allowed the rational, bottom-up design of biorelevant assemblies. Utilizing foresight, polymers can be tailored to self-assemble into nano-, micro-, and macroscopic structures. Given the size scale on which rationally-designed polymers can be tailored, they hold significant promise in the biomedical field. For example, nanoscale materials can be designed to carry small-molecule and gene therapeutics while macroscopic structures can be tailored for cell growth scaffolds. The design process begins by selecting monomers, chain transfer agents, and reaction conditions which will yield the desired polymer architecture and composition.

The work herein builds …

Investigation Of Novel Quasiliving Polyisobutylene Chain-End Functionalization (Quenching) Methods, David Lee Morgan

Dissertations

This volume recounts efforts toward the development and understanding of chain functionalization techniques involving the direct addition of nucleophiles to quasiliving polyisobutylene (PIB). Nucleophiles included in the study were sterically hindered organic bases, (di)sulfides, N-substituted pyrroles, and alkoxybenzenes. A kinetic investigation of the end-quenching of TiCl4-catalyzed quasiliving PIB with sterically hindered amines was used to determine the mode of interaction with TiCl4 and the active species responsible for -proton abstraction. 2,5-disubstituted-N-hydropyrroles formed pyrrole-TiCl3 adducts that were active in formation of exo-olefin chain ends; whereas, with other sterically hindered amines, only an equilibrium fraction of the amine that did not complex …

Nanomaterials From Biologically Active Molecules: Self-Assembly And Molecular Recognition, Min Yu

Dissertations

This dissertation describes the development of molecular assemblies and molecular recognition of phospholipids (PLs) that exhibit potential applications in emerging nanotechnologies. It consists of two parts: (1) structural features of PLs responsible for recognition of synthetic copolymers, and (2) design, synthesis and analysis of magnetic nanotubes obtained from PLs with a common theme of colloidal synthesis served as a platform for film formation and nano-assemblies of nanotubes. Poly(methyl methacrylate/n-butyl acrylate) (p-MMA/nBA) colloidal particles that were stabilized by 1,2-dilauroyl-sn-glycero-3-phosphocholine (DLPC) PLs were synthesized, and upon the particle coalescence, PL stratification resulted in the formation of surface localized ionic clusters (SLICs). These …

Synthesis Of Functional Copolymers Via Aqueous Raft Polymerization For Bioconjugation And Targeted Delivery Of Small Interfering Rna, Adam Wesley York

Dissertations

The versatility of reversible addition-fragmentation chain transfer (RAFT) polymerization has moved this controlled radical technique to the forefront of copolymer construction for bioapplications including polymeric drug/gene delivery vehicles. Strengths of the RAFT process include the capacity to control the polymerization of a wide variety of vinyl monomers under mild conditions, its tolerance to numerous chemical groups that allow the preparation of functional copolymers for facile modification, and the range of copolymer architectures with predetermined end group functionalities which may be synthesized. Given these strengths, RAFT polymerization was utilized in this research to synthesize functional/reactive copolymers for bioconjugation and targeted delivery …

Self-Assembly And Gold Nanoparticle Cross-Linking Of Stimuliresponsive Block Copolymers Synthesized Bt Reversible Addition-Fragmentation Chain Transfer Polymerization, Adam Eugene Smith

Dissertations

The ability of amphiphilic block copolymers to self-assemble into various morphologies in aqueous solution in response to specific stimuli has attracted widespread interest for potential applications as targeted drug delivery and diagnostic vehicles. Stimuli-responsive block copolymers afford a facile method for tuning the hydrophilic mass fraction to provide access to various solution morphologies. Reversible additionfragmentation chain transfer (RAFT) polymerization provides the ability to prepare stimuli-responsive block copolymers while maintaining precise control over the macromolecular characteristics (molecular weight, copolymer composition, functionality, etc.) that dictate nanostructure morphology.

This work may be divided into four sections. In the first section the synthesis and …

Polyisobutylene Chain End Transformations: Block Copolymer Synthesis And Click Chemistry Functionalizations, Andrew Jackson David Magenau

Dissertations

The primary objectives of this research were twofold: (1) development of synthetic procedures for combining quasiliving carbocationic polymerization (QLCCP) of isobutylene (IB) and reversible addition fragmentation chain transfer (RAFT) polymerization for block copolymer synthesis; (2) utilization of efficient, robust, and modular chemistries for facile functionalization of polyisobutylene (PIB). Two site transformation strategies were employed to create block copolymers effectively linking PIB with either poly(methylmethacrylate) (PMMA), polystyrene (PS), and poly(Nisopropylacrylamide) (PNIPAM) block segments. Functionalization of PIB was accomplished by utilizing two click chemistries, the azide-alkyne 1,3-dipolar cyclo addition and the thiol-ene hydrothiolation reaction, and by efficient transformation of the thiol functional …

Molecular Design And Patterning Of Biosurfaces On Poly(Tetrafluoroethylene) (Ptfe), Nattharika Aumsuwan

Dissertations

This dissertation describes the design, synthesis, and development of biocompatible poly(tetrafluoroethylene) (PTFE) surfaces that exhibit anti-microbial, anticoagulant, and dual functional surface properties. It consists of two parts: (1) design, synthesis, and analysis of antimicrobial and anti-coagulant PTFE surfaces, and (2) controllable micropatterning of anti-microbial and anti-coagulant species on the surface. PTFE was modified by Ar microwave plasma reactions in the presence of maleic anhydride, which upon hydrolysis creating COOH groups. These COOH primers were utilized as a platform for further surface reactions to attach polyethylene glycol (PEG) spacers, and penicillin (PEN) or ampicillin (AM) onto the PTFE surfaces. The use …

Aqueous Raft Synthesis Of Stimuli-Responsive, Amphiphilic Block Copolymers And Self-Assembly Behavior In Solution And Incorporation Into Lbl Films, Matthew Grady Kellum

Dissertations

Of all the living radical polymerization techniques, reversible addition– fragmentation chain transfer (RAFT) polymerization is arguably the most versatile in terms of the reaction conditions (e.g. temperature and solvent selection), monomer selection (e.g. neutral, anionic, cationic, and zwitterionic), and purification. Since the introduction of RAFT in 1998, the McCormick research group and others including the Lowe, Sumerlin, and Davis research groups have synthesized a wide range of (co)polymers with predetermined molecular weights, low polydispersities, and advanced architectures utilizing aqueous RAFT (ARAFT) polymerization. These research groups have also studied how various block copolymers exhibit stimuli-responsive behavior due to a change in …

Multi Stimuli-Responsive Copolymers Obtained From Colloidal Dispersions, Fang Liu

Dissertations

This dissertation describes the design, synthesis, and development of multi stimuli-responsive random copolymers that exhibit collective responsiveness to temperature, pH or electromagnetic radiation. New colloidal particles of poly(N-(DL)-(1- Hydroxyymethyl) propylmethacrylamide/n-butyl acrylate) (p(DL-HMPMA/nBA) and poly(2-(N,N′-dimethylamino)ethyl methacrylate/n-butyl acrylate) (p(DMAEMA/nBA)) were synthesized, which upon coalesce to form solid continuous films. The presence of lower glass transition (Tg) nBA components not only facilitate film formation, but also provide sufficient free volume for polymer chain rearrangements. These studies showed that coalesced films exhibit 3D dimensional changes upon external stimuli, which are attributed to the collapse and conformational changes of stimuli-responsive components as well as buckling …

Synthesis, Characterization, And Deuterium Labeling Of Polyamides Studied By Nuclear Magnetic Resonance Spectroscopy, Christopher Allen Lange

Dissertations

The synthesis, characterization, and deuterium labeling of polyamides have been investigated. In Chapter II, selective deuterium labeling of various polyamides was demonstrated via a facile method which does not require organic solvent or catalyst. Quantitative solution-state NMR analysis showed deuterium incorporation at the carbon alpha to the carbonyl ranged from 20-75%. Incorporation in ε-caprolactam increased with repeated treatments. Isotopic shift effects for the deuterated materials were additive for all sites within experimental error.

In Chapter III, the effect of stoichiometric imbalances on the polymerization of poly(dodecamethylene terephthalamide)was investigated. Molecular weight was varied by polymerizing the monomer salt with excess diaminododecane, …

Structure-Property Relationships In The Formation Of Polyphenylsulfone Molecular Composites And Nanocomposites, Paul Joseph Jones

Dissertations

As the constituent phases in a polymer composite approach the molecular level, specific phenomena occur that can lead to significant changes in material properties when only minimal quantities of the additive are incorporated into the polymer matrix. Molecular composite and nanocomposites are state-of-the-art polymeric materials that contain nanostructured additives effectively dispersed within polymer matrices. The properties of molecular composites and nanocomposites are directly related to the interactions of the nanostructured additive and the polymer matrix. Subtle changes to the nanostructured additive can have profound effects on the ultimate properties of the composite material. Therefore, understanding the structure-property relationships in these …

Self-Assembly Of Architecturally Complex Block Copolymers, Juan Hinestrosa

All Dissertations

The term self-assembly denotes the formation of complex structures from simpler building blocks, resembling the manner in which Nature generates functional systems. In this pursuit, block copolymers present a great opportunity to study the interactions, dynamics and self-assembly of soft matter. Block copolymers have the ability to self-assemble into thermodynamically stable microphase segregated domains of precise shape and size, which are controlled by the chemistry of the constituent blocks, their size and connectivity, temperature and solvent conditions. Specifically, in this body of work two different types of branched copolymers with polystyrene (PS) and polyisoprene (PI) constituents are studied. The complex …

Determination Of Polymer Molecular Weight Distributions: Dosy, Maldi, Gpc, Nathan A. Meredith

Honors Capstone Projects and Theses

No abstract provided.

Synthesis Of Chemically Produced Toner (Cpt) By Emulsion Aggregation Process., Ng Wei Goon

Student Works (2010-2019)

This project studied the full process of producing Chemically Produced Toner (CPT) used in laser printer. Latex particles of 0.40 to 0.60 μm were prepared by semicontinuous emulsion polymerization process. A series of latexes was made from the copolymerization of styrene, butyl acrylate and acrylic acid monomers in the presence of surfactants Dowfax 2A1 (anionic) and Ipegal 897 (non-ionic) surfactants with potassium persulphate as the initiator. The addition of different percentage of chain transfer agent (CTA), 1-dodecanethiol was used to control the molecular weight distribution. As the percentage of CTA was increased, the molecular weight and glass transition temperature decreased …

Preparation Of Styrene Acrylic Copolymer Toner Resin By Solution Polymerization., Neo Su Siang

Student Works (2010-2019)

This project has investigated solution polymerization to produce toner resins. There are three stages: (i) synthesis of low molecular weight styrene acrylic copolymer; (ii) synthesis of high molecular weight styrene acrylic copolymer; (iii) mixing high and low molecular weight copolymers. Gel Permeation Chromatography (GPC) was used to study molecular weight distributions, Melt Flow Index (MFI) Instrument to study the flowability of resin, Differential Scanning Calorimetry (DSC) to study the thermal properties of resin, and acid number to quantitate the amount of acidic group in the resin. A comparison of properties between the experimental samples, patent’s claims, and commercial resins had …

Changes To Electrical Conductivity In Irradiated Carbon-Nickel Nanocomposites, David F. Coy

Theses and Dissertations

Pre and post irradiation resistivity and XAFS measurements have been conducted to examine the effects of 0.5 MeV electron irradiations on nickel-carbon composites. Results showed a decrease in surface resistivity in all sample types of 14-30% following irradiation with a total electron exposure of 4 x 10^-16 cm^-2. Results also showed a corresponding decrease in NiO content for the irradiated samples as compared to measurements of non-irradiated samples. Surface resistivity measurement capabilities were established and measurement techniques refined to produce repeatable results of sufficient precision to discern changes in resistivity for an exposure of 2 x 10 …