Materials Science and Engineering Commons^™

Development Of Plasma Functionalized Nano-Additives For Oils And Study Of Their Tribological Properties, Vinay Sharma

Material Science and Engineering Dissertations - Archive

Lubricants used in motor engines contain various chemical species to help enhance energy efficiency and provide increased longevity. Unfortunately, at the same time, these additives become a source of catalytic poisoning, thus increasing emissions from the tailpipe. With growing concern for the negative impacts of human activities on the environment, regulatory bodies for the automobile lubrication industry have set up strict guidelines for chemical compositions of their end products, including engine oils. This research work is a step towards development of a new class of lubricant additives, which are less harmful to the environment and, simultaneously, also reduce friction and …

Artificial Olfactory System For Multi-Component Analysis Of Gas Mixtures., Alexander Aleksandrovich Larin

Electronic Theses and Dissertations

Gas analysis is an important part of our world and gas sensing technology is becoming more essential for various aspects of our life. A novel approach for gas mixture analysis by using portable gas chromatography in combination with an array of highly integrated and selective metal oxide (MOX) sensors has been studied. We developed a system with small size (7 x 13 x 16 inches), low power consumption (~10 W) and absence of special carrier gases designed for portable field analysis (assuming apriori calibration). Low ppb and even sub-ppb level of detection for some VOCs was achieved during the analysis …

Usa Boccia Ball Ramp For Athletes With Quadriplegia, Alissa A. Koukourikos, Matthew Lee, Nathan Bernards

Mechanical Engineering

In this report, the design process in creating an assistive device for Boccia Classification 3 (BC3) players is outlined. The initial research steps, including research into the rules of the game, capabilities of the players, and existing products is documented to show where ideas for the product stemmed from. This transitions into requirements that the sponsor requested, and preliminary designs and ideas for the product. Finally, this report explains the details of the final design, which has been analyzed for safety, ease of use, and ability to function under different conditions. The processes of manufacturing and testing will also be …

Antibacterial Activity Of Zno Nanoparticles On Silica Thin Film For Wastewater Treatment, S Chanrawangyot, S Rattanachan, A Watcharenwong, T Fangsuwannarak

Journal of Metals, Materials and Minerals

Zinc Oxide nanoparticles on silica matrix thin films were prepared by the Sol-gel method and dip coating on ceramic tiles. In this study, EC (Ethyl cellulose) and TP (alpha-terpineol) used as a binder and a solvent in Sol-gel method, respectively, were studied on the characteristics of thin films. The thin films were dried and calcined at the temperature of 500, 600˚C soaking 30 minutes with the heating rate of 1˚C/minutes. The result of Glancing X-Ray Diffraction showed that thin films were ZnO phase on the amorphous phase of silica matrix. Scanning electron microscope showed the ZnO nanoparticles dispersed on thin …

Properties Of Natural Rubber Latex Filled With Bacterial Cellulose Produced From Pineapple Peels, T Saowapark, E Chaichana, A Jaturapiree

Journal of Metals, Materials and Minerals

Bacterial cellulose (BC) is natural biopolymers with unique properties such as high purity and high tensile strength. These properties considerably support for use as filler in rubber applications. In this research, BC was produced from fermentation by Acetobacter xylinum. Additionally, pineapple peels (agricultural waste) were evaluated for carbon sources in BC's production process. Natural rubber latex (NRL) compound was then incorporated BC with various loadings of 0, 5, 10 and 15 phr (parts per hundred of rubber) for enhancement properties of NRL. Furthermore, NRL filled with BC (NRL-BC) compounds were prevulcanized at 70°C for 2 hours and then NRL-BC sheets …

Physical And Optical Properties Of 20cao-(80-X)B2o3-Xzno Glass System, N Jearnkulprasert, O Chaemlek, N Wantana, J Kaewkhao

Journal of Metals, Materials and Minerals

The 20CaO-(80-x)B2O3-xZnO glasses were prepared by melt quenching technique (where x=0, 5, 15 and 20 mol%) in order to study in the physical and optical properties. These glass compositions were heated to 1200 ºC for 3 hours and annealed at 500ºC for 3 hours. Clear glass samples were obtained from these compositions. The density, molar volume, refractive index, optical spectra (in the wavelength of 190-1100 nm), optical band gap, optical basicity and polarizability of glass samples have been investigated in this work.

Optical Flow Method For Blood Flow Velocimetry Based On Digital X-Ray Subtraction Angiography: A Brief Review, Zifeng Yang

Mechanical and Materials Engineering Faculty Publications

Detailed blood flow information has been recognized as the key information for diagnosis of vascular diseases, such as vascular stenosis and aneurysms. Optical flow method (OFM) is an emergent technique as a tool to analyze the digital x-ray subtraction angiographic images of blood vessels to obtain the detailed blood flow distribution in vascular systems. A brief review isconstructed to discuss the status, applicability, accuracy and future direction of the optical flow technique in the physical study of vascular flow.

Investigation On Ti6al4v-V-Cr-Fe-Ss316 Multi-Layers Metallic Structure Fabricated By Laser 3d Printing, Wei Li, Frank W. Liou, Joseph William Newkirk, Karen M. Brown Taminger, William J. Seufzer

Mechanical and Aerospace Engineering Faculty Research & Creative Works

Joining titanium alloy and stainless steel is becoming an urgent need since their outstanding mechanical properties can be utilized integratedly. However, direct fusion joining of Ti6Al4V to SS316 can cause brittle Ti-Fe intermetallics which compromise join bonds’ mechanical properties. In this research, Laser 3D Printing was applied to explore a new Ti6Al4V to SS316 multi-metallic structure. A novel filler transition route was introduced (Ti6Al4V → V → Cr → Fe → SS316) to avoid the Ti-Fe intermetallics. Two experimental cases were performed for comparison to evaluate this novel route’s effect. In the first case, SS316 layer was directly deposited on …

A High Quality And Quantity Hybrid Perovskite Quantum Dots (Cspbx3, X= Cl, Br And I) Powders Synthesis Via Ionic Displacement, Yuhang Yin, Weiling Luan, Chengxi Zhang, Fuqian Yang

Chemical and Materials Engineering Faculty Publications

Recently, all-inorganic perovskites CsPbX₃ (X= Cl, Br and I) quantum dots (QDs) have drawn great attentions because of their PL spectra tunable over the whole visible spectral region (400-700 nm) and adjustable bandgap, which revealed a promising potential on the field of photoelectronic devices, such as solar cells, LEDs and sensors. In this paper, CsPbX₃ QDs and hybrid QDs, CsPbClxBr3-x and CsPbBrxI3-x were synthesized via one-step and two-step methods comparably. The optical bandgaps of CsPbCl₃, CsPbBr₃, and CsPbI₃, were calculated as 3.08, 2.36, and 1.73eV, respectively, based on the Tauc's equation and …

Development Of Wo3 Nanostructure By Acid Treatment And Annealing, T Sanasi, S Pinitsoontorn, M Horprathum, P Eiamchai, C Chananonnawathorn, W Hincheeranun

Journal of Metals, Materials and Minerals

Tungsten oxide (WO3) nanostructure is an interesting material for many applications such as batteries, gas sensors, photocatalysts, display utilizing, and smart windows. In this work, we fabricated the WO3 nanoplates by sputtering, acid treatment and annealing. Firstly, a tungsten film was deposited on a silicon or glass substrate by sputtering. The film was then immersed in nitric acid (HNO3) at 80 °C. The effect of the exposure time, and annealing temperature was investigated. After the acid treatment, the tungsten oxide hydrate or tungstile (WO3•H2O) with nanoplate structure was developed. The optical transmittance in the visible range was significantly improved compared …

Preparation Of Benzoxazine Monomers And Prepolymers From Continuous Reactor: Effects Of Molecular Architecture On Properties, Andrew S. Frazee

Dissertations

Despite the modularity in molecular design and high-performance properties of benzoxazine thermoset chemistries, there are two primary shortcomings of benzoxazine marketability. Firstly, multifunctional benzoxazines are unfavorable for processing as they are glassy solids at ambient temperature. Secondly, benzoxazine chemistries are commercially synthesized using batch reactors, which are energy intensive and require the use of environmentally unfavorable solvents.

The purpose of the work herein is to address these shortcomings, which include:

1.) interrelationships between molecular architectures of synthesized monofunctional benzoxazine monomers and their ambient temperature physical states (i.e. liquid or solid) using molecular dynamics simulations and experimental comparisons,

2.) continuous high-shear …

Thermodynamics And Kinetics Of Dna Origami Cross-Tile Array Formation, Brett Michael Ward

Boise State University Theses and Dissertations

As the cost to continue scaling photolithography to pattern smaller semiconducting devices increases exponentially, new materials and fabrication approaches are being sought to extend and enhance current capabilities. DNA nanostructures have been identified as a promising material for patterning nanoscale devices, and several studies have demonstrated the ability to program DNA nanostructures to self-assemble into large scale arrays. These DNA arrays can be designed to create the patterns necessary for fabricating semiconductor device features. However, these structures are far from ideal and contain a number of defects that limit the adoption of this approach for manufacturing. In order to create …

Effects Of The Internal Magnetic Field On The Magneto-Mechanical Properties Of Magnetic Shape Memory Alloys, Anthony Hobza

Boise State University Theses and Dissertations

Shape memory alloys are a class of functional material which recover from large strains without permanent deformation. The strain is accommodated by the displacement of twin boundaries in the martensite phase. The shape memory alloy Ni-Mn-Ga is also ferromagnetic. Ni-Mn-Ga preferentially magnetizes along a certain crystallographic axis. This direction of easy magnetization changes across twin boundaries, such that the directions in neighboring twin domains are nearly perpendicular.

The interaction of magnetic moments and interfaces including the crystal surface and twin boundary interfaces has a large role in the magnetization process of the material. The goal of this study is to …

A Comparison Study Of Composite Laminated Plates With Holes Under Tension, Joun S. Kim

Master's Theses

A Comparison Study of Composite Laminated Plates with Holes under Tension

A study was conducted to quantify the accuracy of numerical approximations to deem sufficiency in validating structural composite design, thus minimizing, or even eliminating the need for experimental test. Error values for stress and strain were compared between Finite Element Analysis (FEA) and analytical (Classical Laminated Plate Theory), and FEA and experimental tensile test for two composite plate designs under tension: a cross-ply composite plate design of [(0/90)4]s, and a quasi-isotropic layup design of [02/+45/-45/902]s, each with a single, centered hole of 1/8” diameter, and 1/4" diameter (four sets …

Block Copolymer Nanostructures For Inorganic Oxide Nanopatterning, Krishna Pandey

Graduate Theses/Dissertations

Self-assembled nature of block copolymer (BCP) makes them ideal for emerging technologies in nanometer scale. The micro phase separation between two or more dissimilar polymer blocks of BCP leads to uniform periodic nanostructures of different domains of dimension in the range of 5-100 nm, good for the development of emerging microelectronic and optoelectronics devices. Molecular weight and chain architecture of each blocks govern the morphology evolution; gives different structure like spherical, micelles, lamellae, cylindrical, gyroid etc. The morphology evolution of BCP nanostructure also depends on different external factors as well. In the first work of this thesis, three external factors …

Kinetic Study Of Chitosan-Alginate Biopolymeric Nanoparticles For The Controlled Release Of Curcumin Diethyl Disuccinate, S Bhunchu, P Rojsitthisak, P Rojsitthisak

Journal of Metals, Materials and Minerals

The aim of this study was to investigate the release profile, and evaluate the best fitted kinetic model and mechanism, of curcumin diethyl disuccinate (CDD) from chitosan-alginate biopolymeric nanoparticles (CANPs) in simulated gastrointestinal fluids (without enzymes) and simulated body fluid. The CDD-loaded CANPs (CDD-CANPs) were prepared by oil-in-water emulsification and ionotropic gelation under the previously reported optimal condition (3 mg/mL of CDD, 4.05% (w/v) of TweenTM 80 and a chitosan:alginate mass ratio of 0.05:1), which resulted in CDD-CANPs with a favorable particle size (327±14 nm), zeta potential (-27.3±0.2 mV), encapsulation efficiency (51.2±2.2%) and loading capacity (11.2±0.8%). The in vitro release …

Utilization Of Aluminium Dross As A Main Raw Material For Synthesis Of Geopolymer, P Puksisuwan, P Laoratanakul, B Cherdhirunkorn

Journal of Metals, Materials and Minerals

Aluminium dross contains both small particles and large agglomerates, where the recyclable part is the large agglomerates with high aluminium metal content. The residual Al dross is unrecyclable small particles with very low aluminium metal content. In this research, the residual Al dross from the aluminium recycle industry and the bagasse ash from a biomass power plant were used as main raw materials for geopolymer fabrication with alkaline solutions (Na2SiO3 and NaOH) using in the typical geopolymerization process. After mixing with alkaline solutions, the mixtures were uniaxially pressed into a cylinder die. The samples were cured for 3, 7, 14 …

Synthesis And Characterization Of Glycidyl Methacrylate-Based Graft Copolymer Functional Interfaces, Nikolay Brordinov

All Dissertations

Modification of materials properties such as surface energy, wettability, ability to absorb, contain or release specific type of chemicals enables practical application of these materials in various scientific and engineering set-ups. However, designing protocol that could be easily adapted for different situations and simultaneously unlock multiple variations of the resulting properties is a non-trivial task. This dissertation is devoted to application of glycidyl methacrylate-based graft copolymers for the purposes of surface modification, establishing fundamental trends and dependencies of this process and exploring the possible range of applications. These materials have extremely valuable property to undergo controllable post-synthetic modifications including surface …

Nanograin Size Effects On The Strength Of Biphase Nanolayered Composites, Sixie Huang, Irene J. Beyerlein, Caizhi Zhou

Materials Science and Engineering Faculty Research & Creative Works

In this work, we employ atomic-scale simulations to uncover the interface-driven deformation mechanisms in biphase nanolayered composites. Two internal boundaries persist in these materials, the interlayer crystalline boundaries and intralayer biphase interfaces, and both have nanoscale dimensions. These internal surfaces are known to control the activation and motion of dislocations, and despite the fact that most of these materials bear both types of interfaces. From our calculations, we find that the first defect event, signifying yield, is controlled by the intralayer spacing (grain size, d), and not the intralayer biphase spacing (layer thickness, h). The interplay of two internal sizes …

Controlled Electrochemical Reduction Of Gold And Palladium Metal Precursors In Polyaniline, Nicole Goodwin

UNLV Theses, Dissertations, Professional Papers, and Capstones

Polyaniline (PANI) has been extensively studied due to its unique electrochemical properties. The conjugated polymer is conductive with high chemical stability below 100°C, mechanical strength, and large surface area. The applications of PANI have included chemical sensing, corrosion inhibition coatings, light emitting diode and as a substrate for metal composite catalysts. Both chemical and electrochemical methods have been developed and utilized in the synthesis of PANI/metal composites. The simultaneous reduction of aniline and metal precursor produces a composite of PANI encapsulated metal, reducing the active surface area available for catalysis. Alternatively, chemical reduction of the metal precursor into preformed PANI …