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Fischer–Tropsch Synthesis: Effect Of Ammonia On Product Selectivities For A Pt Promoted Co/Alumina Catalyst, Venkat Ramana Rao Pendyala, Wilson D. Shafer, Gary Jacobs, Michela Martinelli, Dennis E. Sparks, Burtron H. Davis 2017 University of Kentucky

Fischer–Tropsch Synthesis: Effect Of Ammonia On Product Selectivities For A Pt Promoted Co/Alumina Catalyst, Venkat Ramana Rao Pendyala, Wilson D. Shafer, Gary Jacobs, Michela Martinelli, Dennis E. Sparks, Burtron H. Davis

Center for Applied Energy Research Faculty and Staff Publications

The effects of co-fed ammonia in synthesis gas on the activity and product selectivities of a typical cobalt catalyst (0.5% Pt–25% Co/Al2O3) were investigated during the Fischer–Tropsch synthesis using a continuously stirred tank reactor (CSTR). The product selectivities were compared at a similar CO conversion level for various concentrations (10–1000 ppmv) of ammonia, as well as clean (un-poisoned) conditions. The addition of 10–1000 ppmv ammonia (concentration of ammonia with respect to the syngas feed) significantly decreased activity; the percentage of deactivation was similar (∼40%) for the various concentrations of ammonia used. At similar CO conversions, the …


The Irreversible Momentum Of Clean Energy, Barack Obama 2017 President of the United States

The Irreversible Momentum Of Clean Energy, Barack Obama

United States Department of Energy: Publications

The release of carbon dioxide (CO2) and other greenhouse gases (GHGs) due to human activity is increasing global average surface air temperatures, disrupting weather patterns, and acidifying the ocean. Left unchecked, the continued growth of GHG emissions could cause global average temperatures to increase by another 4°C or more by 2100 and by 1.5 to 2 times as much in many midcontinent and far northern locations. Although our understanding of the impacts of climate change is increasingly and disturbingly clear, there is still debate about the proper course for U.S. policy—a debate that is very much on display …


Plasmonic Luminescent Down Shifting Layers For The Enhancement Of Cdte Mini-Modules Performance, Hind Ahmed, S.J. McCormack, John Doran 2017 Trinity College Dublin, Ireland

Plasmonic Luminescent Down Shifting Layers For The Enhancement Of Cdte Mini-Modules Performance, Hind Ahmed, S.J. Mccormack, John Doran

Articles

In this investigation, plasmonic coupling between luminescent species (lumogen yellow, and silver nanoparticles (Ag NPs) has been exploited to produce significant enhancement in absorption and fluorescence emission of lumogen yellow dye luminescent downshifting (LDS) layers. The optimum dye concentration in a poly(methyl,methacrylate) polymer LDS layer of ∼100μm thickness was established. Subsequently, plasmonic coupling with Ag NPs was introduced and optimum concentration has been determined for the composite plasmonic Luminescent Down-Shifting (pLDS) layers. The optimum plasmonic coupling has been observed to produce fluorescence emission enhancement of up to 81% for the dye-pLDS layers. The pLDS layers were deposited on top of …


Land Trust Response To Renewable Energy Siting Challenges In New York, Collin David Adkins 2017 Bard College

Land Trust Response To Renewable Energy Siting Challenges In New York, Collin David Adkins

Bard Center for Environmental Policy

Energy policies promoting energy independence, grid modernization, climate change mitigation, and clean energy standards are a leading driver of land-use change in the United States. This has resulted in an increased pressure to develop land. The recent focus by states to expand renewable energy poses an interesting challenge to organizations dedicated to conserving open space and natural resources, creating a potential tension between competing “green” goals. In response, The Land Trust Alliance, a national organization supporting over 1,100 member land trusts, has recently set a goal to “empower land trusts to encourage the buildout of renewable energy facilities while steering …


Computational Modeling Of A Williams Cross Flow Turbine, Sajjan Pokhrel 2017 Wright State University

Computational Modeling Of A Williams Cross Flow Turbine, Sajjan Pokhrel

Browse all Theses and Dissertations

Hydropower is not only the most used renewable energy source in the United States, but in the world. While it is well known that large hydropower facilities, like the Hoover Dam, provide large amounts of electrical power, there is also a tremendous opportunity for hydroelectric power generation from small scale facilities that has largely been overlooked. The work being presented here studies a new cross flow turbine called the Williams Cross Flow Turbine (WCFT), which was designed to extract electric energy from low head, run-of-the-river, small hydropower sites. To spur the implementation of the WCFT in small hydropower applications, and …


Study Of Surface Complexation And Mineral Dissolution During Water-Rock Interaction In High Salinity Waterflooding At Elevated Temperatures, Sameer Salasakar 2017 Missouri University of Science and Technology

Study Of Surface Complexation And Mineral Dissolution During Water-Rock Interaction In High Salinity Waterflooding At Elevated Temperatures, Sameer Salasakar

Masters Theses

"High salinity waterflooding for carbonate reservoirs is efficient and cheap method used for improved oil recovery. Various mechanisms have been proposed including adsorption/desorption on rock surface, mineral dissolution and precipitation, multicomponent ion exchange, interfacial tension reduction, fine migration and double layer expansion. These all process alter the wettability which leads to improved oil recovery.

Objective of this study was to understand processes that occur during water-rock interaction when high salinity water is flooded into the reservoir. In this work, effect of temperature on water-rock interaction is studied along with effect of pH and specific surface areas of calcite at normal …


Leadership Strategies For Maintaining Profitability In A Volatile Crude Oil Market, Lucky Anderson Braimoh 2017 Walden University

Leadership Strategies For Maintaining Profitability In A Volatile Crude Oil Market, Lucky Anderson Braimoh

Walden Dissertations and Doctoral Studies

Volatile crude oil prices significantly affect the profitability of crude oil firms. The purpose of this single case study was to explore strategies some crude oil and gas business leaders used to remain profitable during periods of crude oil price volatility. The target population comprised 8 crude oil and gas business leaders located in Calgary, Canada, whose company remained profitable despite crude oil price volatility. The transformational leadership theory formed the conceptual framework for the study. Data were collected through the use of semistructured face-to-face interviews, company reports, and field notes. Data analysis involved a modified Van Kamm method, which …


Strengthening The Development Of The Short-Rotation Plantations Bioenergy Sector: Policy Insights From Six European Countries, Carlos Parra-Lopez, Martin Holley, Kevin Lindegaard, Samir Sayadi, Gonzalo Esteban-Lopez, Victor Duran-Zuazo, Christoph Knauer, Hans-Georg von Engelbrechten, Ralf Winterber, Annika Henriksson, Annette Lamley, Anders Nylander, Susanne Paulrud, Pauline Leonard, Patrick Daly, Lukasz Drzewaszewski, Wojciech Rzewuski 2017 IFAPA

Strengthening The Development Of The Short-Rotation Plantations Bioenergy Sector: Policy Insights From Six European Countries, Carlos Parra-Lopez, Martin Holley, Kevin Lindegaard, Samir Sayadi, Gonzalo Esteban-Lopez, Victor Duran-Zuazo, Christoph Knauer, Hans-Georg Von Engelbrechten, Ralf Winterber, Annika Henriksson, Annette Lamley, Anders Nylander, Susanne Paulrud, Pauline Leonard, Patrick Daly, Lukasz Drzewaszewski, Wojciech Rzewuski

Articles

This paper, based on a participatory methodological framework involving expert stakeholders and researchers from six European countries (Germany, Ireland, Poland, Spain, Sweden and UK), analyses the priority issues for the development of short-rotation plantations (SRP), and proposes a series of policy strategies to strengthen this development. The results indicate that there is a lack of awareness of the multifaceted benefits of SRP at the level of farmers, policy makers and public authorities. More research is required to put a value on the multifunctionality of SRP and justify its public support. Small-scale projects using established technologies are also required with energy …


Evaluation Of Earth-Abundant Monometallic And Bimetallic Complexes For Catalytic Water Splitting, Kenneth Kwame Kpogo 2017 Wayne State University

Evaluation Of Earth-Abundant Monometallic And Bimetallic Complexes For Catalytic Water Splitting, Kenneth Kwame Kpogo

Wayne State University Dissertations

The development of affordable water splitting catalysts from Earth-abundant transition metal ions such as Co and Mn is of immense scientific interest. Aiming to develop an efficient water splitting catalyst, a Co(II) complex featuring an asymmetric, pentadentate quinolyl-bispyridine ligand with a phenylenediamine backbone was synthesized and characterized by spectroscopic, spectrometric, and X-ray analysis. The Co ion was selected because of its ability to undergo redox conversions from 3d5 CoIV through 3d8 CoI thereby making it a suitable catalyst that can withstand harsh structural and electronic changes during catalysis. The electrocatalytic water reduction activity of the catalyst at neutral pH gave …


Technological Modernization And Its Impact On Agriculture, Fisheries And Fossil Fuel Utilization In The Asia Pacific Countries With Emphasis On Sustainability Perspective, Rajee Olaganathan, Kathleen Quigley 2017 Embry-Riddle Aeronautical University

Technological Modernization And Its Impact On Agriculture, Fisheries And Fossil Fuel Utilization In The Asia Pacific Countries With Emphasis On Sustainability Perspective, Rajee Olaganathan, Kathleen Quigley

Publications

Modernization is a process that moves towards efficiency. This affects most of the fields such as agriculture, fisheries, forestry, urban planning, policy, fossil fuel usage, manufacturing, technology, economic growth etc. This process plays a major role in moving forward making things faster, better and basically more efficient. The effects of modernization on all these fields bring about the major changes to aspects such as social, economic and the environment. The level of operation has increased from a domestic level; small family scale business to large commercial levels. As the level of operation increased, the utilization of natural resources increased gradually …


Sugar Versus Lipid For Sustainable Biofuels, Yaşar Demirel 2017 University of Nebraska-Lincoln

Sugar Versus Lipid For Sustainable Biofuels, Yaşar Demirel

Yaşar Demirel Publications

Introduction

First‐generation biofuels, namely, ethanol and biodiesel, have led to far reaching impact on the peoples’ life world‐wide.[1] However, they inter-fere with the food supply chain and may not be sustainable although some of the biomass are converted to biofuels after those biomasses have met the human needs. Still, the first‐generation–based biofuels have proved that sugar and lipid platforms can be an answer to energy security and global warming concerns without the need for new infrastructure for feedstock delivery as well as for biomass‐to‐biofuel conversion tech-nologies. At the same time, we are discovering and assessing the long‐term environmental im-plications on …


Evaluation Of Flocculation, Sedimentation, And Filtration For Dewatering Of Scenedesmus Algae, Nicholas A. Rhea, Jack Groppo, Czarena Crofcheck 2017 University of Kentucky

Evaluation Of Flocculation, Sedimentation, And Filtration For Dewatering Of Scenedesmus Algae, Nicholas A. Rhea, Jack Groppo, Czarena Crofcheck

Biosystems and Agricultural Engineering Faculty Publications

Algae can be used as a feedstock for agricultural fertilizers, livestock and poultry feeds, anaerobic digestion, and biofuel production. For each end product, the requirements for moisture content (or solids content) vary, such that a desirable water removal strategy needs to be adaptable to varying levels of water removal. Flocculation, sedimentation, and filtration were evaluated as possible strategies for thickening and dewatering of algae. The goal of this study was to validate that algae cells treated by such means could be processed by vacuum belt filters and to determine the conditions under which the solids content could be increased to …


Development Of Computer Program For Wind Resource Assessment, Rotor Design And Rotor Performance, Valentina Jami 2017 Wright State University

Development Of Computer Program For Wind Resource Assessment, Rotor Design And Rotor Performance, Valentina Jami

Browse all Theses and Dissertations

People understand and have seen that renewable energy has many advantages over conventional energy sources. Because of these advantages, more and more emphasis has been given to generating electrical energy with renewable sources. Among the many renewable and conventional ways currently available for a society to generate electrical power, wind turbines are one of the cheapest ways of doing this. The main objective of this thesis work is to develop a computer program that assesses the wind resource at a given location, designs a wind turbine rotor for optimum power capture for one wind speed, and analyzes the performance of …


Development Of A Dynamic Cfd Model For Offshore Oscillating Water Columns With Non-Linear Interactions, Ken O'Connell 2017 Department of Mechanical, Biomedical and Manufacturing Engineering, Cork Ireland.

Development Of A Dynamic Cfd Model For Offshore Oscillating Water Columns With Non-Linear Interactions, Ken O'Connell

Theses

This thesis focuses on the development of a state of the art modelling technique for offshore Oscillating Water Column (OWC) type Wave Energy Converters (WEC) using Computational Fluid Dynamics (CFD). Current literature indicates a limited amount of work has been completed on studying these devices containing non-linear time dependent flow phenomenon. Initially, a 2D Numerical Wave Tank (NWT) is studied to reduce discretisation error in order to reproduce accurately propagating waves. Further development into a 3D domain permits the geometrical requirements of an OWC type spar buoy to be included.

In parallel, a single Degree of Freedom (DOF) model is …


Forward Osmosis For Wastewater Treatment And Energy Recovery: A Techno-Economic Analysis, Patrick William Buckwalter 2017 Humboldt State University

Forward Osmosis For Wastewater Treatment And Energy Recovery: A Techno-Economic Analysis, Patrick William Buckwalter

Cal Poly Humboldt theses and projects

A novel wastewater treatment system was investigated using forward osmosis membranes to treat municipal wastewater. Treatment by forward osmosis was determined to cost $10 million per million gallons per day (MGD) of wastewater capacity over a 20-year lifetime, with an energy consumption of 870 kWh per million gallons. A case study at the Arcata Wastewater Treatment Plant was conducted to investigate a treatment system that combines energy recovery from algae biomass with forward osmosis membrane treatment using local seawater as a draw solution. Total system cost was calculated to be $29.7 million over a 20-year lifetime with a 2.3 MGD …


More Than Food: An Analysis Of Multidimensional Relationships In Our Food System, Jessica Erin Newnan 2017 University of New Hampshire, Durham

More Than Food: An Analysis Of Multidimensional Relationships In Our Food System, Jessica Erin Newnan

Honors Theses and Capstones

Food is an integral part of everyday life for human beings, thus meriting particular attention from research and education. Looking further in depth at the factors that influence food, it becomes apparent that this is a complex topic that is related to several systems within the constructs of society. Here, the food system is approached with the understanding that several systems influence food consumption options and decisions including the agricultural, economic, education, energy, health, and political systems. To identify the relationships more closely, a three-dimensional model was built to represent the food system and depict several key factors, their relationships, …


The Applications Of Rate Constants In Commercial Methane Digesters, Alyssa Nuñez 2017 Parkland College

The Applications Of Rate Constants In Commercial Methane Digesters, Alyssa Nuñez

Natural Sciences Student Research Presentations

This slide presentation for the Natural Sciences Poster Session at Parkland College summarizes a study conducted to test the effectiveness of rate constants to measure stability and productivity in commercial methane digesters. The study concluded that using rate constants can improve peak production and make methane order an economically viable energy option. The study also concluded that nickel supplements have a large effect on rate constants.


The Decline And Recovery Of Thermal Oxidative Stability Of Ultra-Low Sulfur Diesel Blends, Abigail Schoor Cohen 2017 Duquesne University

The Decline And Recovery Of Thermal Oxidative Stability Of Ultra-Low Sulfur Diesel Blends, Abigail Schoor Cohen

Electronic Theses and Dissertations

Dissertation supervised by Professor Bruce D. Beaver

The oxidative stability of ultra-low sulfur diesel (ULSD) has generally been expected to continuously decline over time. However, recent studies have suggested that it may fluctuate.1-2 In this study, the oxidative stability of stored commercially purchased ULSD was monitored with a methanol extraction method.3 In this methodology, proposed by Hardy and Wechter, fuel blends are extracted with methanol before and after thermal stressing.4 The methanol-soluble layer contains the oxygenated and oxidizable components of the fuel (SMORS) and the change in this mass upon stressing thus represents the oxidative stability of …


Depositional Controls And Sequence Stratigraphy Of Lacustrine To Marine Transgressive Deposits In A Rift Basin, Lower Cretaceous Bluff Mesa, Indio Mountains, West Texas, Andrew Anderson 2017 University of Texas at El Paso

Depositional Controls And Sequence Stratigraphy Of Lacustrine To Marine Transgressive Deposits In A Rift Basin, Lower Cretaceous Bluff Mesa, Indio Mountains, West Texas, Andrew Anderson

Open Access Theses & Dissertations

Successful hydrocarbon exploration in former rift basins of the South Atlantic pre-salt has generated interest in understanding depositional, diagenetic, and stratigraphic controls on pre-salt deposits. However, most studies to date have focused on attributes and controls on presalt lacustrine carbonate reservoir systems and little work has been done on the overlying marine sealing facies. Currently our standard sequence stratigraphic model of marine transgression of rift systems involves a single pulse of marine flooding over fluvially-incised valleys resulting in backstepping of fluvial and estuarine siliciclastic facies within the erosionally confined zone of an incised valley. However, the pre-salt systems of the …


Quantifying The Characteristic Length Of A Combustor For An Ionic Liquid Monopropellant Thruster, Kimberly Marie Hogge 2017 University of Texas at El Paso

Quantifying The Characteristic Length Of A Combustor For An Ionic Liquid Monopropellant Thruster, Kimberly Marie Hogge

Open Access Theses & Dissertations

Ionic liquid monopropellants are currently being researched as a promising alternative to hydrazine in propulsion systems. This report presents a flame study that delineates the flame length of the expected decomposition products from an ionic liquid monopropellant. Through these studies, the characteristic length of a combustion chamber will be defined through calculations and empirical correlations. There is limited information on designing a propulsion system for an ionic liquid monopropellant. Therefore, defining the magnitude for an effective characteristic length serves as beneficial in designing a propulsion system for an ionic liquid monopropellant thruster.


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