Energy Systems Commons^™

Challenges And Opportunities Of Layered Cathodes Of Linixmnyco(1-X-Y)O2 For High-Performance Lithium-Ion Batteries, Jason Frank

Mechanical Engineering Undergraduate Honors Theses

High energy density lithium-ion batteries (LIBs) are widely demanded for portable electronic devices and electrical vehicles. Layered-structure LiCoO₂ oxide (LCO) has been the most commonly used cathode material in commercial LIBs. Compared to LCO, LiNi_1-x-yMn_xCo_yO₂ (NMC) cathodes are particularly attractive due to their reduced cost and higher capacity. Among the NMC cathodes, nickel-containing LiNi_0.5Co_0.3Mn_0.2O₂ (NMC532) is one of the most promising cathode materials undergoing intensive investigation, but suffers from a series of technical issues, such as structural instability, performance fading, and safety issues. In this …

Bgaas Alloy Semiconductors For Lasers On Silicon, Joshua Mcarthur

Mechanical Engineering Undergraduate Honors Theses

In the world of semiconductors today, there is a large dissonance between optical devices and electrical application. Due to the limitations of electron transport, photonic integrated circuits are soon-to-be vital in fields like telecommunications and sensing. Right now, these PIC’s are mostly made from indium phosphide. Due to its ubiquitous nature, however, there is a huge push to integrate efficient optics with silicon. It’s cheap, abundant, dope-able, and our electronic infrastructure is based on it. The reason why silicon photonics aren’t already commercialized is because of silicon’s indirect bandgap—it is inefficient with optical applications. The problem with combining direct gap …

The Design Of An Innovative Automotive Suspension For Formula Sae Racing Applications, Jared Darius

Senior Honors Theses

This thesis details an analytical approach to an innovative suspension system design for implementation to the Formula SAE collegiate competition. It focuses specifically on design relating to geometry, mathematical modeling, energy element relationships, and computer analysis and simulation to visualize system behavior. The bond graph approach is utilized for a quarter car model to facilitate understanding of the analytical process, then applied to a comparative analysis between two transverse half car models. The second half car model contains an additional transverse linkage with a third damper, and is compared against the baseline of the first half car model without the …

Construction Of High-Performance 3d Nanostructured Flower-Like Iron-Nickel Sulfide For Supercapacitor, Chen Zhao, Sanket Bhoyate, Chunyang Zhang, Ram K. Gupta, Pawan K. Kahol

Posters

The global energy crisis and environmental pollution have stimulated increasing attention to developing clean and renewable alternative energy sources. One of the most efficient and greenest energy storage devices is supercapacitor which could store energy via electrical double layer and redox reactions. Supercapacitors are widely employed for many portable electronics and hybrid electric vehicles due to their high-power density, fast charge-discharge rate, and good cycle stability. In this work, 3D nanostructured flower-like iron-nickel sulfide was synthesized on the nickel foam using a facile hydrothermal method. The iron-nickel sulfide electrode showed out­standing performance for supercapacitor with a high areal capacitance of …

Nanosheets Of Cuco₂O₄ As A High-Performance Electrocatalyst In Urea Oxidation, Camila Zequine, Ram K. Gupta, Pawan K. Kahol

Posters

The urea oxidation reaction (UOR) is a possible solution to solve the world’s energy crisis. Fuel cells have been used in the UOR to generate hydrogen with a lower potential compared to water splitting, decreasing the costs of energy production. Urea is abundantly present in agricultural waste and in industrial and human wastewater. Besides generating hydrogen, this reaction provides a pathway to eliminate urea, which is a hazard in the environment and to people’s health. In this study, nanosheets of CuCo₂O₄ grown on nickel foam were synthesized as an electrocatalyst for urea oxidation to generate hydrogen as a green fuel. …

Molybdenum Oxides For Energy Generation And Storage Using Efficient Clean Method, Camila Zequine, Pawan K. Kahol, Ram K. Gupta

Posters

To solve the growing energy issues, significant efforts have been focused on the search of earth-abundant ele­ments that can provide multifunctional behavior for both energy generation and storage. Due to the low-cost and rich chemical nature, transition metal oxide nanostructures have been used in the fabrication of energy devices, such as fuel cells and lithium batteries. In this work, nickel, cobalt and iron molybdates were synthesized via a simple hydrothermal method in order to fabricate electrodes for oxygen evolution reaction (OER) and a superca­pacitor. FeMoO₄ required an overpotential of 294 mV to achieve a current density of 10 mA/cm2 for …

Electrocatalytic Properties Of Lanthanum-Based Perovskites For Water Splitting And Energy Storage Applications, Xavier R. Martinez, Khamis Siam, Pawan K. Kahol, Ram K. Gupta

Posters

Recent changes in global weather patterns have punctuated the need for mollification through a cleaner energy option. As part of the plan, hydrogen production for fuel cells offers substantial power without carbon emissions. Overall water splitting, with the aid of a low cost electrocatalyst could prove to be an abundant green fuel source. Utilizing readily available transition metals, three perovskite nanostructures were studied as a multifunctional material for hydrogen production as well as energy storage. LaCoO₃ (LCO), LaFeO₃ (LFO), and LaMnO₃ (LMO) were synthesized and characterized by X-ray diffraction and then dip coated onto nickel foam as electrodes in a …

Metal-Doped Catalysts For Hydrogen Evolution Reaction, Tucker Morey, Ram K. Gupta, Pawan K. Kahol

Posters

The highly efficient electrochemical hydrogen evolution reaction (HER) provides a promising way to solve energy and environment problems. In this work, various transition metals (Fe, Co, Ni, Cu, Ag, and Pt) were selected to support on molybdenum carbides by a simple organic-inorganic precursor carburization process. X-ray diffraction (XRD) analysis results indicated that the ß-MO₂C phase was formed in all metal-doped samples. X-ray photo­electron spectroscopy analysis indicated that the binding energy of MO₂+ species (MO₂C) shifted to a lower value after metal was doped on the molybdenum carbide surface. Comparing with pure ß-MO₂C, the elec­trocatalytic activity for HER was improved by …

Implementation Of Solar Car Technology, Greg Mccartney, Marcus Allen, Dedrick Cooper, Lelan Delissa, Eric Mayer

Posters

Under the leadership of Dr. Erik Mayer, Pittsburg State University hosted the first Kansas Solar Race Competition. The purpose of this competition is to motivate students to learn about different aspects of solar car technology. The competition motivates students by bringing multiple teams together in a friendly competition to test out their uniquely engineered and constructed wireless cars. The cars will compete in different competitions such as an agil­ity competition and a drag race. After the competition, the students are able to learn from the ingenuity of other teams and spark a curiosity to continue to learn about solar car …

Almond Based Electrocatalyst For Fuel Cell Applications, Kinsey Morey, Tucker Morey, Brooks Neria, Khamis Siam, Pawan K. Kahol

Posters

Hydrogen is considered one of the cleanest energy sources. Water spitting is one of the efficient ways to produce hydrogen as a fuel at the industrial level. Water splitting via electrolysis requires an efficient electrocatalyst to reduce the voltage required for water splitting. Currently, precious metals such as platinum are considered as one of the most efficient electrocatalysts for hydrogen production via electrolysis of water. The current challenge is to find a cost-effective alternative for this process. Molybdenum and carbon are low cost and abundant mate­rials which could be used for the synthesis of cost-effective electrocatalysts for hydrogen production. In …

Design Of A Portable Biogas Purification And Storage System, Anikumar Kosna, Bade Shrestha

Faculty Research and Creative Activities Award (FRACAA)

The objective of this study is to propose and design a commercial portable purification and storage system to commercialize biogas (which mainly consists of 45 - 75 % of methane and 15 - 16% of carbon dioxide), produced from household/non-commercial biogas plants. The selection of purification process is based on the portability of the purification system.

Numerical Investigation Of Inclination On The Thermal Performance Of Porous Fin Heatsink Using Pseudospectral Collocation Method, George Oguntala, Gbeminiyi Sobamowo, Raed Abd-Alhameed, James Noras

Karbala International Journal of Modern Science

Numerical investigation of inclination effect on the thermal performance of a porous fin heat sink is presented. The developed thermal model is solved using pseudo-spectral collocation method (PSCM). Parametric studies are carried out using PSCM, and the thermal characterization of heat sink with the inclined porous fin of rectangular geometry is presented. Results show that heat sink of inclined porous fin exhibits higher thermal performance than heat sink of vertical porous fin operating under the same thermal conditions with the same geometrical configurations. Performance of inclined or tilted fin increases with decrease in length-thickness aspect ratio. However, increase in the …

Surface And Interface Properties In Thin-Film Solar Cells: Using Soft X-Rays And Electrons To Unravel The Electronic And Chemical Structure, Lothar Weinhardt, Dirk Hauschild, Clemens Heske

Chemistry and Biochemistry Faculty Research

Thin‐film solar cells have great potential to overtake the currently dominant silicon‐based solar cell technologies in a strongly growing market. Such thin‐film devices consist of a multilayer structure, for which charge‐carrier transport across interfaces plays a crucial role in minimizing the associated recombination losses and achieving high solar conversion efficiencies. Further development can strongly profit from a high‐level characterization that gives a local, electronic, and chemical picture of the interface properties, which allows for an insight‐driven optimization. Herein, the authors' recent progress of applying a “toolbox” of high‐level laboratory‐ and synchrotron‐based electron and soft X‐ray spectroscopies to characterize the chemical …

Solar Thermoelectricity Via Advanced Latent Heat Storage, Michele L. Olsen, Eric S. Toberer, David S. Ginley, Philip A. Parilla, Emily L. Warren, Aaron D. Martinez, Jonathan E. Rea, Corey Lee Hardin, Christopher J. Oshman, Nathan P. Siegel

Other Faculty Research and Publications

An aspect of the present disclosure is a system that includes a thermal valve having a first position and a second position, a heat transfer fluid, and an energy converter where, when in the first position, the thermal valve prevents the transfer of heat from the heat transfer fluid to the energy converter, and when in the second position, the thermal valve allows the transfer of heat from the heat transfer fluid to the energy converter, such that at least a portion of the heat transferred is converted to electricity by the energy converter.

Evaluating Moisture Control Of Variable-Capacity Heat Pumps In Mechanically Ventilated, Low-Load Homes In Climate Zone 2a, Florida Solar Energy Center, Eric Martin

FSEC Energy Research Center®

The well-sealed, highly insulated building enclosures constructed by today's home building industry coupled with efficient lighting and appliances are achieving significantly reduced heating and cooling loads. These low-load homes can present a challenge when selecting appropriate space-conditioning equipment. Conventional, fixed-capacity heating and cooling equipment is often oversized for small homes, causing increased first costs and operating costs. Even if fixed-capacity equipment can be properly specified for peak loads, it remains oversized for use during much of the year. During these part-load cooling hours, oversized equipment meets the target dry-bulb temperatures very quickly, often without sufficient opportunity for moisture control. The …

Fluorescence Of Cdse/Zns Quantum Dots In Toluene: Effect Of Cyclic Temperature, Ting Chen, Weiling Luan, Shaofu Zhang, Fuqian Yang

Chemical and Materials Engineering Faculty Publications

Quantum dots (QDs) are the potential material for the application in optical thermometry, and have been successfully applied to solar cells, LEDs, bio-labeling, structural health monitoring, etc. In this paper, we study the fluorescence properties of CdSe/ZnS QDs in toluene under the action of heating-cooling cycles. The experimental results show that, in a heating-cooling cycle, increasing temperature causes red-shift of the emission peak and the decrease of the PL intensity, and decreasing temperature causes blue-shift of the emission peak and the increase of the PL intensity. The surface structures of the QDs likely are dependent on the cycle numbers, which …

Proposed Delivery And Return Water Temperatures For Dartmouth College Hot Water Network, Storm Mata

ENGS 86 Independent Projects (AB Students)

This study aimed to verify the viability of the planned hot water heating network at Dartmouth, and determine the necessary hot water radiator areas needed to satisfy the empirically-determined heat demand for buildings on campus, using 5 year of steam con- sumption data. In order to verify viability, the pressure and temperature of the delivery steam and return condensate of the current heating network were used to find the amount of heat delivered per pound of steam to campus. The above-mentioned steam consump- tion data were then used to find the max heat demand for the past five years and …

Stair Climbing Hand Truck, James Mcpherson

All Undergraduate Projects

Abstract

Getting a heavy object up a flight of stairs usually requires a team of two or more people. Even with a team of people, the task is often still difficult, dangerous, and possibly insurmountable by one person. This problem is especially prevalent in for those who are moving into apartment complexes. Most apartment complexes have many buildings with two or more floors of living quarters, and elevators are often missing. This project sought to offer a solution to this problem. The solution in question; a motorized hand-truck with 2, trigonal planar pinwheels in place of the stock wheels. The …

A Novel Approach Towards Investigating The Performance Of Different Pvt Configurations Integrated On Test Cells: An Experimental Study, Vivek Tomar, Brian Norton, G. N. Tiwari

Articles

This study elaborates the theoretical and experimental analysis for the effectiveness of different photovoltaic thermal (PVT) configurations along with their building implications. An experiment was performed on especially designed four identical prototype test cells emphasise the building integration photovoltaic thermal (BiPVT) systems. A comparative analysis of four different possible PVT configurations integrated on identical test cells namely; Case 1: Glass-to-glass PV with duct integrated on a test cell, Case 2: Glass-to -glass PV without duct integrated on a test cell, Case 3: Glass to tedlar PV with duct integrated on a test cell and Case 4: Glass to tedlar PV …

Recycling Licoo2 With Methanesulfonic Acid For Regeneration Of Lithium-Ion Battery Electrode Materials., Bin Wang, Xin-Ye Lin, Yuanyuan Tang, Qiang Wang, Michael K.H. Leung, Xiao-Ying Lu

Faculty of Science & Technology (THEi)

With the massive consumption of lithium-ion batteries in portable consumer electronics and electric vehicles, proper disposal of spent batteries is of paramount importance for sustainable development. In this study, biodegradable organic methanesulfonic acid (MSA) is investigated for the first time to leach valuable metals from waste LiCoO2 powders for battery material regeneration. Under the optimal conditions, leaching efficiencies of lithium and cobalt are achieved at nearly ∼100% and ∼100%, respectively. Comparison experiment indicates that MSA can achieve better leaching performance than previously reported organic acids (e.g. citric acid, malonic acid, succinic acid, oxalic acid) under the same conditions. Besides, strong …