Polymer and Organic Materials Commons^™

Direct Contact Pyrolysis Of Hydrocarbons: A Source Of Hydrogen And Interesting Carbon Formations, Peter G. Faught

UNLV Theses, Dissertations, Professional Papers, and Capstones

The work detailed in this document looks at a novel liquid metal supported catalytic system for the generation of hydrogen by decomposition of ethanol through direct contact pyrolysis. The hydrogen is produced at relatively low temperatures (500-600°C) and has carbon and water as co-products. It should be noted that CO is not observed as a product at these low temperatures. This is to be contrasted with the hydrogen produced at higher temperature from ethanol which does contain carbon monoxide. The presence of carbon monoxide in hydrogen complicates fuel cell operation and catalytic chemical processes. Thus, the lack of CO in …

Testing, Modelling And Validation Of Numerical Model Capable Of Predicting Stress Fields Throughout Polyurethane Foam, Conor Briody, Barry Duignan, Stephen Jerrams

Conference Papers

Wheelchair seating systems are specialised for a number of reasons as users can have impaired mobility, which increases the possibility of pressure build up. These areas of high pressure frequently occur in the trunk region under the bony prominences known as the Ischial Tuberosities (IT), pressure ulcers may occur consequently. Polyurethane foam has been in use for some time in wheelchair seating systems as it exhibits good pressure relieving capabilities in most cases. However, little quantitative research has gone into foamed polymers, in comparison with conventional elastomeric materials. This lack of knowledge can ultimately lead to more time being spent …

Morphology Changes In Pcpdtbt:Pcbm And P3ht:Pcpdtbt:Pcbm And Its Effect On Polymer Solar Cell Performance, Galen David Cauble

Physics

Polymer solar cell morphology is sensitive to both heat and time. By thermally annealing polymer solar cells the morphology of the devices can be altered causing immediate changes in device performance. Blending PCPDTBT:PCBM with P3HT:PCPDTBT combines the absorption characteristics of each to create a more even absorption spectrum. Subjecting PCPDTBT:PCBM, and P3HT:PCPDTBT:PCBM polymer solar cells to thermal annealing as well as recording device performance through time has shown that P3HT:PCPDTBT:PCBM devices react positively to thermal annealing (increasing from 0.8% to 1.4%) while PCPDTBT:PCBM devices have varied reactions. Furthermore, the P3HT:PCPDTBT:PCBM devices have achieved efficiencies of 1.6% in AM 1.5 compared …

Quantitative Analysis Of The Reaction Between Gliadin And Citric Acid Under Weak Acidic And Weak Alkaline Conditions, Wei Li

Department of Agricultural and Biological Systems Engineering: Dissertations, Theses, and Student Research

Gliadin was reacted with citric acid under weak acidic and weak alkaline conditions in both wet and dry states and the reaction mechanism was studied. The low morphological stability in an aqueous environment and inferior mechanical properties have restricted the applications of plant proteins, although these materials possess a unique structure, biocompatibility and biodegradability. Carboxylic acids such as citric acid are inexpensive and nontoxic chemicals and are preferred for crosslinking proteins and cellulose to improve the desired properties of the materials.

In this study, gliadin was chosen as a model of plant proteins to react with citric acid. However, previous …

Improving The Efficiency Of Organic Solar Cells By Varying The Material Concentration In The Photoactive Layer, Kevin Anthony Latimer

Electrical & Computer Engineering Theses & Dissertations

Polymer-fullerene bulk heterojunction solar cells have been a rapidly improving technology over the past decade. To further improve the relatively low energy conversion efficiencies of these solar cells, several modifications need to be made to the overall device structure. Emerging technologies include cells that are fabricated with interfacial layers to facilitate charge transport, and tandem structures are being introduced to harness the absorption spectrum of polymers with varying bandgap energies.

When new structures are implemented, each layer of the cell must be optimized in order for the entire device to function efficiently. The most volatile layer of these devices is …

Determining A Method For Rendering Low Cost Cdse(Zns) Core(Shell) Quantum Dots Aqueous Soluble Via Amphiphilic Polymer Wrapping, Patrick Mcbride

Materials Engineering

Herein is described the procedure of two amphiphilic polymer wrapping techniques that may be employed for obtaining aqueous soluble quantum dots (QDs) for use in biological fluorescent imaging applications. The advent of QDs has led to new nanoscale fluorescent materials that exhibit unparalleled quantum yields (QYs), high resistance to photobleaching, tunable emissions, and
absorption over a large optical range. However, the QD synthesis employed here at Cal Poly to obtain bright, photostable CdSe(ZnS) core(shell) QDs involves the use of organic solvents and surfactants, leading to hydrophobic QDs. Since all of biology relies on aqueous solubility, this hydrophobicity creates a major …

Artificial Muscle Project: Process Development Of Polydimethyl Siloxane Thin Films For Use In Dielectric Electroactive Polymer Artificial Muscle Actuators, Vincent J. Gayotin, Richard W. Morrison, Paul A. Preisser

Materials Engineering

An artificial muscle design was created founded on the principles of a dielectric electroactive polymer (DEAP), which is fundamentally similar to a capacitor. A polydimethyl siloxane (PDMS)-based elastomer, Sylgard 184 from Dow Corning, was chosen for the design and spun coat onto polystyrene (PS) Petri dishes at varying speeds to create a thin film, using speeds of 2000 rpm, 3000 rpm, 4000 rpm, 5000 rpm, and 6000 rpm. The film thicknesses were measured optically through use of a microscope with coupled computer imaging software to generate a characteristic curve of film thickness to spin speed, achieving a minimum film thickness …

Processing Pdms Gecko Tape Using Isopore Filters And Silicon Wafer Templates, Boris Luu

Materials Engineering

Gecko tape was processed through nanomolding involving two types of templates. One template was a Millapore Isopore polycarbonate membrane filter and the other template was an n-type silicon wafer processed to include four different pore diameters. These pore diameters were 20, 40, 80, and 160 microns. AutoCAD was used to design to a mask to be used later during photolithography. Two n-type wafers were sputtered with aluminum, underwent photolithography, and then etched using reactive ion etching. A template was placed into a Petri dish and Sylgard 184 polydimethylsiloxane (PDMS) was poured on the template. Once the PDMS cured,   the 1 …

Characterisation, Modelling And Simulation Of Flexible Polyurethane Foam, Conor Briody, Barry Duignan, Stephen Jerrams

Conference Papers

Flexible polyurethane foam is an open-celled polymeric material that exhibits strain rate and temperature effects. It has found various applications in areas including the packaging, medical, sports, aerospace and aeronautical industries. Polyurethane foam is ubiquitous in seating applications and finds particular use in specialised wheelchair seating where customised seating solutions are required which can provide proper comfort and support without the risk of developing pressure ulcers. Proper seating design is critical for users if this problem is to be avoided, but a lack of quantitative knowledge of this material’s behaviour has limited its effectiveness. The objectives of the work presented …

Migration Models - Comparison Of Pvc, Pet And Pla Diffusivity, Combined With A Production Cost Model For Westridge Laboratories, Shelley Cooke, Sarina Surrette

Materials Engineering

This project has two parts: [1] a migration and diffusivity model for candidate plastics used in containers, and [2] a product cost model for Westridge Laboratories (Santa Ana, CA).

Diffusion modeling is a useful tool to predict migration of polymer constituents into exposed liquids.  Polyvinyl chloride (PVC), polyethylene terephthalate (PET) and polylactic acid (PLA) were studied to estimate production costs, and component migration into water-based liquids from plastic containers.  Bis (2-ethylhexyl) phthalate (DEHP), antimony trioxide, and stannous octoate, are components of concern in the three candidate polymers, respectively.  Normal detection limits for these constituents are about 1 - 10 ppb, …

A Least Squares Closure Approximation For Liquid Crystalline Polymers, Traci Ann Sievenpiper

Mathematics & Statistics Theses & Dissertations

An introduction to existing closure schemes for the Doi-Hess kinetic theory of liquid crystalline polymers is provided. A new closure scheme is devised based on a least squares fit of a linear combination of the Doi, Tsuji-Rey, Hinch-Leal I, and Hinch-Leal II closure schemes. The orientation tensor and rate-of-strain tensor are fit separately using data generated from the kinetic solution of the Smoluchowski equation. The known behavior of the kinetic solution and existing closure schemes at equilibrium is compared with that of the new closure scheme. The performance of the proposed closure scheme in simple shear flow for a variety …

An Analytical Model Of Nanometer Scale Viscoelastic Properties Of Polymer Surfaces Measured Using An Atomic Force Microscope, Jacob B. Goldberg

Theses and Dissertations

The United States Air Force and the Department of Defense is increasingly interested in nanomaterials. To study these materials, one needs to measure the mechanics of materials on the nanoscale. Over the past few decades the atomic force microscope (AFM) has been used in various methods to establish local surface properties at the nanoscale. In particular, surface elasticity measurements are crucial to understanding nanoscale surface properties. Problems arise, however, when measuring soft surfaces such as polymers and biological specimens, because these materials have a more complex viscoelastic response. This research focuses on modeling an AFM dynamic nanoindentation experiment intended to …

Rheological Characteristics Of Solvent Free Nanofluids: Thermal Transitions And Reactive Curing, Daniel Chojnowski

Master's Theses and Doctoral Dissertations

Solvent-free nanofluids are a new and exciting class of material that evolved to address the limitations of their predecessors, nanocomposites. One of the most exciting aspects of solvent-free nanofluids is the wide range of tools chemists have to build and study them. Understanding how the structure manipulations impact the rheology of the resulting solvent-free nanofluids is essential if solvent-free nanofluids are truly the technology of the future. This work documents the basic rheological parameters, thermal transitions, and curing kinetics of various solvent-free nanofluids synthesized by Zhiming Qiu and Kejian Bian at the Coating Research Institute at Eastern Michigan University.

Creep In Photovoltaic Modules: Examining The Stability Of Polymeric Materials And Components, David C. Miller, Michael D. Kempe, Stephen H. Glick, Sarah R. Kurtz

Publications (E)

Interest in renewable energy has motivated the implementation of new polymeric materials in photovoltaic modules. Some of these are non-cross-linked thermoplastics, in which there is a potential for new behaviors to occur, including phase transformation and visco-elastic flow. Differential scanning calorimetry and rheometry data were obtained and then combined with existing site-specific time-temperature information in a theoretical analysis to estimate the displacement expected to occur during module service life. The analysis identified that, depending on the installation location, module configuration and/or mounting configuration, some of the thermoplastics are expected to undergo unacceptable physical displacement. While the examples here focus on …

Investigating Wood Welding Parameters Using A Prototype Welding Machine, Timothy R. Melin

Master's Theses

Understanding how different processing variables influence wood welded bonds is vital if the technique will ever be used to create engineered lumber without using adhesives. A variation of vibration welding, wood welding uses pressure and friction to bond materials together. During welding, heat causes a softening in the wood, a naturally occurring composite material. This softening leads to fiber entanglement and a bond forms upon cooling.

The goal of this research was to investigate several processing aspects of the wood welding procedure. A prototype wood welding machine, designed and fabricated from the ground up, was used to investigate the effects …

Irrigation Leak Detection: Using Flow Rate Sensors To Detect Breaks In An Irrigation System, Adam Openshaw, Kalvin Vu

Computer Engineering

This report details the exploration and invention of a mechanism that can detect breaks in an irrigation system. With the ultimate goal of conserving water, we have designed an inexpensive, self sustaining flow rate monitor that can be used to identify anomalies in an irrigation system and wirelessly communicate the status of the system to a base station. Our implementation can also determine the direction of the anomaly based on the nature of the anomaly itself. This means that multiple monitors can be used to pinpoint the location of a break within the system in addition to merely detecting its …

Validation Of A Secondary Fabric Supplier And Characterization Of Alternate Cores For Use In The Aptera 2e Sandwich Core Composite, Bryan Rogers

Materials Engineering

Polymer matrix composites’ high strength to weight ratio has made them an ideal material choice for use in lightweight transportation vehicles. Aptera Motors, a company based out of Oceanside, CA, is currently developing a next-generation high efficiency passenger vehicle called the Aptera 2e. The 2e’s body is composed of a sandwich core composite containing laminates of E-glass fibers embedded within an epoxy matrix sandwiched between a polyester hexagonal core. This project looked to validate a secondary fabric supplier for use in Aptera’s composite and characterize the core shear properties of two alternate core materials for future iterations of Aptera’s vehicle. …

Determining The Optimal Material For Coffee Packaging: Oxygen Transmission Rates And Ink Abrasion Resistance, Laura Kiyoi

Graphic Communication

No abstract provided.

Optimization Of P3ht-Pcbm Polymer Solar Cells Through Device Simulation And Manufacturing, James Boom

Computer Engineering

Given a good model and implementation of that model, computer simulation can be used to reduce the time and material costs of research. To this end I worked with other students to manufacture, test and simulate the single layer P3HT-PCBM solar cell. Using the data collected from this project, future work can then be done with the project's simulator to further optimize these types of solar cell devices.

Polyenvi, Stephen Beard, Josh Engel, Paul Fake, Diego Flores, Alvaro Nunez, Miguel Wong

Electrical Engineering

Poor indoor air quality is a problem that is recognized by the Environmental Protection Agency (EPA) to cause health issues. In order to raise awareness of this problem, this document outlines the construction of a device that economically measures air quality through five metrics: dust, smoke, ozone, humidity, and temperature. The device integrates with a router to provide users access to information about their indoor air quality anywhere over the internet as well as local access to the data via an LCD mounted on the router. By increasing indoor air quality awareness, this device will aid users in making adjustments …