Physical Sciences and Mathematics Commons^™

Evaluating The Effects Of Sodium, Potassium, Magnesium, And Calcium Concentrations On Dolomite Stoichiometry, Cation Ordering, And Reaction Rate, Hanna F. Cohen

Masters Theses

Numerous environmental factors affect dolomitization. Shallow peritidal and restricted marine environments, for example, are often associated with more abundant and more stoichiometric dolomite than deeper marine environments. Higher fluid Mg/Ca ratios resulting from gypsum precipitation are often invoked to explain this observation, even when evidence of evaporites is absent. In this study, high-temperature dolomitization experiments show that the concentrations of major cation concentrations (Na, K, Mg, and Ca) impact dolomite stoichiometry and reaction rate. Nearly 200 batch dolomitization experiments were run whereby 100 mg of natural aragonite ooids were dolomitized at 215°C in ionic solutions. Fluid [NaCl] and [KCl] correlate …

Synthesis And Characterization Of Ion-Implanted Gold Nanoparticles, Nurlathifah Fnu

Masters Theses

Gold negative ions of 70 keV energy were implanted within the quartz substrates at room temperature at seven different fluences starting from 2 x 10¹⁶ particles/cm² to 8 x 10¹⁶ particles/cm² with the increment of 1 x 10¹⁶. Prior to the implantation, Stopping and Range of Ions in Matter (SRIM) calculations were carried to obtain the Bragg peak below the surface of quartz. Rutherford Backscattering Spectrometry (RBS) was carried out using 2.0 MeV He⁺⁺ ions to measure depth and implanted fluence of gold, and learn how they varied with fluence. Backscattered He particles …

Assessing The Impact Of 3d Printed Terrain On Teaching Topography In Introductory Earth Science Labs, Jay Alan Cockrell

Masters Theses

Learning to effectively read topographic maps is challenging for students, as these maps contain 3D representations of terrain displayed on a 2D surface map. This project assessed student learning when 3D terrain printed from a portion of the laboratory quadrangle map currently in use was introduced into an earth science course for non-science majors. Using a quasi-experimental design with nonequivalent groups across two semesters, performance on the Modified Topographic Map Assessment (MTMA) administered as a pre- and posttest was used to compare learning outcomes between the traditional lab and the 3D print lab intervention. Students in the traditional (n = …

Arboriculture Safety Around The World, Jamie Lim

Masters Theses

Arboricultural work is inherently dangerous, with more serious injuries and fatalities than most other professions. Safety standards exist in some jurisdictions, but it is unclear how many standards exist, how they compare to one another, and whether (and how many) jurisdictions share standards. To establish a baseline understanding of these issues, my objectives were to (i) develop a database of existing standards, (ii) identify the most frequently occurring safety topics and (iii) describe similarities and differences in safety topics among standards from different countries. I worked with a variety of contacts and traditional university library resources to identify, obtain, analyze, …

Using Visual Media To Empower Citizen Scientists: A Case Study Of The Outsmart App, Megan E. Kierstead

Masters Theses

To be successful citizen science projects need to do two key things: (1) they need to meaningfully engage the public and they must also provide people with the tools, expertise, and/or training needed to participate in rigorous research that can be used by the scientific community. In some ways, these requirements are potentially at odds. Emphasis on rigor and expertise risks excluding members of the public who do not feel qualified to participate in esoteric or technically difficult scientific research. Conversely, projects that eschew rigorous methods in favor of wider participation might lead to bad data that cannot be used …

Defining And Addressing Interconnected Goals In Groundwater Management Planning Across The Usa, Allison Gage

Masters Theses

Groundwater accounts for approximately 99% of the available freshwater on Earth, and is an important resource for irrigation, potable water, and domestic use in the United States. However, the overuse of groundwater has led to aquifer depletion in several basins across the USA, resulting in storage reduction, contamination, salt water intrusion, and depletion of surface waters. To properly manage groundwater for the future, there is a need for well-informed Groundwater Management Plans (GWMPs) in order to prevent further depletion and erosion of the resource. Previous studies have focused on groundwater management relative to groundwater laws, regulations, and institutional arrangements. This …

Spatial And Temporal Mapping Of Distributed Precipitation, Surface And Groundwater Stable Isotopes Enables Insights Into Hydrologic Processes Operating At A Catchment Scale, Alison Cole

Masters Theses

Isotopic analyses of d¹⁸O and d²H of water through the hydrologic cycle have allowed hydrologists to make better interpretations related to climate and relationships between precipitation, surface water, and groundwater. In this study 394 precipitation samples 1917 surface water samples and 1405 groundwater samples across Massachusetts was used to create an isoscape for each respective water. All samples have been collected by volunteers throughout Massachusetts. A state meteoric water line: d²H = 7.7*d¹⁸O + 9.8, surface water line: d²H = 5.7*d¹⁸O – 4.2, and groundwater line: d^{2 …}

Hydrologic Structure And Function Of Vernal Pools In South Deerfield, Massachusetts, Charlotte Axthelm

Masters Theses

Vernal pools are small, ephemeral wetlands lacking an inlet or outlet. These wetlands, also known as seasonal pools, are found in a wide range of biomes, and their characteristics vary based on location. While the vegetation of western U.S. pools, and amphibians of eastern U.S. pools have been extensively studied, many aspects of vernal pools have not been fully characterized. In particular, although the general seasonal wetting and drying cycle is understood qualitatively, few studies have attempted to quantify the hydrological regime of vernal pools in New England. As water level variation drives many, if not all, of the characteristics …

In-Situ Zircon And Monazite Geochronology From Compositionally Distinct Layers In A Single Migmatitic Paragneiss Sample Located In The Eastern Adirondack Mountains, Ny, Kaitlyn Suarez

Masters Theses

Migmatites are a common rock type in the Adirondack Mountains, NY. We analyzed a single sample of biotite-garnet-sillimanite paragneiss with foliation parallel leucosome along Route 22 south of Whitehall, NY in order to determine the timing of melting using both in-situ monazite and zircon U/Pb geochronology from the restite and leucosome layers of the same rock. Monazite was analyzed via in-situ EMPA on the Ultrachron microprobe at the University of Massachusetts. Zircon was analyzed via LA-ICP-MS (in-situ and mounted mineral separates) at the LaserChron Center. Monazite analyses from the restite yielded six compositionally distinct populations with dates of 1178 ± …

An Exploration Into The Controls And Extent Of Capillary Rise In Fine-Grained Sand, Neal S. Turluck

Masters Theses

Capillary rise in fine-grained sands is especially important due to the wide distribution of fine-grained sediment throughout the unconsolidated sedimentary layers blanketing the earth. The height to which water rises above the water table in porous media is known as the capillary fringe. Tension pulling on the water molecules from the solid surfaces of pores will cause water to rise in the unconsolidated fine-grained sands until the water reaches equilibrium with the downward force of gravity.

Researching the controls behind capillary rise and being able to predict the extent to which water will rise in fine-grained sand helped provide insight …

Eastern Whip-Poor-Will Habitat Associations In Fort Drum, Ny, Kimberly Spiller

Masters Theses

The eastern whip-poor-will (Antrostomus vociferus: hereafter whip-poor-will) has been declining from historical population levels throughout its range in the northeast. Although whip-poor-wills have been reported to use a variety of habitats, most recent studies have associated whip-poor-wills with open habitat, such as early-successional habitats or forest edges. Population declines of other early-successional bird species have been attributed to the loss of early-successional disturbance-dependent habitats in the northeast, and it has been suggested that habitat loss is a significant factor in whip-poor-will population declines, as well. However, there remain substantial gaps in our understanding of whip-poor-will habitat associations, and …

The Climatic And Hydrostratigraphic Controls On Brine-To-Freshwater Interface Dynamics In Hyperarid Climates: A 2-D Parametric Groundwater Modeling Study, Sarah Mcknight

Masters Theses

Density dependent flow occurs in areas where high-salinity groundwater interacts with low-salinity groundwater to create a brine-to-freshwater interface that defies common assumptions about groundwater movement. Yet the geologic and hydrologic factors that impact interface dynamics and migration remain poorly defined. With less than 20 mm•yr^-1 of precipitation and with an extremely dense (i.e. 1.2 g•cm^-3) naturally occurring brine, Chile’s Salar de Atacama (SdA) provides an excellent analog for exploring interface dynamics in other arid regions. Site-specific 2-D models of the interface in the southeastern region of SdA, with interpretations of the hydrostratigraphic framework, provide an analysis for …

Developing 5gl Concepts From User Interactions, David Stuckless Meyer

Masters Theses

In the fulfilling of the contracts generated in Test Driven Development, a developer could be said to act as a constraint solver, similar to those used by a 5th Generation Language(5GL). This thesis presents the hypothesis that 5GL linguistic mechanics, such as facts, rules and goals, will be emergent in the communications of developer pairs performing Test Driven Development, validating that 5GL syntax is congruent with the ways that practitioners communicate. Along the way, nomenclatures and linguistic patterns may be observed that could inform the design of future 5GL languages.

Petrogenesis Of The Eagle East Gabbro In Marquette County, Mi, Usa, Kevin Rupp

Masters Theses

The Eagle East gabbroic intrusion in Michigan’s Upper Peninsula, is a subvertical pluglike intrusion found near the base of the Eagle East Ni-Cu-PGE deposit. U-Pb baddeleyite dating of the gabbro yields an age of 1103.4 ± 1.2 Ma, suggesting formation during the early stages of the Midcontinent Rift System (MRS). Drill core observations show that the intrusion cross-cuts the eastern most portion of the Eagle East ultramafic conduit. The internal portion of the intrusion is made up of two main rock types, gabbro and gabbro norite, which consist of plagioclase (50-60%), clinopyroxene (15-25%), orthopyroxene (0-15%), olivine (0-10%), and are generally …

Chronostratigraphic Correlation Of The Burnt Bluff Group Across The Michigan Basin, Usa, Mohammed A. Al-Musawi

Masters Theses

In the Michigan Basin, the Burnt Bluff Group (BBG) is lower Middle Silurian in age (Llandovery), and is composed of limestones and dolostones. The BBG is bounded above by the Schoolcraft Formation and below by the Cabot Head Shale. The BBG in northern Lower Michigan is composed of three formations, including the Lime Island, Byron, and Hendricks, which reflect deposition on a broad shallow marine shelf. In contrast, the BBG in central Michigan is composed of a single lithologic unit called informally the “undifferentiated BBG (UD-BBG),” which reflects deposition in a deeper marine basin. Lithostratigraphically, the three formations in the …

Depositional Facies And Sequence Stratigraphic Model For The Silurian Reefs, Michigan Basin, Usa, Zaid N. Nadhim

Masters Theses

Depositional models for the Silurian reefs in the Michigan Basin suggest that internal facies are either (i) randomly distributed within a symmetrical reef structure, or (ii) highly asymmetrical and strongly controlled by paleo-wind direction. To further test the applicability of these models, internal facies distributions were mapped using high-resolution core and log data in two sets of Silurian reefs. The results suggest that the relationship between reef geometry, facies distribution and proposed paleo-wind direction is more inconsistent than recently proposed. More specifically, facies descriptions from the Silurian reefs suggest the following. First, overall reef geometry and facies distributions are not …

Thermal Maturation Modeling Of The Michigan Basin, Jack H. Hybza

Masters Theses

Given present day heat flow and burial depths in the Michigan Basin, hydrocarbons should be immature. However, oil and gas are abundant within the basin. Our hypothesis is that thermal maturation distributions in the Michigan Basin can be explained by variations in proximity to the Midcontinent Rift (MCR) system, thermal cooling, crustal convection, high temperature fluid advection, and eroded overburden.

For each of the seven wells in this study, a geohistory plot is coupled with a range of geodynamic models to calculate the thermal and maturation histories of each sediment unit within the well. Backstripping was used to generate basement …

Bedrock Topography Mapping Of The East Leroy And Climax 7.5’ Quadrangles, Mi Using Hvsr And Other Geophysical Methods, Tyler A. Norris

Masters Theses

Geophysical methods were used to estimate bedrock depths below sedimentary cover and infer previously unknown features in two adjacent topographic quadrangles (Climax & East Leroy) in Michigan, USA. The study area contains mostly Mississippian Shale bedrock overlain by Wisconsin-aged glacial drift deposited during multiple glacial advances and retreats of the Saginaw Lobe (Laurentide Ice Sheet). These glacial events created complex landform assemblages that have only recently been mapped in detail near-surface, but are still poorly understood in the subsurface. Buried bedrock valleys typically contain coarse glacial sediment and thus are valuable aquifers, but these can be difficult to locate due …

Utilizing Geophysical Attributes To Investigate The Architecture Of A Pinnacle Reef Complex, Michigan Basin, Usa, Austin M. Johnson

Masters Theses

The Silurian Niagaran Pinnacle Reefs of the Michigan Basin retain their relevance after primary recovery of hydrocarbons and are excellent candidates for carbon dioxide sequestration, natural gas storage, and enhanced oil recovery. Due to the nature of carbonate rocks, these reef complexes are heterogeneous and lateral interpolation between observations in wells, is ambiguous. Ambiguity has led to large uncertainty and disagreement regarding reef architectures and their internal facies distributions. Previous models of these reef complexes have relied almost entirely on well logs and conventional core. This study focused on integrating 3D seismic reflection data to reduce uncertainty when delineating the …

Insar Simulations For Swot And Dual Frequency Processing For Topographic Measurements, Gerard Masalias Huguet

Masters Theses

In Earth remote sensing precise characterization of the backscatter coefficient is important to extract valuable information about the observed target. A system that eliminates platform motion during near-nadir airborne observations is presented in this thesis, showing an improvement on the accuracy of measurements for a Ka- band scatterometer previously developed at Microwave Remote Sensing Laboratory (MIRSL). These very same results are used to simulate the reflectivity of such targets as seen from a spaceborne radar and estimate height errors based on mission-specific geometry. Finally, data collected from a dual-frequency airborne interferometer com- prised by the Ka-band system and an S-band …

Root-Driven Weathering Impacts On Mineral-Organic Associations Over Pedogenic Time Scales, Mariela Garcia Arredondo

Masters Theses

Plant roots are critical weathering agents in deep soils, yet the impact of resulting mineral transformations on the vast deep soil carbon (C) reservoir are largely unknown. Root-driven weathering of primary minerals may cause the formation of reactive secondary minerals, which protect mineral-organic associations (MOAs) for centuries or millennia. Conversely, root-driven weathering may also transform secondary minerals, potentially enhancing the bioavailability of C previously protected in MOAs. Here we examined the impact of root-driven weathering on MOAs and their capacity to store C over pedogenic time scales. I compared soil that experienced root-driven weathering, resulting in the formation of discrete …

Legacy Sediment Controls On Post-Glacial Beaches Of Massachusetts, Alycia Ditroia

Masters Theses

Here we examine seasonal grain-size trends on 18 beaches in the Northeastern US and dispersed along the post-glacial coast of Massachusetts (USA) in order to explore the mechanisms influencing median grain size and slope. Over 800 grain size samples were collected along 200 summer and winter cross-shore beach elevation surveys. Obtained grain size and beach slope data are compared to coastal morphology, sediment source, wave height, and tidal magnitude in order to ascertain controls on beach characteristics. In general, median grain size increases with intertidal beach slope in the study region. However, grain sizes along post-glaciated beaches in the study …

Geophysical Imaging Beneath Lake Chesterfield, Missouri, James Daniell Hayes

Masters Theses

"Lake Chesterfield in Wildwood, Missouri, has been leaking since construction of the earth-fill dam was completed in 1986, despite numerous mitigation efforts. The mitigation efforts, including the injection of grouting and the emplacement of clay liners, has not solve the leakage problem.

In the current study, geophysical (subsurface imaging) data was acquired across the drained and dry lake bed and along the base of the earth-fill dam to 1) map variable depth to top of bedrock, 2) determine the variable quality of the bedrock to depths on the order of 80 ft., 3) identify any significant karst features beneath the …

Exploration For Alteration Halos Around The Ag-W Deposits In Southeastern Missouri, Usa, Daniel Joseph Warbritton

Masters Theses

"The St. Francois Mountains in SE Missouri are an extensive terrane of granitic ring complexes and associated rhyolites. They were an important source of Ag, W, and Sn and mined intermittently from the 1800s until the 1950s. The Ag-W ores occur in the Silvermine Granite and rhyolite roof rocks. The deposits are classified as a xenothermal ore system with mineralization occurring in quartz veins and surrounding greisen (up to 2.5 m). Exploration for hydrothermal ore deposits often focuses on the identification of alteration halos in the surrounding host rocks. In the vast majority of xenothermal ore deposits, such as in …

Identifying Priority Conservation Areas And Strategies For Myotis Sodalis (Chiroptera: Vespertilionidae) Via Habitat And Connectivity Modeling, Ashleigh B. Cable

Masters Theses

Myotis sodalis, the Indiana bat, is a federally endangered bat species in the United States of America (USA). Conservation efforts are typically focused at identified maternity sites at local scales, however, the species is a regional migrant that interacts with its environment at multiple spatial scales. We are limited in our knowledge of landscape-level requirements of this species, especially in large areas such as Illinois, USA, where a wide range of environmental and landscape conditions exist. Many previous M. sodalis habitat studies have limited their focus to smaller spatial scales. Due to limitations in funding, personnel, and time, it …

The Impact Of Dutch Disease: The Case Of Nigeria, Halimat Atinuke Laguda

Masters Theses

Nigeria, over the years, has been showing a rapid appreciation of the domestic currency, a rise in real wages and the service sector and a slow-down in the industrial production which are all signs of presence of Dutch disease which predicts that a country with large natural resource rents may experience a de-industrialization and a lower long term economic growth. This paper analyses the impact of Dutch disease in Nigeria Ordinary Least square method, Two-Stage Least Square and Autoregressive Distributed Lag with a system of equation from 1981 to 2017 and found that the real wage rate emphasizes on the …

Variation In Leaf Morphology Of An Alpine Shrub Community Along Environmental Gradients, Abdulssalam Khafsha

Masters Theses

Mountains represent complex environment gradients which strongly affect local temperature regimes and rainfall. These changes in climate conditions drive a diversity of plant responses. As alpine environments are expected to change dramatically in response to climate change, understanding plant responses to environmental variation is critical in these environments. Although they are a critical component of alpine communities, the environmental responses of shrubs have been much less examined than trees, representing an important knowledge gap. Leaves, as the primary photosynthetic organs on plants, would be expected to respond strongly to local climate conditions. In this study, I documented how the leaf …

Synthesis, Characterization And Mechanistic Studies Of Biomimetic Dinuclear Copper(Ii) Complexes, Millaniyage Nuwanthaka Prasad Jayaweera

Masters Theses

Dinuclear copper complexes are significant synthetic targets due to their use as model compounds for the active sites of type 3 copper proteins like catechol oxidase. A distinct class of ligands used in these studies are built on a phenol core to witch various donor side-arms were appended at the 2 and 6 positions of the arene ring. In our quest to quantify the influence of electron donating or withdrawing groups attached to the central arene ring, we have designed a set of ligands that, upon coordination to copper(II) centers, would produce complexes of the general structure. During this research …

The Correlation Between Sleep And Lifespan In Drosophila Melanogaster, Joshua Randall Lisse

Masters Theses

”Adequate sleep is associated with an individual’s health. Too little sleep is associated with many health problems, including cardiovascular disease, obesity, and a general increase in all-cause mortality. Yet the molecular changes that link poor sleep and changes in health are still not well understood. Individuals have a unique daily need for sleep, and deviations from the animal’s regular sleeping patterns can be indicative of, or result in, underlying changes in its health. Therefore, we hypothesize that changes in the sleep architecture in Drosophila melanogaster reflect changes in the fly’s health.

We determined sleep architecture in wild-type male flies over …

Controlled Switching In Kalman Filtering And Iterative Learning Controls, He Li

Masters Theses

“Switching is not an uncommon phenomenon in practical systems and processes, for examples, power switches opening and closing, transmissions lifting from low gear to high gear, and air planes crossing different layers in air. Switching can be a disaster to a system since frequent switching between two asymptotically stable subsystems may result in unstable dynamics. On the contrary, switching can be a benefit to a system since controlled switching is sometimes imposed by the designers to achieve desired performance. This encourages the study of system dynamics and performance when undesired switching occurs or controlled switching is imposed. In this research, …