Engineering Commons^™

Preparation Of Benzoxazine Monomers And Prepolymers From Continuous Reactor: Effects Of Molecular Architecture On Properties, Andrew S. Frazee

Dissertations

Despite the modularity in molecular design and high-performance properties of benzoxazine thermoset chemistries, there are two primary shortcomings of benzoxazine marketability. Firstly, multifunctional benzoxazines are unfavorable for processing as they are glassy solids at ambient temperature. Secondly, benzoxazine chemistries are commercially synthesized using batch reactors, which are energy intensive and require the use of environmentally unfavorable solvents.

The purpose of the work herein is to address these shortcomings, which include:

1.) interrelationships between molecular architectures of synthesized monofunctional benzoxazine monomers and their ambient temperature physical states (i.e. liquid or solid) using molecular dynamics simulations and experimental comparisons,

2.) continuous high-shear …

A Data Hiding Scheme Based On Chaotic Map And Pixel Pairs, Sengul Dogan Sd

Journal of Digital Forensics, Security and Law

Information security is one of the most common areas of study today. In the literature, there are many algorithms developed in the information security. The Least Significant Bit (LSB) method is the most known of these algorithms. LSB method is easy to apply however it is not effective on providing data privacy and robustness. In spite of all its disadvantages, LSB is the most frequently used algorithm in literature due to providing high visual quality. In this study, an effective data hiding scheme alternative to LSB, 2LSBs, 3LSBs and 4LSBs algorithms (known as xLSBs), is proposed. In this method, random …

Generalized Ellipsometry On Complex Nanostructures And Low-Symmetry Materials, Alyssa Mock

Department of Electrical and Computer Engineering: Dissertations, Theses, and Student Research

In this thesis, complex anisotropic materials are investigated and characterized by generalized ellipsometry. In recent years, anisotropic materials have gained considerable interest for novel applications in electronic and optoelectronic devices, mostly due to unique properties that originate from reduced crystal symmetry. Examples include white solid-state lighting devices which have become ubiquitous just recently, and the emergence of high-power, high-voltage electronic transistors and switches in all-electric vehicles. The incorporation of single crystalline material with low crystal symmetry into novel device structures requires reconsideration of existing optical characterization approaches. Here, the generalized ellipsometry concept is extended to include applications for materials with …

An Unmanned Aerial System For Prescribed Fires, Evan M. Beachly

School of Computing: Dissertations, Theses, and Student Research

Prescribed fires can lessen wildfire severity and control invasive species, but some terrains may be difficult, dangerous, or costly to burn with existing tools. This thesis presents the design of an unmanned aerial system that can ignite prescribed fires from the air, with less cost and risk than with aerial ignition from a manned aircraft. The prototype was evaluated in-lab and successfully used to ignite interior areas of two prescribed fires. Additionally, we introduce an approach that integrates a lightweight fire simulation to autonomously plan safe flight trajectories and suggest effective fire lines. Both components are unique in that they …

Analytical Modeling Of A Communication Channel Based On Subthreshold Stimulation Of Neurobiological Networks, Alireza Khodaei

School of Computing: Dissertations, Theses, and Student Research

The emergence of wearable and implantable machines manufactured artificially or synthesized biologically opens up a new horizon for patient-centered health services such as medical treatment, health monitoring, and rehabilitation with minimized costs and maximized popularity when provided remotely via the Internet. In particular, a swarm of machines at the scale of a single cell down to the nanoscale can be deployed in the body by the non-invasive or minimally invasive operation (e.g., swallowing and injection respectively) to perform various tasks. However, an individual machine is only able to perform basic tasks so it needs to exchange data with the others …

A Novel Approach To Assess Minimally Invasive Surgical Device Failure Utilizing Adverse Event Outcome Severity And Design Complexity., Marie K. Riggs

Electronic Theses and Dissertations

Medical device failure and misuse have the potential to cause serious injury and death. Given the intricate nature of the instruments utilized specifically in minimally invasive surgery (MIS), users and manufacturers of surgical devices share a responsibility in preventing user error and device failure. A novel approach was presented for the evaluation of minimally invasive device failures, which involved assessing the severity of adverse event outcomes associated with the failures modes and investigating aspects of the devices’ design that may contribute to failure. The goals of this research were to 1) characterize the design attributes, failure modes, and adverse events …

Implementing The Heston Option Pricing Model In Object-Oriented Cython, Brandon Hardin

All Graduate Plan B and other Reports, Spring 1920 to Spring 2023

The 1973 Black-Scholes model, a revolutionary option pricing formula whose price is 'relatively close to observed prices, makes an assumption that the volatility is constant and thus, deterministic. This causes some inefficiencies and patterns in the pricing of options due to the model providing evidence of the volatility smile' of the volatility. Many scholars have suggested that the volatility should be modelled by a stochastic process and the (1993) Heston Model is one of many proposed solutions to remedy this problem. The Heston Model allows for the 'smile' by defining the volatility as a stochastic process. This thesis considers a …

Des And Tdes Performance Evaluation For Non-Pipelined And Pipelined Implementations In Vhdl Using The Cyclone Ii Fpga Technology, Edni Del Rosal

Theses and Dissertations

Two ongoing issues that engineers must face in the new era of data analytics are performance and security. Field Programmable Gate Arrays (FPGAs) offer a new solution for optimizing the performance of applications while the Data Encryption Standard (DES) and the Triple Data Encryption Standard (TDES) offer a mean to secure information. In this thesis we present a Non-Pipelined and Pipelined, in Electronic Code Book (EBC) mode, implementations in VHDL of these two commonly utilized cryptography schemes. Using Altera Cyclone II FPGA as our platform, we design and verify the implementations with the EDA tools provided by Altera. We gather …

Single Tower Crane Allocation Models Using Ant Colony Optimization, Carlos Abelardo Treviño

Theses and Dissertations

The construction industry greatly benefits from the utilization of heavy machines and equipment to accomplish successful projects. Tower cranes, in specific, have a crucial role in the transportation of material loads across the site. Because these machines are fixed to the ground, it is essential for planners and managers to position them in a location that provides the most efficient transfer of materials possible. This is commonly known as the tower crane allocation problem, and many researchers have attempted to optimize the tower crane location using mathematical, artificial intelligence, and simulation approaches. However, many works from the literature contain critical …

Pubwc Bathroom Review App, Clay Jacobs

Computer Science and Software Engineering

For my senior project, I developed an iOS application to allow users to find, rate, and review nearby public restrooms. The app takes advantage of crowdsourced data to collect bathroom and review information. I also created a REST API to interface with the backend database that could be used to port the application to other platforms.

Development Of An Insulated Solar Electric Cooker (Isec) With Thermal Storage For Use In Developing World Countries, Amanda Gyokery, Spencer W. Davis, Kyle Henry Smit

Mechanical Engineering

According to the World Health Organization, about half of the world’s population uses biomass stoves to cook their meals. However, biomass fires can be dangerous. Unattended biomass fires and indoor air pollution are responsible for an estimated 600,000 deaths annually and the creation of approximately 4 million instances of chronic disease. They also release CO2 and other pollutants into the air, and require the families to gather enough material to keep it burning (WHO 2017). Although cleaner cooking technology seems like a clear solution, often families are either unwilling to change how they cook food or are unable to afford …

Eigenblades: Application Of Computer Vision And Machine Learning For Mode Shape Identification, Alex W. La

Theses and Dissertations

On August 27, 2016, Southwest Airlines flight 3472 from New Orleans to Orlando had to perform an emergency landing when a fan blade separated from the engine hub and destroyed the cowling and punctured the fuselage. Initial findings from the metallurgical examination conducted in the National Transpiration Safety Board Materials Laboratory found that the fracture surface of the missing blade showed curving crack arrest lines consistent with fatigue crack growth. Fatigue is often cause by resonate vibrations. Modal analysis is a method that can model the natural frequencies and bending modes of turbomachinery blades. When performing modal analysis with finite …

Viscoelastic Behavior Of Carbon Fiber Reinforced Polymer Composites Incorporating Nanomaterials, Amy R. Garner

Civil Engineering ETDs

Carbon fiber reinforced polymer (CFRP) composites are increasingly being used in a variety of industries such as aerospace and infrastructure. This investigation experimentally examines the effect of incorporating alumina nanoparticles (ANPs), non-functionalized multi-walled carbon nanotubes (NF-MWCNTs), and functionalized multi-walled carbon nanotubes (F-MWCNTs) on the off-axis stiffness and stress-relaxation of carbon fiber reinforced polymer (CFRP) composites. Epoxy- nanocomposites incorporating 0.0, 1.0, 2.0, and 3.0 wt.% ANPs; 0.0 0.5, 1.0, and 1.5 wt. % NF-MWCNTs; 0.0 0.5, 1.0, and 1.5 wt. % F-MWCNTs of the total weight of epoxy are examined. Off-axis tension stiffness and stress-relaxation tests were performed on CFRP coupons …

Design And Development Of An Electronic Granular Urea Applicator As An Attachment With Rice Transplanter, Md Towfiqur Rahman

Department of Agricultural and Biological Systems Engineering: Dissertations, Theses, and Student Research

In rice production system, transplanting and fertilizer application are tedious, time consuming and laborious task, and mostly done manually in Bangladesh. Mechanical planting of rice and granular urea placement have distinctive advantages over manual operation. Mechanical planting of rice becoming popular in the country in recent years and few machines have been developed for guti-urea deep placement, however having some limitations. Considering precise guti-urea placement along with rice transplanting, an attempt was under taken to design and fabricate an electronic control guti-urea applicator to be attach with a 4-row walk behind type rice transplanter. Fabrication of the electronic guti-urea applicator …

Performance Assessment Of Electromagnetic Soil Water Sensors In Different Soil Textural, Temperature, And Salinity Conditions, Jasreman Singh

Department of Agricultural and Biological Systems Engineering: Dissertations, Theses, and Student Research

Determination of accurate and continuous measurements of volumetric water content (θ_v) is extremely valuable for irrigation management and other agronomic decisions. Lately, electromagnetic (EM) sensors are being widely used to monitor θ_v continuously which also offer the benefits of ease of installation, fewer regulatory and safety concerns, and cost effectiveness. However, the accuracy of parameters [soil temperature, electrical conductivity (EC_a), dielectric permittivity (ε_ra), and θ_v] reported by EM sensors need to be evaluated for them to be utilized for agricultural water management. In the current study, the accuracy of a wide …

Analyzing The Fundamental Aspects And Developing A Forecasting Model To Enhance The Student Admission And Enrollment System Of Msom Program, Sultanul Nahian Hasnat

Graduate Theses and Dissertations

A forecasting model, associated with predictive analysis, is an elementary requirement for academic leaders to plan course requirements. The M.S. in Operations Management (MSOM) program at the University of Arkansas desires to understand future student enrollment more accurately. The available literature shows that there is an absence of forecasting models based on quantitative, qualitative and predictive analysis. This study develops a combined forecasting model focusing on three admission stages. The research uses simple regression, Delphi analysis, Analysis of Variance (ANOVA), and classification tree system to develop the models. It predicts that 272, 173, and 136 new students will apply, matriculate …

Heterogenization Of Complexes With Redox Active Ligands For Hydrogen Evolution Reaction., Wuyu Zhang

Electronic Theses and Dissertations

Hydrogen fuel is a promising future energy carrier with many applications. Thermodynamically, 1.23 V is needed for the water electrolysis, which is a clean method to generate hydrogen gas. In practice excess potential is required, which is called overpotential, due to kinetic barriers. Catalysts to reduce the overpotential for the hydrogen evolution reaction (HER) include many homogeneous catalysts and heterogeneous catalysts. Heterogenization of homogeneous catalysts on electrode surfaces is an ideal way to study a catalyst by combining homogeneous and heterogeneous study together. In this dissertation, several characterization techniques have been employed, include cyclic voltammetry, linear sweep voltammetry, electrochemical impedance …

Design, Analysis, And Application Of A Cellular Material/Structure Model For Metal Based Additive Manufacturing Process., Shanshan Zhang

Electronic Theses and Dissertations

Powder bed fusion additive manufacturing (PBF-AM) has been broadly utilized to fabricate lightweight cellular structures, which have promising potentials in many engineering applications such as biomedical prosthesis, aerospace, and architectural structures due to their high performance-to-weight ratios and unique property tailorabilities. To date, there is still a lack of adequate understanding of how the cellular materials are influenced by both the geometry designs and process parameters, which significantly hinders the effective design of cellular structures fabricated by PBF-AM for critical applications. This study aims to demonstrate a cellular structure design methodology that integrates geometrical design and process-material property designs. Utilizing …

Fused Filament Fabrication 3d Printing Using Low-Melting Alloys., Nirupama Warrier

Electronic Theses and Dissertations

Fused Filament Fabrication (FFF) 3D printing technology has been a popular method of creating prototypes using plastics in the timeliest and most affordable manner for electronic, automotive, and biomedical applications. 3D printing of metals and alloys using FFF technology could provide low-cost alternatives and solutions to the Laser-Powder Bed Fusion Process (L-PBF) and Binder Jetting processes (BJ). In current work, low melting alloys have been used as a starting material and evaluated for FFF 3D printing using two methodologies. In the first methodology, Sn60Bi40 alloy in the form of wire was used as the feedstock for FFF extrusion and process …

A Framework For Clustering And Adaptive Topic Tracking On Evolving Text And Social Media Data Streams., Gopi Chand Nutakki

Electronic Theses and Dissertations

Recent advances and widespread usage of online web services and social media platforms, coupled with ubiquitous low cost devices, mobile technologies, and increasing capacity of lower cost storage, has led to a proliferation of Big data, ranging from, news, e-commerce clickstreams, and online business transactions to continuous event logs and social media expressions. These large amounts of online data, often referred to as data streams, because they get generated at extremely high throughputs or velocity, can make conventional and classical data analytics methodologies obsolete. For these reasons, the issues of management and analysis of data streams have been researched extensively …

Material Properties Design Using Simulations And Experiments For Powder Injection Molding Of Lead Zirconate Titanate (Pzt)., Bhushan Pramod Bandiwadekar

Electronic Theses and Dissertations

Powder injection molding (PIM) process simulations can be performed to minimize the number of injection molding experiments by estimating material properties necessary for PIM simulations. In current work, lead zirconate titanate (PZT) powder-polymer binder feedstock was compounded for 45 vol. % and 52 vol. % solids loading. PIM experiments on designed micro-pillar array geometry were performed using 52 vol. % PZT. Using PIM experiments results as basis, PIM simulations were performed on designed micro-pillar array geometries to understand the effectiveness of PIM simulations with the use of estimated feedstock properties in predicting molding behavior that have micro-features. Additionally, PIM simulations …

Queue Stability Analysis In Network Coded Wireless Multicast., Nadieh Mohamadi-Moghadam

Electronic Theses and Dissertations

In this dissertation queue stability in wireless multicast networks with packet erasure channels is studied. Our focus is on optimizing packet scheduling so as to maximize throughput. Specifically, new queuing strategies consisting of several sub-queues are introduced, where all newly arrived packets are first stored in the main sub-queue on a first-come-first-served basis. Using the receiver feedback, the transmitter combines packets from different sub-queues for transmission. Our objective is to maximize the input rate under the queue stability constraints. Two packet scheduling and encoding algorithms have been developed. First, the optimization problem is formulated as a linear programming (LP) problem, …

Control Of Power Electronic Interfaces In Distributed Generation., Mohammad Mohebbi

Electronic Theses and Dissertations

Renewable energy has gained popularity as an alternative resource for electric power generation. As such, Distributed Generation (DG) is expected to open new horizons to electric power generation. Most renewable energy sources cannot be connected to the load directly. Integration of the renewable energy sources with the load has brought new challenges in terms of the system’s stability, voltage regulation and power quality issues. For example, the output power, voltage and frequency of an example wind turbine depend on the wind speed, which fluctuate over time and cannot be forecasted accurately. At the same time, the nonlinearity of residential electrical …

Artificial Olfactory System For Multi-Component Analysis Of Gas Mixtures., Alexander Aleksandrovich Larin

Electronic Theses and Dissertations

Gas analysis is an important part of our world and gas sensing technology is becoming more essential for various aspects of our life. A novel approach for gas mixture analysis by using portable gas chromatography in combination with an array of highly integrated and selective metal oxide (MOX) sensors has been studied. We developed a system with small size (7 x 13 x 16 inches), low power consumption (~10 W) and absence of special carrier gases designed for portable field analysis (assuming apriori calibration). Low ppb and even sub-ppb level of detection for some VOCs was achieved during the analysis …

Testing And Modeling Of The Thixotropic Behavior Of Cementitious Materials., Bashir Hasanzadeh

Electronic Theses and Dissertations

During construction, concrete goes under various operations. It is normally transported to the job site, be placed and consolidated in the formwork, etc. The easiness and quality of these operations are very much related to the intrinsic rheological properties of concrete. Therefore, a good understanding of rheological behavior of concrete under various conditions are needed. Thixotropy is an important part of rheology. The thixotropic behaviors of concrete can be good representatives of its flow behaviors on the job site. For example, the breakdown aspect of thixotropy can help to explain how its flow behavior can impact concrete pumping and its …

High Throughput Phenotyping Of Sorghum For The Study Of Growth Rate, Water Use Efficiency, And Chemical Composition, Piyush Pandey

Department of Agricultural and Biological Systems Engineering: Dissertations, Theses, and Student Research

Plant phenotyping using digital images has increased the throughput of the trait measurement process, and it is considered to be a potential solution to the problem of the phenotyping bottleneck. In this study, RGB images were used to study relative growth rate (RGR) and water use efficiency (WUE) of a diverse panel of 300 sorghum plants of 30 genotypes, and hyperspectral images were used for chemical analysis of macronutrients and cell wall composition. Half of the plants from each genotype were subjected to drought stress, while the other half were left unstressed. Quadratic models were used to estimate the shoot …

Thermodynamic Limitations To Agricultural Productivity And Food Security: Livestock In Sub-Saharan Africa, Calvin Harman

Department of Agricultural and Biological Systems Engineering: Dissertations, Theses, and Student Research

By 2050, to feed a nearly tripling and more urbanized population in sub-Saharan Africa (SSA) will require significant increases in crop productivity throughout the region’s agricultural systems, if a greater reliance on imports is to be avoided. Increases in crop yields to maximum potential productivity (closure of crop yield gaps) can produce more calories and protein, but may be insufficient to sustain the burgeoning human population according to recent analysis (van Ittersum et al., 2016). In this thesis, alternative management options (i.e. crop allocation and crop substitutions) are found to increase total energy productivity and the thermodynamic efficiency of food …

Cultivation Of Chlorella Sorokiniana Using Beef Feedlot Runoff Holding Pond Effluent, Mitchell Klaus Goedeken

Department of Agricultural and Biological Systems Engineering: Dissertations, Theses, and Student Research

A study was conducted to test the suitability of utilizing beef feedlot runoff holding pond effluent for cultivating algae. The algae strain used, Chlorella sorokiniana, was previously identified as a potential energy feedstock for cattle. The previous research was initiated in pursuit of a goal to develop a cycle of utilizing nutrients from beef manure to cultivate algae and then utilizing dewatered algae as a feed supplement for beef cattle.

Runoff holding pond effluent samples were collected from commercial beef production operations in Nebraska during spring 2016. Equal portions of samples from each cooperating farm were composited and then aliquoted …

Use Of Long Term Weather Data And Spatially Delineated Field Attributes To Predict Water And Energy Conservation From Variable Rate Irrigation, Sahil Sharma

Department of Agricultural and Biological Systems Engineering: Dissertations, Theses, and Student Research

The declining levels of the Ogallala aquifer calls for more judicious use of water. Studies have shown that VRI has the potential for water savings. But adoption of VRI is still very low. The major reason is lack of information on the returns from the VRI systems and its feasibility in different fields. Also, a quantification of the required reduction in prices of VRI is necessary. So, an economic return analysis of VRI strategies was done to compare it to uniform irrigation management (UIM) using a water balance model based on long term weather data and field properties for a …

A High Quality And Quantity Hybrid Perovskite Quantum Dots (Cspbx3, X= Cl, Br And I) Powders Synthesis Via Ionic Displacement, Yuhang Yin, Weiling Luan, Chengxi Zhang, Fuqian Yang

Chemical and Materials Engineering Faculty Publications

Recently, all-inorganic perovskites CsPbX₃ (X= Cl, Br and I) quantum dots (QDs) have drawn great attentions because of their PL spectra tunable over the whole visible spectral region (400-700 nm) and adjustable bandgap, which revealed a promising potential on the field of photoelectronic devices, such as solar cells, LEDs and sensors. In this paper, CsPbX₃ QDs and hybrid QDs, CsPbClxBr3-x and CsPbBrxI3-x were synthesized via one-step and two-step methods comparably. The optical bandgaps of CsPbCl₃, CsPbBr₃, and CsPbI₃, were calculated as 3.08, 2.36, and 1.73eV, respectively, based on the Tauc's equation and …