Materials Science and Engineering Commons^™

Additive Manufacturing Of Zinc-Based Biomaterials: Fabrication, Performance And Property Evaluation, S. Bandekian, M. Zolfaghari Baghbaderani, J. Drelich, S. Sharif, A.F. Ismail, H. R. Bakhsheshi-Rad

Michigan Tech Publications

The use of zinc and its alloys in additive manufacturing has become an important focus in interventional medical field. This is because zinc as an implant is naturally degradable, has solid mechanical characteristics, and is biocompatible. Biodegradable Zn-based metals made with additive manufacturing offer significant advantages in creating personalized medical implants. This review aims to provide an overview of different types of additive manufacturing methods and processes that can be used in the fabrication of Zn-based medical implants. It offers a comprehensive understanding of additive-manufactured Zn-based alloys for interventional surgeries. The study also summarizes the relationships between degradation properties, mechanical …

Adjustable Dynamometer Motor Mount, Garrett Carson Ng, Elijah Siegel Reuven, Ethan Fong, Daniel Larimer

Mechanical Engineering

The Cal Poly Electrical Engineering Department and sponsor Dr. Dolan needs a manufacturable motor fixture that securely aligns motors of various sizes with dynamometers. Previous lab motor fixtures could not accommodate motors of different sizes, making precise alignment between motors and dynamometers time-consuming and unreliable. Our team developed a modular, manufacturable fixture capable of aligning various motor sizes quickly, accurately, and securely, enhancing lab consistency and usability.

Development And Characterization Of A Pro-Angiogenic Peptide Amphiphile For Deep Dermal Burn Healing Via Spray Delivery, Loria Dimartino

Honors Theses

Severe burns and other dermatological injuries are frequently accompanied by a range of comorbidities and aesthetic challenges that patients must contend with. The complexity of burn care is exacerbated by the lack of a standardized surgical protocol, as treatment strategies are tailored to individual patient factors, including overall health status, wound size and location, as well as the expertise and resources available to the surgical team. Most commonly, deep dermal burns are treated through grafting, which effectively covers the injury site, but requires the creation of a second wound on the body of approximately the same size. This produces a …

Tuning The Morphology Of Triblock Copolymers Via Homopolymer Blending, John F. Searles

Honors Theses

Morphology plays an important role in the physical properties of block copolymer (BCP) materials. Depending on the type of morphology and chemical composition of the blocks, BCPs are used in applications ranging from soft biomaterials for biomedical devices to rigid materials for ballistics protection. Due to incompatibility between comonomers and required block weight ratios to achieve targeted morphologies, it is generally necessary to use complex, time-consuming, and expensive synthetic techniques to prepare BCPs. As a result, there is increased interest in the development of new processing methods to tailor block copolymer morphology without the need for additional synthesis. The morphological …

Interfacial Defect Properties Of High-Entropy Carbides: Stacking Faults, Shockley Partial Dislocations, And A New Evans-Polanyi-Semenov Relation, Samuel E. Daigle, Stefano Curtarolo, William G. Fahrenholtz, Jon Paul Maria, Douglas E. Wolfe, Eva Zurek, Donald W. Brenner

Materials Science and Engineering Faculty Research & Creative Works

Using first principles calculations, {111} intrinsic stacking fault (ISF) energies in groups IVB, VB, and VIB high-entropy transition metal carbides (HETMCs) are shown to be predictable from an optimized rule of mixtures based on the atomic arrangement near the stacking fault. A composition-independent linear relationship is demonstrated between the ISF energies and the unstable stacking fault (USF) energies along the (112¯){111} γsurface slip path. This relationship represents a new application of the Evans-Polanyi-Semenov principle by treating the ISF and USF energies as analogous to the heat of reaction and transition state barrier in chemical reactions. Further, a full defect energy …

Deciphering And Translating Bioinspired Structures For Engineering Materials Design Via Computational Modeling And Machine Learning, Zhangke Yang

All Dissertations

Nature has evolved extraordinary structural materials—such as nacre, bone, and the mantis shrimp’s dactyl club—that achieve remarkable combinations of strength, toughness, and impact resistance. These properties arise from sophisticated synergies between structure and composition. Inspired by these biological systems, this dissertation presents a comprehensive investigation into bioinspired materials, uncovering fundamental mechanisms and providing guidance on designing materials with superior mechanical properties.

This dissertation begins by examining the "brick-and-mortar" structure of nacre, which informs the design of layered polymer-graphene nanocomposite films. Using coarse-grained molecular dynamics simulations, I elucidate mechanisms of dynamic wave propagation and energy dissipation in these systems, providing critical …

Tailoring The Morphology Of Block Copolymers Via Solvent-Vapor Annealing, Bayleigh Madelin Loving

Honors Theses

Triblock polystyrene-polyisobutylene-polystyrene (PS-PIB-PS) copolymers have widespread applications from thermoplastic elastomers to protective coatings for ballistic applications. The incompatibility between the soft PIB and hard PS phases leads to phase separation and subsequent formation of morphological domains like lamellae and cylinders. The structures are stabilized by physical crosslinks, which can greatly improve the toughness of the triblock systems by preventing chain pullout during tensile deformation. We tailored the morphologies (achieving different morphologies with the same block copolymer) by changing the annealing conditions of the block copolymers. Solvent vapor annealing was used to selectively activate the mobility of a particular block, causing …

Exploring Metal Additive Manufacturing In Martian Atmospheric Environments, Zane Mebruer

Mechanical Engineering Undergraduate Honors Theses

On-surface manufacturing is key to the success of a planetary colonization, especially that of Mars. However, traditional subtractive manufacturing processes are equipment, energy, and material intensive, meaning novel additive manufacturing (AM) processes must be pursued for this end. Selective laser melting, one of the most effective and versatile AM methods, would be incredibly beneficial to a Martian mission but requires an artificial argon atmosphere to create effective parts. The purpose of this study was to examine if carbon dioxide, the gas that makes up over 95% of Mars’ surface atmosphere, would be a sufficient substitute for argon in SLM fabrication. …

Thermal Characterization Of 3d Printing Materials For Increasing Insulation Potential And Practicality, Jackson H. Minnick

Mechanical Engineering Undergraduate Honors Theses

This study served as an exploration into the possible existence of a correlation between the infill lattice structure of a 3D printed wall section and the thermal performance of that sample as characterized by thermal conductivity measured in units of Watts per meter Kelvin. With the continual increase in the practicality, fidelity, and applicable fields of additive manufacturing, namely FDM 3D printing, research on specific print characteristics and their effects on the material and thermal characteristics of the part in question is steadily becoming more commonplace. Although the thermal conductivity of 3D printed wall sections as a function of infill …

Flowermd: A Flexible Library Of Organic Workflows And Extensible Recipes For Molecular Dynamics And Machine-Learned Coarse-Grained Simulations Of Isotropic And Anisotropic Systems, Marjan Albooyeh

Boise State University Theses and Dissertations

Molecular dynamics (MD) simulations are essential tools for understanding and predicting material behavior at the atomic and molecular scale. While numerous open-source software packages exist for different stages of MD simulations, assembling a seamless, end-to-end workflow for complex multi-step simulations remains a significant challenge. In this work, we develop FlowerMD, a flexible and extensible Python-based software package that automates molecular simulation workflows, improving both reproducibility and ease of use.

FlowerMD provides modular components that simplify the end-to-end execution of MD workflows, from system initialization and force field application to simulation execution. It also automates multi-step simulation workflows through Recipes—predefined, modular …

Mechanistic Investigation Of Ring-Opening Polymerization Of Polycaprolactone Using Tin(Ii) Catalysts: Ligand Effects And Biomedical Applications, Eva-Larue M. Barber

Honors Scholar Theses

This research explores the mechanistic aspects of ring-opening polymerization (ROP) of ε-caprolactone (CL) to produce polycaprolactone (PCL), a biodegradable polymer widely used in biomedical applications. The study investigates how light exposure and catalyst concentration influence polymerization efficiency, using tin(II) 2-ethylhexanoate [Sn(Oct)₂] as the catalyst in a non-polar toluene solvent at 90 °C. Reactions were conducted under either ambient light or black light bulb (BLB) illumination, with monomer-to-catalyst ratios of 1:1 and 200:1.

Proton nuclear magnetic resonance (¹H NMR) spectroscopy was used to analyze conversion efficiency by tracking the disappearance of monomer signals and appearance of characteristic PCL peaks. Results revealed …

Porous Geopolymer Composite For Geotechnical Applications, Karla Viviana Sierra Flores

Theses and Dissertations

This research investigates the development of a porous geopolymer cement grout for soil grouting applications, aiming to reduce carbon emissions associated with Portland cement while maintaining critical performance characteristics such as strength and permeability. Class F fly ash and metakaolin were used as aluminosilicate precursors, activated by sodium silicate and sodium hydroxide solutions. The addition of hydrogen peroxide served as a foaming agent to introduce porosity by creating a thermodynamic reaction that releases oxygen gas during mixing. Compressive strength, porosity, and hydraulic conductivity were evaluated, with results showing that metakaolin significantly increased compressive strength due to its smaller particle size …

Development And Tribological Characterization Of Uhmwpe-Tin Composite Coatings Deposited By Electrostatic Spraying, Jarrod Keith Perez

Theses and Dissertations

The increasing demand for inert, wear-resistant, cost-efficient, environmentally friendly, and low-friction coatings has driven extensive research into polymer-based solutions. Among these, ultra-high-molecular-weight polyethylene (UHMWPE) has emerged as a strong candidate due to its low density, anticorrosion properties, self-lubricating nature, affordability, and ease of processing. However, its low load-bearing capacity limits its widespread use in high-stress tribological applications. To overcome this limitation, this project investigates the development and characterization of UHMWPE composite coatings reinforced with titanium nitride (TiN) particles at varying concentrations (2.5, 5, and 10 wt%) to enhance their mechanical properties and wear resistance.

Developing Reduced Order Models For Gas Bubble Formation In Irradiated Metals Using Integrated Phase Field Modeling And Koopman Operator Theory, John M. Eggemeyer V

All Theses

Irradiation damage in materials is prevalent in nuclear components, posing significant risks in the safety and reliability of nuclear reactors. Phase field models offer a versatile framework for modeling irradiation damage in materials at mesoscales. Such high fidelity method has been used to model the formation of fission gas bubbles superlattice, a microstructure array occurs at certain irradiation conditions (dose, dose-rate, and temperature). To overcome the high computational cost of phase field modeling, Koopman operator theory is applied to create reduced order models, allowing for instantaneous simulations of fission gas bubble behaviors. These low fidelity models are integrated into machine …

Mechanistic Insights Into Polymer-Assisted Graphene Exfoliation: The Roles Of Velocity, Adhesion, Cohesion, Temperature, Peeling Mode, And Edge Defect Via Coarse-Grained Molecular Dynamics, Linjiale Dai

All Theses

Graphene exfoliation is a critical step in the fabrication of high-quality graphene

layers. However, the underlying fracture mechanisms remain poorly understood. In this

work, I employed coarse-grained (CG) molecular dynamics (MD) simulations to

investigate how factors such as interfacial binding energy, substrate cohesion, temperature,

peeling mode, and edge defects influence the outcome of the exfoliation process. To model

polymer-assisted mechanical exfoliation, I used a finite-size system in which multilayer

graphene (MLG) is sandwiched between two thin polymer films. Leveraging the

spatiotemporal efficiency of the CG model, I performed fifty simulation iterations per

parameter set and analyzed the results from a …

Development And Application Of Computational Tools For Organic Molecular Structure Prediction From Small Molecule Crystal Structure Determination To Polymer Persistence Length, Madilyn E. Paul

Boise State University Theses and Dissertations

This dissertation utilized two areas of computational simulations for organic molecular structure prediction. First, we investigate the possible polymorphism of both barbituric acid dihydrate (BTADH) and violuric acid monohydrate (VAMH) using density functional theory. Crystalline structures that exhibit polymorphism have an increased level of uncertainty in predicting their chemical and physical properties. BTADH was previously thought to undergo a subtle phase transition from P2₁/n to planar Pnma at 217 K. We conclude that barbituric acid dihydrate exhibits crystalline disorder in which the molecules are crystallized in a non-merohedrally twinned P2₁/n configuration below …

Additively Manufactured Dic Patterns For Extreme Environments And The Emerging Technology Impact On The Licensing Of Nuclear Reactors, Kaelee Ann Novich

Boise State University Theses and Dissertations

At the end of 2023, countries from the United Nations Climate Change Conference announced to triple nuclear energy capacity by 2050. The United States makes up approximately 30% of the world’s nuclear capacity; however, only 19% of the energy generated in the Nation is from nuclear power plants. Majority of nuclear reactors are over 40 years old, resulting in reactor closures and no new ones being built. Accordingly, it will be impossible to triple nuclear capacity in the next 25 years by relying on only existing reactors. The nuclear fleet must expand to include advanced reactors to meet energy demand …

Manipulating Martensitic Transformation And Residual Stress Development In Stress Superposed Incremental Forming Of Ss304, Elizabeth M. Mamros, Fabian Maaß, Thomas Gnaupel-Herold, A. Erman Tekkaya, Brad L. Kinsey, Jinjin Ha

Faculty Journal Articles

Stress superposition is one of the strategies used in metal deformation processes to increase the material formability, decrease the required forming forces, and create highly customized components. To investigate the effects of tensile and compressive stresses superposed to the single point incremental forming (SPIF) process, experiments and numerical simulations were conducted for a stainless steel 304 (SS304) truncated square pyramid geometry. Tensile stresses were superposed in-plane on the specimen blank by a custom hydraulic frame, and compressive stresses were incorporated via a polyurethane die. Identified parameters for a martensitic transformation kinetics model for SS304 were used in a two-step finite …

Reproducible Infrastructure For Modeling Thermoplastic Polymer Fusion Welding, Chris D. Jones

Boise State University Theses and Dissertations

Aircraft materials must balance the demands of being light-weight and fuel efficient with being safe, durable, and strong. Carbon-fiber reinforced polymer composites are able to meet both of these requirements, and as a result, they are being utilized more and more in aircraft manufacturing. Thermoset polymers are typically used as the matrix material in these composites; however, thermoset polymers require long curing times in large autoclave ovens in order to form chemical cross-links, which once present, cannot be melted upon further heating. As a result, joining smaller thermoset composite parts together to build larger structures requires using mechanical fasteners, which …

Empirical Models For The Prediction Of Lattice Constants In Perovskite Materials, Bryan Wright

Boise State University Theses and Dissertations

Perovskites are a class of materials famous for their many functional properties and are envisioned as a material that will pave the way for scientific advancement in the fields of renewable energy, high tech sensors, lasers, catalysis, computer chips, and many others. This wide variety of applications is not the result of a single fantastic property of perovskite materials but rather stems from the perovskite structure’s ability to display a host of functional properties. One area where there is room for significant improvement is in the rate of perovskite discovery. The high stability of the perovskite structure is responsible for …