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2021

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Articles 1741 - 1742 of 1742

Full-Text Articles in Chemistry

Determination Of Molecular Markers Of Vaccinium Berry Standard Reference Materials Through Differential Analysis With Ultrahigh Resolution Lc/Ms, Abby Mikolitis Jan 2021

Determination Of Molecular Markers Of Vaccinium Berry Standard Reference Materials Through Differential Analysis With Ultrahigh Resolution Lc/Ms, Abby Mikolitis

Dissertations, Master's Theses and Master's Reports

Blueberries and cranberries have vastly different flavor profiles despite both being a part of the Vaccinium genus. Their high content of phenolics makes them subjects of interest in preventative medicine, especially research in illnesses such as heart disease and cancer. Analysis has primarily focused on the identification and characterization of polyphenols, primarily anthocyanins which are a subclass of polyphenols, with ultra-high performance liquid chromatography coupled with electrospray ionization high resolution mass spectrometry (UHPLC-ES/HRMS). This study aims to develop a novel method of non-targeted UHPLC-ES/MS analysis with post processing and formula assignment performed with MZmine 2.53 and MFAssignR software tools. Pairing …


Cobalt, Molybdenum, And Nickel Complexes, Natural Zeolites, Epoxidation, And Free Radical Reactions, Nicholas K. Newberry Jan 2021

Cobalt, Molybdenum, And Nickel Complexes, Natural Zeolites, Epoxidation, And Free Radical Reactions, Nicholas K. Newberry

Dissertations, Master's Theses and Master's Reports

Chapter 2 is based on the synthesis and study of the compounds of the bidentate ligand ((5-phenyl-1H-pyrazol-3-yl)methyl)phosphine oxide with molybdenum and cobalt as the transition metal. The complexes were analyzed via FTIR, NMR, UV-Vis, Fluorescence Spectroscopy, TGA, DFT, and XRD. Chapter 3 resulted in the synthesis of the complexes [Ni(II)SSRRL](PF6)2 and [Ni(II)SRSRL](Cl)(PF6) of which [Ni(II)SRSRL](Cl)(PF6) had not been previously analyzed. Both products were analyzed via FTIR, NMR, UV-Vis, CV, DFT, and XRD. Chapter 5 contains the results of the characterization and modification of 4 natural zeolites (AZLB-Na, AZLB-Ca, NM-CA, NV-Na) from the United States in an attempt to increase the …