Physical Sciences and Mathematics Commons^™

Synthesis And Characterization Of Novel Organic Ligands With Their Complexes Of Platinum, Copper And Uranium, Mustafa Adnan Yasin Aldulaimi

Dissertations

Transition metal complexes of symmetrical and asymmetrical Schiff bases have played a significant role in the field of coordination, inorganic, and bioinorganic chemistry as models for biological, analytical, industrial, and pharmaceutical applications. Over recent years a great deal of interest has developed in new transition metal complexes of Schiff base ligand. The preparation of novel organic ligands is the most important step in the development of metal complexes that exhibit unique properties and novel reactivity. To highlight the presentation of this dissertation and to provide more detailed investigations, the dissertation was separated into six chapters according to the sequence of …

A Structural And Stratigraphic Study Of The A-2 Carbonate In Southwest Michigan And Reservoir Characterization Of An A-2 Carbonate Gas Storage Field, Clayton Joupperi

Masters Theses

The Overisel and Salem gas storage fields of southwest Michigan annually store 34 Bcf of natural working gas in the upper dolomitized portion of the Silurian A-2 Carbonate. Porosity and permeability in these fields is thought to be enhanced by fracturing and dolomitization associated with the dissolution and collapse of underlying salt units. This study utilizes wire-line logs from 383 wells to explore the structural and stratigraphic controls on the deposition and diagenesis of the A-2 Carbonate in southwest Michigan. Core and thin sections from 4 wells serve as the primary data for investigating the depositional and diagenetic history of …

Characterization Of Γ-Butyrolactone Rings: A Computational And Toxicological Study, Donald C. Kidd

Masters Theses

Given the declining state of the natural environment, identifying green methodologies in synthetic chemistry is becoming paramount. An under explored area of green chemistry, is the use of catalytic systems in green solvents. One interesting concept in green chemistry is the use of N-Heterocyclic Carbenes (NHCs) as organocatalysts.

Thiamine or vitamin B1 was one of the first NHCs recognized. Thiamine is required for carbohydrate metabolism and helps the cell produce adenosine triphosphate (ATP). Over the last 20 years NHCs have been found to be efficient catalysts in carbon-carbon bond forming reactions.

But to date, little research has been done exploring …

Lithologic Properties Of The Upper Ordovician Utica Formation, Michigan Basin, Usa: A Geological Characterization And Assessment Of Carbon Dioxide Confinement Potential, Frank Richard Sattler

Masters Theses

The Utica/Maquoketa Shale is considered to be the primary confining layer for Cambro-Ordovician CO₂ sequestration targets in the Midwest in the Michigan and Illinois basins, respectively. Prospective regional geologic seals in mudrock formations possess a combination of lithologic properties including nanometer scale pore space, elevated breakthrough pressures for non-wetting fluid phases and ductile mechanical deformation. Mineralogical composition is related to and typically controls these properties.

The objective of this study is to investigate the geological controls on stratigraphic and lithologic variability in the Utica/Collingwood in the Michigan basin. Twelve conventional cores and hundreds of modern well logs from the …

Integrating Depositional Facies And Sequence Stratigraphy In Characterizing Unconventional Reservoirs: Eagle Ford Shale, South Texas, Seth Jordan Workman

Masters Theses

The Mid-to-Late Cretaceous Eagle Ford Shale of South Texas is a mixed siliciclastic/carbonate, unconventional resource play with considerable oil and natural gas. Characterization of Eagle Ford reservoir quality and potential is made difficult by complex, small-scale heterogeneities.

The limited availability of subsurface data constrains previous subsurface Eagle Ford investigations. As a result, the internal variability of depositional facies and reservoir attributes remain poorly understood for these Eagle Ford rocks.

This investigation incorporates a representative group of four Eagle Ford cores, and core data, from within the current play area in order to: 1) determine facies successions, 2) establish a hierarchal …