Physical Sciences and Mathematics Commons^™

Kinetics Of The Formation Of The Nickel(Ii) Complex With N, N' -Dimethylethylenediaminediacetic Acid And The Metal Exchange Reaction Between N,N'-Dimethylethylenediaminediacetatonickel(Ii) And Copper(Ii), Roger A. Karel

Masters Theses

The kinetics of the reaction of aquonickel (II) ion with N'N'-dimethlethylenediaminediacetic acid has been studied at 25°C and 0.1M iconic strength over a pH range of 6.0 to 9.3 using stopped-flow techniques. Formation reactions in all cases were first-order in Ni (II) and in ligand. The formation rate constant for the protonated and unprotonated species were evaluated and compared to their theoretical value. The rate-determining step is shown to be ring closure. A comparison of this system with other studies involving complexation of nickel (II) confirm the magnitude of the internal conjugate base effect and also shows a correlation between …

A Study Of Integral Equations For Computing Radial Distribution Functions, Robert C. Scherzer

Masters Theses

The use of integral equations to find radial distribution functions for computing thermodynamic properties is examined. The system considered is a simple classical fluid with interactions according to the Lennard-Jones (6-12) pair potential function. Two parametric integral equations (C and T) are studied in detail. Derivation of equation T and a power series solution are given. Computer solutions at several different temperatures, densities, and parameter values are obtained. Comparisons are made betv/een these results and results from integral equation N, PY, and HNC, and results from Monte Carlo, molecular dynamics, and power series methods. Equations C and N are found …

Resolution Algorithms In A Parallel Processing Environment, Paula Beth Brandman Hencken

Masters Theses

An ever increasing number of processors are becoming available to the multiprocessor user. For faster response and efficient utilization of parallel processing systems it is necessary to develop parallel algorithms to solve a single problem.

This paper evaluates the complexity of resolution algorithms run in a parallel processing environment. An overview of parallel processing is presented along with a discussion of general resolution and resolution-refutation systems. An analysis of the complexity required by different control strategies to perform resolution programing is presented using both uniprocessor and multiprocessor systems.

Hydrogeologic And Geochemical Factors Influencing The Impact Of A Chromium-Arsenic-Copper Wastewater Discharge On A Glacial Outwash Aquifer, Michael J. Gallagher

Masters Theses

A discharge of chromium-arsenic-copper laden wastewater occurred periodically from 1970 to 1980 at a wood preserving company located in southwestern Kalamazoo County, Michigan. As a result of this discharge, soils at the company site became contaminated with chromium, arsenic, and copper, and a local glacial outwash aquifer became contaminated with hexavalent chromium.

Soil samples collected from the discharge site were analyzed for clay-silt-sand-gravel content, organic matter, pH, clay mineralogy, and chromium, arsenic, copper, iron, and manganese content. Background soil samples were analyzed for most of the above catagories. Pearson r coefficients of correlation were calculated to determine the correlation of …

Geology Newsletter- 1984, Department Of Geology

Geological and Environmental Sciences News

Vol.1 No.9

• Dear Alumni and Friends
• Advisory Council
• Geology Development Fund
• Graduate Students
• Geology & Earth Science Club
• W. David Kuenzi Scholarship Fund
• 1983-84 Awards & Scholarships
• Faculty News
• Alumni News

I. A Temperature Dependent Nmr Study Of 6,6-Dicarbethoxy-5,5-Dideuteodi-Benzo--[A,C]-[L, 3]-Cycloheptadiene Ii. The Synthesis Of Four Deuterated Analogs Of 6, 6-Dicarbethoxydibenzo-[A,C]-[1,3]-Cycloheptadiene, Patrick F. Jonas

Masters Theses

The kinetics of conformational interchange of 6,6-dicarbethoxydi-benzo- a,c - 1,3 -cyloheptadiene and its 5,5-dideuterated analog were studied using variable temperature NMR techniques. The free energy of activation for conformational interchange of the parent compound was found to be 9.02 kcal mol^-1 and that of the 5,5-dideuterated analog to be 9.42 kcal mol^-1. Values of the entropy of activation were found to be -19.91 e. u. and -18.12 e. u. respectively. The spectra were recorded on a Nicolet NMC-360 wide bore spectrometer and the data collected treated as an AB spin system.

The 4,8-dideutero, 4,5,5,8-tetradeutero and 5,5,7,7-tetradeutero analogs …

Land Use Effects On Shallow Earth Resistivity, Gary James Barton

Masters Theses

No abstract provided.

Naphthalene-2,3-Dialdehyde: A Synthon To 7,9-Polymethylene-8h-Cyclohepta[B]Naphthalene-8-One And A Study Of Their Aromaticity, Edward O. Crapps

Dissertations

This report describes the synthesis of naphthalene-2,3-dialdehyde, and an analytical method for determining its purity by thin layer chromatography. Subsequently, the dialdehyde was condensed with various cyclic ketones to generate a series of polymethylene bridged naphthotropones. It was found that planarity and aromaticity increase with the size of the methylene bridge, although, the bridge must contain six or more methylene groups for the latter to be true. The claim for aromaticity is supported by NMR and IR data, which indicates the positive charge for a perchlorate cation salt is delocalized over the naphthalene and tropone ring system. Furthermore, from the …

On The Genus Of A Block Design, Joan Marie Rahn

Dissertations

The genus of a design (BIBD or PBIBD) is defined to be the genus of its corresponding hypergraph (objects as vertices, blocks as edges); that is, the genus of the bipartite graph associated with the hypergraph in a natural way. The Euler formula is used to establish a lower bound (gamma) for the genus of a block design. An imbedding of the design of the surface of genus (gamma) is then described by a voltage hypergraph or voltage graph. Use of the lower bound formula leads to a characterization of planar BIBDs. A connection between a block design derived from …

The Synthesis And Characterization Of Some Transition Metal Complexes Prom Mixtures Of Poly Pyrazolyl Borates, Robert Matthew Alway

Masters Theses

This is a report of the synthesis and separation of transition metal complexes of hydrotris(1-pyrazolyl)- borate and hydrotris(3,5-dimethyl-l-pyrazolyl)borate. These complexes contain a central metal ion and two tridentate ligands, one hydrotris(1-pyrazolyl)borate and one hydrotris(3,5-dimethyl-l-pyrazolyl)borate. Mass spectrometry proved to be an extremely useful technique for identifying products. Many mass spectra are included and discussed extensively.

Complexes containing hydrobis(pyrazole)(3,5-dimethyl -1-pyrazolyl)borate and hydrobis(3,5-dimethyl-l-pyrazole) (pyrazolyl)borate also were synthesised and mass spectra obtained.

A Geophysical Investigation Of A Possible Astrobleme In Southwestern Michigan, Suhas L. Ghatge

Masters Theses

A circular pattern to the oil production in Calvin Township, Cass County, Michigan, absence of about 1200 feet of Ordovician sediments and uplift indicated by a deep drill hole in the center of the productive area and absence of anomalies on the regional gravity and magnetic maps led to detailed gravity and magnetic surveys over this structure to delineate it and provide information regarding its genesis.

The Bouguer gravity and magnetic anomaly maps show no anomaly associated with the structure. The 28-mile wavelength second harmonic residual gravity and magnetic maps show linear features in the area. Two dimensional gravity modeling …

Structural Geology Of The Northern Snowcrest Range, Beaverhead And Madison Counties, Montana, Mark Kenneth Sheedlo

Masters Theses

The Snowcrest Range was uplifted in Late Cretaceous and Early Tertiary time as a consequence of thrusting in Precambrian basement and Phanerozoic cover rocks.

The Snowcrest-Greenhorn thrust system is associated with largescale overturned, eastward verging folds. Mean orientation of the thrust system is N.40°E., 35°N.W.. The trend of the thrust system and associated transverse faults appear to be controlled by earlier structures. Mesoscopic and microscopic analyses indicate that metamorphic basement rocks accommodated congressional strain largely by brittle faulting and cataclastic shearing. Kinematic indicators suggest that local stresses were directed east-southeastward.

Northeast-trending Neogene faults along the western flank of the range …

Learning Computer Logic Architectures On Apple Ii System, Falah Reda Al-Saffar

Masters Theses

For this thesis seven computer-assisted instruction packages have been designed to illustrate the design of electronic circuits of gates , the logic of combinational and sequential circuits, and integrated and magnetic core memories.

The programs in these packages have been written in the Pascal computer language on an Apple II microcomputer and stored on a double-sided floppy disk.

A Computer Aided Instructional System And Its Application Towards A Course On Snobol4 Programming Language, Abtin Edelji

Masters Theses

Computers are rapidly replacing humans in many tasks. Computer Aided Instructional System is an application of the computer in the teaching of a subject. Currently, a large number of educational Institutes use Computer Aided Instructional Systems.

The objectives of this thesis is to review some techniques in implementing such systems and to present a Computer Aided Instructional System called TEACH. The emphasis of this thesis is on the type of the directory used to minimize the search time for the TEACH System.

A Query-Processing Optimization Strategy For Generalized File Structures, Donna Marie Kaminski

Masters Theses

In processing a Boolean query against a non-inverted file, a subset of the query's keys must be selected. Only the records satisfying these keys need to be retrieved from the file. A dynamic programming algorithm, the Dual-to-minDF, is developed here for arriving at the optimum set of keys, i.e., the minimum number of external record retrievals. Previously suggested greedy methods yield feasible solutions which may or may not be optimal. This algorithm has exponential time complexity. However, it is useful for applications involving relatively short queries with duplication of keys within different conjuncts, and in cases where the files have …

A Quantitative Study Of The Copper Content In Granite Rocks, Samir F. Al-Mandwee

Masters Theses

A spectrographic analysis was conducted on ten granite samples of different geological origin from the Pioneer Mountains in Central Idaho. A qualitative analysis was performed first and then a quantitative analysis to determine the presence and relative amounts of copper in the various samples. This spectrographic analysis employed a direct current arc source of 340 volts and 4 amperes to excite the samples which were dissolved in acid and dried on the ends of high purity carbon electrodes. The emitted light passed through a step sector and a medium quartz spectrograph to a photographic plate. The optical density of the …

An Improvement In The Performance Of A Learning System For Finite State Machines, Lea F. Fuller

Masters Theses

A learning system is examined which is capable of learning a finite state machine from a class of finite state machines based on the observed behavior of the machine. The size of the search space becomes very large as the number of states in the machine increases. The size of the search space quickly becomes the limiting factor in the size of the class of machines which may be learned. An investigation is made of methods to improve the performance of the learning system. The application of a depth first approach to the development of the search space is shown …

The Chromatic And Cochromatic Number Of A Graph, John Gordon Gimbel

Dissertations

Clearly, there are many ways that one can partition the vertex sets of graphs. In the first chapter of this work I examine the problem of determining, for a given graph, the minimum order of a vertex partition having specified properties. In the remaining chapters I concentrate on partitions of two types--those in which each subset induces an empty graph and those in which each subset induces an empty or a complete graph.

The chromatic number of a graph G is the minimum number of subsets into which V(G) can be partitioned so that each subset induces an empty graph. …

Geology Newsletter- 1983, Department Of Geology

Geological and Environmental Sciences News

Vol. 1 No. 8

• Dear Alumni and Friends
• Geology Development Fund
• Faculty News
• Geology/ Earth Science Club
• 1982-1983 Awards and Scholarships
• Alumni News
• Geology Department Graduate Students

A Magnetic And Resistivity Survey Of Cork Street Landfill, Stanislaw Leja

Masters Theses

Geophysical techniques such as magnetic and electrical resistivity methods are being increasingly applied in investigations of landfills.

For this survey, measurements of the intensity of the earth's magnetic field were taken at regular intervals along traverses. Resistivity readings were taken at selected intervals along the same or very similar traverses. Additional resistivity depth measurements or soundings were obtained at selected points in and around the landfill.

Profiles were analyzed for individual dump structures and for overall magnetic and resistivity response. Contour maps were drawn from the measurements at the site to depict broad trends or patterns. Deeper subsurface geology was …

Non-Equilibrium L-Shell Effects On K-Shell X Rays For 20-54 Mev S+C Collisions, Donald Solon Shippy

Masters Theses

Projectile K x-ray yields have been measured as a function of target thickness (2.0-150 μg/ cm²⁾ for 20-54 MeV S^q+ ions incident on this carbon foils using the WMU EN tandem Van de Graaff accelerator. The measured K x-ray yields were fond to increase for thicknesses < 15 μg/cm² and decease for thicknesses > 15 μg/cm² . The increasing yield is attributed to L-Shell non-equilibrium as the ion traverses the foil, while the decreasing yield is attributed to K-shell non-equilibrium. Analysis of the data was performed by modifying the "two-component" model of Betz et al. to include the effect of …

Environment Of Deposition Of The A-1 Carbonate, Salina Group, Michigan Basin, Barbara June Leonard

Masters Theses

The lower Salina Group of the Michigan Basin is composed of a cyclic succession of carbonate and evaporite units. The lowermost Salina unit is the A-1 unit which consists of a lower A-1 evaporite and an upper A-1 carbonate. The A-1 unit is underlain by Niagara Group carbonates. The transition from Niagaran carbonates to A-1 evaporite to A-1 carbonate has not been thoroughly understood and previous models have not satisfied some of the evidence. This paper sets forth the hypothesis that the A-1 carbonate was deposited in a non-marine lake environment rather than an isolated marine environment. Findings supporting this …

Cationic And Anionic Micellar Catalyzed Hydrolysis Of Hydroxamic Acids, Douglas Eugene Conran

Masters Theses

The hydrolysis of octanohydroxamic and N-methyloctanohydroxamic acids in the presence of cationic and anionic micelles was investigated. Rate constants were determined for the hydrolyses in cetyltrimethylammonium bromide (ctab), the cationic surfactant, with 0.1111 N NaOH and in sodium 1-dodecanesulfonate, the anionic surfactant, with 0.09270 N HC1 at 50.01 + 0.11°C. The acid hydrolysis and the base hydrolysis of N-methyloctanobydroxamic acid followed the standard model for micellar catalysis.

The Geology Of The Southern Bull Mountain Area, Jefferson County, Montana, Michael Edward Streeter

Masters Theses

The Late Cretaceous-Early Tertiary Laramide orogeny was responsible for the northward tilting of the pre-Eocene rocks of the area. The Late Cretaceous deposition of the Elkhorn Mountains Volcanics resulted in the volcanic-Madison Group unconformity. Late Cretaceous faulting took place probably in response to caldera subsidence. Laramide uplift erosion and downstream transport resulted in the deposition of the Conrow Creek conglomerate and debris flows over the Lodgepole Limestone. Block faulting took place in response to regional extension probably during Late Oligocene-Early Miocene time resulting in the formation of the St. Paul's Gulch, Golden Sunlight, and Boulder basin faults. The Oligocene Dunbar …

On Isomorphic Decompositions Of Graphs, Sergio Ruiz

Dissertations

A decomposition of a nonempty graph G is a collection of subgraphs G(,1), G(,2), ... , G(,k) of G such that their edge sets form a partition of the edge set of G. If G(,i) is isomorphic to a fixed graph H for each i, then G has an isomorphic decomposition into the graph H or, equivalently, G is H-decomposable. Several topics, each concerning isomorphic decompositions, are investigated in this dissertation.

An historical introduction to the subject of isomorphic decompositions is given in Chapter I. We also present there some new information on finding regular graphs that are H-decomposable for …

A High Resolution Ground Magnetic Study Of Part Of The Albion-Scipio Trend, Steven James Hoin

Masters Theses

A detailed high resolution ground magnetic survey was conducted over part of the Albion-Scipio Oil Field Trend. The purpose of the survey was to delineate any magnetic anomalies associated with the trend. A field method using two magnetometers was employed. Sixteen simultaneous readings were taken at a mobile and a base station, and the field operator read the total field values using a 'T ', or similar pattern. This method eliminated much of the noise associated with ground surveys. The resulting residual magnetic map indicates that the basement rocks consist of mafic and felsic, dikes and plutons. Several discontinuities are …

An Optimal Design Of Relational Data Model, Pissamai Amatayakul

Masters Theses

The objective of this study was to propose a design methodology to support a designed in mapping a conceptual model to a logical model. The system was created as a semiinteractive software to produce an optimal relational data model for a given database. The software was developed by combining a well known normalization method from a theory of relational data model which was presented by Codd and the ideas of new normal form which were presented recently by many researchers in the field of database design. The complete description of data objects and their associations are initially defined as a …

A Uniform System For Data Base Directories, Karl Chang

Masters Theses

The objective of this study is to provide an efficient uniform system for data base directories, so that every file in the data base will have the same type of efficient directory. Data base directories will then be uniformly generated, updated and maintained.

The uniform system which is developed here can handle not only discrete attributes, but also range attributes. For the range attributes, it provides the uniform ranges (i.e., a set of ranges such that the records are distributed uniformly between ranges.)

In this thesis, the design and implementation of the hybrid B-plus tree and inverted files which is …

Design, Construction, And Testing Of A Microprocessor-Controlled Interface Between Analog Geophysical Equipment And A Digital Cassette Recorder, Mohd. Nawawi Mohd. Nordin

Masters Theses

A Digital Data Acquisition System (DDAS) microcomputer was designed and constructed to interface between a six-channel analog seismograph and a digital cassette recorder. The DDAS microcomputer is a relatively inexpensive microcomputer built around the popular Z-80 microprocessor chip. It is portable and has 26K bytes of memory. It was designed to convert analog data in to digital with some processing performed before storing on the digital cassette recorder, for later analysis. The same hardware or circuitry of the DDAS microcomputer can perform other functions and work with other geophysical equipment by changing the software of the microcomputer.

A Microprocessor Controlled Pulsed Hollow Cathode Lamp For An Atomic Absorption Spectrometer, James B. Schilling

Masters Theses

A Jarrell-Ash Atomic Absorption/Flame Emission 82-360 Spectrometer was interfaced to a Heathkit ETA-3400 microprocessor. The microprocessor is used to pulse the hollow cathode lamp from a "steady" current to a "peak " current during the opening of the chopper. The current from the photomultiplier-tube is converted to a proportional voltage which is supplied to a sample-and-hold circuit. A successive approximation routine is used to convert the voltage to a representative digital value. Digital values are obtained for the "blank" and "sample" and are used to calculate percent absorption values. The system can also be used to obtain emission values.

The …