Materials Science and Engineering Commons^™

Potential Of Biduri Fiber (Calotropis Gigantea) As Material For Oil Spill Absorbent, Anne Sukmawati, Wulan Septiani

Journal of Materials Exploration and Findings

Biduri fiber (Calotropis gigantea) is a natural hollow fiber with hydrophobic and oleophilic properties potentially used as oil spilled sorbent from seawater. This study aims to determine the absorption capacity and efficiency of the Biduri fiber and membrane to fuel oil. Measurement of oil absorption to seawater was carried out at various fiber weights (0.5-1.5 g), fiber composition (50-95%), contact time (10-90 minutes), temperature (30 and 50°C), and compared with commercial products. The results showed that the fiber weight variation of 0.5-1.5 g has an average absorption efficiency of 96.67%, and the highest absorption was obtained in a weight of …

The Effects Of Phosphorus Pentoxide Additions On The Thermal, Rheological, And Structural Properties Of Sodium Borosilicate Glass, K. L. Skerratt-Love, J. L. George, A. M.T. Bell, F. Sweeney, D. Cutforth, C. (Charmayne) E. Lonergan, D. R. Dixon, A. A. Kruger, P. A. Bingham

Materials Science and Engineering Faculty Research & Creative Works

This research has characterized the effects of P₂O₅ additions on the physical, chemical, thermal, rheological properties and the structure of SiO₂-B₂O₃-Na₂O glasses relevant to radioactive waste immobilization. Properties analyzed include high-temperature viscosity, glass transition temperature (T_g) and structure. X-ray diffraction (XRD) confirmed a solubility limit of between 3.0 and 4.0 mol% P₂O₅ for the onset of crystallinity with formation of Na₃PO₄ and Na₄P₂O₇ in annealed bulk glasses; and between 4.0 and 5.0 mol% P₂O …

Network Structures And The Properties Of Na-Ca-Sr-Borophosphate Glasses, Parker T. Freudenberger, Rebekah L. Blatt, Randall E. Youngman, Richard K. Brow

Materials Science and Engineering Faculty Research & Creative Works

Borophosphate glasses were prepared with the nominal molar compositions 16Na2O-(24-y)CaO-ySrO-xB2O3-(60-x)P2O5 (mol%), where 0≤x≤60 and y=0, 12, and 24. Information about the compositional dependence of borate and phosphate site speciation and next nearest neighbor linkages was obtained by 11B and 31P MAS NMR and Raman spectroscopies, and by high pressure liquid chromatography (HPLC). With the initial replacement of P2O5 by B2O3, tetrahedral borate sites linked to four phosphate anions, B(ØP)4, are created in the glass structure, and the average phosphate anion becomes smaller as bridging PØP bonds are replaced by bridging PØB bonds. With further increases in the B2O3 content, borate …

Network Structures And The Properties Of Na-Ca-Sr-Borophosphate Glasses, Parker T. Freudenberger, Rebekah L. Blatt, Randall E. Youngman, Richard K. Brow

Materials Science and Engineering Faculty Research & Creative Works

Borophosphate glasses were prepared with the nominal molar compositions 16Na₂O-(24-y)CaO-ySrO-xB₂O₃-(60-x)P₂O₅ (mol%), where 0≤x≤60 and y=0, 12, and 24. Information about the compositional dependence of borate and phosphate site speciation and next nearest neighbor linkages was obtained by ¹¹B and ³¹P MAS NMR and Raman spectroscopies, and by high pressure liquid chromatography (HPLC). With the initial replacement of P₂O₅ by B₂O₃, tetrahedral borate sites linked to four phosphate anions, B(ØP)₄, are created in the glass structure, and the average phosphate anion …

Network Structures And The Properties Of Na-Ca-Sr-Borophosphate Glasses, Parker T. Freudenberger, Rebekah L. Blatt, Randall E. Youngman, Richard K. Brow

Mathematics and Statistics Faculty Research & Creative Works

Borophosphate glasses were prepared with the nominal molar compositions 16Na2O-(24-y)CaO-ySrO-xB2O3-(60-x)P2O5 (mol%), where 0≤x≤60 and y=0, 12, and 24. Information about the compositional dependence of borate and phosphate site speciation and next nearest neighbor linkages was obtained by 11B and 31P MAS NMR and Raman spectroscopies, and by high pressure liquid chromatography (HPLC). With the initial replacement of P2O5 by B2O3, tetrahedral borate sites linked to four phosphate anions, B(ØP)4, are created in the glass structure, and the average phosphate anion becomes smaller as bridging PØP bonds are replaced by bridging PØB bonds. With further increases in the B2O3 content, borate …

Temperature, Pressure, And Adsorption Dependent Redox Potentials: Iii. Processes Of Co Conversion To Value-Added Compounds, Siyuan Fang, Yun Hang Hu

Michigan Tech Publications, Part 1

Carbon monoxide (CO) is a primary air pollutant and a poisonous species for human beings, animals, and some catalytic reactions. Meanwhile, CO is also a versatile feedstock in the chemical industry to produce high‐value chemicals and clean fuels, which has stimulated extensive research interests in exploiting efficient CO conversion processes. Redox potential is a key thermodynamic quantity in these processes whereas only standard reduction potentials at 25°Cand 1 atm are currently available. Herein, it is the first time to report the effects of temperature (0–1000°C), pressure (1–100 atm), and adsorption on the redox potentials of 18 CO conversion reactions to …

Liquid-Liquid Equilibria Of Water + Ethanol + Castor Oil And The Effect Of Cellulose Nanocrystal/Fe3o4 And Lignin/Fe3o4 Nanoparticles, Mohammad J. Hasan, Fariba Yehaneh, Amy Ciric, Peng Chen, Erick S. Vasquez, Esteban E. Ureña-Benavides

Chemical and Materials Engineering Faculty Publications

Castor oil has been proposed as a renewable solvent for the liquid extraction of ethanol from water as an alternative to more traditional energy intensive distillation-based methods. The liquid–liquid equilibrium (LLE) of the ternary system water + ethanol + castor oil was determined at 295.15 K using high performance liquid chromatography (HPLC). Castor oil was herein treated as a pseudo-component with the molecular weight of the triglyceride of ricinoleic acid. The experimental data was fitted to the UNIQUAC and NRTL models to obtain parameters for castor oil, and binary interaction parameters for castor oil/ethanol and castor oil/water pairs. The separation …

Architecture Of Heptagonal Metallo-Macrocycles Via Embedding Metal Nodes Into Its Rigid Backbone, A.M.Shashika D. Wijerathna, He Zhao, Qiangqiang Dong, Qixia Bai, Zhiyuan Jiang, Jie Yuan, Jun Wang, Mingzhao Chen, Markus Zirnheld, Rockwell T. Li, Yuan Zhang, Yiming Li, Pingshan Wang

College of Sciences Posters

Metal-organic macrocycles have received increasing attention not only due to their versatile applications such as molecular recognition, compounds encapsulation, anti-bacteria and others, but also for their important role in the study of structure-property relationship at nano scale. However, most of the constructions utilize benzene ring as the backbone, which restricts the ligand arm angle in the range of 60, 120 and 180 degrees. Thus, the topologies of most metallo-macrocycles are limited as triangles and hexagons, and explorations of using other backbones with large angles and the construction of metallo-macrocycles with more than six edges are very rare.

In this study, …

Advanced Microstructural Characterization Of Functionally Graded Dental Ceramic Material For Materials-Informed Finishing, Angani Vigneswaran

Theses and Dissertations--Manufacturing Systems Engineering

Yttria-stabilized tetragonal zirconia polycrystal (Y-TZP) has gained popularity as the choice of material for dental prosthetics. Ivoclar Vivadent’s IPS e.max ZirCAD Prime dental ceramic incorporates a unique gradient technology that varies the yttria content over the thickness of the material. The top layer is composed of 5Y-TZP which is desired for its optical properties while the bottom layer is composed of a much stronger 3Y-TZP. In between the two layers, 5Y-TZP and 3Y-TZP are mixed to form a transition layer. Varying the amount of yttria allows for more esthetically pleasing translucency in the visible areas of the restoration without compromising …

Achieving Strong Chemical Interface And Superior Energy-Saving Capability At The Crosslinks Of Rubber Composites Containing Graphene Oxide Using Thiol-Vinyl Click Chemistry, Rui Zhang, Jiaye Li, Zongchao Xu, Stephen Jerrams, Shui Hu, Li Lui, Shipeng Wen, Liqun Zhang

Articles

Rapidly developments in international transportation inevitably lead to an increase in the consumption of energy and resources. Minimizing the rolling resistance of tires in this scenario is a pressing challenge. To lower the rolling resistance of tires, enhancing the interaction between fillers and rubber molecules while improving the dispersion of fillers are required to reduce the internal mutual friction and viscous loss of rubber composites. In this study, graphene oxide (GO) was modified using γ-mercaptopropyltrimethoxysilane (MPTMS) with thiol groups. A modified GO/natural rubber (MGO/NR) masterbatch with a fine dispersion of MGO was then introduced into solution-polymerized styrene butadiene rubber (SSBR) …

A Partial Discharge Inception Voltage Modeling Approach, Shilpi Mukherjee, Tristan Mark Evans, David Huitink, H. Alan Mantooth

Electrical Engineering Faculty Publications and Presentations

A partial discharge inception voltage modeling approach promoting design-for-reliability considerations in advanced power modules is presented. As power modules are being operated at higher voltages and become more compact to meet power density demands, there is an increased risk of partial discharge, the silent precursor to electrical breakdown that degrades insulation material. The trade-off between voltage class and module compaction must be quantified. This work presents a methodology to model the tradeoff for any substrate and encapsulant material. A surface charge density-based partial discharge inception voltage (PDIV) model was developed to overcome the challenges in electric field-based models. The model …

Development Of High Current Electromigration Test System For Evaluation Of Novel Solder Structures, Nicholas Pareis

Electronic Theses and Dissertations, 2020-2023

Electromigration reliability of ball-grid-array (BGA) solder joints is emerging as a critical area of research for advanced microelectronic devices, especially those with high power requirements. In this study, a novel high current electromigration test system, including a temperature sensing capability, was designed and developed for the purpose of performing electromigration characterization of various BGA solder joint structures, including features designed for reduced current crowding. This study consisted of two main parts: design and development of a novel high current electromigration test system, and using this novel system for electromigration characterization of BGA solder joints. In the first portion of this …

Xps Study Of Calcium Lanthanum Sulfide Ceramics, Brian E. Butkus

Graduate Thesis and Dissertation 2023-2024

Long wave infrared (LWIR) optics that transmit in the 8 to 14 m wavelength range and, additionally, can withstand severe physical and thermal stresses are needed for advanced remote sensing, guidance and communication-based applications. However, most non-oxide transparent LWIR optics do not have the wider transmission range, nor the hardness and resistance to thermal shock needed for extreme environments. Because of these limitations, research is circling back to a promising material, calcium lanthanum sulfide (CLS), that could meet LWIR needs for extreme environments.

In this thesis, we will demonstrate the abilities of x-ray photoelectron spectroscopy (XPS) as a technique for …

Functionalization Of 1d And 2d Nanostructures And Their Applications, Yuen Yee Li Sip

Graduate Thesis and Dissertation 2023-2024

Material discovery and development has been playing a significant role in shaping human civilizations, by studying and improving materials for appealing observations to aid in our survival as well as to satisfy our curiosity. From the common earthly materials that give us strong building structures and hunting weapons to the Silicon Age that contributes to the creation of modern electronics and computers, the development of novel and enhanced materials continues to grow. Recently, a new field has emerged that is rapidly expanding the engineering circle; these are called nanomaterials. By shrinking bulk materials into structures with nanoscale dimensions, there is …

Development Of Advanced Germanium Detectors For Rare Event Physics, Sanjay Bhattarai

Dissertations and Theses

High Purity Germanium (HPGe) detectors are widely used in rare-event physics searches for dark matter, neutrinoless double-beta decay, and solar neutrinos. This dissertation fo- cuses on improving crystal quality by controlling the impurity concentration, dislocation density, and growth environment as well as developing advanced Ge detectors for various physics applications. The dissertation presents experimental investigations of electrical conduction mechanisms in p-type amorphous germanium (a-Ge), which is used as an elec- trical contact material in HPGe detectors. By measuring the surface leakage current from three high-purity planar Ge detectors, we determine the localization length and hopping parameters in a-Ge. The dissertation …

A Thermal, Mechanical, And Materials Framework For A Shape Memory Alloy Heat Engine For Thermal Management And Energy Recovery, Maria Chikhareva

Electronic Theses and Dissertations, 2020-2023

Shape memory alloy (SMA) heat engines possess an inherent property of sensing a change in temperature, performing work, and rejecting heat through the shape memory effect resulting from a temperature-induced phase transformation. This work presents a framework for the design and implementation of an SMA-based Stirling heat engine for maximum power or speed incorporating and combining mechanical, thermal, and material aspects. The motivation for this work comes from the growing need for reliable thermal management and energy recovery in both ground and space applications of interest to NASA and commercial space companies. In future lunar and Mars missions, an SMA …

Investigation Of Fiber Orientation And Mechanical Properties Of Pyrolysis Recycled Carbon-Fiber Reinforced Thermoset Composite, Reva N. Simmons, Harry Lee, Garam Kim

Discovery Undergraduate Interdisciplinary Research Internship

With increasing demand of carbon fiber reinforced fiber thermoset composites, establishing a sustainable cycle for these materials becomes crucial. Pyrolysis is a process of reclaiming carbon fiber from thermoset composites by thermally degrading the polymer at high temperatures allowing the fibers to be extracted. Carbon fiber reclaimed through current pyrolysis processes for thermoset composites typically loses its original shape and orientation, making it difficult to reorganize the fibers. This study investigated the feasibility of maintaining the fiber orientations for continuous fiber reinforced thermoset composite during pyrolysis by stitching the carbon fiber layup to a conformable copper mesh during the manufacturing …

Laser Powder Bed Fusion Of Bimetallic Structures, Asif Mahmud

Graduate Thesis and Dissertation 2023-2024

Laser powder bed fusion (LPBF) is a popular additive manufacturing (AM) technique that has demonstrated the capability to produce sophisticated engineering components. This work reports the crack-free fabrication of an SS316L/IN718 bimetallic structure via LPBF, along with compositional redistribution, phase transformations and microstructural development, and nanohardness variations. Constituent intermixing after LPBF was quantitatively estimated using thermo-kinetic coefficients of mass transport and compared with the diffusivity of Ni in the austenitic Fe-Ni system. The intermixing of primary solvents (Ni and Fe) in SS316L/IN718 bimetallic structures was observed for an intermixing zone of approximately 800 µm, and their intermixing coefficient was estimated …

Nanostructured Alloy Thin Film Fabrication And Application For Zinc-Air Battery And Lithium-Ion Battery, Guanzhi Wang

Electronic Theses and Dissertations, 2020-2023

The depletion of unsustainable fossil fuels and growing environmental issues have given rise to scientific challenges and research interests in the development of renewable energy technologies to meet the rising global energy demand. Electrochemical energy storage and conversion technologies (ESCTs), such as lithium-ion batteries, metal-air batteries, supercapacitors, and fuel cells, etc., offer a clean and sustainable strategy for utilizing energy. As the core components, the electrode materials, including anodes, cathodes, and catalysts, play a direct decisive role in the device's performance in practical application. Therefore, the development of high-performance and low-cost electrode materials is critical for the success of these …

Electroanalytical Investigations Of Microrna-Conjugated Cerium Oxide Based Nanomaterials For Biomedical Applications, Chaimae El Ghzaoui

Electronic Theses and Dissertations, 2020-2023

Diabetes patients are increasingly suffering from wound-healing impairments coupled with other severe medical conditions. High levels of oxidative stress and proinflammatory cytokines are predominant pathologic characteristics of diabetic wounds. Applying microRNA (miRNA) in gene therapy often successfully treats various disorders by generating highly specific bio-responses. Studies revealed that microRNA146a (miR146a), a regulator of inflammation, is downregulated in diabetic wounds. However, miR203 is found to be highly-expressed in diabetic foot ulcers in positive correlation with disease severity. We have synthesized Cerium oxide nanoparticles (CNPs) since they are used in various biomedical applications due to their high enzyme-mimetic activities and reactive oxygen …