Astrophysics and Astronomy Commons^™

Probing Charge Recombination In Organic Solar Cells, Ally C. Hurd, Awwad Alotaibi, Acacia Patterson, Obaid Alqahtani, James Doyle, Brian Akira Collins

Macalester Journal of Physics and Astronomy

Printable and flexible organic solar panels are promising sources of inexpensive, large-scale renewable energy, where panels can be manufactured by printing from polymer inks. There are some limitations to these types of solar cells, however. First, toxic halogenated solvents have historically been necessary to dissolve polymers to make the ink. In addition, organic solar cells typically have high rates of recombination, which limits their efficiency. Here, we use a transient photovoltage (TPV) technique to measure charge lifetimes in cells made from two different organic solvents. The first solvent is toxic, halogenated dichlorobenzene (DCB) which is typically used to make organic …

Investigation Of Tantalum Sodium Lead Borate Glass Using Laser Ionization Time Of Flight Mass Spectrometry (Litof-Ms), Siri Erickson-Green

Macalester Journal of Physics and Astronomy

Laser ionization time of flight mass spectrometry (LITOF-MS) is a spectrometry method which can measure, with exceptional accuracy, the composition of ions within a glass system. Additionally, unlike other spectroscopy and spectrometry methods, this technique allows insight into the abundance of each kind of ion within a given glass system. This specific project tackled the topic of tantalum-doped sodium and lead borate glasses, as sodium and lead borate glasses doped with a transition metal is a topic which has not been thoroughly explored. Our group synthesized such a glass and was able to use LITOF-MS to gain insights into how …

Strain Methods For Changing Local Electric Field Gradient In Bafe2as2, Caleb Williams

Macalester Journal of Physics and Astronomy

In this study, we introduce a novel approach aimed at advancing the investigation of local nematicity in BaFe2As2 via dynamically pulsed strain fields. Our research is motivated by the pursuit of a more sensitive alternative to existing static strain methods. Employing nuclear magnetic resonance techniques, we measure the nuclear quadrupolar energy splittings, utilizing them as a sensitive indicator of the electric field gradient (EFG) that couples strongly to the orbital occupations of the 75As p-orbitals. In the new method, we discern an EFG response through changes in the phase acquired by the nuclear magnetization while time-evolving in the strain field, …

Linking The Population Of Binary Black Holes With The Stochastic Gravitational-Wave Background, Olivia X. Laske

Macalester Journal of Physics and Astronomy

The astrophysical stochastic gravitational-wave background (SGWB) is the product of overlapping waveforms that create a single unresolvable background. While current LIGO sensitivity is insufficient to uncover the SGWB, future space-based detectors and Third Generation (3G) experiments are expected to probe deep enough for detection. Predictions of the SGWB can constrain future searches as well as provide insight into star formation, merger history, and mass distribution. Here, three primary methods are used to calculate a theoretical SGWB. The first method integrates over a precomputed mass distribution probability grid, while the second and third employ Monte Carlo integration with simulated data. After …

Simulation Of Polymerization On Surfaces: Implications For Abiogenesis, Sylvia Greene

Macalester Journal of Physics and Astronomy

How did life arise from the prebiotic conditions of the early earth? This problem has vexed scientists for decades with no consensus on its solution. Significant spontaneous formation of biopolymers such as proteins and nucleic acids in the aqueous phase appears to be improbable due to thermodynamic constraints. It has been proposed that mineral surfaces could have served as a catalyst for the initial formation of biopolymers. However, the feasibility of this mechanism has not been thoroughly studied. In this study, a particle simulation of polypeptide formation on surfaces is developed to assess the feasibility of this mechanism. Elementary processes …

Variability Of High-Degree Modes Over Multiple Solar Cycles Using Local Helioseismic Data From Gong, Nicholas Cebula, Sushanta Tripathy, Kiran Jain, John M. Cannon

Macalester Journal of Physics and Astronomy

In this investigation we use the local helioseismic technique of ring diagrams to study the power, energy, and damping rates of high degree solar acoustic modes. Our data covers the period from the maximum phase of solar cycle 23 to the ascending phase of cycle 25. The goal is to examine the variations in the mode parameters with solar activity as well as the differences between different cycles. For this, we use different proxies of solar activity. We use 10.7 cm radio flux measurements and a measure of magnetic flux known as magnetic activity index from magnetograms.

Ammonia Emission In The Milky Way Galactic Bar Dust Lanes, Charles G. Burton

Macalester Journal of Physics and Astronomy

The Central Molecular Zone (CMZ) of the Milky Way is a region of molecular gas within the inner few hundred parsecs of the Galaxy. This inner region of the Milky Way is hotter and more turbulent when compared with the disk of the Milky Way. Gas is thought to be funneled into the CMZ through dense gaseous dust lanes that are associated with the Galactic Bar. I studied two regions of one of these dust lanes using the NH3 inversion transitions of (J,K) = (1,1), (2,2), (3,3), and (4,4). Data has been obtained from the Green Bank Telescope targeting these …

Unbiased Estimation Of Gravitational-Wave Anisotropies From Noisy Data, Nikolaos Kouvatsos, Alexander C. Jenkins, Arianna I. Renzini, Joseph D. Romano, Mairi Sakellariadou

Physics & Astronomy Faculty Publications

One of the most exciting targets of current and future gravitational-wave observations is the angular power spectrum of the astrophysical GW background. This cumulative signal encodes information about the large-scale structure of the Universe, as well as the formation and evolution of compact binaries throughout cosmic time. However, the finite rate of compact binary mergers gives rise to temporal shot noise, which introduces a significant bias in measurements of the angular power spectrum if not explicitly accounted for. Previous work showed that this bias can be removed by cross-correlating GW sky maps constructed from different observing times. However, this …

Technology Innovation Is The Key To Future Space Science Missions, Ji Wu

Bulletin of Chinese Academy of Sciences (Chinese Version)

Space science is one of the important space activities of China together with space technology and space application. Although it is a space program aimed at scientific discovery and breakthrough, with the development of technology and the increasing number of achievements received in the past, space science missions require more and more technological innovation to achieve their goals. This study first reviews the development trend of space science missions since their birth, then analyzes the cultivation process of space science mission proposals with technological innovation and the responsibilities of the chief scientist leading such tasks, and finally analyzes and proposes …

A Novel Positive-Contrast Magnetic Resonance Imaging Line Marker For High-Dose-Rate (Hdr) Mri-Assisted Radiosurgery (Mars), Li Wang, Yao Ding, Teresa L. Bruno, R. Jason Stafford, Eric Lin, Tharakeswara K. Bathala, Jeremiah W. Sanders, Matthew S. Ning, Jingfei Ma, Karen S. Martirosyan

Physics & Astronomy Faculty Publications

Magnetic resonance imaging (MRI) can facilitate accurate organ delineation and optimal dose distributions in high-dose-rate (HDR) MRI-Assisted Radiosurgery (MARS). Its use for this purpose has been limited by the lack of positive-contrast MRI markers that can clearly delineate the lumen of the HDR applicator and precisely show the path of the HDR source on T1- and T2-weighted MRI sequences. We investigated a novel MRI positive-contrast HDR brachytherapy or interventional radiotherapy line marker, C4:S, consisting of C4 (visible on T1-weighted images) complexed with saline. Longitudinal relaxation time (T1) and transverse relaxation time (T2) for C4:S were measured on a 1.5 T …

Nidus Idearum. Scilogs, Xiii: Structure / Neutrostructure / Antistructure, Florentin Smarandache

Branch Mathematics and Statistics Faculty and Staff Publications

In this thirteenth book of scilogs – one may find topics on Neutrosophy, Plithogeny, Physics, Mathematics, Philosophy – email messages to research colleagues, or replies, notes, comments, remarks about authors, articles, or books, spontaneous ideas, and so on. It presents new types of soft sets and new types of topologies.

Exchanging ideas with Mohammad Abobala, Ishfaq Ahmad, Ibrahim M. Almanjahie, Fatimah Alshahrani, Nizar Altounji, Muhammad Aslam, Said Broumi, Victor Christianto, R. Diksh, Feng Liu, Frank Julian Gelli, Erick Gonzalez Caballero, Riad Hamido, Yaser Al-Hasan, Ahmed Hatip, Yasin Karmouta, Nivetha Martin, Preda Mihăilescu, V. Lakshmana Gomathi Nayagam, Ze Carlos Tiago de …

Avoiding Pitfalls In Molecular Simulation Of Vapor Sorption: Example Of Propane And Isobutane In Metal–Organic Frameworks For Adsorption Cooling Applications, Filip Formalik, Haoyuan Chen, Randall Q. Snurr

Physics & Astronomy Faculty Publications

This study introduces recommendations for conducting molecular simulations of vapor adsorption, with an emphasis on enhancing the accuracy, reproducibility, and comparability of results. The first aspect we address is consistency in the implementation of some details of typical molecular models, including tail corrections and cutoff distances, due to their significant influence on generated data. We highlight the importance of explicitly calculating the saturation pressures at relevant temperatures using methods such as Gibbs ensemble Monte Carlo simulations and illustrate some pitfalls in extrapolating saturation pressures using this method. For grand canonical Monte Carlo (GCMC) simulations, the input fugacity is usually calculated …

Analysis Of Modeled 3d Solar Magnetic Field During 30 X/M-Class Solar Flares, Seth H. Garland, Vasyl B. Yurchyshyn, Robert D. Loper, Benjamin F. Akers, Daniel J. Emmons Ii

Faculty Publications

Using non-linear force free field (NLFFF) extrapolation, 3D magnetic fields were modeled from the 12-min cadence Solar Dynamics Observatory Helioseismic and Magnetic Imager (HMI) photospheric vector magnetograms, spanning a time period of 1 hour before through 1 hour after the start of 18 X-class and 12 M-class solar flares. Several magnetic field parameters were calculated from the modeled fields directly, as well as from the power spectrum of surface maps generated by summing the fields along the vertical axis, for two different regions: areas with photospheric |B_z|≥ 300 G (active region—AR) and areas above the photosphere with the …

Chandra Hetg X-Ray Spectra And Variability Of Π Aqr, A Γ Cas-Type Be Star, David P. Huenemoerder, Pragati Pradhan, Claude R. Canizares, Sean Gunderson, Richard Ignace, Joy S. Nichols, A.M.T. Pollock, Norbert S. Schulz, Dustin K. Swarm, José M. Torrejón

Publications

High-resolution X-ray spectra of π Aqr, a γ Cas-type star, obtained with the Chandra/HETG spectrometer, revealed emission lines of H-like ions of Mg, Si, S, and Fe; a strong, hard continuum; and a lack of He-like ions, indicating the presence of very hot thermal plasma. The X-ray light curve showed significant fluctuations, with coherent variability at a period of about 3400 s in one observation. The hardness ratio was relatively constant except for one observation in which the spectrum was much harder and more absorbed. We interpret the X-ray emission as arising from accretion onto the secondary, which is likely …

Sunyaev-Zeldovich Effect In The Intra-Cluster Medium, Nathan Fronk

Senior Seminars and Capstones

This paper covers the Sunyaev-Zeldovich effect, it’s derivation, and it’s applications in astronomy. The effect is a result of inverse Compton scattering in a cloud of hot charged particles, causing an increase in the temperature of the the cosmic microwave background radiation passing through the cloud. This change in temperature can be measured, and used to calculate the physical properties of the structure in question. This paper focuses on the a method used by Adam et al. (2017) to find a temperature map of the intra-cluster medium.

Theoretical Spectroscopic Predictions Of Electronically Excited States, Noah R. Garrett

Honors Theses

The quest for faster computation of anharmonic vibrational frequencies of both ground and excited electronic states has led to combining coupled cluster theory harmonic force constants with density functional theory (DFT) cubic and quartic force constants for defining a quartic force field (QFF) utilized in conjunction with vibrational perturbation theory at second order (VPT2). This work shows that explicitly correlated coupled cluster theory at the singles, doubles, and perturbative triples level [CCSD(T)-F12] provides accurate anharmonic vibrational frequencies and rotational constants when conjoined with any of B3LYP, CAM-B3LYP, BHandHLYP, PBE0, and ωB97XD for roughly one-quarter of the computational time of the …

Nanograv 15-Year Gravitational-Wave Background Methods, Aaron D. Johnson, Patrick M. Meyers, Paul T. Baker, Neil J. Cornish, ‪Jeffrey S. Hazboun, Tyson B. Littenberg, Joseph D. Romano, Stephen R. Taylor, Michele Vallisneri

Physics & Astronomy Faculty Publications

Pulsar timing arrays (PTAs) use an array of millisecond pulsars to search for gravitational waves in the nanohertz regime in pulse time of arrival data. This paper presents rigorous tests of PTA methods, examining their consistency across the relevant parameter space. We discuss updates to the 15-year isotropic gravitational-wave background analyses and their corresponding code representations. Descriptions of the internal structure of the flagship algorithms enterprise and ptmcmcsampler are given to facilitate understanding of the PTA likelihood structure, how models are built, and what methods are currently used in sampling the high-dimensional PTA parameter space. We introduce a novel version …

Examining Galaxy Bulge Regions With The Sloan Digital Sky Survey, Sarah E. Draves, Ariyeh Maller

Publications and Research

Nearly all of the ordinary matter in the universe is located in galaxies, which are made up stars, gas, dust, and black holes, and range in size from a few thousand to a few hundred thousand light years across. Galaxies come in different shapes, but many of them are spiral shaped, and some of those have a central bulge region that is distinct from the rest of the galactic disk. This project used a large data set of galaxies that had their bulge and disk components separated to see what correlations those fractions of each galaxy have with other galaxy …

Cn Stretches Around 4.4 Microns Dominate The Ir Absorption Spectra Of Cyanopolycyclic Aromatic Hydrocarbons, Vincent J. Esposito, Ryan C. Fortenberry, Christiaan Boersma, Alexandros Maragkoudakis, Louis J. Allamandola

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

Anharmonic quantum chemical computations reveal a strong, narrow (width = 0.075 μm) band in the 4.3–4.5 μm region of the absorption spectra of the cyano-substituted polycyclic aromatic hydrocarbons (CN-PAHs) cyanonaphthalene, cyanoanthracene, c yanophenanthrene, and c yanopyrene. This narro w windo w with intense IR lines implies that CN-PAHs of various shapes and sizes offer little variation in both wavelength and intensity in this region. Subsequently, this band can be used as a tracer for CN-PAHs. The distinct features making up the band are assigned to mixed vibrational states consisting of the CN stretch fundamental and various combination bands, including in-plane …

Analysis Of Bayesian Transfer Function Fitting Method - A Potential Tool For Estimating Interferometer Uncertainty, Caden Swain

Honors Thesis

The Response Function of the LIGO Interferometer is central to reconstructing the strain produced by incoming gravitational waves. As a function of the interferometer's response to external stimuli, the Response Function is both analytically modeled and experimentally measured using excitations from the photon calibrator system at discrete frequencies. The uncertainty in each data point is propagated to the residual between the model and measurements, with both the uncertainty and residual being interpolated over a broadband frequency range. This project explores an alternative method to estimating the uncertainty and systematic error present in the Response function model through the utilization of …