Materials Science and Engineering Commons^™

Effect Of Anisotropic Elasticity On Dislocation Pile-Ups At Grain Boundaries, Xiaolei Chen, Stéphane Berbenni, Christian Motz, Thiebaud Richeton

Nanomechanical Testing in Materials Research and Development VII

This study deals with in-situ micromechanical tests of micron-sized bi-crystals and observations coupling SEM, AFM and EBSD. Different FCC bi-crystals are obtained from FIB machining. A SEM in-situ compression test with a low strain is performed on a micron-sized bi-crystal in order to induce single slip deformation. Spatial variations in the surface step height due to dislocation activity in localized slip bands terminating at the grain boundary (GB) are measured by AFM. This allows the determination of the Burgers vector distribution and hence the dislocation positions in the pile-up as shown in Figure 1. Furthermore, local misorientation along slip bands …

Conference Program, Jon Molina-Aldareguia

Nanomechanical Testing in Materials Research and Development VII

No abstract provided.

Optical Response Of Bifeo3 Films Subjected To Uniaxial Strain, Andrew Herklotz, Stefania Rus, Changhee Sohn, Santosh Kc, Valentino Cooper, Er-Jia Guo, Thomas Ward

Faculty Publications

The impact of single-axis lattice expansion on the optical response of BiFeO3 films is examined. Low-energy He implantation is used to tailor morphotropic phases of BiFeO3 films and study changes in their optical spectra with continuously increasing lattice expansion. He ion implantation of epitaxial rhombohedral (R)- and tetragonal (T)-like BiFeO3 films induces uniaxial out-of-plane strain that, on R-like films, eventually leads to a complete R-T phase transition. This approach allows us to provide insights into the optical response of BiFeO3 films. Strain doping of T-like films leads to a significant redshift of the optical absorption spectra that is theoretically explained …

Optimization And Structural Stability Of Gold Nanoparticle–Antibody Bioconjugates, Robert T. Busch, Farzia Karim, John Weis, Yvonne Sun, Chenglong Zhao

Chemical and Materials Engineering Faculty Publications

Gold nanoparticles (AuNPs) bound with biomolecules have emerged as suitable biosensors exploiting unique surface chemistries and optical properties. Many efforts have focused on antibody bioconjugation to AuNPs resulting in a sensitive bioconjugate to detect specific types of bacteria. Unfortunately, bacteria thrive under various harsh environments, and an understanding of bioconjugate stability is needed. Here, we show a method for optimizing Listeria monocytogenes polyclonal antibodies bioconjugation mechanisms to AuNPs via covalent binding at different pH values, from 2 to 11, and 2-(N-morpholino)ethanesulfonic acid (MES), 3-(N-morpholino)propanesulfonic acid, NaOH, HCl conditions. By fitting Lorentz curves to the amide I and II regions, we …

Force Oscillations Distort Avalanche Shapes, Louis W. Mcfaul, Wendelin J. Wright, Jordan Sickle, Karin A. Dahmen

Faculty Journal Articles

Contradictory scaling behavior in experiments testing the principle of universality may be due to external oscillations. Thus, the effect of damped oscillatory external forces on slip avalanches in slowly deformed solids is simulated using a mean-field model. Akin to a resonance effect, oscillatory driving forces change the dynamics of avalanches with durations close to the oscillation period. This problem can be avoided by tuning mechanical resonance frequencies away from the range of the inverse avalanche durations. The results provide critical guidance for experimental tests for universality and a quantitative understanding of avalanche dynamics under a wide range of driving conditions.

Application Of Active And Edible Films Of Sodium Caseinate To Extend The Shelf-Life Of Argentine Pategrás Cheese, Brenda S. Álvarez, Natalia Damiani, Marina Czerner, Josefa F. Martucci, Liesel B. Gende

Journal of Applied Packaging Research

Argentine Pategrás cheese is one of the most popular types of cheese in Argentina. The main spoilage causes in these products are microbiological contamination and lipid rancidity. Semi-hard cheeses are usually covered with a paraffin wax that favors its preservation. When pieces are stored, cutting faces must be protected to prevent desiccation and contamination. Active biodegradable films are an alternative to the traditional materials, in particular, casein-based edible films are attractive for food applications. In the present work, active films of sodium caseinate with oregano (Origanum vulgare) and laurel (Laurus nobilis) essential oils were produced for …

Mitigating Reflective Cracking Through The Use Of A Ductile Concrete Interlayer, Qian Zhang, Mohammad Khattak, Adway Das

Data

Corresponding data set for Tran-SET Project No. 18PLSU13. Abstract of the final report is stated below for reference:

"Reflective cracking is considered one of the most important issues that causes premature deterioration of composite pavements. Many types of mitigation methods have been studied in the past. However, they are either not effective in delaying the reflective cracking, or they only extend the service life by a few years. To address this critical issue and significantly extend the service life of the composite pavement, in this research, a ductile interlayer made of engineered cementitious composites (ECC) was proposed. It was hypothesized …

Development Of Geopolymer-Based Cement And Soil Stabilizers For Transportation Infrastructure, Miladin Radovic, Anand Puppala

Data

Corresponding data set for Tran-SET Project No. 18CTAM03. Abstract of the final report is stated below for reference:

"Geopolymer Cement (GPC) has drawn much attention in the recent years as an alternative to Ordinary Portland Cement (OPC) for soil stabilization, pavements, bridges and other transportation structures due to their good mechanical properties in comparison to OPC. In addition, GPC can be processed at room temperatures from aqueous solutions of waste materials (e.g. fly ash) or abundant natural sources (e.g. clay), thereby significantly reducing CO2 production associated with processing of OPC. As such, GPC proves to be a more sustainable and …

Toward Non-Corrosion And Highly Sustainable Structural Members By Using Ultra-High-Performance Materials For Transportation Infrastructure, Shih-Ho Chao, Ashish Karmacharya

Data

Corresponding data set for Tran-SET Project No. 18STUTA01. Abstract of the final report is stated below for reference:

"This research focused on investigating a highly sustainable and efficient reinforced concrete structural member for future infrastructure by utilizing emerging high-performance materials. These materials include ultra-high-performance fiber-reinforced concrete (UHP-FRC) and corrosion-resistant high-strength fiber-reinforced polymer (FRP) bars. Four reduced scale UHP-FRC specimens were tested under large displacement reversals to prove the proposed new ductile-concrete strong-reinforcement (DCSR) design concept by fully utilizing these ultra-high-performance materials. Micro steel fibers were incorporated into three specimens and ultra-high molecular weight polyethylene fibers were blended into the fourth …

Rare But Conceivable: Determining The Likelihood Of Meteors And Other Infrequent Events, Michael S. Schmidt, Maria Vega-Westhoff

Engineering Management and Systems Engineering Faculty Research & Creative Works

In the aftermath of a rare but devastating disaster, there is a tendency to overestimate how frequent such an event may be, hence a tendency to overestimate the risk associated with such an event. Those concerned with process safety will acknowledge that though rare, events like meteors, hurricanes, and airplane crashes that can impact chemical plants are conceivable. Typically, though, they have nothing more than feelings to decide whether these events are likely enough to be considered "credible." This compiles data from the literature for several "meteors," both natural and man-made, that often become a cause of general concern after …

Mitigating Reflective Cracking Through The Use Of A Ductile Concrete Interlayer, Qian Zhang, Mohammad Khattak, Adway Das

Publications

Reflective cracking is considered one of the most important issues that causes premature deterioration of composite pavements. Many types of mitigation methods have been studied in the past. However, they are either not effective in delaying the reflective cracking, or they only extend the service life by a few years. To address this critical issue and significantly extend the service life of the composite pavement, in this research, a ductile interlayer made of engineered cementitious composites (ECC) was proposed. It was hypothesized that by adding a thin layer of highly ductile ECC material between the existing pavement and overlay, reflective …

Investigation Of Physical And Dynamic Properties Of High Porous Concrete, Ildar Akhmadullin

Publications

This project pursued two main objectives: (1) providing opportunities to Baton Rouge Community College (BRCC) students to develop hands-on laboratory skills and exposure to the transportation field, and (2) investigating porous concrete properties. Several BRCC student groups performed the work presented within this report; students prepared samples with different porosity and permeability according to standard specifications. The testing of the samples was performed at the Louisiana Transportation Research Center (LTRC) facility under the supervision of LTRC specialists. Findings indicate that the porosity of samples is backward proportional to the compression strength. This function is not linear but can be estimated …

Toward Non-Corrosion And Highly Sustainable Structural Members By Using Ultra-High-Performance Materials For Transportation Infrastructure, Shih-Ho Chao, Ashish Karmacharya

Publications

This research focused on investigating a highly sustainable and efficient reinforced concrete structural member for future infrastructure by utilizing emerging high-performance materials. These materials include ultra-high-performance fiber-reinforced concrete (UHP-FRC) and corrosion-resistant high-strength fiber-reinforced polymer (FRP) bars. Four reduced scale UHP-FRC specimens were tested under large displacement reversals to prove the proposed new ductile-concrete strong-reinforcement (DCSR) design concept by fully utilizing these ultra-high-performance materials. Micro steel fibers were incorporated into three specimens and ultra-high molecular weight polyethylene fibers were blended into the fourth specimen. One specimen with ASTM A1035 MMFX high-strength steel rebars, one with high-strength glass fiber reinforced polymer (GFRP) …

Development Of Geopolymer-Based Cement And Soil Stabilizers For Transportation Infrastructure, Miladin Radovic, Anand Puppala

Publications

Geopolymer Cement (GPC) has drawn much attention in the recent years as an alternative to Ordinary Portland Cement (OPC) for soil stabilization, pavements, bridges and other transportation structures due to their good mechanical properties in comparison to OPC. In addition, GPC can be processed at room temperatures from aqueous solutions of waste materials (e.g. fly ash) or abundant natural sources (e.g. clay), thereby significantly reducing CO2 production associated with processing of OPC. As such, GPC proves to be a more sustainable and environmentally friendly alternative than OPC. This research explores methods to develop GPC with desired properties and evaluate their …

Grain Size Effects In Selective Laser Melted Fe-Co-2v, Wesley Everhart, Joseph William Newkirk

Materials Science and Engineering Faculty Research & Creative Works

The material science of additive manufacturing (AM) has become a significant topic due to the unique way in which the material and geometry are created simultaneously. Major areas of research within inorganic materials include traditional structural materials, shape memory alloys, amorphous materials, and some new work in intermetallics. The unique thermal profiles created during selective laser melting (SLM) may provide new opportunities for processing intermetallics to improve mechanical and magnetic performance. A parameter set for the production of Fe-Co-2V material with additive manufacturing is developed and efforts are made to compare the traditional wrought alloy to the AM version of …

Improving Boron For Combustion Applications, Kerri-Lee Annique Chintersingh

Dissertations

Boron has received much attention as a potential additive to explosives and propellants due to its high theoretical gravimetric and volumetric heating values. The challenge, however, is that boron particles tend to agglomerate, have lengthy ignition delays and very low combustion rates. Prior research indicates that boron’s long ignition delays are due to its inhibiting naturally occurring oxide layer, impeding the diffusion of reactants for oxidation. For combustion, current studies report that boron particles have two consecutive stages, but the actual reaction mechanism is poorly understood. Despite many years of relevant research, quantitative combustion data on micron-sized boron particles are …

Low-Cost Open Source Ultrasound-Sensing Based Navigational Support For The Visually Impaired, Aliaksei Petsiuk, Joshua M. Pearce

Michigan Tech Publications, Part 1

Nineteen million Americans have significant vision loss. Over 70% of these are not employed full-time, and more than a quarter live below the poverty line. Globally, there are 36 million blind people, but less than half use white canes or more costly commercial sensory substitutions. The quality of life for visually impaired people is hampered by the resultant lack of independence. To help alleviate these challenges this study reports on the development of a low-cost, open-source ultrasound-based navigational support system in the form of a wearable bracelet to allow people with the lost vision to navigate, orient themselves in their …

Modifications Of The Cztse/Mo Back-Contact Interface By Plasma Treatments, Wenjin Chen, Teoman Taskesen, David Nowak, Ulf Mikolajczak, Mohamed H. Sayed, Devendra Pareek, Jorg Ohland, Thomas Schnabel, Erik Ahlswede, Dirk Hauschild, Lothar Weinhardt, Clemens Heske, Jurgen Parisi, Levent Gutay

Chemistry and Biochemistry Faculty Research

Molybdenum (Mo) is the most commonly used back-contact material for copper zinc tin selenide (CZTSe)-based thin-film solar cells. For most fabrication methods, an interfacial molybdenum diselenide (MoSe2) layer with an uncontrolled thickness is formed, ranging from a few tens of nm up to ≈1 μm. In order to improve the control of the back-contact interface in CZTSe solar cells, the formation of a MoSe2 layer with a homogeneous and defined thickness is necessary. In this study, we use plasma treatments on the as-grown Mo surface prior to the CZTSe absorber formation, which consists of the deposition of stacked metallic layers …

Abrasion Resistance Of High Early-Strength Concrete For Rapid Repair, Nader Ghafoori, Matthew O. Maler, Meysam Najimi, Ariful Hasnat

Civil and Environmental Engineering and Construction Faculty Research

This paper examines the abrasion resistance of high early-strength concrete developed for rapid repair of highways and bridge decks. The cement types chosen for this study included ASTM Type III, ASTM Type V, and Calcium Sulfoaluminate (CSA) cements. A cement content of 386 kg/m3 (650 lb/yd3 ) was maintained for all studied concretes. Test samples were tested after 24 hours and 28 days of curing in order to evaluate compressive strength and depth of wear. Test results revealed that the opening time to attain minimum required compressive strength for CSA cement concrete was one hour, whereas the values for Type …

Properties Of High Early-Strength Type V Cement Concrete For Rapid Repair, Nader Ghafoori, Matthew O. Maler, Meysam Najimi, Ariful Hasnat

Civil and Environmental Engineering and Construction Faculty Research

This study examines the suitability of ASTM Type V cement concrete for rapid repair applications. To this end, experimental results on transport and durability properties of high earlystrength concretes using ASTM Type V cement were compared with those of a more traditional cement used for rapid repair, i.e. Type III cement. A cement content of 445 kg/m3 (750 lb/yd3 ) was maintained for all studied concretes. The experimental program included compressive strength, absorption, rapid chloride migration, corrosion resistance, and mass loss due to freezing and thawing regimes. The results of this study revealed that use of Type III and V …