Materials Science and Engineering Commons^™

Experimental And Numerical Evaluation Of A New Composite Pressure Pipe For A Trenchless Rehabilitation Technology, Xuanchen Yen

Doctoral Dissertations

The information presented in this dissertation is based on research work conducted at Trenchless Technology Center (TTC) at Louisiana Tech University. This work was performed through a contract with China University of Geoscience (CUG) for a gas company. China's gas pipelines need replacement or rehabilitation after 15 to 30 years of service. China's gas industry is looking for suitable techniques to transfer into their market.

When compared to conventional excavation pipeline renewal or replacement methods, there are obvious advantages of TRT for gas pipelines that can impact the triple bottom-line of economic, social and environmental benefits. An introduction of TRT …

Formation Of Phase Icosahedral And Decagonal Quasicrystalline Alloys Al62,2cu25,3fe12,5/Al65ni15co20 Influence On The Oxidation, Lcla Jamshidi, Rj Rodbari, L Nascimento

Journal of Metals, Materials and Minerals

In this article we will cover a study of the formation of icosahedral and decagonal phases two quasicrystals Al62,2Cu25,3Fe12,5 And Al65Ni15Co20,and the influence of oxidation in this alloy. For this purpose research used the diffraction of X-ray (XRD), scanning electron microscopy (SEM)/Energy Dispersive Spectroscopy (EDS), Differential Scanning Calorimetry (DSC) and Thermogravimetric Analysis (TG) .The results displayed found aspects of morphological structural as well as the surface of the two compositions of quasicrystals, these were prepared and obtained in electric arc furnaces and induction and arc. Oxidation of Al62,2Cu25,3Fe12,5 alloy, intermetallic phases presented with combinations of alloying elements and above 675C …

X-Ray Attenuation Of Cotton Fabrics Coated With Barium Sulphate, B Kusuktham, C Wichayasiri, S Udon

Journal of Metals, Materials and Minerals

The x-ray attenuation performance of barium sulphate coated cotton fabrics was evaluated. 10-50 wt% barium sulphate/binder mixture was prepared and then coated onto cotton fabrics. For x-ray shielding evaluation, the fabrics with the different layers were tested under the x-ray radiation at 50kV-100 kV energy levels. The results showed that the shielding x-ray radiation were in the range of 1.48-77%, indicating that x-ray attenuation significantly increased with an increase in BaSO4 content. In addition, the number of fabric layers also played an important role. Finally, it was found that BaSO4 coated cotton fabrics exhibited satisfactory durability with respect to rubbing …

Wide Bandgap Organo‐Lead Trihalide Perovskites For Solar Cells, Miao Hu

Department of Mechanical and Materials Engineering: Dissertations, Theses, and Student Research

Methylammonium lead trihalide perovskite (MAPbX3, where MA is methylammonium, and X is a halide)-based solar cells have been extensively investigated recently, with a demonstrated and certified solar power conversion efficiency (PCE) exceeding 20%. To further boost the PCE beyond the Schockley–Queisser limit, tandem structured solar cells have been investigated based on integrating MAPbX3 and the lower bandgap solar cells. Although the best reported efficiency for this type of tandem cells is not close to the theoretically achievable value, mixed-halide perovskite MAPbBrxI3–x is still one of the most promising candidates as the wide-bandgap light absorber for the tandem application to match …

Carbon Nanotube Based Groundwater Remediation: The Case Of Trichloroethylene, Kshitij C. Jha, Zhuonan Liu, Hema Vijwani, Mallikarjuna Nadagouda, Sharmila M. Mukhopadhyay, Mesfin Tsige

Mechanical and Materials Engineering Faculty Publications

Adsorption of chlorinated organic contaminants (COCs) on carbon nanotubes (CNTs) has been gaining ground as a remedial platform for groundwater treatment. Applications depend on our mechanistic understanding of COC adsorption on CNTs. This paper lays out the nature of competing interactions at play in hybrid, membrane, and pure CNT based systems and presents results with the perspective of existing gaps in design strategies. First, current remediation approaches to trichloroethylene (TCE), the most ubiquitous of the COCs, is presented along with examination of forces contributing to adsorption of analogous contaminants at the molecular level. Second, we present results on TCE adsorption …

Verifying The Implementation Of An Anisotropic Grain Boundary Energy Model In Idaho National Lab’S Marmot, John-Michael H. Bradley, Evan D. Hansen, Jarin C. French, Yongfeng Zhang (Mentor)

Idaho Conference on Undergraduate Research

This work aims to verify the correct implementation of an anisotropic grain boundary (GB) energy model for face-centered cubic (FCC) and fluorite materials in Idaho National Laboratory’s phase field fuel performance code MARMOT. The model was recently implemented in MARMOT with the purpose of enabling higher fidelity simulations of UO₂ nuclear fuels. As part of verification, tests were performed to measure the energy dependence on misorientation of high symmetry GBs in an FCC metal (Cu). The energies of the [100], [110], and [111] twist boundaries result as predicted, as do the energies of the [111] symmetric tilt boundaries. However, …

Open Source Laser Polymer Welding System: Design And Characterization Of Linear Low-Density Polyethylene Multilayer Welds, John Laureto, Serguei V. Dessiatoun, Michael M. Ohadi, Joshua M. Pearce

Department of Materials Science and Engineering Publications

The use of lasers to weld polymer sheets provides a means of highly-adaptive and custom additive manufacturing for a wide array of industrial, medical, and end user/consumer applications. This paper provides an open source design for a laser polymer welding system, which can be fabricated with low-cost fused filament fabrication and off-the-shelf mechanical and electrical parts. The system is controlled with free and open source software and firmware. The operation of the machine is validated and the performance of the system is quantified for the mechanical properties (peak load) and weld width of linear low density polyethylene (LLDPE) lap welds …

Properties In Hardness Of Al-Cu Couples Diffused At 813 K, J Hinojosa-Torres, Jm Aceves-Hernández

Journal of Metals, Materials and Minerals

Al-Cu couples were heated to 813 K during 200, 320 and 480 hours. The heat treatment conditions caused the welding of the metals. After the mentioned conditions, it was observed the formation of two contiguous plates like (~15 to 30 micrometres, width) in parallel direction to the contact section. These plates like were chemically identified and its compositions corresponded to the h2 (CuAl) phase and to the q (CuAl2) phase of the aluminium-copper system. The measurements of micro hardness that were carried out on these plates like gave values of 620HV0.05 and 500HV0.05 (on the average) respectively. In the Cu-rich …

Column-Grid-Array (Cga) Versus Ball-Grid-Array (Bga): Boardlevel Drop Test And The Expected Dynamic Stress In The Solder Material, Ephraim Suhir, Reza Ghaffarian

Mechanical and Materials Engineering Faculty Publications and Presentations

Board level drop test is considered with an objective to develop a physically meaningful analytical predictive model for the evaluation of the expected impactinduced dynamic stresses in the solder material. Ball-gridarray (BGA) and column-grid-array (CGA) designs are addressed. Intuitively it is felt that while the application of the CGA technology to relieve thermal stresses in the solder material might be quite effective (owing to the greater interfacial compliance of the CGA in comparison with the BGA), the situation might be quite different when the PCB/package experiences dynamic loading. This is because the mass of the CGA joints exceeds considerably that …

A Comparison Of Microstructure And Uniaxial Compressive Response Of Ice-Templated Porous Alumina Scaffolds Fabricated From Two Different Particle Sizes, Nikhil D. Dhavale

Mechanical & Aerospace Engineering Theses & Dissertations

Development of bio-inspired highly porous (>50 vol.%) cellular ceramics is crucial to meet the demand of high-performance lightweight and damage-tolerant materials for a number of cutting-edge applications including impact energy absorption, biomedical implants, and energy storage. A key design feature that is observed in many natural materials (e.g., nacre, bamboo, wood, etc.) is the presence of hierarchical microstructure that results in an excellent synergy of various material properties, which are otherwise considered as mutually exclusive in current paradigm of materials design. To this end, development of multilayered, interconnected and anisotropic cellular ceramics could benefit the aforementioned applications. However, mimicking …

Technical Developments In Fish Exclusion, Guidance, And Collection Materials, A. L. Peters

International Symposium on Hydraulic Structures

Construction of mills, dams and other structures in rivers and streams, and the withdrawal of water for irrigation or cooling industrial facilities vital to social and economic progress, have impacted the survival of marine life. Barriers and guidance or collection nets can protect fish and aquatic species while allowing water to flow unimpeded for commercial and industrial use. However, nets can attract aquatic growth, fill with debris, degrade with environmental stress, and be expensive to operate and maintain.

A closer look at the technical developments of materials and net designs in diverse settings can offer guidance that will be of …

Green Synthesis Nanocomposite Membranes, Dibakar Bhattacharyya, Vasile Smuleac, Rajender S. Varma, Subhas K. Sikdar

Chemical and Materials Engineering Faculty Patents

A nanocomposite membrane includes a macroporous polymer membrane having a plurality of pores. A plurality of metal nanoparticles are synthesized and immobilized within those plurality of pores. The nanoparticles are reduced and capped with a green reducing and capping agent such as green tea extract.

Controlling The Corrosion And Cathodic Activation Of Magnesium Via Microalloying Additions Of Ge, R. L. Liu, M. F. Hurley, A. Kvryan, G. Williams, J. R. Scully, N. Birbilis

Materials Science and Engineering Faculty Publications and Presentations

The evolution of corrosion morphology and kinetics for magnesium (Mg) have been demonstrated to be influenced by cathodic activation, which implies that the rate of the cathodic partial reaction is enhanced as a result of anodic dissolution. This phenomenon was recently demonstrated to be moderated by the use of arsenic (As) alloying as a poison for the cathodic reaction, leading to significantly improved corrosion resistance. The pursuit of alternatives to toxic As is important as a means to imparting a technologically safe and effective corrosion control method for Mg (and its alloys). In this work, Mg was microalloyed with germanium …

The Progress Of Order-Structured Membrane Electrode Assembly, Shang-Feng Jiang, Bao-Lian Yi

Journal of Electrochemistry

Performances of proton exchange membrane fuel cells (PEMFCs) have been recently improved. However, the cost and Pt loading must be further reduced for the commercialization of PEMFCs. Previous researches have proved that the order-structured electrode is beneficial to the effective utilization of Pt-based catalysts, decreasing the Pt loading and increasing the three-phase boundary for reaction. Especially, the nanostructure thin films (NSTFs) electrode, an ultra-thin catalytic layer developed by 3M Company, demonstrates high performance and durability. Besides, some other researchers have employed the high conductive carbon nanotube arrays or high stable metal oxide arrays as the order-structured catalyst supports for fundamental …

Recent Progress In Solid-State Nmr Study Of Electrode/Electrolyte Materials For Lithium/Sodium Ion Batteries, Gui-Ming Zhong, Zi-Geng Liu, Da-Wei Wang, Qi Li, Ri-Qiang Fu, Yong Yang

Journal of Electrochemistry

Solid state NMR technique is a powerful tool for characterizing the local structure and compositions of solid materials quantitatively. A comprehensive understanding of the structure evolution during the electrochemical reactions of the materials for lithium/sodium ion batteries will be obtained with the combination of solid state NMR, XRD, and XAS methods. Through analyzing solid state NMR spectra, we can obtain the compositions, local structures and ion diffusion dynamics of electrodes, electrolytes and surface layers for lithium/sodium ion batteries, providing an important theoretical support for the design and development of high-performance materials for batteries. In this paper, we review the recent …

Reduced Graphene Oxide (Rgo) Hollow Network Cages For High-Performance Electrochemical Energy Storage, Chi Zhang, Xu-Jun He, Gao-Ren Li

Journal of Electrochemistry

The reduced graphese oxide (RGO) hollow network cages were synthesized via zinc oxide (ZnO) template-assisted electrodeposition. The as-prepared RGO hollow network cages exhibited the multi-level architectures, from nano sheets, porous structures, networks, to 3D microscaled hollow cages, which can simultaneously optimize transport of electroactive species, utilization rate of electrode material, and super capacitive performance. Electrochemical measurements confirmed the superior performance of RGO hollow network cages for supercapacitors (SCs), such as high Csp (393 F⋅g^-1 at 1.0 A⋅g^-1), excellent rate capability (21.2% Csp loss from 1.0 to 20 A⋅g^-1), and superior cycling stability (< 1% Csp loss after 10000 cycles).

Preparation And Characterization Of Van Der Waals Heterostructures, Horacio Coy Diaz

USF Tampa Graduate Theses and Dissertations

In this dissertation different van der Waals heterostructures such as graphene-MoS₂ and MoTe₂-MoS₂ were prepared and characterized. In the first heterostructure, polycrystalline graphene was synthesized by chemical vapor deposition and transferred on top of MoS₂ single crystal. In the second heterostructure, MoTe₂ monolayers were deposited on MoS₂ by molecular beam epitaxy.

Characterization of graphene-MoS₂ heterostructures was conducted by spin and angle resolve spectroscopy which showed that the electronic structure of the bulk MoS₂ and graphene in this van der Waals heterostructures is modified. For MoS₂ underneath the graphene, a band …

Synthesis, Structural Diversity, And Redox Control Of Cyclometalated Monoruthenium Complexes, Zhong-Liang Gong, Jiang-Yang Shao, Yu-Wu Zhong

Journal of Electrochemistry

Cyclometalated ruthenium complexes have received increasing attractions recently due to their excellent redox and photophysical properties. One structural feature of these complexes is that there is a ruthenium-carbon (Ru-C) σ bond presented in the molecule. Three common methods, namely, the “late metalation”, “early metalation”, and “transmetalation” methods, for the synthesis of cyclometalated ruthenium complexes are discussed and summarized. General strategies for the design of cyclometalating ligand and cyclometalated ruthenium complexes are introduced. By using different ancillary ligands, such as pyridine, imidazole, triazole, and pyrimidine, a great number of ruthenium complexes can be prepared. The presence of the Ru-C bond significantly …

3, 4-Ethylenedioxythiophene Monomer As Safety-Enhancing Additive For Lithium Ion Batteries, Wei-Xiao Ji, Feng Wang, Jiang-Feng Qian, Yu-Liang Cao, Xin-Ping Ai, Han-Xi Yang

Journal of Electrochemistry

Safety concern is a major obstacle hindering the wide applications of large-capacity lithium ion batteries (LIBs) in electric vehicles. In this paper, a polymerizable monomer of 3, 4-ethylenedioxythiophene (EDOT) was proposed and tested as an electrolyte additive for enhancing the safety of LIBs. The electro-oxidative polymerization behaviors and influence of PEDOT additive on the thermal behavior of LiCoO₂ cathode, as well as the safety performance and electrochemical properties of LiCoO₂-based LIBs were investigated. The results from cyclic voltammetry (CV) and transmission electron microscope (TEM) characterizations indicated that the monomer additive can be electro-oxidatively polymerized to form a …

Developments Of Photo-Assisted Fuel Cells, Ling-Ling Zhang, Shao-Jun Dong

Journal of Electrochemistry

The exploitation and utilization of fossil fuels have led to serious energy crisis and environmental pollution. In this case, the development of renewable energy is an alternative to traditional energy consumption. Fuel cells (FCs) can convert chemical energy into electricity via the electrochemical reaction, which is green and environment-friendly. Photo-assisted FCs integrate photo-responsive components into FCs, leading to the dual routes of energy conversion including light energy to electricity and chemical energy to electricity, and thus, improving the energy utilization efficiency. The development of photo-assisted FCs is significant for practical application and promising to solve the coming energy crisis. In …