Materials Science and Engineering Commons^™

The Effects Of Uncommon Silicides On The Oxidation Of Alloys From The Nb-Cr-Si System, Daniel Brendan Voglewede

Open Access Theses & Dissertations

Niobium based alloys are being tapped as potential successors to current nickel base superalloys in high temperature applications. In the aerospace industry, high temperature materials are constantly being pushed to higher temperature regimes in order to improve engine efficiency however current superalloys cannot be pushed further due to melting temperature limitations. Niobium, being a refractory metal, can withstand much higher temperatures than nickel however its oxidation properties are woefully inadequate.

The purpose of this study is to ascertain whether increased silicon additions can improve niobium oxidation properties by: forming ternary silicides with better oxidation properties and by preventing the formation …

Development Of Advanced Polymer Nanocomposite Capacitors, Miguel Mendoza

Open Access Theses & Dissertations

The current development of modern electronics has driven the need for new series of energy storage devices with higher energy density and faster charge/discharge rate. Batteries and capacitors are two of the most widely used energy storage devices. Compared with batteries, capacitors have higher power density and significant higher charge/discharge rate. Therefore, high energy density capacitors play a significant role in modern electronic devices, power applications, space flight technologies, hybrid electric vehicles, portable defibrillators, and pulse power applications. Dielectric film capacitors represent an exceptional alternative for developing high energy density capacitors due to their high dielectric constants, outstanding breakdown voltages, …

Hafnia-Based Nanostructured Thermal Barrier Coatings For Next Generation Gas Turbine Technology, Mohammed Noor-A-Alam

Open Access Theses & Dissertations

Extensive efforts have been directed in the last several decades towards improving thermodynamic efficiency of industrial gas turbines for power generation plants. The central theme of the efforts is to increase the turbine operating temperature and, thus, allowing higher efficiency. Thermal barrier coatings (TBC) constitute an advanced technology to protect the metallic surface from high temperature exposure for long time operation. The TBCs protect the gas turbine components from high temperature and allows further increase in engine operating temperature which subsequently increases the efficiency of the gas turbine power plant. However, the current TBC materials are capable of allowing the …

A Study Of Wo3 And W0.95ti0.05o3 Thin Films Using Comparative Spectroscopy, James Heyward Howard

Open Access Theses & Dissertations

Tungsten oxide (WO3) is important and well-studied in materials science, particularly for sensor applications. In this research work, we consider the innovation of adding Ti to thin films of this material. Since the characteristics of any such material are strongly dependent on the conditions and methods used in its deposition, the main objective of this project is to provide a detailed spectroscopic characterization by Raman scattering, infrared absorption, and X-ray photoelectron spectroscopy (XPS) of WO3 and of W0.95Ti0.05O3. This characterization will be based on comparison of the morphology and composition of WO3-based thin films, grown by radio frequency magnetron reactive …

Zno Nanostructures: Growth, Characterization And Applications, Mikhail Ladanov

USF Tampa Graduate Theses and Dissertations

ZnO nanostructures have been investigated for quite a long time. However, only recently they triggered much interest due to advances in materials synthesis and characterization, as well as emerging demand for new nanostructured materials in novel device implementations.

A large part of the work was devoted to exploring new methodology for patterning growth sites and controlling nanowires morphology using the deposition methods that are compatible with integrated circuits (IC) processing. Microcontact printing was used to pattern the seeding layer, and, subsequently, ZnO nanowires through a resistless soft lithography process.

When considering hydrothermal growth of ZnO nanowires in the framework of …

Development Of A Reliable Metal-Insulator-Metal Bilayer Tunnel Junction For Wideband Detectors, Rudraskandan Ratnadurai

USF Tampa Graduate Theses and Dissertations

Detectors and sensors are an integral part of modern electronics and are crucial to highly sensitive applications. Metal-Insulator-Metal (MIM) tunnel junctions have been explored for the past five decades and are still being investigated due to its wide use of applications such as mixers, capacitors, detectors, rectifiers and energy conversion devices. In this research, various designs of thin film based tunnel junctions have been investigated and the optimum one picked for the purpose of a wide band detector up to 10GHz based on their sensitivities. A modified design with an isolation layer incorporating a self-aligning method to increase fabrication throughput …

Chemical Mechanical Planarization Of Electronic Materials, Fnu Atiquzzaman

USF Tampa Graduate Theses and Dissertations

In the modern semiconductor manufacturing processes, chemical mechanical planarization (CMP) has attained important processing step because of its ability to provide global planarization. CMP is the planarization technique which is used for the removal of excess material, as left over from the previous processing steps. In addition, CMP offers a uniform surface that is essential for subsequent processing steps, especially for the high resolution photolithography processes. In simpler notation, CMP is a process where a chemical reaction enhances in obtaining a planar surface through removal of the mechanical materials from a wafer.

In this study, CMP performance of three electronic …

Crack Analysis In Silicon Solar Cells, Maria Ines Echeverria Molina

USF Tampa Graduate Theses and Dissertations

Solar cell business has been very critical and challenging since more efficient and low costs materials are required to decrease the costs and to increase the production yield for the amount of electrical energy converted from the Sun's energy. The silicon-based solar cell has proven to be the most efficient and cost-effective photovoltaic industrial device. However, the production cost of the solar cell increases due to the presence of cracks (internal as well as external) in the silicon wafer. The cracks of the wafer are monitored while fabricating the solar cell but the present monitoring techniques are not sufficient when …

Shape-Shifting Surfaces For Rapid Release And Direct Stamping Of Organized Micro-Tissues, Samuel James Dupont

USF Tampa Graduate Theses and Dissertations

The primary aim of the research in this study is to develop a robust and simple platform for the in vitro organization of cells on surfaces which facilitate rapid cell release and allows for the direct stamping of highly organized micro-tissues. Current approaches towards this goal have been very successful but are lengthy and subject cells to harsh conditions for extended periods of time raising questions regarding cell health and maintenance of physiological state. To address these concerns a platform was developed to allow for rapid cell release by utilizing a release mechanism different from previous work.

Micron-scale structures comprised …

Growth And Characterization Of Functional Nanoparticulate Films By A Microwave Plasma-Assisted Spray Deposition Process, Ted Wangensteen

USF Tampa Graduate Theses and Dissertations

Nanoparticle and nanoparticulate films have been grown by a unique approach combining a microwave and nebulized droplets where the concentration and thus the resulting particle size can be controlled. The goal of such a scalable approach was to achieve it with the least number of steps, and without using expensive high purity chemicals or the precautions necessary to work with such chemicals. This approach was developed as a result of first using a laser unsuccessfully to achieve the desired films and particles. Some problems with the laser approach for growing desired films were solved by substituting the higher energy microwave …

The Significance Of Equi-Biaxial Bubble Inflation In Determining Elastomeric Fatigue Properties, Stephen Jerrams, Niall Murphy, John Hanley

Books/Book Chapters

It is well documented that for the effective modelling of the static and dynamic behaviour of elastomeric components using the finite element (FE) method it is essential to obtain material parameters that are derived from a range of physical tests. For a conventional linear solid, uniaxial testing suffices to fully characterise the material, but for rubber it is necessary to test in at least two deformation modes. Also, the determination of fatigue lives of rubber components is still in its infancy and a reliable, repeatable fatigue test for rubber will have important consequences for component design, functionality, maintenance and cost. …

Effect Of Impurities On The Superheating Field Of Type-Ii Superconductors, F. Pei-Jen Lin, A. Gurevich

Physics Faculty Publications

We consider the effect of nonmagnetic and magnetic impurities on the superheating field H_s in a type-II superconductor. We solved the Eilenberger equations, which take into account the nonlinear pairbreaking of Meissner screening currents, and calculated H_s(T) for arbitrary temperatures and impurity concentrations in a single-band s-wave superconductor with a large Ginzburg-Landau parameter. At low temperatures, nonmagnetic impurities suppress a weak maximum in H_s(T), which has been predicted for the clean limit, resulting, instead, in a maximum of H_s as a function of impurity concentration in a moderately clean limit. It is shown that …

Encapsulation Of High Temperature Phase Change Materials For Thermal Energy Storage, Rupa Nath

USF Tampa Graduate Theses and Dissertations

Thermal energy storage is a major contributor to bridge the gap between energy demand (consumption) and energy production (supply) by concentrating solar power. The utilization of high latent heat storage capability of phase change materials is one of the keys to an efficient way to store thermal energy. However, some of the limitations of the existing technology are the high volumetric expansion and low thermal conductivity of phase change materials (PCMs), low energy density, low operation temperatures and high cost. The present work deals with encapsulated PCM system, which operates at temperatures above 500°C and takes advantage of the heat …

Effective Dielectric Constant Of Two Phase Systems, Vladimir Petrovsky, Piotr Z. Jasinski, Fatih Dogan

Materials Science and Engineering Faculty Research & Creative Works

Theoretical approaches to electrical characterization of two phase systems are mostly limited to the systems where the individual components exhibit the same type of conductivity (pure dielectric or pure conductive systems). In this article, the brick wall geometry is extended to the mixed conductive systems with percolation. Impedance spectroscopy techniques were used for experimental investigation of slurries. Various metal oxide powders and host liquids were analyzed using a wide range of solids loadings. Comparison of experimental results with theoretical predictions shows good fitting of the experimental data. Parameters (the values of permittivity for both phases and percolation threshold) calculated from …

Deposition Of Cerium-Based Conversion Coatings On Aluminum Alloy 380, Ci Lin, Surender Maddela, William Fahrenholtz, Matthew O'Keefe

Materials Science and Engineering Faculty Research & Creative Works

Cerium-based conversion coatings were deposited on as-cast aluminum alloy 380 substrates by a spontaneous immersion process. In this study, the effects of rinsing temperature prior to immersion in the coating deposition solution were studied with respect to the surface morphology, electrochemical response, and corrosion resistance of the coatings. Panels rinsed at 25 degrees celsius prior to coating had large cracks and holes in the coating. In contrast, panels rinsed at 100 degrees celsius prior to coating had a uniform coating morphology with fewer, smaller cracks. Electrochemical testing revealed that coatings deposited on substrates rinsed at 100 degrees celsius had higher …

Directional Anisotropy In The Mechanical Behavior Of Friction Stir Processed And Aged Az91 Alloy, Vipin Jain, Wei Yuan, R. S. Mishra, Gouthama, Anil K. Gupta

Materials Science and Engineering Faculty Research & Creative Works

Friction stir processing (FSP) is an emerging grain refinement technique for magnesium alloys. in this study, a cast AZ91 alloy was processed by a single-pass FSP to achieve an average grain size of ∼6 μm in the nugget zone. the FSP is found to introduce texture in the alloy due to preferred alignment of basal poles in the processing direction. the mechanical behavior is significantly influenced by texture. after FSP, the alloy was aged at different temperatures and times for continuous and discontinuous precipitation of β-Mg17Al12. a high anisotropy in yield stress is observed in the processing and transverse direction …

Numerical Simulation Of Natural Convection In Rectangular Enclosures Of Varying Aspect Ratios And Its Feasibility In Environmental Impact Management Studies, Charles R. Walker

College of Graduate Studies: Theses & Dissertations

Author's abstract: Numerical simulation was used to investigate natural convection in horizontal and vertical enclosures with and without an internal heat source. Natural convection in rectangular enclosures is found in many real-world applications. Included in these applications are the energy efficient design of buildings, operation and safety of nuclear reactors, solar collector design, passive energy storage, heat transfer across multi-pane windows, thermo-electric refrigeration and heating devices, and the design-for-mitigation of optical distortion in large-scale laser systems. Considering all these applications, especially controlling heat transfer in nuclear power plants, knowledge and research results of natural convection in enclosure play a vital …

Development And Validation Of Probabilistic Fatigue Models Containing Out-Life Suspensions, Noel S. Murray

College of Graduate Studies: Theses & Dissertations

Author's abstract: In the area of reliability engineering it is necessary to be confident that a component or system of components will not fail under use for safety and cost reasons. One major mechanism of failure to a mechanical component is fatigue. This is the repetitious motion of loading and unloading of the material, typically below the ultimate tensile strength of the material, which ultimately leads to a catastrophic failure. To ensure this does not happen, engineers design components based on tests to determine the life of these components. These tests are typically conducted on a bench type tester in …

Growth Analysis Of (Ag,Cu)Inse2 Thin Films Via Real Time Spectroscopic Ellipsometry, S. A. Little, V. Ranjan, R. W. Collins, S. Marsillac

Electrical & Computer Engineering Faculty Publications

In situ and ex situ characterization methods have been applied to investigate the properties of (Ag,Cu)InSe₂ (ACIS) thin films. Data acquired from real time spectroscopic ellipsometry (RTSE) experiments were analyzed to extract the evolution of the nucleating, bulk, and surface roughness layer thicknesses. The evolution of these layer thicknesses suggests a transition from Volmer-Weber to Stranski-Krastanov type behavior when Cu is replaced by Ag. The complex dielectric functions of ACIS at both deposition and room temperature as a function of film composition were also extracted from the RTSE data, enabling parameterization of the alloy optical properties.

Ferroelectric Control Of Magnetocrystalline Anisotropy At Cobalt/Poly(Vinylidene Fluoride) Interfaces, Pavel Lukashev, Tula R. Paudel, Juan M. López-Encarnación, Shireen Adenwalla, Evgeny Y. Tsymbal, Julian P. Velev

Shireen Adenwalla Papers

Electric field control of magnetization is one of the promising avenues for achieving high-density energy-efficient magnetic data storage. Ferroelectric materials can be especially useful for that purpose as a source of very large switchable electric fields when interfaced with a ferromagnet. Organic ferroelectrics, such as poly(vinylidene fluoride) (PVDF), have an additional advantage of being weakly bonded to the ferromagnet, thus minimizing undesirable effects such as interface chemical modification and/or strain coupling. In this work we use first-principles density functional calculations of Co/PVDF heterostructures to demonstrate the effect of ferroelectric polarization of PVDF on the interface magnetocrystalline anisotropy that controls the …