Materials Science and Engineering Commons^™

Impact Of Intermetallic Precipitates On The Tribological And/Or Corrosion Performance Of Cast Aluminium Alloys: A Short Review, David Culliton, Tony Betts, David Kennedy

Articles

The role of various intermetallic precipitates (IMP), or secondary phase particles, in governing the wear and corrosion performance characteristics of cast aluminium alloys is outlined in this brief review. Such alloys are especially important in transport applications where their low weight, low cost and recyclability make them very attractive. However alloy wear and/or corrosion behaviour often limit their industrial application and more work needs to done to extend their use into other areas. Careful control of IMP nucleation and growth rates may be beneficial, especially in alloys exposed to corrosive environments. Silicon, copper and magnesium are all important elements for …

Effect Of Vortex Hotspots On The Radio-Frequency Surface Resistance Of Superconductors, A. Gurevich, G. Ciovati

Physics Faculty Publications

We present detailed experimental and theoretical investigations of hotspots produced by trapped vortex bundles and their effect on the radio-frequency (rf) surface resistance Rs of superconductors at low temperatures. Our measurements of Rs, combined with the temperature mapping and laser scanning of a 2.36-mm-thick Nb plate incorporated into a 3.3-GHz Nb resonator cavity cooled by the superfluid He at 2 K, revealed spatial scales and temperature distributions of hotspots and showed that they can be moved or split by thermal gradients produced by the scanning laser beam. These results, along with the observed hysteretic field dependence of Rs which can …

Preparation, Characterization And Catalytic Activity Study Of Transition Metal Doped Porous Γ-Alumina, Seham Nasser Al Hadrami

Theses

Transition-metal ions -doped γ-alumina composites with various dopant concentrations (Cr³⁺, Fe³⁺, Ce³⁺, Zn²⁺, Mn²⁺, V²⁺ and Cu²⁺) were prepared by straightforward tempIate-free sol-gel method. They were characterized by XRD, FTIR, SEM, NMR and N₂ adsorption-desorption isotherm technique. The presence of dopant metal ions, generally, enhanced the gel formation and their behavior was dependent on the nature of the metal ion and its concentration. Certain ions, especially Fe³⁺, resulted in rapid formation of a transparent gel upon hydro lysis. The presence of the acetylacetonate …

Effect Of Inhomogeneous Deformation On Anisotropy Of Az31 Magnesium Sheet, Jidong Kang, David S. Wilkinson, Raja K. Mishra, Wei Yuan, Rajiv S. Mishra

Materials Science and Engineering Faculty Research & Creative Works

Inhomogeneous plastic deformation in AZ31 magnesium sheet has been studied during uniaxial tensile testing using digital image correlation and electron backscatter diffraction techniques. Large strain gradients develop on the sheet surface parallel and perpendicular to the loading direction while very little deformation occurs in the thickness direction. This lack of thinning leads to an abrupt fracture following the development of a premature but extensive diffuse neck but without any localized neck. The strain distribution on the sheet surface evolves nonlinearly with strain, impacting the measured plastic strain ratio, r-value. The results show that r-value should be measured at "points" rather …

Tailoring Spin-Orbit Torque In Diluted Magnetic Semiconductors, Hang Li, Xuhui Wang, Fatih Dogan, Aurelien Manchon

Materials Science and Engineering Faculty Research & Creative Works

We study the spin orbit torque arising from an intrinsic linear Dresselhaus spin-orbit coupling in a single layer III-V diluted magnetic semiconductor. We investigate the transport properties and spin torque using the linear response theory, and we report here: (1) a strong correlation exists between the angular dependence of the torque and the anisotropy of the Fermi surface; (2) the spin orbit torque depends nonlinearly on the exchange coupling. Our findings suggest the possibility to tailor the spin orbit torque magnitude and angular dependence by structural design.

Universal Emergence Of Spatially Modulated Structures Induced By Flexoantiferrodistortive Coupling In Multiferroics, Eugene A. Eliseev, Sergei V. Kalinin, Yijia Gu, Maya D. Glinchuk, Victoria V. Khist, For Full List Of Authors, See Publisher's Website.

Materials Science and Engineering Faculty Research & Creative Works

We proved the existence of a universal flexoantiferrodistortive coupling as a necessary complement to the well-known flexoelectric coupling. The coupling is universal for all antiferrodistortive systems and can lead to the formation of incommensurate, spatially modulated phases in multiferroics. Our analysis can provide a self-consistent mesoscopic explanation for a broad range of modulated domain structures observed experimentally in multiferroics.

Microstructure And Mechanical Properties Of Friction Stir Welded Oxide Dispersion Strengthened Alloy, Jiye Wang, Wei Yuan, Rajiv S. Mishra, Indrajit Charit

Materials Science and Engineering Faculty Research & Creative Works

Effect of friction stir welding (FSW) on microstructure and mechanical properties of oxide dispersion strengthened alloy MA956 was investigated. Fine grained microstructure was developed in the processed region with slight particle coarsening. Tensile behavior of the processed material was compared with that of the as-received material at room temperature. Results indicated that significant grain refinement during FSW compensated for the reduced particle strengthening contribution and enhanced tensile strength by 145 MPa without loss in ductility. Further analysis indicated a good agreement between experimentally measured yield strength and the strength calculated by Pythagorean superimposition of strengthening contribution in FSWed material. © …

Thermal Characterization Of Glasses Prepared From Simulated Compositions Of Lunar Soil Jsc-1a, A. S. Pinheiro, Z. M. Da Costa, M. J.V. Bell, V. Anjos, Signo Tadeu Dos Reis

Materials Science and Engineering Faculty Research & Creative Works

The thermal conductivity (K), thermal diffusivity (α), and specific heat capacity (ρc) for a glass prepared from JSC-1A lunar soil simulant were measured using a combination of open photoacoustic cell (OPC) and thermal relaxation techniques. The values of K and α for the JSC-1A glass were (20 ± 3) mW/cmK and (14 ± 2) cm2/s, respectively, and are somewhat larger than those of the comparable silicate glasses. The specific heat capacity (ρc) for this glass was (1.44 ± 0.07) J/cm3K, which is a little smaller than the comparable silicate glasses. Materials with high values of K and α rapidly adjust …

The Effect Of Gamma Radiation On Fibre Bragg Grating Sensors When Used As Radiation Dosimeters, Des Baccini

Theses : Honours

The effects of Gamma Radiation on Fibre Bragg Gratings (FBGs), when used as a radiation dosimeter, was proposed. The focus of this study centred on the FBG performance, and in particular the Bragg Wavelength Shift (BWS) whilst being exposed to ionizing radiation. Current research suggests that certain types of fibres manufactured by varying methods produce different results. The different responses to exposure from gamma irradiation between Germanium (Ge) doped optical fibres, with and without Hydrogen loading, along with the standard SMF-28 fibre with Hydrogen, were used and results noted and compared to previous work. The FBG’s in each fibre were …

Prediction Of The Thermomechanical Behavior Of Particle-Reinforced Metal Matrix Composites, Yi Hua, Linxia Gu

Department of Mechanical and Materials Engineering: Faculty Publications

The objective of this paper was to predict the thermomechanical behavior of 2080 aluminum alloy reinforced with SiC particles using the Mori–Tanaka theory combined with the finite element method. The influences of particle volume fraction, stiffness, aspect ratio and orientation were examined in terms of effective Young’s modulus, Poisson’s ratio and coefficient of thermal expansion (CTE) of the composite. The microstructure induced local stress and strain field was obtained through the numerical models of the representative volume element. Results suggested that particle volume fraction had significant impact on the effective Young’s modulus, Poisson’s ratio and CTE of the composite. Stiffer …

Review Of Anchorage Systems For Externally Bonded Frp Laminates, Stephen V. Grelle, Lesley Sneed

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

No abstract provided.

Infiltrated Composite Electrodes For Solid Oxide Fuel Cells, Aligul Buyukaksoy

Doctoral Dissertations

"Solid oxide fuel cells (SOFCs) are electrochemical devices which can convert chemical energy to electrical energy with efficiencies up to 60%. In order for SOFCs to be favorable energy conversion devices, the power obtained from a unit volume should be improved. This corresponds to minimized resistances from SOFC components (composite electrodes and electrolyte). Stability of the generated power is another important issue. Degradation of SOFCs with time due to microstructural processes or chemical reactions that occur at operating conditions; and due to reduction/oxidation cycles caused by the changes in the anode has been an important obstacle that has prevented the …

Recycling Of Electronic Waste: Printed Wiring Boards, Alex Luyima

Doctoral Dissertations

"Pyrolysis and leaching are the dominant techniques applied in the recycling of waste printed wiring boards (PWBs). Waste PWB pyrolysis is a highly polluting technology and produces brominated pyrolysis oils in addition to hydrogen bromide (HBr) gas. Moreover, leaching as a treatment process of waste PWBs is not well investigated. In this work, the pyrolysis of waste PWBs has been studied with the aim of reducing the amount of brominated oils and HBr gas evolved. The effects of powder inorganic chemicals (CaO, CaCO₃, Fe₂O₃, Al₂O₃, Y-Zeolite, and ZSM-5) additions on the pyrolysis of waste PWBs has been studied through experiments …

On The Effect Of Silicon And Phosphorus During The Precipitation Of Κ-Carbide In Fe-Mn-Al-C Alloys, Laura Bartlett

Doctoral Dissertations

"Implementation of lightweight high manganese and aluminum steels for use in high energy absorbing applications requires a detailed knowledge of how alloying additions and impurities affect age hardening and high strain rate fracture properties. Dynamic fracture toughness is an important design criterion but has not been reported previously in these alloys. In addition, previous studies have shown that silicon and phosphorus increased the strength and aged hardness; however, the mechanism was unknown. This research mainly focuses on the effect of silicon and phosphorus on the precipitation of Κ-carbide and alloy partitioning during aging. Short range ordering, SRO, of Fe-Al-C into …

Rbd2po4: Room Temprature Synthesis, Chemical And Structural Stablity Upon Heating, Masoud Mollaee

Open Access Theses & Dissertations

Monoclinic RbD2PO4 polycrystals were synthesized via the room temperature crystallization of RbH2PO4 dissolved in D2O. Powder x-ray diffraction (XRD) data collected at T=25 ºC indicate that this deuterated compound crystallizes in space group P21/m with unit cell parameters a=7.688í?, b=6.192í?, c=4.781í? and β=109.02°, and is isomorphic with the intermediate-temperature phase of its hydrogenated counterpart rubidium dihydrogen phosphate (RDP). We found no evidence of previously reported [Phase Transitions 80, 17 (2007)] polymorphic phase transition in rubidium dideuterium phosphate (DRDP) upon heating from room temperature to 210 ºC. All lattice parameters vary smoothly within this temperature range, demonstrating that the P21/m phase …

Microstructure And Properties For Titanium Aluminide Superalloy Prototypes Fabricated By Electron Beam Melting And Thermally Processed, Jennifer Hernandez

Open Access Theses & Dissertations

Gamma TiAl has been considered to be an ideal replacement for Ni-base superalloy aerospace applications, particularly in weight-critical applications. While bulk, fully dense gamma-TiAl is 50% less dense than Ni-base superalloys, it also has excellent mechanical properties at high temperature (up to ~800°C). Pre alloyed (Ti-48Al-2Cr-2Nb) powder was used to fabricate solid, fully dense (3.85 g/cm3) components and foam components with densities ranging from 0.33 g/cm³ to 0.46 g/cm³ by electron beam melting (EBM). A 10:1 blend of 2-phase TiAl (Ti-48Al-2Cr-2Nb in ^a/_o) : Inconel 625 (Ni-22Cr-6Mo-2Nb in ^a/_o) pre-alloyed powders produced …

Experimental Study On The Fabrication Of Advanced Materials For Energy Applications Using High Energy Mechanical Milling, Ashvin Kumar Narayana Swamy

Open Access Theses & Dissertations

The reaction of aluminum (Al) powder with water has the potential for on demand hydrogen generation. Conventional Al powders, however, react with water slowly due to a highly protective oxide layer on the particle surface. Current methods for Al activation involve harmful and expensive materials. The nano-scale Al powders also remain very expensive and have problems such as a large amount of oxide on the surface. The use of aluminum in an energy generation cycle is also hindered by the fact that, although Al is the most abundant metal in the Earth's crust, its recovery from ore consumes a lot …

Effect Of Hafnium-Incorporation On The Microstructure And Dielectric Properties Of Cobalt Ferrite Ceramics, Stephen Josiah Wells

Open Access Theses & Dissertations

The effect of hafnium ion (Hf⁴⁺) incorporation in cobalt ferrite (CFO) was studied. Samples of Hf substituted CFO ceramic (CoFe_2-xHf_xO₄), were synthesized in the laboratory with hafnium concentrations ranging from x=0.000 to x=0.200. X-ray diffraction scans show that the Hafnium CFO crystalizes in the inverse spinel phase. Inclusion of hafnium causes lattice expansion, increasing the lattice parameter from 8.374 í? for pure CoFe2O4 to 8.391 í? for the highest concentration of hafnium tested (x=0.020). The dielectric properties of CFO are greatly enhanced by inclusion of hafnium. The enhancement is due to the …

Comparative Characterization Of Ni-Base Superalloys Fabricated By Laser And Electron Beam Melting Technologies, Krista Amato

Open Access Theses & Dissertations

Nickel-base superalloys have been used in cast and wrought, and powder metallurgy forms for nearly four decades for industrial and automotive applications. One drawback of cast alloys is that upon solidification, there is minimal microstructural control. Another issue to be improved is to eliminate the limitations of shapes and forms of fabricated alloys.

Rapid prototyping is a new technology of additive manufacturing that shows to be promising for the freeform fabrication of novel superalloys, including nickel-base alloys. New rapid manufacturing technologies allow us to produce parts in any shape that can be designed by computer-aided design (CAD) software. Additionally, the …

Thermal Barrier Coatings (Tbc's) For High Heat Flux Thrust Chambers, Christopher Michael Bradley

Open Access Theses & Dissertations

The last 30 years materials engineers have been under continual pressure to develop materials with a greater temperature potential or to produce configurations that can be effectively cooled or otherwise protected at elevated temperature conditions. Turbines and thrust chambers produce some of the harshest service conditions for materials which lead to the challenges engineers face in order to increase the efficiencies of current technologies due to the energy crisis that the world is facing. The key tasks for the future of gas turbines are to increase overall efficiencies to meet energy demands of a growing world population and reduce the …