Oceanography and Atmospheric Sciences and Meteorology Commons^™

Understanding N-Nitrosodimethylamine Formation In Water: Chloramine Chemistry, Kinetics, And A Proposed Reaction Pathway, Huong Thu Pham

Graduate Theses and Dissertations

The formation of N-nitrosodimethylamine (NDMA) in drinking water systems is a concern because of its potential carcinogenicity and occurrence at toxicologically relevant levels. The postulated mechanism for NDMA formation involves a substitution between dichloramine and amine-based precursors to form an unsymmetrical dimethylhydrazine (UDMH), which is then oxidized by ground-state molecular oxygen to form NDMA. However, this latter reaction is spin forbidden, thus likely occurs at a slow rate. It is hypothesized that the reaction between monochloramine and hydroxylamine (a nitrification product) may form an intermediate, which is involved in the NDMA formation pathway. This intermediate may also be generated from …

The Role Of Sulfur Dioxide In Stratospheric Aerosol Formation Evaluated By Using In Situ Measurements In The Tropical Lower Stratosphere, A. W. Rollins, T. D. Thornberry, L. A. Watts, P. Yu, K. H. Rosenlof, M. Mills, E. Baumann, F. R. Giorgetta, T. V. Bui, M. Höpfner, P. F. Bernath

Chemistry & Biochemistry Faculty Publications

Stratospheric aerosols (SAs) are a variable component of the Earth's albedo that may be intentionally enhanced in the future to offset greenhouse gases (geoengineering). The role of tropospheric-sourced sulfur dioxide (SO₂) in maintaining background SAs has been debated for decades without in situ measurements of SO₂ at the tropical tropopause to inform this issue. Here we clarify the role of SO₂ in maintaining SAs by using new in situ SO₂ measurements to evaluate climate models and satellite retrievals. We then use the observed tropical tropopause SO₂ mixing ratios to estimate the global flux of …

Ab Initio Computation Of Radiative Properties Of Monatomic Hydrogen, Fanny Thomas

Doctoral Dissertations and Master's Theses

With renewed interest in planetary atmospheric entry, descent, and landing, NASA has noted a need for improved physics modeling in computational fluid dynamics. Uncertainty in experimental data used in radiation heat transfer computations leads to “over-engineering” of entry body heat shields, at large weight and cost penalties. There is interest in developing hypersonic thermophysics models from the known “first principles” of physics.

A method for computing high temperature gas emissivity and absorptivity from quantum mechanics principles is developed. The Schroedinger wave equation is cast as a discretized matrix eigenvalue problem which is solved using the ERAU parallel supercomputer. The numerical …

Solar Wind-Magnetosphere Coupling: A Global Perspective Of Reconnection In The Magnetotail, Miles Thomas Bengtson

Doctoral Dissertations and Master's Theses

We present a case study of the 25 December 2015 substorm which occurred between 08:15 and 08:45 Universal Time. During this interval, fast particle flows and field geometry consistent with magnetic reconnection were detected in the mid-tail region. An ejected plasmoid was observed by the lunar-orbiting Acceleration, Reconnection, Turbulence and Electrodynamics of Moon’s Interaction with the Sun (ARTEMIS) probes and corresponding dipolarization signature was observed by the Time History of Events and Macroscale Interactions During Substorms (THEMIS) spacecraft earthward of the reconnection site, which was determined to be approximately -33 RE. Ground signatures indicative of substorm activity were also observed …

Environmental Changes Across The Early Mississippian Carbon Isotope Excursion, Dev Krishna Maharjan

UNLV Theses, Dissertations, Professional Papers, and Capstones

The Early Mississippian K–O (Kinderhookian-Osagean) δ13C excursion or TICE (mid-Tournaisian carbon isotope excursion) is characterized by an anomalous carbonate carbon isotope value of ≥5‰ that has been documented from numerous stratigraphic sections across the globe. This δ13C excursion coincides with global cooling and sea-level fall and predicts a significant change in seawater chemistry. However, sulfate sulfur isotope data across the K-O δ13C excursion reported in previous studies seem not to be responsive to the carbon cycle. Likewise, a recent study has documented a unidirectional increase in nitrogen isotopes across this excursion, which is not anticipated considering the amount of organic …

Age, Growth, And Reproduction Of Vermilion Snapper (Rhomboplites Aurorubens) In The North-Central Gulf Of Mexico, Trevor Dalton Moncrief

Master's Theses

Vermilion Snapper is a commonly harvested species of reef fish in the northern Gulf of Mexico (GOM). It supports both a large commercial and popular recreational fishery, however knowledge of this fish’s life history is limited spatially. Non-linear curve fitting was used to estimate growth parameters and Akaike information criteria (AIC) was used to determine relative model fit. The 2-parameter von Bertalanffy growth function provided the best model fit and lowest AIC score. Histological examination indicated that Vermilion Snapper are batch spawners with asynchronous oocyte development. Additionally, 17% of Vermilion Snapper in the actively spawning phase containing 24 hour POF’s …

A Multi-Millennial Drought Reconstruction For West-Central New Mexico Using Rocky Mountain Juniper (Juniperus Scopulorum, Sarg.), Joshua S. Oliver

Master's Theses

A new multi-millennial tree-ring record from living and remnant Rocky Mountain juniper (Juniperus scopulorum, Sarg.) wood from Candelaria in west-central New Mexico is used to determine the temporal and spatial variability of scPDSI over the past two millennia (B.C. 492 to A.D. 2014). Our record indicates extreme drought events found within other hydroclimatic proxy records in the Colorado Plateau region spanning the time period (16^th century and 2^nd century megadroughts). By ranking the extreme drought events by magnitude, duration, intensity, and overall score, the most extreme drought events of this record are compared to drought events …

Ecological Importance Of Invader Source Population And Disturbance In Aquatic Invasions, Nicole Elizabeth Graham

Graduate Theses and Dissertations

Invasive species are a global problem and their effects on recipient ecosystems may be mediated by disturbance and intraspecific variation. Crayfish can substantially influence stream structure and function, and invasive crayfish often have differential impacts than native crayfish in aquatic ecosystems. Since species traits often vary across a distribution, it is possible that invasive crayfish from different source populations may have distinct impacts on recipient ecosystem structure and function. In the Ozark Highlands of Arkansas and Missouri, USA, invasive O. neglectus (the Ringed Crayfish) may be leading to the displacement of native O. eupunctus (the Coldwater Crayfish). The objective of …

A Global Study Of Gpp Focusing On Light-Use Efficiency In A Random Forest Regression Model, Suhua Wei, Chuixiang Yi, Wei Fang, George Hendrey

Publications and Research

Light-use efficiency (LUE) is at the core of mechanistic modeling of global gross primary production (GPP). However, most LUE estimates in global models are satellite based and coarsely measured with emphasis on environmental variables. Others are from eddy covariance towers with much greater spatial and temporal data quality and emphasis on mechanistic processes, but in a limited number of sites. In this study, we conducted a comprehensive global study of tower-based LUE from 237 FLUXNET towers, and scaled up LUEs from in situ tower level to global biome level. We integrated the tower-based LUE estimates with key environmental and biological …

Investigating The Application Of Multibeam Sonar And Remotely Operated Vehicles In Fish Population Monitoring On Artificial Reefs, Robert Figueroa-Downing

Theses and Dissertations

Implementation of ROVs and multibeam imaging sonar in fisheries research has the potential to improve the accuracy and efficiency of current monitoring practices. This study aimed to 1) compare ROV video and diver abundance estimates; 2) evaluate fish length measurement accuracy from sonar; 3) investigate key differentiating sonar characteristics. Results indicate: 1) Diver surveys captured greater diversity of species; survey methods were comparable with regards to conspicuous species (r = 0.089, p = 0.074); 2) Length measurements from multibeam imaging sonar had high predictive power (Rho = 0.998; p < 0.001) of actual standard lengths and; 3) variations between samples were largely due to swim bladder echo, relative position of the target fish, and schooling characteristics. We conclude that 1) ROVs are less apt at observing cryptic species; 2) The Blueview P900-90 sonar can accurately measure fish length; and 3) swim bladder morphology plays an important role in fish identification.

Using An Altimeter-Derived Internal Tide Model To Remove Tides From In Situ Data, Edward D. Zaron, Richard D. Ray

Civil and Environmental Engineering Faculty Publications and Presentations

Internal waves at tidal frequencies, i.e., the internal tides, are a prominent source of variability in the ocean associated with significant vertical isopycnal displacements and currents. Because the isopycnal displacements are caused by ageostrophic dynamics, they contribute uncertainty to geostrophic transport inferred from vertical profiles in the ocean. Here it is demonstrated that a newly developed model of the main semidiurnal (M2) internal tide derived from satellite altimetry may be used to partially remove the tide from vertical profile data, as measured by the reduction of steric height variance inferred from the profiles. It is further demonstrated that the internal …

Investigation Of The 2013 Alberta Flood From Weather And Climate Perspectives, Bernardo Teufel, G. T. Diro, K. Whan, S. M. Milrad, Et Al.

Publications

During 19–21 June 2013 a heavy precipitation event affected southern Alberta and adjoining regions, leading to severe flood damage in numerous communities and resulting in the costliest natural disaster in Canadian history. This flood was caused by a combination of meteorological and hydrological factors, which are investigated from weather and climate perspectives with the fifth generation Canadian Regional Climate Model. Results show that the contribution of orographic ascent to precipitation was important, exceeding 30% over the foothills of the Rocky Mountains. Another contributing factor was evapotranspiration from the land surface, which is found to have acted as an important moisture …

Design And Characterization Of A Time-Of-Flight Mass Spectrometer For Composition Measurements In The Upper Atmosphere, E. Addison Everett

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

The mesosphere/lower thermosphere (MLT) is perhaps the least understood region of Earth's atmosphere. Too high for balloons and winged aircraft, yet too low for satellites, direct access to the MLT to make in-situ measurements is via high-speed sounding rockets for brief periods of at most a few minutes. Mass spectrometers have previously been used to make composition measurements in this region. But, mass spectrometry in the MLT is difficult, mainly due to the ambient pressures here and also the high speeds and short flight durations of sounding rocket missions. Time-of-flight mass spectrometers (TOF-MS) are capable of making fast, accurate measurements …

Modeling And Projection Of The North American Monsoon Using A High-Resolution Regional Climate Model, Jonathan D.D. Meyer

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

The North American Monsoon (NAM) is a dominant climate feature across the southwestern United States and Mexico during the summertime. Rainfall from the NAM elicits a significant response from the regional ecology as well as supports the socioeconomic well-being of both rural and urban populations. Due to the large variability in the yearly intensity and location of where the NAM rainfall occurs, the region is highly susceptible to prolonged and exceptional periods of drought; compounded by significant population growth projections through the 21st century. Reliable prediction for the NAM is highly beneficial on timescales ranging from shortterm weather forecasting to …

Environmental Factors Affecting Loggerhead Sea Turtle (Caretta Caretta) Nesting, Hatching, And Incubation Patterns In Broward County, Florida, Zoey Ellen Best

HCNSO Student Theses and Dissertations

Reproductive success in loggerhead (Caretta caretta) sea turtles is strongly dependent on the effective placement and internal conditions of their nests. Embryos rely on optimal incubation conditions for proper development and growth, which determines how many hatchlings will emerge from the nest. The internal microclimate of each nest is delicately balanced and can be easily influenced by external environmental conditions. This study was designed to examine several environmental variables and determine their effects on sea turtle nesting numbers, hatching success, and incubation conditions in Broward County Florida. Over a span of 25 years (1991-2015), the Broward County Sea …

Sensitivity Of Mangrove Range Limits To Climate Variability, Kyle C. Cavanaugh, Michael J. Osland, Remi Bardou, Gustavo Hinojosa-Arango, Juan M. Lopez-Vivas, John D. Parker, Andre S. Rovai

United States Geological Survey: Staff Publications

Aim: Correlative distribution models have been used to identify potential climatic controls of mangrove range limits, but there is still uncertainty about the relative importance of these factors across different regions. To provide insights into the strength of climatic control of different mangrove range limits, we tested whether temporal variability in mangrove abundance increases near range limits and whether this variability is correlated with climatic factors thought to control large scale mangrove distributions.

Location: North and South America.

Time period: 1984–2011.

Major taxa studied: Avicennia germinans, Avicennia schuaeriana, Rhizophora mangle, Laguncularia racemosa.

Methods: We characterized temporal variability in the enhanced …

Assessment Of Marine Weather Forecasts Over The Indian Sector Of Southern Ocean, Anitha Gera, D K. Mahapatra, Kuldeep Sharma, Satya Prakash, A. K. Mitra, G. R. Iyengar, E. N. Rajagopal, N. Anil Kumar

Publications and Research

The Southern Ocean (SO) is one of the important regions where significant processes and feedbacks of the Earth's climate take place. Expeditions to the SO provide useful data for improving global weather/climate simulations and understanding many processes. Some of the uncertainties in these weather/climate models arise during the first few days of simulation/forecast and do not grow much further. NCMRWF issued real-time five day weather forecasts of mean sea level pressure, surface winds, winds at 500 hPa & 850 hPa and rainfall, daily to NCAOR to provide guidance for their expedition to Indian sector of SO during the austral summer …

Geospatial Analysis Of Tursiops Truncatus, Common Bottlenose Dolphin, From Noaa Cetacean Stranding Data In Florida To Explore Human Fishery Impacts, Jamie S. Ahn

HCNSO Student Capstones

Cetacean strandings provide valuable biological and geographic information, including various human impacts to vulnerable populations. This study utilizes global information systems (GIS) to conduct geospatial analyses of common bottlenose dolphin, Tursiops truncatus, strandings impacted by fishery interactions in Florida from 2002 to 2014 along with summary statistics of the types of interaction and gear involved. In addition four human impact factors, average human population, average number of boat licenses, average number of fishing permits, and coastline length, were compared to the stranding densities per county for association and predictability. Four regions of stranding “hotspots” were identified, and all human impact …

Mapping The Spatial-Temporal Variation In Ras Ghanada Seagrass Meadows And Sand Shoals Between 1996, 2006 & 2012, Ryan Brookbank

HCNSO Student Theses and Dissertations

Seagrass meadows offshore Ras Ghanada, as elsewhere, are an important component to the ecosystem providing numerous benefits to both aquatic and human life. This work focused on mapping the spatial and temporal distribution of seagrass meadows offshore Ras Ghanada using aerial photography acquired in 1996 and high-resolution satellite images captured in 2006 and 2012. The movements of sand shoals were also tracked, so as to further explain the dynamics of this ecosystem, as it is the area between the shoal crests that hosts the best developed seagrass meadows. The natural limiting factor for seagrass on the Ras Ghanada coastal shelf …

Growth Of Orbicella Faveolata In La Parguera, Puerto Rico, Darren B. Marshall

HCNSO Student Theses and Dissertations

Reef-building corals are subject to high amounts of stress, including pollution and rising sea surface temperatures due to climate change. These factors can affect the ability of corals to produce their calcium carbonate skeletons. Evaluation of the effects of climate change may be facilitated by evaluation of records of coral skeletal growth over a long period of time. The aim of this study was to evaluate skeletal growth of the coral Orbicella faveolata in La Parguera, Puerto Rico over a 32-year period. For this, 14 Orbicella faveolata core samples were collected from corals at two reefs (1.2 km apart) in …