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Heterostructure Engineering In Electrode Materials For Sodium-Ion Batteries: Recent Progress And Perspectives, Eric Gabriel, Chunrong Ma, Kincaid Graff, Angel Conrado, Dewen Hou, Hui Xiong 2023 Boise State University

Heterostructure Engineering In Electrode Materials For Sodium-Ion Batteries: Recent Progress And Perspectives, Eric Gabriel, Chunrong Ma, Kincaid Graff, Angel Conrado, Dewen Hou, Hui Xiong

Materials Science and Engineering Faculty Publications and Presentations

Sodium-ion batteries (SIBs) have stepped into the spotlight as a promising alternative to lithium-ion batteries for large-scale energy storage systems. However, SIB electrode materials, in general, have inferior performance than their lithium counterparts because Na+ is larger and heavier than Li+. Heterostructure engineering is a promising strategy to overcome this intrinsic limitation and achieve practical SIBs. We provide a brief review of recent progress in heterostructure engineering of electrode materials and research on how the phase interface influences Na+ storage and transport properties. Efficient strategies for the design and fabrication of heterostructures (in situ methods) …


Study Of All-Group-Iv Sigesn Mid-Ir Lasers With Dual Wavelength Emission, Grey Abernathy, Solomon Ojo, Abdulla Said, Joshua M. Grant, Yiyin Zhou, Hryhorii Stanchu, Wei Du, Baohua Li, Shui-Qing Yu 2023 University of Arkansas, Fayetteville

Study Of All-Group-Iv Sigesn Mid-Ir Lasers With Dual Wavelength Emission, Grey Abernathy, Solomon Ojo, Abdulla Said, Joshua M. Grant, Yiyin Zhou, Hryhorii Stanchu, Wei Du, Baohua Li, Shui-Qing Yu

Electrical Engineering Faculty Publications and Presentations

Direct band gap GeSn alloys have recently emerged as promising lasing source materials for monolithic integration on Si substrate. In this work, optically pumped mid-infrared GeSn lasers were studied with the observation of dual-wavelength lasing at 2187 nm and 2460 nm. Two simultaneous lasing regions include a GeSn buffer layer (bulk) and a SiGeSn/GeSn multiple quantum well structure that were grown seamlessly using a chemical vapor deposition reactor. The onset of dual lasing occurs at 420 kW/cm2. The wider bandgap SiGeSn partitioning barrier enables the independent operation of two gain regions. While the better performance device in terms …


The Effect Of Through Thickness Reinforcement Angle On The Disbonding Behavior In Skin-Stringer Configuration, Christopher John Morris 2023 Old Dominion University

The Effect Of Through Thickness Reinforcement Angle On The Disbonding Behavior In Skin-Stringer Configuration, Christopher John Morris

Mechanical & Aerospace Engineering Theses & Dissertations

Post-cure through thickness reinforcement is a method used to increase the mechanical properties of composite laminates in the transverse direction. This study conducted a test on skin-stringer structures bonded together in three configurations using an epoxy or thermoplastic adhesive at the interface with reinforcing pins inserted through the laminate thickness located at the edge of the stringer at differing angles between -30º and 30º. The fabrication of these samples in configurations B and C consisted of the use of carbon fiber prepeg laminate at a ply orientation of [02902]2s for the skin and [0 90] …


Mechanism Underlying Effect Of Expansive Agent And Shrinkage Reducing Admixture On Mechanical Properties And Fiber-Matrix Bonding Of Fiber-Reinforced Mortar, Kamran Aghaee, Taihao Han, Aditya Kumar, Kamal Khayat 2023 Missouri University of Science and Technology

Mechanism Underlying Effect Of Expansive Agent And Shrinkage Reducing Admixture On Mechanical Properties And Fiber-Matrix Bonding Of Fiber-Reinforced Mortar, Kamran Aghaee, Taihao Han, Aditya Kumar, Kamal Khayat

Materials Science and Engineering Faculty Research & Creative Works

Expansive agent (EA) and shrinkage reducing admixture (SRA) are utilized to reduce shrinkage and risk of cracking in concrete. EA compensates shrinkage by initial expansion, and SRA reduces surface tension in the pore fluid. Although EA and SRA effectively reduce shrinkage, they can impair micro-structure of concrete at high contents. The shrinkage reduction effect of EA and SRA is well known; however, there is limited knowledge about their negative effect on microstructure and fiber matrix interfacial transition zone (ITZ). The current study explores the effect of using 10 % CaO-based EA, 2 % SRA, and their combination on mechanical, shrinkage, …


Switching Of Control Mechanisms During The Rapid Solidification Of A Melt Pool, Yijia Gu, Jiandong Yuan, Lianyi Chen 2023 Missouri University of Science and Technology

Switching Of Control Mechanisms During The Rapid Solidification Of A Melt Pool, Yijia Gu, Jiandong Yuan, Lianyi Chen

Materials Science and Engineering Faculty Research & Creative Works

The Solidification of Alloys is Typically Controlled by Solute Diffusion Due to the Solute Partitioning Happening at the Solid-Liquid Interface. in This Study, We Show that the Switching from Solute Diffusion-Controlled Growth to Thermal Diffusion-Controlled Growth May Happen at the Solidification Front during Rapid Solidification Processes of Alloys Such as Additive Manufacturing using a Phase-Field Model. the Switching is Found to Be Triggered by the Cooling of the Solid-Liquid Interface When It Becomes Colder Than the Solidus Temperature. the Switching Introduces a Sudden Jump of Growth Velocity, an Increase in Solute Concentration, and the Refining of the Resulting Microstructures. All …


On The Prediction Of The Mechanical Properties Of Limestone Calcined Clay Cement: A Random Forest Approach Tailored To Cement Chemistry, Taihao Han, Bryan K. Aylas-Paredes, Jie Huang, Ashutosh Goel, Narayanan Neithalath, Aditya Kumar 2023 Missouri University of Science and Technology

On The Prediction Of The Mechanical Properties Of Limestone Calcined Clay Cement: A Random Forest Approach Tailored To Cement Chemistry, Taihao Han, Bryan K. Aylas-Paredes, Jie Huang, Ashutosh Goel, Narayanan Neithalath, Aditya Kumar

Materials Science and Engineering Faculty Research & Creative Works

Limestone calcined clay cement (LC3) is a sustainable alternative to ordinary Portland cement, capable of reducing the binder's carbon footprint by 40% while satisfying all key performance metrics. The inherent compositional heterogeneity in select components of LC3, combined with their convoluted chemical interactions, poses challenges to conventional analytical models when predicting mechanical properties. Although some studies have employed machine learning (ML) to predict the mechanical properties of LC3, many have overlooked the pivotal role of feature selection. Proper feature selection not only refines and simplifies the structure of ML models but also enhances these models' prediction performance and interpretability. This …


Fabrication Of Smooth Sac305 Thin Films Via Magnetron Sputtering And Evaluations Of Microstructure, Creep, And Electrical Resistivity, Manish Ojha 2023 Old Dominion University

Fabrication Of Smooth Sac305 Thin Films Via Magnetron Sputtering And Evaluations Of Microstructure, Creep, And Electrical Resistivity, Manish Ojha

Mechanical & Aerospace Engineering Theses & Dissertations

SAC305 (96.5%Sn-3%Ag-0.5%Cu) is the leading alternative to the traditional Sn-Pb solder eutectic alloy owing to its low melting temperature, better compatibility with other components, and excellent mechanical/structural properties. In the realm of modern electronics, where devices are increasingly miniaturized, the design and characterization of thin solder joints become paramount. The orientation and size of the grains within the solder can influence its ability to withstand mechanical stresses. However, research on SAC thin films remains sparse, and these films present unique challenges and characteristics compared to their bulk counterparts, influenced by factors like interfaces, stresses, thickness, microstructure, and the nature of …


L(D)-Tyrosine-Mediated One-Step Chiral Graphene Production For Chirality-Dependent Sensing, Fnu Pranav, Ali Ashraf, Meena Jaggi, Subhash C. Chauhan, Murali M. Yallapu 2023 The University of Texas Rio Grande Valley

L(D)-Tyrosine-Mediated One-Step Chiral Graphene Production For Chirality-Dependent Sensing, Fnu Pranav, Ali Ashraf, Meena Jaggi, Subhash C. Chauhan, Murali M. Yallapu

Research Symposium

Background: Chirality has been the most iconic phenomenon that occurred in nature. The idea of mirror-image asymmetry associated with the biological entity is still unsolved The emergence of 2D layered nanomaterials which have already shown amazing properties and a wide range of applications, especially in the areas of sensing.Amino acids enantiomers have similar physical and chemical properties however their physiological responses get changed based on the enantiomers. For example, L from amino acids helps body in protein formation, and generation of biological signals etc. whereas the D-form may cause toxic effects. We have developed a novel and facile synthesis method …


Asymmetric Electrode-Electrolyte Interfaces For High-Performance Rechargeable Lithium-Sulfur Batteries, Jia Chou, Ya-Hui Wang, Wen-Peng Wang, Sen Xin, Yu-Guo Guo 2023 CAS Key Laboratory of Molecular Nanostructure and Nanotechnology, CAS Research/Education Center for Excellence in Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences (CAS), Beijing 100190, China; University of Chinese Academy of Sciences, Beijing 100049, China

Asymmetric Electrode-Electrolyte Interfaces For High-Performance Rechargeable Lithium-Sulfur Batteries, Jia Chou, Ya-Hui Wang, Wen-Peng Wang, Sen Xin, Yu-Guo Guo

Journal of Electrochemistry

With a high cell-level specific energy and a low cost, lithium-sulfur (Li-S) battery has been intensively studied as one of the most promising candidates for competing the next-generation energy storage campaign. Currently, the practical use of Li-S battery is hindered by the rapidly declined storage performance during battery operation, as caused by irreversible loss of electroactive sulfide species at the cathode, dendrite formation at the anode and parasitic reactions at the electrode-electrolyte interface due to unfavorable cathode-anode crosstalk. In this perspective, we propose to stabilize the Li-S electrochemistry, and improve the storage performance of battery by designing asymmetric electrode-electrolyte interfaces …


Hydrophobicity Optimization Of Cathode Catalyst Layer For Proton Exchange Membrane Fuel Cell, Hao-Jie Chen, Mei-Hua Tang, Sheng-Li Chen 2023 Hubei Key Laboratory of Electrochemical Power Sources, Department of Chemistry, Wuhan University, Wuhan 430072, China

Hydrophobicity Optimization Of Cathode Catalyst Layer For Proton Exchange Membrane Fuel Cell, Hao-Jie Chen, Mei-Hua Tang, Sheng-Li Chen

Journal of Electrochemistry

Hydrophobicity of the cathode catalyst layers (CCLs) crucially determines the performance of proton exchange membrane fuel cells (PEMFCs) by affecting the transports of oxygen and liquid water. In this regard, polytetrafluoroethylene (PTFE) is usually used as a hydrophobic additive to facilitate the oxygen and water transports in CCLs. So far, there remains lacking systematic effort to optimize the addition methods of PTFE in CCLs and the mechanisms behind. In this work, the effects of the approaches for PTFE addition and the distribution of PTFE on the mass transport of oxygen and the proton conduction in CCLs were studied by using …


Dependence Of Heat Transfer Model On The Structure Of Electrically Coil-Heated Microelectrodes, Ju Li, Sen Yang, Jian-Jun Sun 2023 School of Henan Industry and Trade Vocational College, Zhengzhou, 451191, China;Key Laboratory of Targeting Therapy and Diagnosis for Critical Diseases, Henan Province, Key laboratory of Advanced Drug Preparation Technologies, Ministry of Education, Collaborative Innovation Center of New Drug Research and Safety Evaluation, School of Pharmaceutical Sciences, Zhengzhou University, Zhengzhou, 450001, China

Dependence Of Heat Transfer Model On The Structure Of Electrically Coil-Heated Microelectrodes, Ju Li, Sen Yang, Jian-Jun Sun

Journal of Electrochemistry

Electrically heated microelectrodes have gained much attention in electroanalytical chemistry in recent years. It has been shown that the promotion of mass transport and reaction kinetics at high-temperatures often results in increased current signals. However, there is no study about the heat transfer inner the microelectrodes which is necessary for the design and operation for microsensors. This report introduces a finite element software (COMSOL) to analyze the factors that influence the surface temperature (Ts), which is crucial for the heating ability of micro-disk electrodes with coils. Distances between the electrode surface and the bottom of the heated copper …


Synergistic Effect Of Nanoclay And Barium Sulfate Fillers On The Corrosion Resistance Of Polyester Powder Coatings, Jinbao Huang, Marshall Shuai Yang, Chengqian Xian, James Joseph Noel, Yolanda S. Hedberg, Jian Chen, Ubong Eduok, Ivan Barker, Jeffrey Daniel Henderson, Haiping Zhang, Liqin Wang, Hui Zhang, Jesse Zhu 2023 Western University

Synergistic Effect Of Nanoclay And Barium Sulfate Fillers On The Corrosion Resistance Of Polyester Powder Coatings, Jinbao Huang, Marshall Shuai Yang, Chengqian Xian, James Joseph Noel, Yolanda S. Hedberg, Jian Chen, Ubong Eduok, Ivan Barker, Jeffrey Daniel Henderson, Haiping Zhang, Liqin Wang, Hui Zhang, Jesse Zhu

Chemistry Publications

No abstract provided.


High-Sensitivity Electronic Stark Spectrometer Featuring A Laser-Driven Light Source, J. S. Huff, K. M. Duncan, C. J. Van Galen, M. S. Barclay, W. B. Knowlton, B. Yurke, P. H. Davis, D. B. Turner, R. J. Stanley, R. D. Pensack 2023 Boise State University

High-Sensitivity Electronic Stark Spectrometer Featuring A Laser-Driven Light Source, J. S. Huff, K. M. Duncan, C. J. Van Galen, M. S. Barclay, W. B. Knowlton, B. Yurke, P. H. Davis, D. B. Turner, R. J. Stanley, R. D. Pensack

Materials Science and Engineering Faculty Publications and Presentations

We report developmental details of a high-sensitivity Stark absorption spectrometer featuring a laser-driven light source. The light source exhibits intensity fluctuations of ∼0.3% over timescales ranging from 1 min to 12 h, minimal drift (≤ 0.1%/h), and very little 1/f noise at frequencies greater than 200 Hz, which are comparable to or better than an arc-driven light source. Additional features of the spectrometer include balanced detection with multiplex sampling, which yielded lower noise in A, and constant wavelength or wavenumber (energy) spectral bandpass modes. We achieve noise amplitudes of ∼7 × 10−4 and ∼6 × 10−6 …


Correlative Imaging Of Three-Dimensional Cell Culture On Opaque Bioscaffolds For Tissue Engineering Applications, Mone’t Sawyer, Josh Eixenberger, Olivia Nielson, Jacob Manzi, Cadré Francis, Raquel Montenegro-Brown, Harish Subbaraman, David Estrada 2023 Boise State University

Correlative Imaging Of Three-Dimensional Cell Culture On Opaque Bioscaffolds For Tissue Engineering Applications, Mone’T Sawyer, Josh Eixenberger, Olivia Nielson, Jacob Manzi, Cadré Francis, Raquel Montenegro-Brown, Harish Subbaraman, David Estrada

Materials Science and Engineering Faculty Publications and Presentations

Three-dimensional (3D) tissue engineering (TE) is a prospective treatment that can be used to restore or replace damaged musculoskeletal tissues, such as articular cartilage. However, current challenges in TE include identifying materials that are biocompatible and have properties that closely match the mechanical properties and cellular microenvironment of the target tissue. Visualization and analysis of potential 3D porous scaffolds as well as the associated cell growth and proliferation characteristics present additional problems. This is particularly challenging for opaque scaffolds using standard optical imaging techniques. Here, we use graphene foam (GF) as a 3D porous biocompatible substrate, which is scalable, reproducible, …


Fatigue Behavior Of Cu-Zr Metallic Glasses Under Cyclic Loading, Nikolai Priezjev 2023 Wright State University - Main Campus

Fatigue Behavior Of Cu-Zr Metallic Glasses Under Cyclic Loading, Nikolai Priezjev

Mechanical and Materials Engineering Faculty Publications

The effect of oscillatory shear deformation on the fatigue life, yielding transition, and flow localization in metallic glasses is investigated using molecular dynamics simulations. We study a well-annealed Cu-Zr amorphous alloy subjected to periodic shear at room temperature. We find that upon loading for hundreds of cycles at strain amplitudes just below a critical value, the potential energy at zero strain remains nearly constant and plastic events are highly localized. By contrast, at strain amplitudes above the critical point, the plastic deformation is gradually accumulated upon continued loading until the yielding transition and the formation of a shear band across …


Summarization Of Reliability Theory For Condition Assessment Of Brige Structurs, PENG Jianxin, CHAI Ying, ZHANG Jianren 2023 School of Civil Engineering, Changsha University of Science & Technology, Changsha, Hunan 410114, China

Summarization Of Reliability Theory For Condition Assessment Of Brige Structurs, Peng Jianxin, Chai Ying, Zhang Jianren

Journal of China & Foreign Highway

This paper briefly reviewed the principles and development of structural design theories, and summarized the current research of structural reliability theories. Meanwhile, various applicable methods of reliability theories were finely described and analyzed, with the latest progress in structural reliability analysis and reliability-based design optimization outlined. Additionally, the uncertainty propagation methods and reliability assessment methods were analyzed, and the development trend of structural reliability was summarized, which can provide a summary and reference for future researchers to study structural reliability.


Study On Laws Of Surface Movement A Nd Deformation Of Goaf Under Subgrade In Sand-Loess Area, LEI Mingxuan, LIU Guotian, SU Weiwei, ZHANG Liujun, YIN Lihua 2023 CCCC First Highway Consultants Co., Ltd., Xi'an, Shaanxi 710065, China

Study On Laws Of Surface Movement A Nd Deformation Of Goaf Under Subgrade In Sand-Loess Area, Lei Mingxuan, Liu Guotian, Su Weiwei, Zhang Liujun, Yin Lihua

Journal of China & Foreign Highway

A large number of goaf under sand-loess areas in China greatly restrict the highway construction development in sand-loess areas. Meanwhile, the goaf evaluation beneath under subgrade in sand-loess areas is especially important. According to the characteristics of goaf beneath the highway of sand-loess areas, based on FLAC3D software, this paper selected reasonable parameters to build the model of goaf under subgrade. Additionally, based on the mechanical property analysis of sand loess, the laws of surface movement and deformation parameters of the goaf under the subgrade were summarized, and the surface movement and deformation areas were identified, with the range of …


Exploring Long-Term Protective Effect Of High Vertical Sand Barrier On Top Of Complex Longitudinal Sand Ridge In Taklamakan Desert, JIN Changning 2023 Foshan University, Foshan, Guangdong 528000, China

Exploring Long-Term Protective Effect Of High Vertical Sand Barrier On Top Of Complex Longitudinal Sand Ridge In Taklamakan Desert, Jin Changning

Journal of China & Foreign Highway

By taking the high vertical sand barriers deployed on the top of the complex longitudinal sand ridges in the hinterland of Taklamakan Desert as the object, this paper investigated the sand protection effect from the long-term perspective on the basis of several years’ comparative observation. The result analysis shows that in addition to the recognized sand blocking effect, high vertical sand barriers also have a more important role of sand fixation, which means that the barriers can change the original overall movement of sand dunes into only the falling sand slope forward, with the windward slopes basically fixed. Even if …


Experimental Study On Dynamic Resilient Modulus Of Cement-Improved Fine-Grained Soils In Wet Subgrade, HUANG Chongwei, ZHU Baobing, ZHANG Yi, SUN Yu, GUO Dandan 2023 Department of Transportation Engineering, University of Shanghai for Science and Technology, Shanghai 200093, China

Experimental Study On Dynamic Resilient Modulus Of Cement-Improved Fine-Grained Soils In Wet Subgrade, Huang Chongwei, Zhu Baobing, Zhang Yi, Sun Yu, Guo Dandan

Journal of China & Foreign Highway

To investigate the design and construction of wet subgrade in southern China, this paper selected three typical soil samples of the new highway subgrade of Ecological Avenue in Chongming District, Shanghai, and improved the samples by cement disposal technology. Meanwhile, the effects of the water content, degree of compaction, cement content, age of maintenance and stress state on the dynamic resilient modulus were analyzed by experimental methods. The results show that the effects of cement content, water content and age of maintenance on the dynamic resilient modulus of three kinds of cement-improved fine-grained soil in wet subgrade are larger, and …


Study On Stability Analysis And Treatment Of A Expressway Landslide, HUANG Hongchao 2023 CCCC Second Highway Consultants Co., Ltd., Wuhan, Hubei 430056, China

Study On Stability Analysis And Treatment Of A Expressway Landslide, Huang Hongchao

Journal of China & Foreign Highway

In highway construction of mountainous areas, landslides are easily triggered due to the complex geological conditions, thereby causing serious economic loss and even casualties. Therefore, the study of landslide treatment schemes has caught increasingly more attention from scholars. By taking the giant landslide treatment on a highway of southeastern Yunnan as an example, this paper analyzed the process and cause of giant landslide formation, and then conducted inverse calculations to determine the stability analysis parameters of landslides via combining the topography and geology and slope state before and after slope excavation. Finally, according to the calculation results of the residual …


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