Double-Sided Corrugated Composite Tube And Axle Protective Mechanism For Railway Vehicles,
2019
University of Nebraska-Lincoln
Double-Sided Corrugated Composite Tube And Axle Protective Mechanism For Railway Vehicles, Hozhabr Mozafari
Department of Mechanical and Materials Engineering: Dissertations, Theses, and Student Research
Structural elements in transportation vehicles are exposed to different types of dynamic loadings and impact scenarios. Protecting passengers against injury and providing mechanisms to avoid impact induced damages to the critical components are the two hot topics in crashworthiness engineering. The presented research work includes two parts. The first part is about designing a novel double-sided composite corrugated tube that can be implemented in front chassis rail of ground vehicles to improve their crashworthiness against collision and car accidents. To maximize the controllable energy absorption of corrugation troughs as observed in the single sided corrugated (SSC) tube, we proposed and …
Fabrication And Characterization Of Electrical Energy Storage And Harvesting Energy Devices Using Gel Electrolytes,
2019
University of South Florida
Fabrication And Characterization Of Electrical Energy Storage And Harvesting Energy Devices Using Gel Electrolytes, Belqasem Aljafari
USF Tampa Graduate Theses and Dissertations
Redox-active materials in the bulk of gel electrolytes are unquestionably holding the primary roles in developing energy harvesting and storage technology. Both technologies are necessary in order to cope with the current challenges of the environmental crises of global warming and finite non-renewable sources while the demand for energy modern societies have been speedily increased. One of the most challenges of making a hybrid device of energy conversion and storage is the cost of the fabrication process. Therefore, gel electrolyte-based materials with redox-active properties can potentially be a promising solution to improve the performance of electrochemical and photoelectrochemical devices for …
Sorption Of Benzene, Toluene, Ethylbenzene And Different Ratios Of Mixture Solvent By Plasticized Pema Films Using A Qcm Sensor,
2019
University of South Florida
Sorption Of Benzene, Toluene, Ethylbenzene And Different Ratios Of Mixture Solvent By Plasticized Pema Films Using A Qcm Sensor, Xinpeng Li
USF Tampa Graduate Theses and Dissertations
VOCs (volatile organic compounds) can cause great harm to human health especially benzene, toluene and ethylbenzene. In this work a Quartz Crystal Microbalance (QCM) sensor with a polymer/plasticizer film was developed to quantify the VOCs both in air and water. QCM is an acoustic wave sensor that can be used well in detecting the aromatic compounds in the film. Because more than one VOC is present in the air, this thesis focuses on finding the sorption of different ratios of VOCs (benzene, toluene, ethylbenzene) using a polymer/plasticizer film in QCM. Poly (ethyl methacrylate) (PEMA) was used as the polymer because …
From Critical Behavior To Catastrophic Runaways: Comparing Sheared Granular Materials With Bulk Metallic Glasses,
2019
University of Illinois at Urbana-Champaign
From Critical Behavior To Catastrophic Runaways: Comparing Sheared Granular Materials With Bulk Metallic Glasses, Alan A. Long, Dmitry Denisov, Peter Schall, Todd C. Hufnagel, Xiaojun Gu, Wendelin J. Wright, Karin A. Dahmen
Faculty Journal Articles
The flow of granular materials and metallic glasses is governed by strongly correlated, avalanche-like deformation. Recent comparisons focused on the scaling regimes of the small avalanches, where strong similarities were found in the two systems. Here, we investigate the regime of large avalanches by computing the temporal profile or “shape” of each one, i.e., the time derivative of the stress-time series during each avalanche. We then compare the experimental statistics and dynamics of these shapes in granular media and bulk metallic glasses. We complement the experiments with a mean-field model that predicts a critical size beyond which avalanches turn into …
Extrusion Of Perovskite Oxide/ Silica Composites For Thermochemical Carbon Dioxide Conversion,
2019
University of South Florida
Extrusion Of Perovskite Oxide/ Silica Composites For Thermochemical Carbon Dioxide Conversion, Qian Li
USF Tampa Graduate Theses and Dissertations
In order to solve the increasing greenhouse effect problem, perovskite-type oxides have been used to convert CO2 to CO in a reverse water-gas shift chemical looping (RWGS-CL) process. Currently, the process is at the micro-reactor scale and used catalyst in powder form. However, formed materials are needed if the scale is to be increased.
Our research focus is on increasing the conversion yield of perovskite oxides with SiO2 support and scaling up the powder form perovskite-type oxides to pellet by extrusion. The binder added during the extrusion process must be removed to avoid affecting the performance of the catalyst and …
Thermo-Oxidative Degradation Of Hdpe Geomembranes: Effect Of Phenolic Antioxidant And Hindered Amine Light Stabilizer Concentrations,
2019
University of South Florida
Thermo-Oxidative Degradation Of Hdpe Geomembranes: Effect Of Phenolic Antioxidant And Hindered Amine Light Stabilizer Concentrations, Yasin Kocak
USF Tampa Graduate Theses and Dissertations
High density polyethylene (HDPE) geomembrane is most common geomembrane which is mainly used for civil engineering applications. However, HDPE geomembrane loses its properties under oxidative degradation progress. This study aims to assess geomembranes which have different percentage of phenolic antioxidant and hindered amine light stabilizer (HALS) with under the six months of the thermal-oxidative degradation. The interactions between phenolic antioxidant, HALS and carbon black can affect the mechanical, physical and chemical properties. To monitor these properties, Differential Scanning Calorimetry (DSC), Fourier-transform Infrared Spectroscopy (FTIR), Thermogravimetric Analysis (TGA), Scanning Electron Microscopy coupled with Energy Dispersive X-ray spectroscopy (SEM/EDX), Melt Index tests, …
Development Of A Technology For Producing A Gel Composition For The Treat-Ment Of An Allergy Complicated By Fungal Infection,
2019
Institute of Bioorganic Chemistry, Tashkent, Uzbekistan
Development Of A Technology For Producing A Gel Composition For The Treat-Ment Of An Allergy Complicated By Fungal Infection, Filatova Albina Vasilevna, Turaev Abbaskhan Sabirkhanovich, Djurabaev Djalol Turgunbaevich
CHEMISTRY AND CHEMICAL ENGINEERING
The results of the development of the technology of the combined external drug for the treatment of allergies compli-cated by fungal infection are given. The rheological properties of the gel composition were studied in comparison with the similar preparation Fenistil gel, it was shown that the dynamic viscosity of the drug is 4.1 Pa·s, the active components (diphenylhydramine, fluconazole, Timoptin) do not destroy the structure of the gel base. A technological and instrumental scheme for the production of the drug has been developed.
Properties Of Model Rubber Compounds With Modified Angren Kaolin,
2019
Tashkent Chemiсal-Technological Institute, Uzbekistan
Properties Of Model Rubber Compounds With Modified Angren Kaolin, Vapaev Murodjon Dusummatovih, Teshabaeva Elmira Ubaydullaevna, Ibadullaev Ahmadjon
CHEMISTRY AND CHEMICAL ENGINEERING
As a result of studies, the effect of modified Angren kaolin on the properties of elastomeric compositions based on synthetic polyisoprene and oil-filled styrene-butadiene rubbers were revealed. Plastoelastic and relaxation properties, as well as resistance to scorching and vulcanization kinetics of rubber compounds with traditional and modified Angren kaolin, were determined. The relationship of the elastic-strength properties of vulcanizates with the type and quantitative content of the modified Angren kaolin used is established.
Proppant For Use In Hydraulic Fracturing To Stimulate A Well,
2019
University of Kentucky
Proppant For Use In Hydraulic Fracturing To Stimulate A Well, Thomas Lee Robl, Anne Elizabeth Oberlink
Center for Applied Energy Research Faculty Patents
A proppant for use in hydraulic fracturing to stimulate a well is provided. The proppant is fly ash particles having a mean particle size (d50) of between 45 μm and 150 μm and a size distribution defined by (d10) ≤ 5 μm and (d98) ≤ 250 μm.
Three-Dimensional Porous Vn Octahedron Catalyst With High Electrocatalytic Efficiency Toward Hydrogen Evolution Reaction,
2019
State Key Laboratory of Power Transmission Equipment & System Security and New Technology, The School of Chemistry and Chemical Engineering, Chongqing University, Chongqing, 400044, China;
Three-Dimensional Porous Vn Octahedron Catalyst With High Electrocatalytic Efficiency Toward Hydrogen Evolution Reaction, Can Yin, Wei-Wei Fu, Ling Fang, Shi-Li You, Hui-Juan Zhang, Yu Wang
Journal of Electrochemistry
With the rapid development of China’s economy, the demand for energy is increasing, and environmental problems are becoming more and more serious. The development and utilization of highly-clean new energy fuel can effectively alleviate the energy crisis and environmental pollution. Nowadays, exploring high-efficiency, environment-friendly and low-cost catalysts remains the focus of research in the hydrogen evolution reaction (HER). In this research, firstly, we proposed a three-dimensional porous vanadium nitride (VN) with octahedral structure, which was prepared by a calcination treatment method. The VN catalyst showed a good electrocatalytic activity toward HER, involving a small overpotential of 94.0 mV at -10 …
Influences Of Morphology And Nitrogen Doping On The Electrocatalytic Characteristics For Oxygen Reduction Reaction Of Nio/Rgo,
2019
Shandong Provincial Key Laboratory of Fluorine Chemistry Material, School of Chemistry and Chemical Engineering, University of Jinan, Jinan 250022, China;
Influences Of Morphology And Nitrogen Doping On The Electrocatalytic Characteristics For Oxygen Reduction Reaction Of Nio/Rgo, Dong Liang, Heng-Yi Fang, Shuo Yao, Jie-Mei Yu, Zhao-Liang Zhang, Zhan-Kun Jiang, Xue-Ping Gao, Tai-Zhong Huang
Journal of Electrochemistry
In this research, the reduced graphene oxide (rGO) supported sheet-like NiO (NiO/rGO) and spherical-like NiO (NiO/N-rGO) catalysts for oxygen reduction reaction (ORR) were prepared. The structures, morphologies and chemical states of the two catalysts were characterized by X-ray diffraction (XRD), Raman spectroscopy, X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The electrochemical catalytic performance of the two catalysts for ORR were investigated by cyclic voltammetry (CV), Tafel, linear sweeping voltammetry (LSV), rotating disc electrode (RDE) and rotating ring disc electrode (RRDE) tests. Electrochemical results showed that the current density and onset potential (about 0.89 V) …
Special Issue: Electrocatalysis And Fuel Cells,
2019
State Key Laboratory of Chemo/Biosensing and Chemometrics College of Chemistry and Chemical Engineering Hunan University;
Special Issue: Electrocatalysis And Fuel Cells, Shuangyin Wang
Journal of Electrochemistry
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Pd Nanoparticles Supported On The Etched Ni Foams As High-Performance Electrocatalysts For Direct Ethanol Fuel Cells,
2019
MOE Laboratory of Bioinorganic and Synthetic Chemistry, The Key Lab of Low-carbon Chemistry & Energy Conservation of Guangdong Province, School of Chemistry, Sun Yat-sen University,Guangzhou 510275, China;
Pd Nanoparticles Supported On The Etched Ni Foams As High-Performance Electrocatalysts For Direct Ethanol Fuel Cells, Chi Zhang, Cheng-Fei Li, Gao-Ren Li
Journal of Electrochemistry
The development of non-Pt anode electrocatalysts with high activity and long-term durability at low cost for fuel cells still remains enormous challenge. Here we report the Pd nanoparticles supported on Ni foams etched by the mixed acids (HNO3+H2SO4+H3PO4+CH3COOH) (Pd/ME-NF) that are designed and fabricated as high-performance electrocatalysts for ethanol oxidation in alkaline media. Because of the advantages of large open space, fast electrolyte penetration/diffusion and rapid electron transfer process, the Pd/ME-NF catalysts exhibited significantly improved electrocatalytic activity and durability compared with the commercial Pd/C catalysts.
A Facile Route To Synthesize Pt-Wo3 Nanosheets With Enhanced Electrochemical Performance For Her,
2019
School of Physics and Electronics, College of Materials Science and Engineering, Key Laboratory for Micro-Nano Optoelectronic Devices of Ministry of Education, Hunan University, Changsha 410082, China;
A Facile Route To Synthesize Pt-Wo3 Nanosheets With Enhanced Electrochemical Performance For Her, Peng-Jie Jiang, Yi Lv, Chang-Miao Chen, Hong-Cheng He, Yong Cai, Ming Zhang
Journal of Electrochemistry
Platinum-tungsten trioxide (Pt-WO3) nanosheets were synthesized on nickel foams (NFs) directly. As great conductive networks, NFs substrates could greatly improve the electrode performance of WO3. The modified platinum nanoparticles not only enhanced the electron transformation of catalysts, but also increased the active sites for hydrogen evolution reaction (HER). Pt-WO3/NF revealed a better catalytic activity than WO3/NFs with a smaller Tafel slope (80 mV·dec-1) and a lower overpotential of 72 mV at the current density of 10 mA·cm-2. In addition, Pt-WO3/NF showed great durability and stability during …
Progress In Solar Photocatalytic Hydrogen Production,
2019
State Key Laboratory of Physical Chemistry of Solid Surfaces, Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian, China;
Progress In Solar Photocatalytic Hydrogen Production, Zhi Wu, Lan Sun, Chang-Jian Lin
Journal of Electrochemistry
With the rapid development of human society and dramatically consumption of traditional energy, energy shortage and environmental pollution have become an important factor restricting the sustainable development of human society. At present, the development of clean and environmentally friendly renewable energy system has drawn much attention and becomes an important priority stratagem in the world. In many green and sustainable new energy projects, semiconductor-based photocatalytic hydrogen production technology which utilizes the available clean and renewable solar energy to prepare clean hydrogen energy is excepted to solve the crisis of energy shortage and environmental pollution, has become one of the most …
Nickel Selenide Derived From [Ni(En)3](Seo3) Complex For Efficient Electrocatalytic Overall Water Splitting,
2019
Key Laboratory of Applied Surface and Colloid Chemistry, Ministry of Education and School of Chemistry and Chemical Engineering, Shaanxi Normal University, Xi’an 710119, China;
Nickel Selenide Derived From [Ni(En)3](Seo3) Complex For Efficient Electrocatalytic Overall Water Splitting, Dan-Dan Chen, Xue-Qing Gao, Hong-Fei Liu, Wei Zhang, Rui Cao
Journal of Electrochemistry
Electrocatalytic water splitting is considered as a promising technology for renewable energy. The development of efficient, stable, cost-effective, and bifunctional catalysts for both water reduction and oxidation has continued to face significant challenges. Herein, we report a robust and highly active nickel selenide (NiSe) spheres grown on carbon cloth (CC) by electrodeposition from a nickel selenite complex which is a single source containing both Ni and Se. A combination of two chemicals containing, separately, Ni and Se is used in traditional preparations of metal selenides, causing possible problems in the uniformity of the products. The as-prepared NiSe-EA/CC electrode exhibited electrocatalytic …
Preparation Of Nanostructural Mno-Porous Graphene Hybrid Material By Thermally-Driven Etching Of Mno For Lithium-Air Batteries,
2019
Laboratory of Clean Energy Chemistry and Materials, Lanzhou Institute of Chemical Physics, Chinese Academy of Science, Lanzhou 730000;
Preparation Of Nanostructural Mno-Porous Graphene Hybrid Material By Thermally-Driven Etching Of Mno For Lithium-Air Batteries, Juan Yang, Jun-Wei Lang, Peng Zhang, Bao Liu
Journal of Electrochemistry
In this paper, improving the surface morphology of graphene(GNSs) as designed concept. we describe a MnO/porous-graphene(MnO-PGNSs) was synthesized by a simple site-localized Mn2+ on GO (Mn-GO) by charge adsorption and then driving by high-temperature calcination, growing MnO nanoparticles and etching GNSs achieved on step. And Then focus on the key factors of influenced the etch hole formation are analyzed, founded the dispersion of Mn-GO; layer number of GO and calcination temperature also affected the formation of holes. In addition, the MnO-PGNSs as lithium-air battery cathode exhibits high reversible capacity compared with GNSs and PGNs and it is able to …
Investigations In Electrochemical Thermodynamic And Kinetic Properties Of As-Cast And As-Quenched Cemg10Ni2 Hydrogen Storage Alloys,
2019
Department of Functional Material Research, Central Iron and Steel Research Institute,Beijing 100081, China;The School of Materials and Metallurgy, Inner Mongolia University of Science and Technology, Baotou 014010, Inner Mongolia, China;
Investigations In Electrochemical Thermodynamic And Kinetic Properties Of As-Cast And As-Quenched Cemg10Ni2 Hydrogen Storage Alloys, Feng Hu, Li-Rong Luo, Yong-Zhi Li, Ting-Ting Zhai, Xin Zhao, Yang-Huan Zhang
Journal of Electrochemistry
In order to improve the electrochemical hydrogen storage properties of CeMg10Ni2 alloy, the rapid quenching technology was used to prepare CeMg10Ni2 alloys with nano-crystalline and amorphous structure. The microstructures of as-cast and as-spinning sample were characterized by X-ray diffraction (XRD) and transmission electron microscopy (TEM). The electrochemical hydrogen storage properties were investigated by an automatic galvanostatic charging/discharging, high rate discharging (HRD), electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization techniques. The results revealed that the as-cast alloy was composed of multiphase structures. The as-quenched alloys were made up of nano-crystalline and/or amorphous structures, and the …
Vanadium-Based Nanomaterials For Improved Zn Ion Storage,
2019
Louisiana State University and Agricultural and Mechanical College
Vanadium-Based Nanomaterials For Improved Zn Ion Storage, Jianwei Lai
LSU Master's Theses
Rechargeable aqueous zinc-ion batteries (ZIBs) have been intensively studied as novel promising large-scale energy storage systems recently, owing to their advantages of high abundance, cost effectiveness, and high safety. However, the development of suitable cathode materials with superior performance are severely hampered by the sluggish kinetics of Zn2+ with divalent charge in the host structure.
Our Work demonstrates boosting the electrochemical performances of nanostructured cathode materials for aqueous ZIBs. The first project is focused on the interlayer-expanded V6O13∙nH2O nanosheets as promising cathodes. Benefiting from the synthetic merits of its favorable architecture and expanded …
Magnetocaloric Effect Near Room Temperature In Quintenary And Sextenary Heusler Alloys,
2019
Central Washington University
Magnetocaloric Effect Near Room Temperature In Quintenary And Sextenary Heusler Alloys, Benjamin D. White, R. I. Barabash, O. M. Barabash, I. Jeon, M. B. Maple
All Faculty Scholarship for the College of the Sciences
An inverse magnetocaloric effect is studied in Ni2Mn1+xX1-x-type Heusler alloys. Principally known for their shape-memory properties, these alloys also exhibit significant entropy and temperature changes (ΔS and ΔTAd, respectively) under adiabatic conditions when a modest magnetic field is applied. We investigated the impact on magnetocaloric properties of introducing substantial chemical disorder on the X-site (X = Si, Ga, In), of replacing Ni with nonmagnetic Ag, and of replacing a small amount of Mn with Gd. While a reduction in ΔS is observed in the first two cases, we observe a significant enhancement …
