Physical Sciences and Mathematics Commons^™

The Polarographic Determination Of Germanium, Herbert L. Bowkley

Masters Theses

"The purpose of this investigation was to study the polarographic behavior of germanium in various aqueous solutions. In addition to the simple polarographic behavior of germanium some attention was given to the applications or polarography for the development of an anlytical [sic] procedure for its quantitative determination in zinc ore concentrates and spelter fume materials"--Introduction, page 1.

Geology Of The North Half Of The Meramec Spring Quadrangle, Missouri, Harold Edward Mueller

Masters Theses

"The Ozark region is visited by many persons each year, and one of its popular tourist attractions is Meramec Spring. In recent years, with the advent of better roads and swifter means of transportation, visitors are coming to this beautiful spring in increasing numbers. For those who are geologists, this work will serve as a handy guide; for those who are laymen, this work may give a better understanding of the geologic events which have made this part of the Ozarks a place of scenic beauty. Mapping of the Meramec Spring Quadrangle will complete a program of geologic mapping of …

Integrated Scattering Of Microwaves By Small Metal Spheres, A. L. Merts

Masters Theses

"When electromagnetic radiation falls upon a material body of any kind, the associated electric field induces periodic oscillations of the electrons of the material synchronous with the incident radiation. The material serves as a secondary source and emits energy in the form of scattered radiation with a frequency equal to that of the incident electromagnetic wave. The polarization and intensity of the scattered radiation are determined by the size, shape, electric constants, and interactions among the scattering elements.

The scattering of electromagnetic waves is an old problem in physics. Such names as Rayleigh, Debye, and Mie have become associated with …

Mineral Composition In Relation To Particle Size For A Missouri Plastic Fire Clay, John Edward May

Masters Theses

"From the rather modest beginning of the refractory industry in Missouri prior to the Civil War, the industry has grown to challenge those of other states as the third largest producer of refractory clays and products in the United States. As Roberts (1950) points out, the development of the metallurgical and glass industries increased the demand for high grade refractory materials. A prominent factor in the development of the fire clays of Missouri was the discovery that flint clay could be mixed with the plastic or semi-plastic refractory clays to yield an excellent product. Perhaps the most important reason many …

Radiolaria From The Porters Creek Formation (Paleocene, Midway Group) Of Stoddard County, Missouri, Eldridge Sellers Middour

Masters Theses

"Fossil Radiolaria are described and figured from the Porters Creek formation (Paleocene) of Ardeola, Stoddard County Missouri. This is the first detailed treatment of fossil radiolarians from the Gulf Coast area. Thirty-one species are described and figured, all believed to be new, belonging to twenty-four genera. Fifteen families are represented, ten referable to the Legion Spumellaria, five to the Legion Nassellaria. Stratigraphic descriptions or the section at Ardeola is presented, and a discussion of laboratory techniques is included"--Abstract, page 3.

An Application Of The Atomic Distribution Function Of Liquid Mercury, Robert Lee Choate

Masters Theses

"The study of liquids and the knowledge of an adequate description of liquid structure have not advanced as rapidly as it has in the case of solids and gases. In a perfect crystal, the atoms or molecules are held in equilibrium positions by strong intermolecular forces. There are vibrations about these positions, but the translational energy is negligible. The molecules of an ideal gas move independently of each other and the intermolecular potential energy may be neglected. For each of these cases it is possible to derive a partition function from which the properties of the state can be readily …

A Stratigraphic Study Of Fusulinid Foraminifera In The Cherokee Group (Pennsylvanian) Of Western Missouri And Kansas, Ralph Orlansky

Masters Theses

"Limestones or shaly limestones, from four stratigraphic levels in the Cherokee group (Desmoinesian series) of Missouri and Kansas, contain eight species and two varieties of fusulinid foraminifera, of which four species and two varieties are new, and one ophthalmidiid foraminiferal species (Hemigordius cf. regularis Plummer). The next to highest limestone (cap rock of the Fleming coal) is correlated with the Seahorne limestone of western Illinois, the Stonefort limestone of southern Illinois, and the Munterville limestone of Iowa. Hemigordius regularis, a limestone facies foraminifer apparently marks a correlatable interval in the Ardmore limestone. Descriptions of the fusulinids and the …

Radioactive Carbon Labeled Molecules: A Method Of Synthesis, Glen E. Benedict

Masters Theses

"Use of isotopic carbon in determining organic reaction mechanisms is becoming more popular daily. The reasons for this trend are, the increasing availability of intermediate compounds, the increase in isotope handling knowledge, and mechanisms defined by well ordered tracer reactions are considered infallible.

The mechanism of reaction of halo-epoxides has been a point of conjecture for some time"--Introduction, page 1.

Square Wave Modulation, Richard Henry Duncan

Masters Theses

"Modulation of a radio frequency carrier can be defined as the variation of some wave parameter such as amplitude, frequency, or phase, in accordance with intelligence to be transmitted. An unmodulated carrier is simply a continuous sine wave and contains no information other than the fact that the transmitter has been turned on. The spectrum of an unmodulated signal consists of a single frequency. Any type of modulation is characterized by the appearance of additional frequencies, known as sidebands. One of the fundamental problems in radio engineering is to reduce the number of sidebands to a minimum and still adequately …

The Completion, Adjustment, And Operation Of A Grazing Incidence Vacuum Ultraviolet Spectrograph, William Clinton Johnson-Chamberlain

Masters Theses

"Most gases, and particularly oxygen and nitrogen, are nearly opaque to radiation in the region from about 1800 Å downward to about 2 Å and hence, for spectroscopic work in this region, the removal of these gases is mandatory. Popular usage generally refers to the range mentioned above as the vacuum ultraviolet. That there remains much experimental work to be done in the vacuum ultraviolet has been pointed out by Boyce in his exhaustive survey of vacuum ultraviolet spectroscopy. In order to fill in some of these gaps, Mr. L. H. Chapin, in the, spring of 1950, undertook the construction …

Torsional Modulus Of Rupture Of Thick-Walled Magnesium Alloy Fs-1 Tubing, Delbert R. Cox

Masters Theses

"Magnesium is taking a more prominent position in the structure of aircraft, and because of this, it is important that the mechanical properties of the material be understood more fully. In the high speeds of today, the tendency is toward the use of thick-walled tubing instead of the thin-walled tubing with stiffening structures. For this reason, it is of interest to note the characteristics of thick-walled tubing when subjected to torsion.

This thesis was first suggested by a circular letter on proposed thesis titles from the Commanding General, Air Materiel Command, Wright-Patterson Air Force Base, Dayton, Ohio. When interest was …

A Light Source To Be Used With A Vacuum Spectrograph, Roy George Woodle Jr.

Masters Theses

"A grazing incidence vacuum grating spectrograph for use in the vacuum ultraviolet was designed and partially constructed by Mr. L. H. Chapin, as a research project for a Master’s Degree. This instrument is designed to photograph the region of the spectrum from 100 Å to 1000 Å. As Boyce pointed out in his exhaustive review, there is much important observational work to be done in this region.

The author of this paper has undertaken to develop a satisfactory source for the region from 100 Å to 1000 Å. This is part of a project to photograph the emission and absorption …

A Lead Sulfide Near Infrared Detection System, William V. Cummings Jr.

Masters Theses

"The infrared region of the spectrum is conveniently divided into the near infrared, which extends from the red end of the visible to about 25 microns, and the far infrared, which continues to an ill-defined division point of approximately 1,000 microns. The near infrared region has been further subdivided on the basis of instrumental techniques so that the particular portion of the spectrum consisting of radiations of wave length up to 3 microns has become known as the photoelectric infrared.

Several types of detection instruments have been designed and perfected for work in the photoelectric region, but new methods and …

A Correlation Function For Liquid Argon, Walter Graham

Masters Theses

"X-ray scattering patterns have given considerable information concerning atomic distributions in matter, both crystalline and amorphous. Work on the diffraction of x-rays by crystals was begun in 1912 by Friedrich, Knipping, and Laue, and much valuable information concerning the arrangement of atoms in crystals has been supplied by this method. Diffraction of x-rays by gases was studied as early as 1911, and work in this field has given information concerning the arrangement of atoms in molecules and electron distribution in atoms. Work on the diffraction of x-rays by liquids was begun by Friedrich who obtained diffraction patterns of Canada Balsam, …

Geology And Mineralization Of The Jefferson Mine, Hardin County, Illinois, Robert Joe Cronk

Masters Theses

"Purpose of the Investigation: The geology of the Jefferson Mine was mapped to determine the relationship of the two fluorspar veins exposed on the 260-foot level to the single vein on the 200-foot level to study the mineralogy and paragenesis of the ore, and to gain any other information that would lead to a better understanding of the fluorspar deposits"--Introduction, page 1.

The Energy Levels Of Potassium Chloride, Clifford L. Adams

Masters Theses

"An understanding of the electronic energy states of solids has long been considered of importance. And the energy levels of the alkali halides have been the subject of much study in recent years. The present work is an attempt to set up an energy-level diagram for potassium chloride"--Introduction, page 1.

The Theory Of The Specific Heat Of A Body Centered Cubic Lattice, Curtis Cleveland Webster

Masters Theses

"In normal crystalline solids the atoms are at rest in their lattice points at absolute zero of temperature. Increasing the temperature of the crystal increases the motion of the atoms about their lattice points. Approximately, each atom or ion may be treated as a harmonic oscillator. then from the equations of motion of the atoms, by the Born-von Karman theory of specific heats, the normal modes of vibration of the lattice can be expressed as the roots of a secular determinant. Application of this theory to determine the thermodynamic properties of crystals has resulted either in solutions that are inaccurate …

The Theory Of The Specific Heat Of A Face-Centered Cubic Lattice, Charles Robert Bonnell

Masters Theses

"It is generally accepted that a normal crystalline solid can be pictured at absolute zero as an assembly of atoms at rest arranged at periodic lattice points. Since at higher temperatures each molecule becomes a harmonic oscillator about its lattice point, it is necessary to know the distribution of normal modes of vibration in order to calculate the thermodynamic properties of the lattice...Many approaches have been made to get a simple solution of the problem, but either accuracy is sacrificed for simplicity, or the solutions demand a very considerable amount of labor. The classical theories failed to explain the change …

The Determination Of The Solubility Of Hafnium Oxide In Aqueous Solution By The Radioactive Tracer Technique, Hampden O. Banks

Masters Theses

"To date, there is no information in the open literature concerning the solubility of hafnium oxide in water other than the fact that it is very insoluble. This lack of experimental information is due, partly, to the fact that hafnium is a relatively new addition to the list of known elements"--Introduction, page 1.

Intermolecular Potential Functions For Liquid Argon And Liquid Mercury, Richard H. Kerr

Masters Theses

"The purpose of this research is to obtain such intermolecular potential functions for liquid argon and liquid mercury by use of the experimental radial density functions available for these two liquids over a wide range of temperatures. We shall introduce the notion of a correlation between the motions of atoms in neighboring cells in a cell theory of liquid structure, and derive a theoretical radial density function involving the intermolecular potential function for a pair of atoms in the liquid. This radial density function, or as it is frequently termed, the atomic distribution function, applied to the experimental data should …

Ammonium And Alkylammonium Salts Of Carboxylic Acids As Characterizing Derivatives, Hal Gilbert Lankford

Masters Theses

"One of the methods widely used to establish the identity and purity of an organic compound is to prepare various derivatives, the properties of which have been reported in the literature. The object of this investigation was to prepare ammonium and alkylammonium salts of carboxylic acid and determine their utility as characterization derivatives. Should these salts meet the requirements of a satisfactory derivative, they would be particularly valuable from a standpoint time, since they are generally very quickly formed"--Introduction, page 1.

A Determination Of The Surface Tension Of Bismuth, Cadmium, Tin, And Lead, Edward Mckee Chandler

Masters Theses

"Various methods have been employed for the determination of surface tension including capillary rise, drop weight, maximum bubble pressure, sessile drops on flat surfaces, sessile bubbles formed underneath flat surfaces, and the shape of pendent drops. Each method is subject to characteristic advantages and disadvantages. Only two of these will be discussed. The method of maximum bubble pressure allows the formation of a fresh surface for every bubble but does not permit the study of a given sample over a period of time. The sessile drop in direct contrast, allows the observation of the same sample over any period of …

A Grazing Incidence Vacuum Grating Spectrograph For Far Ultra Violet Spectroscopy, Lawrey Huber Chapin

Masters Theses

"Spectroscopy, in the region of the far ultraviolet from 100 Angstroms to 1000 Angstroms, requires special equipment and techniques, inasmuch as these wavelengths are highly absorbed by air. Many gases have resonant frequencies corresponding to the wavelengths mentioned and hence absorption bands appear in the spectrograms obtained by using spectrographs for the visible region. One solution of the problem of obtaining data in this region is to construct a spectrograph from which all intervening gas molecules have been removed, thus eliminating the absorbing material. A vacuum of 10⁻⁴ mm. of mercury is necessary to reduce the absorption to a value …

The Reflection Coefficient At The Truncated Corner Of A Rectangular Wave Guide, John Raymond Barcroft

Masters Theses

"The term wave guide refers to a hollow conducting tube (usually of rectangular or circular cross section) filled with a dielectric (or vacuum) and used for the transmission of electromagnetic waves. We shall consider the guide to be bounded by a perfect conductor and to be filled with a lossless homogeneous isotropic dielectric (or vacuum). The electromagnetic wave in the guide must of course satisfy Maxwell's equation. It must also satisfy the boundary condition that there be no tangential component of electric field at the surface of the conductor. If the electromagnetic waves traveling along the guide meet a discontinuity …

An Ecological Study Of The Foraminifera Of Mason Inlet, North Carolina, Daniel N. Miller Jr.

Masters Theses

"Mason Inlet. North Carolina is a lagoonal marsh area with warm-temperate water, the salinity ranging from fresh to salt water. Nine collecting stations comprise an ecological gradient across the environment.

Forty-two species of foraminifera are recorded from the inlet, ranging in their affinities from brackish water to open-sea facies. Several extensions of range are recorded both northward and southward.

Substratum conditions apparently control the distribution of foraminifera within the inlet. Clean, fine sand provided the largest faunal populations. A depauperate assemblage was found in an inorganic, argillaceous substratum. The largest population of arenaceous forms was found at the channel through …

Geology Of The Crystal Mine, Hardin County, Illinois, John Amsden Emery

Masters Theses

"The study of the geology and mineralization of the Crystal Mine was undertaken at the suggestion of Mr. Dodson G. Gibson of the Crystal Fluorspar Company, who allowed access to the mine and its records for this purpose. The problem was to develop a system of prospecting the so-called bedded-replacement fluorspar deposits of Hardin County, Illinois. It is believed that an economically feasible method has been developed. This method involves not only the actual finding of fluorspar, but also serves as a guide in revealing structural trends suggestive of mineralization.

The fluorspar deposits of the Crystal Mine are representative of …

Application Of Electrical Prospecting Methods To Two Types Of Sulphide Ore Deposits, Robert Van Nostrand

Masters Theses

"Although certain types of sulphide ores, especially those near the surface of the earth, lend themselves very well to electrical prospecting methods, quite the opposite is true of the extensive deposits of the type found in the Mississippi River Valley. The purpose of this investigation was to discover additional facts concerning two distinct types of sulphide ores, and therefrom to develop a new technique which would be applicable to prospecting for the lead and zinc deposits found in the Mississippi Valley"--Introduction, page 1.

Geology And Mineralization Of The Minerva Mine No. 1, Hardin County, Illinois, Matthew Peter Nackowski

Masters Theses

"This study originally was undertaken to describe the witherite identified in specimens collected at the Minerva Oil Company Mine No. 1, Hardin County, Illinois. The original specimens of witherite were collected on October 25, 1948, by Charles E. Tothill, while on a senior trip through the fluorspar mine. The witherite was identified by Dr. O. R. Grawe, Chairman of the Geology Department, Missouri School of Mines, Rolla, Missouri, to whom the specimens were presented. Dr. Grawe suggested that the writer visit the southern Illinois fluorspar area to determine the occurrence and distribution of the witherite. This mineral had been described …

Plateau Characteristics Of Geiger Counters With Respect To Different Gas Mixtures And Pressures, Ralph E. Lee

Masters Theses

"The section of a Geiger Counter is characterized by the so-called plateau curve. In this curve the counting rate of a given counter is plotted as a function of voltage, when the gas which it contains and the radiation to which it is exposed are both kept the same. These curves are characterized by a rapid rise beyond the starting potential (potential at which the counter begins to respond) until a more or less flat region is reached. This flat region is called the plateau of the curve. The slope and width of the plateau curve are dependent upon the …

A Determination Of The Surface Tension Of Tin In The Solid State, Charles Merton Rice

Masters Theses

"Many studies have been made on the surface tension of metals but almost exclusively in the liquid state. Information on metals in the solid state is needed in pure physics to test theories of cohesion and in physical metallurgy to explain sintering. The common approach to the problem of surface tension in the solid state is to hang a weight on a thin wire or leaf of metal and then heat this weighted sample to a temperature at which flow is appreciable. The shrinkage or stretch of the sample is then a measure of the surface tension. Of the recent …