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2019

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Articles 1531 - 1560 of 10505

Full-Text Articles in Engineering

Moving From Walkability? Evaluation Traditional And Merging Data Sources For Evaluating Changes In Campus-Generated Greenhouse Gas Emissions, Troy Kawahara, Bo Liu, Anurag Pande, Calvin Thigpen, Carole Turley Voulgaris Nov 2019

Moving From Walkability? Evaluation Traditional And Merging Data Sources For Evaluating Changes In Campus-Generated Greenhouse Gas Emissions, Troy Kawahara, Bo Liu, Anurag Pande, Calvin Thigpen, Carole Turley Voulgaris

Mineta Transportation Institute

Universities are increasingly committing to reduce campus-generated greenhouse gas emissions, whether voluntarily or in response to a legal mandate. As an initial step to keeping these commitments, universities need an accounting of baseline greenhouse gas emissions levels and means of monitoring changes in campus-generated greenhouse gas emissions over time. Commute-generated greenhouse gas emissions from travel to and from campus by students and employees are among the most difficult to quantify. This report examines some of the challenges associated with estimating campus-generated greenhouse gas emissions and evaluates ways to address those challenges. The purpose of this study is to identify changes …


Investigating The Accuracy Of One-Dimensional Volcanic Plume Models Using Laboratory Experiments And Field Data, James S. Mcneal, Graham Freedland, L. G. Mastin, Raúl Bayoán Cal, S. A. Solovitz Nov 2019

Investigating The Accuracy Of One-Dimensional Volcanic Plume Models Using Laboratory Experiments And Field Data, James S. Mcneal, Graham Freedland, L. G. Mastin, Raúl Bayoán Cal, S. A. Solovitz

Mechanical and Materials Engineering Faculty Publications and Presentations

During volcanic eruptions, model predictions of plume height are limited by the accuracy of entrainment coefficients used in many plume models. Typically, two parameters are used, 𝛼 and 𝛽, which relate the entrained air speed to the jet speed in the axial and cross-flow directions, respectively. To improve estimates of these parameters, wind tunnel experiments have been conducted for a range of cross-wind velocities and turbulence conditions. Measurements are compared directly to computations from the 1-D plume model, Plumeria, in the near-field, bending region of the jet. Entrainment coefficients are determined through regression analysis, demonstrating optimal combinations of effective 𝛼 …


Investigations Of Thermal Treatment Of Softwood Kraft Lignin Under Fractional And Ablative Pyrolytic Conditions, Dideolu J. Daniel Oct 2019

Investigations Of Thermal Treatment Of Softwood Kraft Lignin Under Fractional And Ablative Pyrolytic Conditions, Dideolu J. Daniel

LSU Master's Theses

Lignin is second to cellulose in abundance among polymers in nature. Research studies on the development of new products and material combinations in which lignin degradation/conversion products are involved are still in their infancy, because fundamental knowledge about its structure, reactivity, and material and polymer behavior, is still lacking.

The objective of this research study was to investigate the complex thermal deconstruction and mechanistic behavior of a type of technical lignin, known as Kraft lignin, under depolymerization and to develop operating conditions for parameters influencing resulting product yields and operation of pyrolysis reactors.

Softwood Kraft lignin (s-KL) and methanol-fractionated (ex-KL) …


Bowling Green, Kentucky - Waterworks (Sc 3488), Manuscripts & Folklife Archives Oct 2019

Bowling Green, Kentucky - Waterworks (Sc 3488), Manuscripts & Folklife Archives

Manuscript Collection Finding Aids

Finding aid and full-text scan of documents (Click on "Additional Files" below for Manuscripts Small Collection 3488. “Changes in Plans and Specifications for Water Works Improvements, Contracts Nos. 1 to 5, Incl[usive] for the City of Bowling Green, Bowling Green, Kentucky, December 12, 1947.”


Program Progress Performance Report #5, Missouri University Of Science And Technology. Inspire - University Transportation Center Oct 2019

Program Progress Performance Report #5, Missouri University Of Science And Technology. Inspire - University Transportation Center

Semi-Annual Progress Reports

No abstract provided.


Enhancing Secrecy And Capacity Of Wireless Systems Using Directive Communications, Mohammed A. Hafez Oct 2019

Enhancing Secrecy And Capacity Of Wireless Systems Using Directive Communications, Mohammed A. Hafez

USF Tampa Graduate Theses and Dissertations

The emerging advances in wireless communications make it an essential component of our everyday life. Moreover, the current research aims towards involving wireless communications in health monitoring applications, which helps medical personnel to remotely keep track of the development of the condition of their patients. Such information is considered highly sensitive and may cause significant harm if acquired by an adversary. The wireless environment has a broadcast type of nature, where the emitted electromagnetic waves spread all over the surrounding area of the transmitting antenna. This broadcast nature raises a considerable concern about the secrecy of this sensitive information while …


Thermo-Oxidative Degradation Of Hdpe Geomembranes: Effect Of Phenolic Antioxidant And Hindered Amine Light Stabilizer Concentrations, Yasin Kocak Oct 2019

Thermo-Oxidative Degradation Of Hdpe Geomembranes: Effect Of Phenolic Antioxidant And Hindered Amine Light Stabilizer Concentrations, Yasin Kocak

USF Tampa Graduate Theses and Dissertations

High density polyethylene (HDPE) geomembrane is most common geomembrane which is mainly used for civil engineering applications. However, HDPE geomembrane loses its properties under oxidative degradation progress. This study aims to assess geomembranes which have different percentage of phenolic antioxidant and hindered amine light stabilizer (HALS) with under the six months of the thermal-oxidative degradation. The interactions between phenolic antioxidant, HALS and carbon black can affect the mechanical, physical and chemical properties. To monitor these properties, Differential Scanning Calorimetry (DSC), Fourier-transform Infrared Spectroscopy (FTIR), Thermogravimetric Analysis (TGA), Scanning Electron Microscopy coupled with Energy Dispersive X-ray spectroscopy (SEM/EDX), Melt Index tests, …


Chemolithotrophic Denitrification Of Nitrate Contaminated Groundwater Using Sulfur-Bearing Minerals, John Sutton Oct 2019

Chemolithotrophic Denitrification Of Nitrate Contaminated Groundwater Using Sulfur-Bearing Minerals, John Sutton

USF Tampa Graduate Theses and Dissertations

Nitrate contamination in groundwater resources poses a serious threat, not only to the health of those who would drink it, but also as a potential nutrient for eutrophication. Current methods of nitrate removal can efficiently remove nitrate below 10 mg/L as nitrogen, but may require resources unavailable to small community water systems (SCWS). Sulfur-oxidizing biological denitrification is a promising alternative that may be more suitable for SCWS. Sulfur-oxidizing denitrification has previously been shown to have a high nitrate removal efficiency; however, it produces water high in sulfate. Utilization of sulfide-bearing minerals, rather than elemental sulfur as an electron donor, may …


A Dual-Modality Smartphone Microendoscope For Quantifying The Physiological And Morphological Properties Of Epithelial Tissues, Xiangqian Hong, Tongtong Lu, Liam Fruzyna, Bing Yu Oct 2019

A Dual-Modality Smartphone Microendoscope For Quantifying The Physiological And Morphological Properties Of Epithelial Tissues, Xiangqian Hong, Tongtong Lu, Liam Fruzyna, Bing Yu

Biomedical Engineering Faculty Research and Publications

We report a nonconcurrent dual-modality fiber-optic microendoscope (named SmartME) that integrates quantitative diffuse reflectance spectroscopy (DRS) and high-resolution fluorescence imaging (FLI) into a smartphone platform. The FLI module has a spatial resolution of ~3.5 µm, which allows the determination of the nuclear-cytoplasmic ratio (N/C) of epithelial tissues. The DRS has a spectral resolution of ~2 nm and can measure the total hemoglobin concentration (THC) and scattering properties of epithelial tissues with mean errors of 4.7% and 6.9%, respectively, which are comparable to the errors achieved with a benchtop spectrometer. Our preliminary in vivo studies from a single healthy human subject …


Selection Of Optimal Conditions For The Cultivation Of Insect Cells For Use In Biotechnology, Khasanоv Shuhrat, Sasmakоv Sobir, Abdurakhmanоv Jaloliddin, Ashirоv Оybek Oct 2019

Selection Of Optimal Conditions For The Cultivation Of Insect Cells For Use In Biotechnology, Khasanоv Shuhrat, Sasmakоv Sobir, Abdurakhmanоv Jaloliddin, Ashirоv Оybek

CHEMISTRY AND CHEMICAL ENGINEERING

The article discusses use of the insect cell cultures for biotechnological purposes. Optimal conditions for the cultiva-tion of Spodoptera exigua and Lymantria dispar cell lines were selected.


Development Of A Method Of Oriented Immobilization Of Lipases On A Solid Carrier, Ziyavitdinov Jamolitdin Fazlitdinovich, Inogamov Utkir Kudratillayevich, Berdiev Nodir Sharifovich, Ishimov Uchkun Jomuradovich Oct 2019

Development Of A Method Of Oriented Immobilization Of Lipases On A Solid Carrier, Ziyavitdinov Jamolitdin Fazlitdinovich, Inogamov Utkir Kudratillayevich, Berdiev Nodir Sharifovich, Ishimov Uchkun Jomuradovich

CHEMISTRY AND CHEMICAL ENGINEERING

The methods of oriented immobilization of lipases on a solid carrier - Silochrome C-80 have been developed. The resulting sorbents were tested in the process of obtaining biodiesel from cotton oil. It was shown that immobilized lipase on Silochrome C-80 with NH2 group has the highest transetrification ability and stability, while in sorbents with the enzyme immobilized with -COOH and -SH groups this value was 87 and 53%, respectively. Biocatalysis using an affinity sorbent of immobilized lipase with the –NH2 group has a high operational stability, which, after 240 hours of operation, retains more than 50%, and after 480 hours, …


Study Of Amino-Acid Composition Of Seed Of Oats Fruit (Avena Sativa L.), Nurullaeva Dilobar, Farmanova Nodira Oct 2019

Study Of Amino-Acid Composition Of Seed Of Oats Fruit (Avena Sativa L.), Nurullaeva Dilobar, Farmanova Nodira

CHEMISTRY AND CHEMICAL ENGINEERING

For the first time, the amino acid composition of the seed oat fruit harvested in the Republic of Uzbekistan was stud-ied. Chromatographic detection of amino acids was performed by the method of ascending one-dimensional paper chroma-tography; violet, red-violet and yellow staining was observed, indicating the presence of free amino acids in the raw materi-al under study. The determination of the qualitative and quantitative content of amino acids of oat fruit was carried out by high performance liquid chromatography (HPLC) on an Agilent Technologies 1200 chromatograph, column 75x4.6 mm Discovery HS C18. Qualitative analysis and quantitative calculation of the concentration of …


Research Of Physical And Chemical Indicators And Food Value Of Semi-Finished Products Of Sauce-Past Of Fruits And Vegetables, Atakhanov Shukhrat, Dadamirzaev Muzaffar, Akramboev Rasuljon, Otakhanov Shokirjon Oct 2019

Research Of Physical And Chemical Indicators And Food Value Of Semi-Finished Products Of Sauce-Past Of Fruits And Vegetables, Atakhanov Shukhrat, Dadamirzaev Muzaffar, Akramboev Rasuljon, Otakhanov Shokirjon

CHEMISTRY AND CHEMICAL ENGINEERING

Development of technology for the storage and processing of fruits and vegetables and an increase in the degree of consumption of pro-cessed products among the population is an urgent problem of the present time.Developed recipes for semi-finished sauce-pastes, consisting of fruits, vegetables and their mixtures, the technology of their production. These recipes rationally used sesame of Yerusalem artichoke - secondary raw materials of the canning industry, the powder of the peel of Walnuts, sunflower seeds. Used existing methods for the determination of physical-chemical parameters and nutritional value of semi-finished sauce-paste. A recipe and production technology for a semi-finished product, persim-mon …


Extraction Of The Cotton Cake By The Influence Of Pulse Electric Field, Kayimov Fazliddin, Mazhidov Qahramon Oct 2019

Extraction Of The Cotton Cake By The Influence Of Pulse Electric Field, Kayimov Fazliddin, Mazhidov Qahramon

CHEMISTRY AND CHEMICAL ENGINEERING

The technology of extraction of cotton cake by the influence of a pulsed electric field on the extracted mass is researched. The dependence of the specific conductivity on the inverse temperature using the influence of a pulsed electric field has been estab-lished. The technological process of extraction of vegetable oil is accelerated and an increase in oil yield is ensured.


Development Of A Technology For Producing A Gel Composition For The Treat-Ment Of An Allergy Complicated By Fungal Infection, Filatova Albina Vasilevna, Turaev Abbaskhan Sabirkhanovich, Djurabaev Djalol Turgunbaevich Oct 2019

Development Of A Technology For Producing A Gel Composition For The Treat-Ment Of An Allergy Complicated By Fungal Infection, Filatova Albina Vasilevna, Turaev Abbaskhan Sabirkhanovich, Djurabaev Djalol Turgunbaevich

CHEMISTRY AND CHEMICAL ENGINEERING

The results of the development of the technology of the combined external drug for the treatment of allergies compli-cated by fungal infection are given. The rheological properties of the gel composition were studied in comparison with the similar preparation Fenistil gel, it was shown that the dynamic viscosity of the drug is 4.1 Pa·s, the active components (diphenylhydramine, fluconazole, Timoptin) do not destroy the structure of the gel base. A technological and instrumental scheme for the production of the drug has been developed.


Properties Of Model Rubber Compounds With Modified Angren Kaolin, Vapaev Murodjon Dusummatovih, Teshabaeva Elmira Ubaydullaevna, Ibadullaev Ahmadjon Oct 2019

Properties Of Model Rubber Compounds With Modified Angren Kaolin, Vapaev Murodjon Dusummatovih, Teshabaeva Elmira Ubaydullaevna, Ibadullaev Ahmadjon

CHEMISTRY AND CHEMICAL ENGINEERING

As a result of studies, the effect of modified Angren kaolin on the properties of elastomeric compositions based on synthetic polyisoprene and oil-filled styrene-butadiene rubbers were revealed. Plastoelastic and relaxation properties, as well as resistance to scorching and vulcanization kinetics of rubber compounds with traditional and modified Angren kaolin, were determined. The relationship of the elastic-strength properties of vulcanizates with the type and quantitative content of the modified Angren kaolin used is established.


Gasification Of Pelletized Corn Residues With Oxygen Enriched Air And Steam, Poramate Sittisun, Nakorn Tippayawong, Sirivatch Shimpalee Oct 2019

Gasification Of Pelletized Corn Residues With Oxygen Enriched Air And Steam, Poramate Sittisun, Nakorn Tippayawong, Sirivatch Shimpalee

Faculty Publications

This work studied generation of producer gas using oxygen-enriched air and steam mixture as gasifying medium. Corn residues consisting of cobs and stover were used as biomass feedstock. Both corn residues were pelletized and gasified separately with normal air, oxygen enriched air and steam mixture in a fixed bed reactor. Effects of oxygen concentration in enriched air (21-50%), equivalence ratio (0.15-0.35), and steam to biomass ratio (0-0.8) on the yield of product gas, the combustible gas composition such as H2, CO, and CH4, the lower heating value (LHV), and the gasification efficiency were investigated. It was found that the decrease …


How To Create And Maintain An Effective Information Architecture And Navigation System For Science Gateway Websites, Noreen Y. Whysel, Omni Marketing Interactive Oct 2019

How To Create And Maintain An Effective Information Architecture And Navigation System For Science Gateway Websites, Noreen Y. Whysel, Omni Marketing Interactive

Publications and Research

Whether you have an existing Science Gateway website or are creating your first one, this hands-on tutorial will show you, step by step, how to create and update gateway websites so that their content is easier to find and easier to use.

As a Science Gateway provides its web-based tools and resources, it is essential that these sites utilize specific usability tests and other research methods to ensure positive and productive experiences with the sites. Successful information architecture (IA), intuitive site navigation, and clear user interfaces (UIs) all rely on knowing where various users expect to find needed information.

Since …


Cleared To Land: Pilot Visual Detection Of Small Unmanned Aircraft During Final Approach, Ryan J. Wallace, Samuel M. Vance, Jon M. Loffi, Jamey Jacob, Jared C. Dunlap, Taylor A. Mitchell, Robert Thomas, Seabrook R. Whyte Oct 2019

Cleared To Land: Pilot Visual Detection Of Small Unmanned Aircraft During Final Approach, Ryan J. Wallace, Samuel M. Vance, Jon M. Loffi, Jamey Jacob, Jared C. Dunlap, Taylor A. Mitchell, Robert Thomas, Seabrook R. Whyte

International Journal of Aviation, Aeronautics, and Aerospace

Sighting reports of unmanned aircraft systems (UAS) by pilots, air traffic controllers, and other aviation stakeholders have continued to rise since the Federal Aviation Administration (FAA) began tracking in 2014. In 2018, the FAA received 2,307 such reports, with 22.8% (n = 526) occurring during the final approach phase of flight. The threat of a midair collision between a manned aircraft and UAS is heightened during the final approach phase of flight, as the aircraft transitions from higher-altitude airspace to the low-altitude arena, now shared with drones. Absent UAS sense and avoid systems, pilots are forced to rely on …


Morphometry And Density Analysis Of The Fifth Metacarpal, Amrita Unnikumaran Oct 2019

Morphometry And Density Analysis Of The Fifth Metacarpal, Amrita Unnikumaran

USF Tampa Graduate Theses and Dissertations

The fifth metacarpal bone fracture is a common type of fracture among the young male population. With the increasing demand for early recovery from such fractures with surgical reduction, the medical manufacturers and clinicians are interested in designing a better intramedullary device for fixation. This study is an attempt to investigate the dimensional parameters of the fifth metacarpal bone and its intramedullary canal, using 3D CT scan images of cadaveric hands. The algorithm used for measurement applies principal component analysis on the subject bone, to control the information loss and normalize the spatial position of the subject. This analysis provides …


Factors Influencing Retirement Decision Making For Louisiana State Government Employees, Osama A. Amous Oct 2019

Factors Influencing Retirement Decision Making For Louisiana State Government Employees, Osama A. Amous

LSU Doctoral Dissertations

ABSTRACT

Public pension members continually face factors affecting their decision to retire in the changing American society. Workers are living longer and need more medical care with better retirement benefits. For Louisiana public employees specifically, no prior studies have examined the factors affecting workers’ decision to retire nor evaluated the factors impacting workers’ decision.

This multiphase study aimed to identify factors and evaluate the decision-making process that enables Louisianans to retire happily and satisfied with a guaranteed income, and to examine millennials’ decision-making process. In the initial phase, ten active and retired male and female participants answered questions in-person, leading …


Spatio-Temporal Variability Of Drought In Pakistan Using Standardized Precipitation Evapotranspiration Index, Shoaib Jamro, Ghulam Hussain Dars, Kamran Ansari, Nir Krakauer Oct 2019

Spatio-Temporal Variability Of Drought In Pakistan Using Standardized Precipitation Evapotranspiration Index, Shoaib Jamro, Ghulam Hussain Dars, Kamran Ansari, Nir Krakauer

Publications and Research

Pakistan is among the top ten countries adversely affected by climate change. More specifically, there is concern that climate change may cause longer and severer spells of droughts. To quantify the change in the characteristics of droughts in Pakistan over the years, we have evaluated spatio-temporal trends of droughts in Pakistan over the period 1902–2015 using Standardized Precipitation Evapotranspiration Index (SPEI). Additionally, the Spatial “K” luster Analysis using Tree Edge Removal (SKATER) method was employed to regionalize droughts into five contiguous zones. The run theory was then applied to each zone to identify drought events and characterize them in terms …


Proppant For Use In Hydraulic Fracturing To Stimulate A Well, Thomas Lee Robl, Anne Elizabeth Oberlink Oct 2019

Proppant For Use In Hydraulic Fracturing To Stimulate A Well, Thomas Lee Robl, Anne Elizabeth Oberlink

Center for Applied Energy Research Faculty Patents

A proppant for use in hydraulic fracturing to stimulate a well is provided. The proppant is fly ash particles having a mean particle size (d50) of between 45 μm and 150 μm and a size distribution defined by (d10) ≤ 5 μm and (d98) ≤ 250 μm.


Impact Of The Number Of Lane-Changing Times On Throughput By Fundamental Diagram Based On Ngsim Data, Gangyan Zhang Oct 2019

Impact Of The Number Of Lane-Changing Times On Throughput By Fundamental Diagram Based On Ngsim Data, Gangyan Zhang

USF Tampa Graduate Theses and Dissertations

In the present report, the characteristics of the fundamental diagram (FD) are exploited to delve into the effect of the number of times of lane changes on traffic throughput. The NGSIM data are classified and screened by splitting the regions of US-101 and I-80; the relevant traffic variables (e.g., traffic flow, density and speed) are calculated. Appropriate statistical approaches are employed to verify the correlation of the impact of lane changes on different traffic variables. Lane changes could affect traffic throughput in light congestion instead of in heavy congestion. The causes of the effects of lane changes on throughput are …


Design And Measurement Of Strongarm Comparators, Nathan Robert Whitehead Oct 2019

Design And Measurement Of Strongarm Comparators, Nathan Robert Whitehead

Theses and Dissertations

The StrongARM comparator is utilized in many analog-to-digital converters (ADCs) because of its high power efficiency and rail-to-rail outputs. The performance of the comparator directly affects the speed, power, and accuracy of an ADC. However, the StrongARM comparator performance parameters such as delay, noise, and offset measured directly from silicon prototypes are rare in literature and often consist of small sample sets. In addition, existing techniques to measure the comparator require large chip areas, making it impractical to characterize a large number of comparators to obtain stochastic parameters such as offset and noise. This work presents novel circuit techniques to …


Modeling Of Buildings With Electrochromic Windows And Thermochromic Roofs, Hua-Ting Kao Oct 2019

Modeling Of Buildings With Electrochromic Windows And Thermochromic Roofs, Hua-Ting Kao

USF Tampa Graduate Theses and Dissertations

Air conditioning and heating have increased substantially during the past two decades. According to a survey, buildings consume about 73% of the total electricity in the United States, accounting for 41% of all other energy in the world. At the same time, building skin technologies are constantly improving. Electrochromic and thermochromic are two exciting new technologies that can help reduce the energy consumption of a building. The purpose of this work is to increase our understanding of how much the use of electrochromic (EC) and thermochromic (TC) technologies can reduce the energy consumption of residential and commercial buildings in two …


Unidirectional And Nonreciprocal Nanophotonic Devices Based On Graphene And Magneto-Optical Materials, Vahid Foroughi Nezhad Oct 2019

Unidirectional And Nonreciprocal Nanophotonic Devices Based On Graphene And Magneto-Optical Materials, Vahid Foroughi Nezhad

LSU Doctoral Dissertations

In this dissertation, we first introduce compact tunable spatial mode converters for graphene parallel plate (GPP) waveguides. The converters are reciprocal and based on spatial modulation of graphene’s conductivity. The wavelength of operation of the mode converters is tunable in the mid-infrared wavelength range by adjusting the chemical potential of a strip on one of the graphene layers of the GPP waveguides. We also introduce optical diodes for GPP waveguides based on a spatial mode converter and a coupler, which consists of a single layer of graphene placed in the middle between the two plates of two GPP waveguides. \par …


Synthesis And Analysis Of Separation Processes For Extracellular Chemicals Generated From Microbial Conversions, Wenzhao Wu, Kirti Maheshkumar Yenkie, Christos T. Maravelias Oct 2019

Synthesis And Analysis Of Separation Processes For Extracellular Chemicals Generated From Microbial Conversions, Wenzhao Wu, Kirti Maheshkumar Yenkie, Christos T. Maravelias

Henry M. Rowan College of Engineering Departmental Research

Recent advances in metabolic engineering have enabled the production of chemicals via bio-conversion using microbes. However, downstream separation accounts for 60–80% of the total production cost in many cases. Previous work on microbial production of extracellular chemicals has been mainly restricted to microbiology, biochemistry, metabolomics, or techno-economic analysis for specific product examples such as succinic acid, xanthan gum, lycopene, etc. In these studies, microbial production and separation technologies were selected apriori without considering any competing alternatives. However, technology selection in downstream separation and purification processes can have a major impact on the overall costs, product recovery, and purity. To this …


Three-Dimensional Porous Vn Octahedron Catalyst With High Electrocatalytic Efficiency Toward Hydrogen Evolution Reaction, Can Yin, Wei-Wei Fu, Ling Fang, Shi-Li You, Hui-Juan Zhang, Yu Wang Oct 2019

Three-Dimensional Porous Vn Octahedron Catalyst With High Electrocatalytic Efficiency Toward Hydrogen Evolution Reaction, Can Yin, Wei-Wei Fu, Ling Fang, Shi-Li You, Hui-Juan Zhang, Yu Wang

Journal of Electrochemistry

With the rapid development of China’s economy, the demand for energy is increasing, and environmental problems are becoming more and more serious. The development and utilization of highly-clean new energy fuel can effectively alleviate the energy crisis and environmental pollution. Nowadays, exploring high-efficiency, environment-friendly and low-cost catalysts remains the focus of research in the hydrogen evolution reaction (HER). In this research, firstly, we proposed a three-dimensional porous vanadium nitride (VN) with octahedral structure, which was prepared by a calcination treatment method. The VN catalyst showed a good electrocatalytic activity toward HER, involving a small overpotential of 94.0 mV at -10 …


Influences Of Morphology And Nitrogen Doping On The Electrocatalytic Characteristics For Oxygen Reduction Reaction Of Nio/Rgo, Dong Liang, Heng-Yi Fang, Shuo Yao, Jie-Mei Yu, Zhao-Liang Zhang, Zhan-Kun Jiang, Xue-Ping Gao, Tai-Zhong Huang Oct 2019

Influences Of Morphology And Nitrogen Doping On The Electrocatalytic Characteristics For Oxygen Reduction Reaction Of Nio/Rgo, Dong Liang, Heng-Yi Fang, Shuo Yao, Jie-Mei Yu, Zhao-Liang Zhang, Zhan-Kun Jiang, Xue-Ping Gao, Tai-Zhong Huang

Journal of Electrochemistry

In this research, the reduced graphene oxide (rGO) supported sheet-like NiO (NiO/rGO) and spherical-like NiO (NiO/N-rGO) catalysts for oxygen reduction reaction (ORR) were prepared. The structures, morphologies and chemical states of the two catalysts were characterized by X-ray diffraction (XRD), Raman spectroscopy, X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The electrochemical catalytic performance of the two catalysts for ORR were investigated by cyclic voltammetry (CV), Tafel, linear sweeping voltammetry (LSV), rotating disc electrode (RDE) and rotating ring disc electrode (RRDE) tests. Electrochemical results showed that the current density and onset potential (about 0.89 V) …