Physical Sciences and Mathematics Commons^™

The Thermal Conductivity Of Potassium Chloride At Elevated Temperatures, Wendell D. Miller

Masters Theses

"The transport of heat in solids is attributed to the combined effect of the quantized vibrations of lattice points, or phonons, and the flow of valence electrons. In dielectric solids, the thermal conductivity is due almost entirely to phonons, while in metals the latter method preponderates. Scattering processes in dielectric solids, giving rise to thermal resistance, also serve to limit the thermal conductivity. Scattering results from vacancies, dislocations, interstitial atoms and phonon interaction. Crystal boundaries also function as scattering points and in crystals of small dimensions, this process is the most pronounced conductivity-limiting factor. At low temperatures the thermal resistance …

Direct Correlation Functions For Liquid Argon, Arthur Reetz Jr.

Masters Theses

"The purpose of this research is to obtain the direct interaction functions from the liquid argon x-ray scattering structure factors of Eisenstein at various temperatures and over a wide range of interatomic separations"--Introduction, page 1.

The Effect Of Ph On Phase Reversals Of Protein-Stabilized Emulsions, Samuel Arthur Bradford

Masters Theses

"The phase reversal of an emulsion from a system in which oil droplets are dispersed in a water medium to a system in which water droplets are dispersed in oil is dependent upon the interfacial characteristics of the liquids and the emulsifying agent being used, as well as the volume ratio of the two liquid phases. A preliminary investigation at this institution has indicated a possible relationship between phase reversal and the isoelectric point of gelatin used as the emulsifying agent. Since the properties of proteins vary so greatly with the hydrogen ion concentration, particularly near their isoelectric points, research …

Geothermometry At The Balmat No. 2 Mine, New York By The Fes-Zns System, Bruce R. Doe

Masters Theses

"Definition Of The Study. The study consists of an investigation of the variation in the temperature of formation of sphalerite on the 500 and 1500 ft levels of the Balmat zinc deposit at Balmat, New York. A subsidiary investigation was performed on the use of x-ray fluorescence as a means of chemical quantitative analysis. Twelve samples of sphalerite from the 500 ft level and 13 samples from the 1500 ft level were analyzed for atomic percent iron content by measuring Zn/Fe x-ray fluorescent ratios. The x-ray fluorescent ratios were standardized by ''wet" quantitative analysis. The results of the analyses are …

The Effect Of Metallic Naphthenates On The Oxidation Of Linoleic Acid, David Elliott Troutner

Masters Theses

"It has been known for many years that certain metallic soaps catalyse the drying of oils. A great deal of information is available concerning the use of these soaps, but there is little knowledge of the actual manner in which the soaps catalyse drying. As the drying is known to be an autoxidation reaction, it is generally believed that the soaps must affect the oxidation of the oil in some way. The work described in this thesis was undertaken to gain some knowledge of the mechanism of the catalysis, and to correlate the effect of the soaps on the drying …

Pre-Cambrian Geology Of Washington County Area, Missouri, Gordon Blair French

Masters Theses

"The Problem.

Washington County, Missouri contains a limited number of outcrops of pre-Cambrian igneous rocks, the majority of which are in the extreme southern part of the county. The known association of lead ore with buried or partially buried pre-Cambrian igneous knobs and ridges in this part of Missouri has led the St. Joseph Lead Company to prospect in areas known to contain these features. In its exploration program, the St. Joseph Lead Company has drilled a number of prospect holes which have encountered other occurrences of pre-Cambrian igneous rocks within the limits of Washington County. This drilling, correlated with …

Mathematicians And Royalty: A Historical Survey, Loren W. Pixley

Masters Theses

No abstract provided.

Correlation Functions For Use In Small Angle X-Ray Scattering, James Edwin Thomas Jr.

Masters Theses

"Thus, the determination of the structure of the material, and obtaining a distribution function which will enable the theoretical scattering to be predicted is the major problem.

In this work the diffraction material shall be considered to contain scattering regions of identical geometrical forms at such a distance from one another that they will essentially scatter the incident beam independently of their closest neighbor. An effort will be made to determine a correlation function characteristic of these forms, which may be interpreted as a distribution function, that might allow the low angle scattering pattern to be predicted. This correlation function …

Morphology And Systematic Position Of Some Anomalinid Foraminifera, Billy G. Deaver

Masters Theses

"Morphological studies of the following species are the basis for a partial revision of the Family Anomalinadae: Anomalina acuta Plummer, A. midwayensis (Plummer), A. pseudopapillosa Carsey, A. vulgaris (Plummer), Anomalinoides pinguis (Jennings), Cibicides alleni (Plummer), C. beaumontianus (d’Orbigny), c. harperi (Sandidge), Cibicidina danvillensis (Howe and Wallace), Planulina correcta (Carsey), and P. dumblei (Applin); a description of Stensioina americana Cushman and Dorsey, discorbid foraminifer, is included for comparison. The classificatory position and incomplete content of the family are: Superfamily Discorbidea; Family Anomalinidae; Subfamily Anomalininae (revised) -- with ventral supplementary apertures: Anomalina , Planulina ; Subfamily Cibicidinae -- with dorsal supplementary apertures: …

Separation Of Germanium, Lead, Zinc, And Cadmium By Anion Exchange, Franklin Maynard Hill

Masters Theses

"The object of this study was to investigate the ion exchange behavior of germanium and apply the anion exchange technique for the separation of germanium, cadmium, lead, and zinc.

A new interest in germanium has developed because of its recent industrial application as a semi-conductor. Analytical methods for the separation and analysis of germanium in low concentrations have not been perfected. Krause and Johnson, in a recent review, discussed and evaluated a number of methods.

Most of the methods for the analysis of germanium require a preliminary separation. The analytical methods for germanium reported in the literature are troublesome and …

Addition Of Ketene To Ethylene Oxide, John Philip Friedrich

Masters Theses

"The object of this work was to study the reaction between ethylene oxide and ketene, and if possible, to isolate and identify the postulated γ-butyrolactone. Although the results could hardly be described as completely gratifying, they were at least in a sense positive. Many possibilities remain with regard to further modifications of the experimental work on this problem, however it is the author's sincere wish that this investigation will serve some useful purpose in the future"--Introduction, page 4.

The Thermal Conductivity Of Sodium Chloride At Elevated Temperatures, Howard Martin Brown

Masters Theses

"The thermal conductivity of solids has been attributed to a combined effect of the quantized vibration of the lattice points, called phonons, and the flow of valence electrons. In nonconductors the thermal conductivity is due almost entirely to phonons, as was shown by Debye, whereas in metals the conductivity is due mostly to the flow of valence electrons. After Debye, Peierls calculated the lattice conductivity at elevated temperatures using quantum mechanics and demonstrated that it is proportional to 1/T. There are not enough data available to substantiate any theory but what data there are seem to indicate a mixed conductivity …

The Velocity Of Ultrasonics In Liquids, Mack A. Breazeale

Masters Theses

"In acoustics the term ultrasonics is used to refer to those frequencies which are above the range of human hearing; that is, frequencies above approximately 20,000 cycles per second. Since the laws of sound which are valid for the audible range are also valid in the ultrasonic range and since the wave length of ultrasonics is much shorter than that of audible sound, ultrasonic has proved very valuable in the calculation of both the velocity and the absorption coefficient of sound in various media. This is especially notable in the case of liquids, where the velocity of sound is much …

Geology Of The South Half Of The Meramec Spring Quadrangle, Missouri, Howard Joseph Yorston

Masters Theses

"This report is a continuation of the work initiated by Mueller in his mapping of the north half of the Meramec Spring Quadrangle. The completion of this work provides not only a geologic map of the whole quadrangle but also completes the mapping of the geology of a strip of quadrangles extending from Rolla to the Mississippi River. In addition to being a step closer to the goal of complete geologic coverage for the state, this work will be of value to those concerned with the prediction of depths of wells drilled in search for water, which in view of …

A Study Of The Emission And Absorption Spectra Of Nacl And Kcl Between 100 A And 1000 A, Paul Henry Blackmon

Masters Theses

"This investigation was begun with the idea of obtaining the emission and absorption spectra of NaCl and KCl in the region between 100 A and 1000 A. From these data, it is hoped that useful information concerning the energy levels of these two substances may be obtained.

The vacuum ultraviolet region is rather difficult to investigate because of the necessity of removing all air, lenses and other absorbing material from the light path. Many writers have enumerated the problems involved and some have indicated that much work still needs to be done in the vacuum ultraviolet.

In order to do …

Foraminifera Of The Type Section Of The Archusa Marl Of Mississippi (Eocene, Claiborne Group, Wautubbee Formation), Nathan Eugene Crockett

Masters Theses

"The type locality of the Archusa marl member of the Wautubbee formation is situated south of Quitman, Clarke County, Mississippi. Stratigraphically, the unit falls within the middle Eocene Claiborne group, being roughly equivalent to the upper part of the Lisbon formation of Alabama and the lower part of the Cook Mountain. The marl falls within the Ostrea sellaefonnis zone and the zone of "Ceratobulimina eximia.” The type section consists of 48 feet of sandy marls, with a thin oyster bed near the middle.

The Archusa foraminifera fauna consists of 87 species and varieties, belonging to 49 genera and …

The Mineralogy Of The Grassy Creek And Saverton Formations, Dirk Pieter Van Duym

Masters Theses

"A study of the mineralogy of the Grassy Creek and Saverton formations of Northeast Missouri was undertaken to determine whether a division is justified, as proposed by some stratigraphers, of these argillaceous beds into two formations. The formations were sampled systematically at surface exposures on the northeast limb of the Lincoln Arch in the vicinity of Hannibal and Louisiana, Missouri. The samples were investigated mineralogically in the laboratory. Previous studies showed that the fossils of the Grassy Creek and Saverton beds were virtually identical. The present study demonstrates that the Grassy Creek and Saverton beds are too near alike in …

Coloration Of Glass By High Energy Radiation, Thomas L. Nickens

Masters Theses

"Purpose of Investigation: One of the objects of this investigation is to determine the amount of CeO₂ required to prevent the discoloration of glass when exposed to gamma radiation. By discoloration, it is meant that there has been a change in the absorption bands of visible light. Another objective is an attempt to prevent the coloration by the introduction of two oxides not previously used. Finally, a theory is presented which could explain why glass containing CeO₂ does not change color upon irradiation by gamma rays"--Introduction, page 1.

Determination Of The Thermal Conductivity Of Sodium Chloride At Elevated Temperatures, Harold Robert Weisbrod

Masters Theses

"The purpose of this research is to investigate possible methods of determining the thermal conductivity of small poorly conducting samples at elevated temperatures, and, further, to assemble a suitable apparatus, followed by measurement of thermal conductivity of one or more cubic lattice samples.

Basic requirements of the apparatus are few. It is first required that the measurement of thermal conductivity be made over a considerable range temperature. It is also preferred that the basic apparatus be placed in a vacuum where undesirable heat flow by convection is eliminated and air corrodible samples are preserved.

The apparatus must use only the …

A Model For X-Ray Scattering From A Free-Volume Liquid, Charles A. Hewett

Masters Theses

"Investigation of the diffraction of x-rays by liquids was begun soon after the well-known work of Friedrich, Knipping, and Laue proved to be of value in supplying information as to the arrangement of atoms in crystalline matter. Friedrich in 1913 reported x-ray diffraction patterns of Canadian Balsam, paraffin, and amber; three years later Debye and Scherrer, in their work on benzene, (among other liquids investigated) showed that the diffraction phenomenon exhibited was one of interference. Still later, in 1922, Keesom and de Smedt reported similar investigations carried out on argon, nitrogen, and oxygen in the liquid state, the results of …

The Chemistry Of Digestion, Lester B. Burrus

Masters Theses

No abstract provided.

A Study Of Immiscibility In The Carbonates From The Metamorphic Rocks Of Southeastern Vermont, Ralph D. Cotter

Masters Theses

"This problem is an attempt to correlate grade of metamorphism (normally assumed to be temperature dependent) with the shape and dimensions of a solid miscibility gap. Such a correlation might permit mapping of a continuously variable function of metamorphism. The system, calcite and dolomite-ankerite, was chosen for study because of its relative simplicity. Samples of quartz-carbonate granulite were collected from the Waits River formation in southeastern Vermont through a range of metamorphic grades. Refractive index, "molecular" volume, manganese content, and density were determined for the carbonates of four of these samples. These values are plotted on a compositional diagram to …

A Petrographic And Chemical Study Of The Bevier Coal Seam, Philip John Clarke

Masters Theses

"Samples of coal were taken at three inch intervals vertically down the Bevier seam at three localities in Macon and Randolph Counties. Channel samples were collected at the three localities. All samples were analyzed for ash content, total sulphur content, crucible swelling number, and volatile content. The channel samples were analyzed for "pyritic" sulphur, “sulphate" sulphur, and "organic" sulphur. Thin sections of the samples were used in an estimation of anthraxylon and attritus contents.

In all the samples studied, volatile content of the coal seemed to be related to the ash content and the sulphur content. Crucible swelling number also …

A Linear Polymer X-Ray Scattering Model, Bernard Cohen

Masters Theses

"In the development of X-ray scattering intensity curves physical models are necessary for the theoretical mathematical development involved. The purpose of this paper is the development of a physical model suitable for X-ray diffraction analysis or a linear polymer.

X-ray intensity patterns may be used to give a greater insight as to the atomic structure, configuration or atoms, molecular weight, and therefore a greater knowledge of the structure of matter, both microscopic and macroscopic. The converse may sometimes be used. An atom or molecular model is constructed, from this model X-ray scattering curves may be derived. These curves may be …

The Fluorescence Of Uranium In Solid Solution, Robert Emmett Kelly

Masters Theses

"The fluorescence of uranium finds its greatest application in the so-called "bead test" which is a method of qualitative analysis. In the form of a bead, the uranium is in solid solution, and if the proper chemical solvent is used, the bead will fluoresce under ultraviolet radiation.

In the systematic separation of the metallic elements, uranium is associated with the aluminum group in that it is not precipitated by hydrogen sulfide in 0.3 N H ion but is precipitated by ammonium hydroxide and ammonium sulfide. In the analytical scheme, uranium acts like beryllium. This process of detection is sometimes tedious …

Halogenated Epoxide-Phenol Reactions A Mechanism Study, Richard L. Rowton

Masters Theses

"The object of this investigation was to study the reactions of two other halogenated epoxides--namely, 3-bromo-1,2-epoxybutane and l-bromo-2,3-epoxybutane--with the phenolate ion, with the hope that the results obtained would shed additional light upon the mechanisms of such reactions. At the present time, no direct practical applications of the results can be forseen. However, the information gained will be a worthwhile addition to the vast existing store of knowledge already at our disposal, and might be of some help to future investigators"--Introduction, page 2.

A Study Of The Effect Of Jointing On The Blasting Of Granite, Graniteville, Missouri, Avery Ala Drake

Masters Theses

"Purpose of investigation: The purpose of this investigation is to attempt to determine the influence that joints exert upon the blasting of granite and if joints are induced by blasting. The problem grew out of an explosive evaluation project that was conducted by the Mining Department, Missouri School of Mines. In late May 1950, the project was moved into the granite area near Graniteville, Missouri. It became apparent upon study of this area that the jointing would have certain effects upon the results obtained. Dr. J. D. Forrester, Chairman, Department of Mining Engineering, Missouri School of Mines, Rolla, Missouri, suggested …

The Partition Function Of Silver, Ralph H. Lilienkamp

Masters Theses

"The study of the thermodynamic properties of solids at low temperatures has shown that most theories either break down or become too cumbersome.

A theory based upon a crystal lattice of atoms gives the best physical picture of a solid. Fisher has developed partition functions from this theory for the simple cubic, body-centered cubic, and the face-centered cubic lattices. In his paper Fisher gave three partition functions of increasing complexity and accuracy for each of the three lattices. In this paper the three partition functions for a face-centered cubic lattice shall be applied to silver and compared.

The Helmholtz free …

4-Benzoyl-4-Methyl-1, 2-Epoxypentane, An Attempted Synthesis, Robert L. Snell

Masters Theses

"The object of this research was to prepare first the simplest homologue of the epoxy-ketone considered by Russell to have been his product. If this homologue, 4-benzoyl-4-methyl-1,2-epoxypentane, could be prepared and caused to form a cyclic derivative of the type given by 1,4-diketones with 2,4-dinitrophenylhydrazone, the organic chemist would be given a new approach to substituted 1,2-diazines as well as a previously unreported reaction of the epoxide grouping. If this reaction could be made to occur, other epoxides of this series would be prepared and treated in the same manner.

It was decided that the shortest route to 4-benzoyl-4-methyl-1,2-epoxypentane would …

A Critical Analysis Of Several Product And Factoring Formulas, Herbert Wills

Masters Theses

No abstract provided.