Physical Sciences and Mathematics Commons^™

Heterocyclic Syntheses Utilizing Aryl Cyanates, Joseph Eugene Drumm

Masters Theses

No abstract provided.

Geology Of A Section Of The Northwest Tobacco Root Mountains, Madison County, Southwest Montana, Kiff James Samuelson

Masters Theses

The northwest Tobacco Root Mountains are located on the boundary between two major tectonic provinces: the fold and thrust belt and the Rocky Mountain foreland. Deformation typical of the Rocky Mountain foreland is present in the form of two major northwest trending faults with associated folds. Paleozoic rocks were passively draped over at least one of the elevated Precambrian blocks. Foliation of the Precambrian rocks also appears to have been gently folded in the process.

Folds and thrusts occur within the Precambrian and Paleozoic rocks, on the westernmost flank of the range, appearing to follow the general trend of the …

Hydrogeologic And Geochemical Factors Influencing The Impact Of A Chromium-Arsenic-Copper Wastewater Discharge On A Glacial Outwash Aquifer, Michael J. Gallagher

Masters Theses

A discharge of chromium-arsenic-copper laden wastewater occurred periodically from 1970 to 1980 at a wood preserving company located in southwestern Kalamazoo County, Michigan. As a result of this discharge, soils at the company site became contaminated with chromium, arsenic, and copper, and a local glacial outwash aquifer became contaminated with hexavalent chromium.

Soil samples collected from the discharge site were analyzed for clay-silt-sand-gravel content, organic matter, pH, clay mineralogy, and chromium, arsenic, copper, iron, and manganese content. Background soil samples were analyzed for most of the above catagories. Pearson r coefficients of correlation were calculated to determine the correlation of …

Uranium-Lead Zircon Ages And Crustal Contamination Of The Northeastern Idaho Batholith, James J. Dexter

Masters Theses

The magmas which formed the northeastern Idaho batholith were contaminated with, or derived from, old crustal material as evidenced, from previous studies, by high whole-rock ⁸⁷Sr/⁸⁶Sr ratios, relatively high ²⁰⁷Pb/²⁰⁶Pb ages, and Archean to Proterozoic upper intercept ages for batholithic zircons.

The old zircon component has been identified in this study by separating zircons into fractions based on size and morphology. Pb/U isotopic ratios are distributed on a chord with a lower concordia intercept intrusive age of 73.6+6 m.y. Zircons from a batholithic sample located one kilometer inward from the contact were separated according …

The Depositional History Of The Point Pleasant Member Of The Cynthiana Formation In Northern Kentucky, Gary J. Stefaniak

Masters Theses

Bioclastic limestones, siltstones, and shales of the Point Pleasant Member were deposited in a shallow marine environment immediately below normal effective wave base. High-energy conditions produced by storms lowered the effective wave base and stirred the bottom sediments and redistributed them into bedforms. The different types of contacts, distribution of the faunal groups, and fabrics permit inferences regarding energy levels and assignment of samples to a mode of deposition. Vertical and lateral trends were then deduced. High-energy conditions are believed to have occurred during Early and Late Point Pleasant time, whereas, low-energy conditions prevailed during deposition of the middle Point …

The Application Of Multiderivative Infrared Spectroscopy To Iodine Number Determination, Jeffrey C. Lowry

Masters Theses

The Food and Drug Administration requires the disclosure of total unsaturation of commercial products as an indication of nutritional value. This unsaturation is a guide to the expected stability of food additives, such as edible oils and foods in which they are used. Unsaturation is typically evaluated as an iodine number, calculated for these additives based on their consumption of iodine through addition across the carbon-carbon double bonds. This titration method can typically take 45 minutes.

The investigation presented develops an alternative method for determining iodine numbers of some common oils using a computerized infrared spectophotometer. The analysis time, as …

Petrology Of The Farmington Gabbro-Metagabbro Complex, North Carolina, James Thomas Harden

Masters Theses

The Farmington gabbro-metagabbro complex is located along the western margin of the Charlotte belt of North Carolina. At least twp or more intrusions occur within the complex. The Farmington gabbroic intrusion is postmetamorphic and contains plagioclase, hornblende, orthopyroxene, clinopyroxene, and olivine. Small amounts of magnetite, ilmenite, pyrite, pyrrhotite, pentlandite, hematite, hercynitic spinel, and biotite occur. Textures are hypidiomorphic granular to hypidiomorphic inequigranular. Four types of gabbroic rocks are present; hornblende gabbronite, olivine-hornblende gabbronorite, hornblende norite, and olivine-hornblende norite, with olivine-hornblende gabbronorite predominating. A limited range of progressive differentiation is indicated by restricted increases in FeO/(FeO +MgO) ratios for mafic silicates …

Resolution Algorithms In A Parallel Processing Environment, Paula Beth Brandman Hencken

Masters Theses

An ever increasing number of processors are becoming available to the multiprocessor user. For faster response and efficient utilization of parallel processing systems it is necessary to develop parallel algorithms to solve a single problem.

This paper evaluates the complexity of resolution algorithms run in a parallel processing environment. An overview of parallel processing is presented along with a discussion of general resolution and resolution-refutation systems. An analysis of the complexity required by different control strategies to perform resolution programing is presented using both uniprocessor and multiprocessor systems.

Kinetics Of The Formation Of The Nickel(Ii) Complex With N, N' -Dimethylethylenediaminediacetic Acid And The Metal Exchange Reaction Between N,N'-Dimethylethylenediaminediacetatonickel(Ii) And Copper(Ii), Roger A. Karel

Masters Theses

The kinetics of the reaction of aquonickel (II) ion with N'N'-dimethlethylenediaminediacetic acid has been studied at 25°C and 0.1M iconic strength over a pH range of 6.0 to 9.3 using stopped-flow techniques. Formation reactions in all cases were first-order in Ni (II) and in ligand. The formation rate constant for the protonated and unprotonated species were evaluated and compared to their theoretical value. The rate-determining step is shown to be ring closure. A comparison of this system with other studies involving complexation of nickel (II) confirm the magnitude of the internal conjugate base effect and also shows a correlation between …

The Kinetics Of The Metal Exchange Reaction Between N-(2-Hydroxyethyl) Iminodiacetatonickelate (Il) And Copper(Ii), Craig R. Weed

Masters Theses

The reaction between copper(II) and N -(2-hydroxyethyl)iminodiacetatonickelate( II) (NiHEIDA) was studied between pH 4.0 and 5.6 over a 70 fold variation in copper concentration at an ionic strength of 1.25 and a temperature of 25° C. The reaction order in both NiHEIDA and Cu(U) is first. The reaction rate is pH sensitive and a hydrogen dependent pathway as w ell as copper dependent and copper and hydrogen independent pathways were found.

Evidence is given for a stepwise mechanism for the unwrapping of HEIDA from its nickel complex, follow ed by copper attack to give a dinuclear intermediate, which then breaks …

A Study Of Integral Equations For Computing Radial Distribution Functions, Robert C. Scherzer

Masters Theses

The use of integral equations to find radial distribution functions for computing thermodynamic properties is examined. The system considered is a simple classical fluid with interactions according to the Lennard-Jones (6-12) pair potential function. Two parametric integral equations (C and T) are studied in detail. Derivation of equation T and a power series solution are given. Computer solutions at several different temperatures, densities, and parameter values are obtained. Comparisons are made betv/een these results and results from integral equation N, PY, and HNC, and results from Monte Carlo, molecular dynamics, and power series methods. Equations C and N are found …

Late Quaternary Vegetational History At Cupola Pond, Ozark National Scenic Riverways, Southeastern Missouri, Everett Newman Smith Jr.

Masters Theses

A 12 meter core of lacustrine sediments from Cupola Pond, Ripley County, Missouri, Provides the first continuous record in the Ozark Plateaus Region of ecologic changes from full-glacial time to the present. From 17,100 to 15,350 yr B.P., forest communities were dominated by jack and/or red pine (northern Diploxylon Pinus) and spruce (Picea). A late-glacial, transitional forest of oak (Quercus), ash (Fraxinus), pine and spruce characterized the upland vegetation that occurred during a period of climatic amelioration between 15,350 and 12,300 yr B.P. The early Holocene period from 12,300 to 9,100 yr B.P. …

I. A Temperature Dependent Nmr Study Of 6,6-Dicarbethoxy-5,5-Dideuteodi-Benzo--[A,C]-[L, 3]-Cycloheptadiene Ii. The Synthesis Of Four Deuterated Analogs Of 6, 6-Dicarbethoxydibenzo-[A,C]-[1,3]-Cycloheptadiene, Patrick F. Jonas

Masters Theses

The kinetics of conformational interchange of 6,6-dicarbethoxydi-benzo- a,c - 1,3 -cyloheptadiene and its 5,5-dideuterated analog were studied using variable temperature NMR techniques. The free energy of activation for conformational interchange of the parent compound was found to be 9.02 kcal mol^-1 and that of the 5,5-dideuterated analog to be 9.42 kcal mol^-1. Values of the entropy of activation were found to be -19.91 e. u. and -18.12 e. u. respectively. The spectra were recorded on a Nicolet NMC-360 wide bore spectrometer and the data collected treated as an AB spin system.

The 4,8-dideutero, 4,5,5,8-tetradeutero and 5,5,7,7-tetradeutero analogs …

Land Use Effects On Shallow Earth Resistivity, Gary James Barton

Masters Theses

No abstract provided.

An Improvement In The Performance Of A Learning System For Finite State Machines, Lea F. Fuller

Masters Theses

A learning system is examined which is capable of learning a finite state machine from a class of finite state machines based on the observed behavior of the machine. The size of the search space becomes very large as the number of states in the machine increases. The size of the search space quickly becomes the limiting factor in the size of the class of machines which may be learned. An investigation is made of methods to improve the performance of the learning system. The application of a depth first approach to the development of the search space is shown …

A Quantitative Study Of The Copper Content In Granite Rocks, Samir F. Al-Mandwee

Masters Theses

A spectrographic analysis was conducted on ten granite samples of different geological origin from the Pioneer Mountains in Central Idaho. A qualitative analysis was performed first and then a quantitative analysis to determine the presence and relative amounts of copper in the various samples. This spectrographic analysis employed a direct current arc source of 340 volts and 4 amperes to excite the samples which were dissolved in acid and dried on the ends of high purity carbon electrodes. The emitted light passed through a step sector and a medium quartz spectrograph to a photographic plate. The optical density of the …

Learning Computer Logic Architectures On Apple Ii System, Falah Reda Al-Saffar

Masters Theses

For this thesis seven computer-assisted instruction packages have been designed to illustrate the design of electronic circuits of gates , the logic of combinational and sequential circuits, and integrated and magnetic core memories.

The programs in these packages have been written in the Pascal computer language on an Apple II microcomputer and stored on a double-sided floppy disk.

A Computer Aided Instructional System And Its Application Towards A Course On Snobol4 Programming Language, Abtin Edelji

Masters Theses

Computers are rapidly replacing humans in many tasks. Computer Aided Instructional System is an application of the computer in the teaching of a subject. Currently, a large number of educational Institutes use Computer Aided Instructional Systems.

The objectives of this thesis is to review some techniques in implementing such systems and to present a Computer Aided Instructional System called TEACH. The emphasis of this thesis is on the type of the directory used to minimize the search time for the TEACH System.

The Synthesis And Characterization Of Some Transition Metal Complexes Prom Mixtures Of Poly Pyrazolyl Borates, Robert Matthew Alway

Masters Theses

This is a report of the synthesis and separation of transition metal complexes of hydrotris(1-pyrazolyl)- borate and hydrotris(3,5-dimethyl-l-pyrazolyl)borate. These complexes contain a central metal ion and two tridentate ligands, one hydrotris(1-pyrazolyl)borate and one hydrotris(3,5-dimethyl-l-pyrazolyl)borate. Mass spectrometry proved to be an extremely useful technique for identifying products. Many mass spectra are included and discussed extensively.

Complexes containing hydrobis(pyrazole)(3,5-dimethyl -1-pyrazolyl)borate and hydrobis(3,5-dimethyl-l-pyrazole) (pyrazolyl)borate also were synthesised and mass spectra obtained.

A Geophysical Investigation Of A Possible Astrobleme In Southwestern Michigan, Suhas L. Ghatge

Masters Theses

A circular pattern to the oil production in Calvin Township, Cass County, Michigan, absence of about 1200 feet of Ordovician sediments and uplift indicated by a deep drill hole in the center of the productive area and absence of anomalies on the regional gravity and magnetic maps led to detailed gravity and magnetic surveys over this structure to delineate it and provide information regarding its genesis.

The Bouguer gravity and magnetic anomaly maps show no anomaly associated with the structure. The 28-mile wavelength second harmonic residual gravity and magnetic maps show linear features in the area. Two dimensional gravity modeling …

A Query-Processing Optimization Strategy For Generalized File Structures, Donna Marie Kaminski

Masters Theses

In processing a Boolean query against a non-inverted file, a subset of the query's keys must be selected. Only the records satisfying these keys need to be retrieved from the file. A dynamic programming algorithm, the Dual-to-minDF, is developed here for arriving at the optimum set of keys, i.e., the minimum number of external record retrievals. Previously suggested greedy methods yield feasible solutions which may or may not be optimal. This algorithm has exponential time complexity. However, it is useful for applications involving relatively short queries with duplication of keys within different conjuncts, and in cases where the files have …

Structural Geology Of The Northern Snowcrest Range, Beaverhead And Madison Counties, Montana, Mark Kenneth Sheedlo

Masters Theses

The Snowcrest Range was uplifted in Late Cretaceous and Early Tertiary time as a consequence of thrusting in Precambrian basement and Phanerozoic cover rocks.

The Snowcrest-Greenhorn thrust system is associated with largescale overturned, eastward verging folds. Mean orientation of the thrust system is N.40°E., 35°N.W.. The trend of the thrust system and associated transverse faults appear to be controlled by earlier structures. Mesoscopic and microscopic analyses indicate that metamorphic basement rocks accommodated congressional strain largely by brittle faulting and cataclastic shearing. Kinematic indicators suggest that local stresses were directed east-southeastward.

Northeast-trending Neogene faults along the western flank of the range …

Program Modeling And Control Synthesis For Robotic Manipulators, Ramiz Najib Ballou

Masters Theses

"The control and programming methodology of industrial robots is becoming increasingly important. The speed and accuracy of data generation, and the performance of the robot are considered the most important factors in robotics control.

This paper presents and discusses algorithms that solve for the inverse solution for a given point in space at a very high speed based on the top down abstract method. The algorithms are independent of any specific type of manipulator configuration or programming language. The algorithms were implemented or the IBM-PC using the FORTRAN language to control the Armdroid robot. The program generates 500 sets of …

The Optimal Trajectory Modelling Of Robot Manipulators, Mary Claire Miller

Masters Theses

"Greater robot capability can be achieved through the use of robot manipulator control systems. Crucial to the success of these control systems is the optimal trajectory modelling of the path traced by the end- effector. To create this optimal path the utilization of B-Spline curve functions will be investigated, and compared to Cubic Spline curve functions"--Abstract, page ii.

Ciegen: A System For Testing Knowledge Base Compilation Heuristics On A Microcomputer, Jayne D. Ward

Masters Theses

"The expert system has proven itself to be a valuable aid in diagnosing and treating problems in domains requiring expertise. The commercial world has been alerted to this fact and the thrust is to make the expert system portable and available on small computers.

The goal of this research has been to lay the groundwork for a domain independent expert system builder on a microcomputer. The result of this effort was CIEGEN, a system consisting of a rule compiler, inference engine, and rule generator developed on the IBM PC. It is domain independent, responsible for transforming a knowledge base of …

Oil Producing Upper Cherokee And Lower Marmaton (Pennsylvanian) Channel Sandstones Of Jackson And Cass Counties, Missouri, Stephen Thomas Carroll

Masters Theses

"Approximately 240 gamma ray-neutron logs were interpreted and correlated in an attempt to isolate separate channels collectively referred to as "Squirrel" sands in the upper Cherokee and lower Marmaton (Pennsylvanian) rocks of Jackson and Cass counties, Missouri. Isopach maps were prepared for two of the identifiable fluvial sandstones and a structure map was drawn on the laterally extensive Anna Shale.

The term "Squirrel" has been applied to as many as five different sandstone packages, and thus, has been the source of a great deal of confusion. In an attempt to sort out the confusion this thesis recognizes and defines three …

Survey Of Routing Algorithms For Computer Networks, Lu Yu

Masters Theses

"This thesis gives a general discussion of routing for computer networks, followed by an overview of a number of typical routing algorithms used or reported in the past few years. Attention is mainly focused on distributed adaptive routing algorithms for packet switching (or message switching) networks. Algorithms for major commercial networks (or network architectures) are reviewed as well, for the convenience of comparison"--Abstract, page ii.

The Design And Implementation Of The Programming Language Natural, Alan L. Sparks

Masters Theses

"This paper reports progress on the development of the programming language Natural, currently under design by Dr. Thomas J. Sager at the University of Missouri--Rolla. Natural is a very high-level language with a mathematical flavor, and includes several concepts relatively uncommon in programming language design.

The text also discusses an implementation on the IBM Personal Computer of Mini-Natural, a subset of Natural, and presents examples of programs written in Mini-Natural"--Abstract, page ii.

Relation Of Bitumen To Ore In The Magmont West Orebody, Southeast Missouri, Mark Alan Marikos

Masters Theses

"Bitumen in the form of oil blebs from the Magmont West orebody of the Viburnum Trend was examined and analysed in an attempt to relate hydrocarbon distribution and origin to ore genesis. Hydrogen, carbon, nitrogen, sulfur and oxygen percentages were determined by elemental analyses. Trace element composition was determined by emmission spectroscopy and the composition of the bitumen was calculated with respect to aromatic hydrocarbons, saturated hydrocarbons and NSO (nitrogen-sulfur-oxygen) components. The bitumen and kerogen from associated shale samples were evaluated by Rock-Eval pyrolysis and pyrolysis-gas chromatography.

The bitumen was calculated to be approximately 40 to 50 percent aromatic and …

A Study Of Oxygen Functional Groups In Illinois Coal Fractions, Kenneth R. Osborne

Masters Theses

Ferric chloride/acetic anhydride reacted with butyl phenyl ether in acetonitrile at 80° to give a 75.6% yield of p-butoxyacetophenone. Reactions with benzyl aryl ethers gave 30% cleavage. The reaction of benzyl phenyl ether gave 10.3% p-benzyloxyacetophenone as well as cleavage product. Reaction of a pyridine soluble, toluene insoluble fraction (preasphaltene) of an Illinois No. 6 coal with ferric chloride/acetic anhydride in acetonitrile gave a product 94% insoluble in pyridine. The insolubility was ascribed to condensation reactions.

Phenols were measured in coals, preasphaltenes and preasphaltene derivatives by acetylation with acetic anhydride in pyridine. Suggestions for improvement in the method were presented. …