Engineering Commons^™

Probabilistic Characteristics Of Processes In Models Of The Operation Of Row Crop Cultivator Aggregates, F.А. Alimova, B.Sh. Primkulov

Technical science and innovation

The main agrotechnical requirements for cultivators working between rows are as follows: uniform of rows loosening between rows (stability of depth of loosening), complete destruction of weeds in spacings and rows, absence of damage to cultivated plants in rows and falling asleep with their soil (keeping the width of the protective zone). The highest quality of work will be if the trace of the last to the row of the working body copies the line of the row. The article presents a model for processing information when performing a cultivator technological process, presents the results of the probabilistic characteristics of …

Research Of Technical Properties Of Silicon Containing Antipyrens For Practical Application In The Production Of Water-Dispersion Coatings, M.A. Kurbanova, D.A. Khamidova, A.T. Tillaev, A.V. Lityaga

Technical science and innovation

In the modern world, widely used water-borne paints and varnishes form coatings with high resistance to the action of water and chemicals, good electrical insulation, physico-mechanical and decorative properties. Everyone knows they are used for painting radio and electrical products, in the automotive industry, agricultural machinery, in the production of household products and residential buildings.The article discusses the technical justification of research results for the practical use of silicon-containing flame retardants in the production technology of fire-retardant water-dispersion paint. The regulations and an effective technological scheme for the production of AP-1 silicon-containing oligomeric flame retardant and the technology for producing …

Determination Of Probability - Temporary Characteristics Of Communication Channels When Transmitting Priority And Non-Priority Data., Sh.S. Karimov

Technical science and innovation

The article discusses the issues of finding the main indicators of the quality of the communication channel in computer networks when transmitting priority and non-priority data at different frame lengths. To solve this problem, methods of the theory of queuing using Petri nets are proposed. The proposed method for calculating the temporal and probabilistic characteristics of computer networks allows determinining the main indicators of the quality of the channel in a stationary mode when transmitting priority and non-priority data of computing tools at various values of the input stream intensity. To simulate the transmission of priority and non-priority frames, a …

Changes In Pore Size Distribution With Pyrolysis Temperature, Particle Aspect Ratio And Pretreatment By Leaching Of Large Beech Wood Particles, Przemyslaw Maziarka, Peter Sommersacher, Stefan Retschitzegger, Wolter Prins, Frederik Ronsse

Bio-Char II: Production, Characterization and Applications

When assessing the usefulness of pyrolysis chars as porous materials for the application as adsorbents, catalysts or catalyst supports, one of the most important parameters of the assessment, besides the specific surface area, is their pore size distribution [1, 2]. The aforementioned processes are highly pore size selective, hence inappropriate pores sizes of the applied material can lead to the material’s uselessness for a given application. In terms of the application of pyrolysis char as a soil amendment (i.e., biochar), pore size also plays a major role. For example, in case of a too large share of micropores, even though …

Nanoindentation Characterization Of Microwave-Pyrolysis Biochar, Muhammad T. Afzal, Chase Wallace, Gobinda Saha

Bio-Char II: Production, Characterization and Applications

This study investigates the nanoindentation hardness and Young’s modulus of microwave pyrolysis biochar developed from hemp and softwood feedstocks. Recent studies have produced encouraging results on the potential for biochar as a reinforcing filler in composite materials, owing to the high porosity and hardness of the carbonous material. In order to further the understanding of the effect of biochar as an additive, and to develop predictive models for the composites, mechanical properties of the chars are needed.

The biochar was synthesized from both hemp and softwood feedstocks, in-house through a microwave-pyrolysis process at 2700 watts, for one hour, with heating …

Activation Of Biochar From Olive Residues: A Predictive Model For Yield And Surface Area, Franco Berruti, Anastasia Colomba, Cedric Briens

Bio-Char II: Production, Characterization and Applications

A great amount of work in the literature is dedicated to the kinetic modelling of gasification reactions, while a limited number of authors have paid attention to the evolution of physical parameters, which are very important in the case in which the reaction is applied to the production of activated carbons. The Volume reaction model (VRM) [1], the Shrinking core model (SCM) [2], and the Random pore model (RPM) [3] are unable to provide a relationship between kinetics and the physical properties of the activated carbon and, particularly, between yield and surface area.

Please click Additional Files below to see …

Biochar - Just A Black Matter Is Not Enough!, Andreas Hornung, Fabian Stenzel

Bio-Char II: Production, Characterization and Applications

What differs biochar from charcoal? The simple answer is: Biochar is a carbon rich product obtained from the thermal decomposition of organic material, at the presence of no or a little oxygen. As we can see in principle, the production of biochar is comparable to the production of charcoal, one of the oldest and most established processes used by mankind. While charcoal is made traditionally from wood, biochar can be based on a wide range of biomass and biomass residues.

However, a variety of technologies for the production of biochar was developed in the recent years. The technologies are based …

Characteristic Studies On The Biochars Produced By Hydro-Thermal And Steam Gasification Of Canola Hull And Canola Meal Fuel Pellets, Franco Berruti, Sonil Nanda, Ajay K. Dalai, Janusz A. Kozinski

Bio-Char II: Production, Characterization and Applications

Biochars, based on their production process and biomass precursor, can have a broad range of structural, compositional, chemical, and physical properties. These properties are important for identifying the biochar performance and stability in further applications. Non-food biomass has a great potential to produce biochars. Two inherent agricultural biomasses from Canadian prairies including canola hull and canola meal were used for the production of fuel pellets. This study provides information on the specific features of biochars produced by steam and hydro-thermal gasification of these fuel pellets compared with those of well-known pyrolysis biochars. For steam gasification, the steam to biomass ratio …

Sequencing Heparan Sulfate Using Hilic Lc-Netd-Ms/Ms, Jiandong Wu, Juan Wei, Pradeep Chopra, Geert Jan Boons, Cheng Lin, Joseph Zaia

Chemical and Biochemical Engineering Faculty Research & Creative Works

Heparan Sulfate (HS) Mediates a Wide Range of Protein Binding Interactions Key to Normal and Pathological Physiology. Though Liquid Chromatography Coupled with Mass Spectrometry (LC-MS) based Disaccharide Composition Analysis is Able to Profile Changes in HS Composition, the Heterogeneity of Modifications and the Labile Sulfate Group Present Major Challenges for Liquid Chromatography Tandem Mass Spectrometry (LC-MS/MS) Sequencing of the HS Oligosaccharides that Represent Protein Binding Determinants. Here, We Report Online LC-MS/MS Sequencing of HS Oligosaccharides using Hydrophilic Interaction Liquid Chromatography (HILIC) and Negative Electron Transfer Dissociation (NETD). a Series of Synthetic HS Oligosaccharides Varying in Chain Length (Tetramers and Hexamers), …

Optimization And Structural Stability Of Gold Nanoparticle–Antibody Bioconjugates, Robert T. Busch, Farzia Karim, John Weis, Yvonne Sun, Chenglong Zhao

Chemical and Materials Engineering Faculty Publications

Gold nanoparticles (AuNPs) bound with biomolecules have emerged as suitable biosensors exploiting unique surface chemistries and optical properties. Many efforts have focused on antibody bioconjugation to AuNPs resulting in a sensitive bioconjugate to detect specific types of bacteria. Unfortunately, bacteria thrive under various harsh environments, and an understanding of bioconjugate stability is needed. Here, we show a method for optimizing Listeria monocytogenes polyclonal antibodies bioconjugation mechanisms to AuNPs via covalent binding at different pH values, from 2 to 11, and 2-(N-morpholino)ethanesulfonic acid (MES), 3-(N-morpholino)propanesulfonic acid, NaOH, HCl conditions. By fitting Lorentz curves to the amide I and II regions, we …

Model Predictive Control Of Parametric Excited Pitch-Surge Modes In Wave Energy Converters, Ossama Abdelkhalik, Rush D. Robinett Iii, Shangyan Zou, David G. Wilson, Giorgio Bacelli, Umesh Korde, Ryan G. Coe

Michigan Tech Patents

A parametric excitation dynamic model is used for a three degrees-of-freedom (3-DOF) wave energy converter. Since the heave motion is uncoupled from the pitch and surge modes, the pitch-surge equations of motion can be treated as a linear time varying system, or a linear system with parametric excitation. In such case the parametric exciting frequency can be tuned to twice the natural frequency of the system for higher energy harvesting. A parametric excited 3-DOF wave energy converter can harvest more power, for both regular and irregular waves, compared to the linear 3-DOF. For example, in a Bretschneider wave, the harvested …

Pd Nanoparticles Supported On Copper Oxide Prepared Via Microwave – Assisted Synthesis: An Efficient Catalyst For Suzuki Cross-Coupling, Hany A. Elazab Dr

Chemical Engineering

We report here a scientific investigation of a simple and versatile synthetic rote for the synthesis of palladium nanoparticles decorated with copper oxideand supported on reduced Graphene oxide (rGO) as a highly active catalyst usedfor Suzuki, Heck, and Sonogashira cross coupling reactions with remarkable turnover number (7000) and turnover frequency of 85000 h^-1. Pd-CuO nanoparticles supported on reduced Graphene oxide nanosheets (Pd-CuO/rGO) exhibited an outstanding performance through high catalytic activity towards cross coupling reactions. A simple, reproducible, and reliable method was used to prepare this efficient catalyst using microwave irradiation synthetic conditions. The synthesis approach requires simultaneous reduction …

Supercritical Co2 Foam Enhanced Oil Recovery: From Mechanistic Model Fit To Lab Experiments To Field-Scale Evaluation, Mohammad Izadi

LSU Doctoral Dissertations

This study investigates how a mechanistic foam modeling approach based on bubble population balance is applied to a series of laboratory experimental data of a supercritical CO₂ foam in reservoir conditions to extract model parameters (topic 1). The model with model parameters determined from the fit is then used to estimate how far fine-textured strong foam can propagate into the reservoir, before turning into coarse-textured weak foam and before being segregated by gravity (topic 2). With the help of mechanistic model, a possible range of gas mobility for supercritical CO₂ foam is calculated and the resulting gas-phase mobility …

Academic Skill Learning And The Problem Of Complexity I: Creational Purposeful Integrated Capability At Skill (Cpics), Martin F. Gardiner

Northeast Journal of Complex Systems (NEJCS)

Physical and mental skills are intended to achieve success at acting purposefully. As capability at any skill increases, the need to adjust details of application to complexity of context and goals will increase as well. It will become more and more important to prepare mentally for what I now term Creational Purposeful Integrated Capability at Skill (CPICS). This paper develops what I mean by CPICS. Theory concerning Complex Dynamical Systems (CDS) such as the brain and other evidence points to the likelihood that the mental operations by which our brain produces any kind of skillful behavior cannot remain constant, …

Strategies And Software Tools For Engineering Protein Tunnels And Dynamical Gates, Jiri Damborsky, David Bednar, Sergio Marques, Piia Kokkonen, Gaspar Pinto, Joan Planas Iglesias, Milos Musil, Jiri Hon, Lenka Sumbalova, Ondrej Vavra, Jiri Filipovic, Bara Kozlikova, Martin Marek, Zbynek Prokop, Jan Stourac

Enzyme Engineering XXV

Improvements in the catalytic activity, substrate specificity or enantioselectivity of enzymes are traditionally achieved by modification of enzymes’ active sites. We have recently proposed that the enzyme engineering endeavors should target both the active sites and the access tunnels/channels [1,2]. Using the model enzymes haloalkane dehalogenases, we have demonstrated that engineering of access tunnels provides enzymes with significantly improved catalytic properties [3] and stability [4]. User-friendly software tools Caver [5], Caver Analyst [6], CaverDock [7] and Caver Web [8], have been developed for the computational design of protein tunnels/channels; FireProt [9] and HotSpot Wizard [10] for automated design of stabilizing …

Influence Of Heating Rate On The Solid Yield Of Biomass Pyrolysis, Markus Lang, Kathrin Weber, Peter Quicker

Bio-Char II: Production, Characterization and Applications

The use of biochar has become increasingly popular over the last decade. The possible applications are vast and range from renewable carbon carrier in industrial and energetic applications to soil amendment and fodder additive. The various applications have different demands on the properties of biochar. These can be influenced by the choice of feedstock, reactor and production conditions. Regardless of production process and application however, achieving a high yield of the solid product is desirable from an economic point of view. The higher the treatment temperature, the more material is devolatilized and the lower is the amount of biochar that …

Smart Engineering Of Various Enzymes For Asymmetric Synthesis Of Chiral Molecules On Industrial Scale, Haibin Chen, Marco Bocola, Thomas Daußmann, Yong Koy Bong

Enzyme Engineering XXV

The commercialization of sustainable enzymatic and microbial catalysis technology is gaining increasing priority for the synthesis of chiral compounds from achiral precursors that require high selectivity and high substrate load. Thus, the fast and cost-effective development of novel biocatalytic processes using an integrated platform offers significant opportunities to fine chemical, pharmaceutical, food & feed, material and related industries.

Please click Additional Files below to see the full abstract.

Sustainable Biocatalytic Synthesis Of Β-Hydroxyl-Α-Amino Acids On An Industrial Scale, Haibin Chen, Haibin Chen, Yong Koy Bong, Marco Bocola, Thomas Daußmann

Enzyme Engineering XXV

The development and commercialization of sustainable enzymatic and microbial catalysis technologies is gaining increasing priority to reduce the environmental impact of chemical and related industries.

Enzymes offer, as common platform, significant opportunities for innovations to enhance production capabilities to meet these new reduced impact demands, whilst retaining product quality and keeping costs down. To enable cost efficient biocatalytic processes, however, high selectivity, high activity, high substrate loadings and tolerance to organic solvents are required. This is in general not sufficiently displayed by natural enzymes, despite providing high selectivity and activity on native substrates under physiological conditions. As a solution, enzyme …

Influence Of Feedstock And Operational Conditions On Bio-Chars Derived From The Pyrolysis Of Selected Biomasses, David Chiaramonti, David Casini, Giovanni Ferraro, Emiliano Fratini, Giuditta Pecori, Andrea Maria Rizzo, Luca Rosi

Bio-Char II: Production, Characterization and Applications

The proprieties of bio-char, the solid product from biomass pyrolysis, depends on both the feedstock and process conditions during thermochemical conversion^[1]. As regards the interaction of the char with soil (i.e. as soil amendment), surface areas, size and shape of pores are among the most important factors to be considered.

^[1] P. R. Bonelli , G. Nunell , M. E. Fernández , E. L. Buonomo & A. L. Cukierman

(2012) The Potential Applications of the Bio-char Derived from the Pyrolysis of an Agro-industrial

Waste. Effects of Temperature and Acid-pretreatment, Energy Sources, Part A: Recovery,

Utilization, and Environmental Effects, …

Understanding Promiscuity In Class Ii Pyruvate Aldolases, Ulf Hanefeld, Stefan Marsden, Isabel Bento

Enzyme Engineering XXV

Aldolases are grouped based on their strict donor specificity. To expand the use of these versatile enzymes it is essential to identify aldolases that utilize different donors. Recently a number of pyruvate aldolases that accepted hydroxypyruvate was identified [1]. The class II hydroxy ketoacid aldolase A5VH82 from Sphingomonas wittichii RW1 (SwHKA) accepts hydroxypyruvate and was expressed for detailed studies. A thorough investigation including X-ray crystallography allowed new insights into the mechanistic details. This revealed a phosphate dependence of the enzyme and a preference for Mn (II) [2]. More importantly the substrate scope was studied. SwHKA is promiscuous …

Effect Of Pyrolysis Conditions On Sewage Sludge Derived Biochars For High Value Composites Applications, Paola Giudicianni, Maurizio Troiano, Roberto Solimene, Raffaele Ragucci, Mauro Giorcelli, Alberto Tagliaferro, Mattia Bartoli

Bio-Char II: Production, Characterization and Applications

The economy of the whole wastewater treatment system is significantly burdened by the increasing amounts of sewage sludge due to the progressive implementation of the Urban Waste Water Treatment Directive 91/271/EEC and by the complexity of the treatments required for guaranteeing a safe handling and a proper end-of-life of the sludge. For this reason, thermal treatments of sewage sludge have been studied in the past for their efficient valorization in terms of energy and/or matter recovery. Among them, pyrolysis represents a viable route aiming at the recycling of resources without production of harmful substances to the humans or the environment. …

Biochar Production Though Combined Solar Drying & Single Chamber Pyrolysis, Dirk Weichgrebe, Moni M Mondal, Rahul Ramesh Nair

Bio-Char II: Production, Characterization and Applications

In this study, the challenging management of fibrous organic wastes (FOW) and dewatered municipal sewage sludge (MSS) in urban areas of Asia’s newly industrialised countries is presented with high energy efficiency, negative CO₂ balance and biochar generation. This study investigates the feasibility and benefits of a combined treatment approach for both of the substrates, comprising solar drying (SD) and pyrolysis process (PYR). Based on material investigations, a calculation model is developed to project the material and energy flows of this process combination on the example of Chennai, India.

Please click Additional Files below to see the full abstract.

Experimental Design And Testing In A Pilot-Scale Rotary Kiln For The Torrefaction Of Beech Wood Under System Restrictions, Jorge López-Ordovás, Ibai Funcia-Muguerza, Katie Chong, Javier Gil, Raúl Pérez-Vega, Tony Bridgwater

Bio-Char II: Production, Characterization and Applications

The torrefaction process increases the energy density of the torrefied feedstock through the loss of volatiles and moisture. The anhydrous weight loss (AWL) measures the loss of volatiles and it is easily correlated with the net calorific value (NCV) of the torrefied product.

This work has two different parts. The first part consists of the design of the experiments and the second includes the experiments with results. The system used in CENER, where the simulation and experiments were completed, is a rotary kiln with a maximum capacity of 500 kg/h and a range of operating temperatures between 220-310°C. The innovative …

Bibliometric Survey On Incremental Clustering Algorithms, Archana Chaudhari, Rahul Raghvendra Joshi, Preeti Mulay, Ketan Kotecha, Parag Kulkarni

Library Philosophy and Practice (e-journal)

For clustering accuracy, on influx of data, the parameter-free incremental clustering research is essential. The sole purpose of this bibliometric analysis is to understand the reach and utility of incremental clustering algorithms. This paper shows incremental clustering for time series dataset was first explored in 2000 and continued thereafter till date. This Bibliometric analysis is done using Scopus, Google Scholar, Research Gate, and the tools like Gephi, Table2Net, and GPS Visualizer etc. The survey revealed that maximum publications of incremental clustering algorithms are from conference and journals, affiliated to Computer Science, Chinese lead publications followed by India then United States. …

Volcano Monitoring From Space Using High-Cadence Planet Cubesat Images Applied To Fuego Volcano, Guatemala, Anna Aldeghi, Simon Carn, Rudiger Escobar-Wolf, Gianluca Groppelli

Michigan Tech Publications, Part 1

Fuego volcano (Guatemala) is one of the most active and hazardous volcanoes in the world. Its persistent activity generates lava flows, pyroclastic density currents (PDCs), and lahars that threaten the surrounding areas and produce frequent morphological change. Fuego’s eruption deposits are often rapidly eroded or remobilized by heavy rains and its constant activity and inaccessible terrain makes ground-based assessment of recent eruptive deposits very challenging. Earth-orbiting satellites can provide unique observations of volcanoes during eruptive activity, when ground-based techniques may be too hazardous, and also during inter-eruptive phases, but have typically been hindered by relatively low spatial and temporal resolution. …

Conference Program, Huimin Zhao, John Wong

Enzyme Engineering XXV

No abstract provided.

Conference Program, Franco Berruti, David Chiaramonti, Ondrej Masek, Manuel Garcia-Perez

Bio-Char II: Production, Characterization and Applications

No abstract provided.

Biochar Beyond Carbon Sequestration: Life-Cycle Emission Reductions, Nutrient Recycling And Food Security, Johannes Lehmann

Bio-Char II: Production, Characterization and Applications

Carbon dioxide withdrawal from the atmosphere is increasingly seen as an indispensable approach to mitigate climate change in concert with emission reductions from fossil fuel use. Conversion of biomass into biochar decreases mineralizability by one to two orders of magnitude and typically constitutes half of life-cycle emission reductions of biochar systems focusing on crop or forestry residues. In addition, emission reductions related to changes in nitrous oxide emissions or photosynthesis may contribute to climate change mitigation. While impacts of pyrolyzing carbon-rich crop or forestry residues on greenhouse gas emissions have been widely investigated, less attention has been paid to nutrient-rich …

Inter-Comparison Of Reflectivity Measurements Between Gpm Dpr And Nexrad Radars, Munsung Keem, Bong Chul Seo, Witold F. Krajewski, K. Robert Morris

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

This study demonstrates the potential use of the NASA's Global Precipitation Measurement (GPM) Dual-frequency Precipitation Radar (DPR) to examine ground radar (GR) miscalibration and other uncertainty sources (e.g., partial beam blockage). We acquired the GPM Ground Validation System Validation Network reflectivity matchups between the DPR and three GRs (two in Iowa and one in South Dakota) for 2014–2017. We then refined the matching parameters (e.g., time separation) to reduce uncertainty in the matchup samples by analyzing the sensitivity of the matchup statistical properties to changes in these parameters. To reconcile the same observables (i.e., reflectivity) with different observational properties among …

A Patterning Approach To Complexity Thinking And Understanding For Students: A Case Study, Shae L. Brown

Northeast Journal of Complex Systems (NEJCS)

Complexity thinking and understanding are vital skills for young people in these times of uncertainty and change. Such skills contribute to resilience and capacities for adaptivity and innovation. Within my teaching practice I have found students to be aware of complex dynamics, uncertainty and change, both in their lives and in the world. However, the current curriculum lacks language and process to conceptualise, articulate and develop complexity understanding. To address this problem, I developed and introduced a patterns-based design and process to a cohort of Australian secondary students. Comprising flowform patterning together with ecological metaphors, the design forms a conceptual …