Oceanography and Atmospheric Sciences and Meteorology Commons^™

Paleo-Environmental Changes In The Uvs Nuur Basin (Northwest-Mongolia), Michael Walther

Erforschung biologischer Ressourcen der Mongolei / Exploration into the Biological Resources of Mongolia, ISSN 0440-1298

Geomorphological, geochemical, sedimentological and palynological results are presented against the background of palaeoclimatic changes during the past 15,000 years, yielding a chrono-, bio- and morphostratigraphical model of landscape evolution in the region of northern Central Asia. Holocene and Late-Glacial climatic fluctuations there are shown to correlate well with conditions in central Europe. Particular attention is given to the importance of the palaeoclimatic interpretation of lake Basin sediments when reconstructing the palaeoenvironment.

Absorption And Biotransformation Of Polybrominated Diphenyl Ethers De-71 And De-79 In Chicken (Gallus Gallus), Mallard (Anas Platyrhynchos), American Kestrel (Falco Sparverius) And Black-Crowned Night-Heron (Nycticorax Nycticorax) Eggs, Moira A. Mckernan, Barnett A. Rattner, Jeff S. Hatfield, Robert C. Hale, Mary Ann Ottinger

United States Geological Survey: Staff Publications

We recently reported that air cell administration of penta-brominated diphenyl ether (penta-BDE; DE-71) evokes biochemical and immunologic effects in chicken (Gallus gallus) embryos at very low doses, and impairs pipping (i.e., stage immediately prior to hatching) and hatching success at 1.8 µg g^-1 egg (actual dose absorbed) in American kestrels (Falco sparverius). In the present study, absorption of polybrominated diphenyl ether (PBDE) congeners was measured following air cell administration of a penta-BDE mixture (11.1 lg DE-71 g^-1 egg) or an octa-brominated diphenyl ether mixture (octa BDE; DE-79; 15.4 lg DE-79 g^{- …}

Post-Coring Entrapment Of Modern Air In Some Shallow Ice Cores Collected Near The Firn-Ice Transition: Evidence From Cfc-12 Measurements In Antarctic Firn Air And Ice Cores, Murat Aydin, S. A. Montzka, M. O. Battle, M. B. Williams, Warren J. De Bruyn, J. H. Butler, K. R. Verhulst, C. Tatum, B. K. Gun, D. A. Plotkin, B. D. Hall, Eric S. Saltzman

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

In this study, we report measurements of CFC-12 (CCl2F2) in firn air and in air extracted from shallow ice cores from three Antarctic sites. The firn air data are consistent with the known atmospheric history of CFC-12. In contrast, some of the ice core samples collected near the firn-ice transition exhibit anomalously high CFC-12 levels. Together, the ice core and firn air data provide evidence for the presence of modern air entrapped in the shallow ice core samples that likely contained open pores at the time of collection. We propose that this is due to closure of the open pores …

United States Land Cover Land Use Change, Albedo And Radiative Forcing: Past And Potential Climate Implications, Christopher A. Barnes

Electronic Theses and Dissertations

Land Cover Land Use (LCLU) change affects Earth surface properties including albedo that impose a radiative forcing on the climate. Recent spatially explicit satellite derived contemporary LCLU, albedo, and projected LCLU data are used to study the impact of LCLU change from 1973 to 2000, and from 2000 to 2050, on albedo and surface radiative forcing for the conterminous United States. Four research hypotheses concerned with past and potential future climate implications of LCLU change are addressed. The research described in this dissertation makes an important contribution to advancing understanding of the role of LCLU change on the climate system, …

Absence Of Predation Eliminates Coexistence: Experience From The Fish-Zooplankton Interface, Z. M. Gilwicz, Wayne A. Wurtsbaugh, E. Szymansk

Watershed Sciences Faculty Publications

Examples from fishless aquatic habitats show that competition among zooplankton for resources instigates rapid exclusion of competitively inferior species in the absence of fish predation, and leads to resource monopolization by the superior competitor. This may be a single species or a few clones with large body size: a cladoceran such as Daphnia pulicaria, or a branchiopod such as Artemia franciscana, each building its population to a density far higher than those found in habitats with fish. The example of zooplankton from two different fish-free habitats demonstrates the overpowering force of fish predation by highlighting the consequences of its absence. …

Trace Metal Biogeochemistry In The Western North Pacific, Peter Lynn Morton

OES Theses and Dissertations

Dissolved and suspended particulate samples collected during the Intergovernmental Oceanographic Commission 2002 Contaminant Baseline Survey were analyzed to determine the surface and vertical distributions of Cd, Co, Cu, Mn, Ni Zn and Pb across the western and central North Pacific.

Dissolved trace metal concentrations were measured using a novel isotope dilution-ICP-MS method after extraction over an 8-hydroxyquinoline resin column and validated through the use of the SAFe consensus reference materials. Filtered suspended particulate matter was digested using an HCl/HNO3/HF mixture and analyzed by HR-ICP-MS to obtain total particulate concentrations for the trace metals and other tracer elements such as Al, …

Interannual Differences In Nutrient Dynamics During A Brown Tide Bloom (Aureococcus Anophagefferens) And The Interaction Of A. Anophagefferens With Heterotrophic Bacteria, George Eric Boneillo

OES Theses and Dissertations

Blooms of Aureococcus anophagefferens (Brown Tides) in Chincoteague Bay were observed over a six-year period (2002–2007) during which interannual differences in nitrogen and carbon uptake and concentrations of dissolved constituents were compared at two sites, one in Maryland and the other in Virginia. Overall, I observed an increase in bloom intensity and duration over time. No single nitrogen compound was responsible for fueling blooms. Instead, A. anophagefferens demonstrated the ability to use a wide range of nitrogen compounds to meet its nutritional demands. Results show that NO₃-, NH₄+, urea, and DFAA were taken up simultaneously during …

Concentrations, Distributions And Chemical Speciation Of Zinc And Cadmium In The Equatorial And South Atlantic Ocean, Gonzalo G. Carrasco

OES Theses and Dissertations

Certain trace metals are important cofactors in enzymatic systems and are thus, essential for life in the world's oceans. Two of these metals, Zn and Cd, are required by phytoplankton for enzymes that facilitate carbon uptake (Morel and Price, 2003). In seawater the total dissolved concentration of a metal (MTD) is distributed among different chemical species and this chemical speciation dictates a metal's bioavailability. Strong organic metal-binding ligands greatly affect the metal's chemical speciation in the ocean, potentially limiting phytoplankton growth by reducing the concentrations of Zn²⁺ and Cd²⁺, the bioavailable forms of these two metals to …

Development Of A Spectral 2-D Fast Fourier Transform Analysis For Sand Ripple Morphology Interpretation, Christopher M. Englert

Honors Theses

A MATLAB-based 2-Dimensional Fast Fourier Transform spectral analysis is developed and tested for its applicability to bedform morphology and hydrodynamic data from a hydrodynamically complex field site. The aspects of the procedure tested are (1) the use of an 8 sub-region arrangement for analysis versus five other arrangements, (2) the procedure for averaging the wavelength-and-orientation outputs from each sub-region to produce a single representative value for each image, (3) methods for eliminating and/or filtering poor quality data, and (4) the procedural steps in the spectral analysis that can appropriately incorporate automation versus manual involvement and interpretation. The automated technique is …

Benthic Ecology From Space: Optics And Net Primary Production In Seagrass And Benthic Algae Across The Great Bahama Bank, Heidi M. Dierssen, Richard C. Zimmerman, Lisa A. Drake, David J. Burdige

OES Faculty Publications

Development of repeatable and quantitative tools are necessary for determining the abundance and distribution of different types of benthic habitats, detecting changes to these ecosystems, and determining their role in the global carbon cycle. Here we used ocean color remote sensing techniques to map different major groups of primary producers and estimate net primary productivity (NPP) across Great Bahama Bank (GBB). Field investigations on the northern portion of the GBB in 2004 revealed 3 dominant types of benthic primary producers: seagrass, benthic macroalgae, and microalgae attached to sediment. Laboratory measurements of NPP ranged from barely net autotrophic for grapestone sediment …

On The Fractional Solubillity Of Copper In Marine Aerosols: Toxicity Of Aeolian Copper Revisited, Edward R. Sholkovitz, Peter N. Sedwick, Thomas M. Church

OES Faculty Publications

Paytan et al. (2009) argue that the atmospheric deposition of aerosols lead to copper concentrations that are potentially toxic to marine phytoplankton in a large area of tropical and subtropical North Atlantic Ocean. A key assumption in their model is that all marine aerosols (mineral dust and anthropogenic particles) have a high (40%) fractional solubility of copper. Our data show that the fractional solubility of copper for Saharan dust over the Sargasso Sea and Bermuda is significantly lower (1-7%). In contrast, anthropogenic aerosols with non-Saharan sources have significantly higher values (10-100%). Hence, the potential Cu toxicity in the tropical and …

Modeling The Vertical Distributions Of Downwelling Plane Irradiance And Diffuse Attenuation Coefficient In Optically Deep Waters, X. J. Pan, Richard C. Zimmerman

OES Faculty Publications

The diffuse attenuation coefficient Kᵈ is critical to understand the vertical distribution of underwater downwelling irradiance (Eᵈ). Theoretically Eᵈ is composed of the direct solar beam and the diffuse sky irradiance. Applying the statistical results from Hydrolight radiative transfer simulations, Kᵈ is expressed into a mathematical equation (named as PZ06) integrated from the contribution of direct solar beam and diffuse sky irradiance with the knowledge of sky and water conditions. The percent root mean square errors (RMSE) for the vertical distribution of Eᵈ(z) under various sky and water conditions between PZ06 and Hydrolight results are typically less than 4%. Field …

The Widespread Occurrence Of Coupled Carbonate Dissolution/Reprecipitation In Surface Sediments On The Bahamas Bank, David J. Burdige, Xinping Hu, Richard C. Zimmerman

OES Faculty Publications

Using two complimentary approaches (pore water advection/diffusion/reaction modeling and stable isotope mass balance calculations) we show that carbonate dissolution/reprecipitation occurs on early diagenetic time scales across a broad range of sediments on the Great Bahamas Bank. The input of oxygen into the sediments, which strongly controls sediment carbonate dissolution, has two major sources belowground input by seagrasses (that is, seagrass O₂ pumping), and permeability-driven advective pore water exchange. The relative importance of these O₂ delivery mechanisms depends on both seagrass density, and on how bottom water flow interacts with the seagrass canopy and leads to this advective exchange. …

The Path To Preservation: Using Proteomics To Decipher The Fate Of Diatom Proteins During Microbial Degradation, Brook L. Nunn, Ying S. Ting, Lars Malmström, Yihsuan S. Tsai, Angela Aquier, David R. Goodlett, H. Rodger Harvey

OES Faculty Publications

We drew upon recent advances in tandem mass spectrometry-based proteomic analyses in order to examine the proteins that remain after a diatom bloom enters the stationary phase, precipitates out of the photic zone, and is subjected to microbial degradation over a 23-d period within a controlled laboratory environment. Proteins were identified from tandem mass spectra searched against three different protein databases in order to track proteins from Thalassiosira pseudonana and any potential bacterial contributions. A rapid loss of diatom protein was observed over the incubation period; 75% of the proteins initially identified were not detected after 72 h of exposure …

Turbulent Mixing In A Strongly Forced Salt Wedge Estuary, David K. Ralston, W. Rockwell Geyer, James A. Lerczak, Malcolm Scully

OES Faculty Publications

Turbulent mixing of salt is examined in a shallow salt wedge estuary with strong fluvial and tidal forcing. A numerical model of the Merrimack River estuary is used to quantify turbulent stress, shear production, and buoyancy flux. Little mixing occurs during flood tides despite strong velocities because bottom boundary layer turbulence is dislocated from stratification elevated in the water column. During ebbs, bottom salinity fronts form at a series of bathymetric transitions. At the fronts, near-bottom velocity and shear stress are low, but shear, stress, and buoyancy flux are elevated at the pycnocline. Internal shear layers provide the dominant source …

Effect Of The Heterotrophic Dinoflagellate Oxyrrhis Marina And The Copepod Acartia Tonsa On Vertical Carbon Flux In And Around Thin Layers Of The Phytoflagellate Isochrysis Galbana, A. B. Bochdansky, S. M. Bollens, G. C. Rollwagen-Bollens, A. H. Gibson

OES Faculty Publications

Dynamics of material and energy flow through food webs differ when resources are allocated in patches in comparison to situations in which the same resources are distributed evenly throughout the water column. Thin layers of plankton are special cases of such resource patches. While previous studies have predominantly focused on the response of organisms to these layers, we investigated how 2 types of grazers in turn affect thin layers. In an experimental study with tightly controlled environmental conditions, we monitored the redistribution of particulate organic (POC), dissolved organic (DOC) and inorganic (DIC) carbon from thin layers of Isochrysis galbana. …

Role Of Macroscopic Particles In Deep-Sea Oxygen Consumption, Alexander B. Bochdansky, Hendrik M. Van Aken, Gerhard J. Herndl

OES Faculty Publications

Macroscopic particles (> 500 µg), including marine snow, large migrating zooplankton, and their fast-sinking fecal pellets, represent primary vehicles of organic carbon flux from the surface to the deep sea. In contrast, freely suspended microscopic particles such as bacteria and protists do not sink, and they contribute the largest portion of metabolism in the upper ocean. In bathy- and abyssopelagic layers of the ocean (2,000-6,000 m), however, microscopic particles may not dominate oxygen consumption. In a section across the tropical Atlantic, we show that macroscopic particle peaks occurred frequently in the deep sea, whereas microscopic particles were barely detectable. In …

Determination Of Total Dissolved Cobalt In Uv-Irradiated Seawater Using Flow Injection With Chemiluminescence Detection, Rachel U. Shelley, Bernhard Zachhuber, Peter N. Sedwick, Paul J. Worsfold, Maeve C. Lohan

OES Faculty Publications

A sensitive flow-injection method with chemiluminescence detection (FI-CL) for the determination of dissolved cobalt in open ocean samples, suitable for shipboard use has been developed. To date, FI methods for dissolved cobalt have been used only in coastal and estuarine waters. Therefore, significant modifications to existing methods were required, including (1) the use of a commercially available iminodiacetate (IDA) resin (Toyopearl AF-chelate 650M) in place of resin immobilized 8-hydroxyquinoline for online preconcentration and matrix removal, (2) the introduction of acidified ammonium acetate (pH 4) as a column-conditioning step before sample loading and rinse steps, and most importantly, (3) UV irradiation …

Causes Of Tropical Atlantic Paleo-Salinity Variation During Periods Of Reduced Amoc, Xiuquan Wan, Ping Chang, Matthew W. Schmidt

OES Faculty Publications

During periods of reduced Atlantic meridional overturning circulation (AMOC) associated with a freshening of northern North Atlantic surface water, paleo proxy records indicate a corresponding surface salinity increase over the entire tropical Atlantic. Although latitudinal-shifts in the mean position of the Atlantic Intertropical Convergence Zone (ITCZ) can explain certain features of the paleo salinity reconstructions, this mechanism does not offer an explanation for the reconstructed basin-wide paleo-salinity response to AMOC change. Here, we present new results from general circulation model simulations that suggest the sea surface salinity (SSS) increase in the tropical north Atlantic during periods of weakened AMOC is …

A Seasonal Study Of Dissolved Cobalt In The Ross Sea, Antarctica: Micronutrient Behavior, Absence Of Scavenging, And Relationships With Zd, Cd, And P., M. A. Saito, T. J. Goepfert, A. E. Noble, E. M. Bertrand, Peter N. Sedwick, Giacomo R. Ditullio

OES Faculty Publications

We report the distribution of cobalt (Co) in the Ross Sea polynya during austral summer 2005-2006 and the following austral spring 2006. The vertical distribution of total dissolved Co (dCo) was similar to soluble reactive phosphate (PO(4)(3-)), with dCo and PO(4)(3-) showing a significant correlation throughout the water column (r(2) = 0.87, 164 samples). A strong seasonal signal for dCo was observed, with most spring samples having concentrations ranging from similar to ~ 45-85 pM, whereas summer dCo values were depleted below these levels by biological activity. Surface transect data from the summer cruise revealed concentrations at the low range …