Physical Sciences and Mathematics Commons^™

Preparation And Electrochemical Properties Of Flake-Like Liv3O8 By Soft Template Assisted Sol-Gel Method As Anode Material For Aqueous Li-Ion Battery, Shuai Tan, Dan Sun, Hai-Yan Wang, Tian-Li Hou, Zhong-Xing Xiao, You-Gen Tang

Journal of Electrochemistry

Composite electrode of CuF₂/MoO₃/C was fabricated through high energy mechanical milling. The properties of CuF₂/MoO₃/C were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), high resolution transmission electron microscopy (TEM), galvanostatic charge-discharge measurements, cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). The results showed that the grain sizes of CuF₂ and MoO₃ after milling were 200 ~ 300 nm, and the initial discharge capacity of CuF₂/MoO₃/C was 647 mAh·g^-1 at room temperature and at a current density of 10 mAh·g^-1. However, the …

Synthesis And Electrochemical Performance Of Nano Licopo4 By Polyol Method, Fei Wang, Yang Jun

Journal of Electrochemistry

High potential LiCoPO₄ cathode material was synthesized by polyol method. Carbon layer of ca. 3 nm thick was coated on the LiCoPO₄ surfaces by chemical vapor deposition from methylbenzene. Crystalline structure, morphology and electrochemical performance of the sample were studied by XRD, SEM, TEM, CV and galvanostatic charge/discharge curve. The synthesized material via polyol method showed a pure phase of LiCoPO₄. The LiCoPO₄/C electrode delivered a high discharge capacity of 132 mAh·g^-1 and maintained 78% of the initial capacity after 50 cycles at 0.1C rate. The two-step extraction/insertion behavior of Li⁺ in …

Electrochemical Na-Storage Materials And Their Applications For Na-Ion Batteries, Jiang-Feng Qian, Xue-Ping Gao, Han-Xi Yang

Journal of Electrochemistry

Oncoming large scale electric energy storage (EES) requires battery systems not only to have sufficient storage capacity but also to be cost-effective and environmentally friendly. Li-ion batteries for widespread EES applications may be limited due to the constraint of global lithium resource. From the considerations of available resources and environmental impact, Na-ion batteries have potential advantages as next generation secondary batteries and an alternative to Li-ion batteries. However, in the present state of the art, the Na-storage cathodes reported so far are still deficient both in energy density and power capability, while the carbon and alloy anodes for Na-ion batteries …

Cmk-3/Sulfur Composite (CXSY) And Room-Temperature Na/S Battery, Qing Zhao, Yu-Xiang Hu, Kai Zhang, Li-Jiang Wang, Zhan-Liang Tao, Jun Chen

Journal of Electrochemistry

A series of ordered mesoporous carbon (CMK-3)/sulfur composite (C_xS_y) with different sulfur contents were synthesized via a melt-diffusion method. XRD, Raman, BET, SEM, and TEM techniques were used to characterize the structure and morphology of the as-prepared composite. The electrochemical performance of CMK-3/sulfur composite as the electrode of Na/S battery was tested at room temperature. Cyclic voltammograms show that one obvious reduction peak was located at about 1.61V, which is corresponding to the formation of Na₂S_x (x=2~5), while two oxidation peaks were displayed at about 1.82V and 1.95V, which are belonging to the …

Preparation Of The Particle Size Controllable Lifepo4/C And Its Electrochemical Profile Characterization, Ming-E Wang, Jing-Yuan Liu, Meng-Yan Hou, Yong-Yao Xia

Journal of Electrochemistry

We adopted an effective route to prepare the particle size controllable core-shell structure carbon-coated LiFePO₄ from different sized FePO₄ precursors, varying from 80 nm, 200 nm and 1 μm by an in situ polymerization method integrated with a surface modification technology. The discharge capacities of the three sized LiFePO₄/C are, respectively, 162 mAh·g^-1, 142 mAh·g^-1 and 92 mAh·g^-1 at 0.1C rate. The nano-sized LiFePO₄-a/C (80 nm) delivers a discharge capacity as large as 100 mAh·g^-1 even at 30C, while the macroscopic LiFePO₄-c/C (1 μm) exhibits a much …

Surface Composition Structure And Electrochemical Performance Of Aluminum Doped Lifepo4, Huai-Fang Shang, Wei-Feng Huang, Wang-Sheng Hu, Ding-Guo Xia, Zi-Yu Wu

Journal of Electrochemistry

Despite there are many successful reports about the preparation of electrode materials with surface coating for lithium ion batteries, the study in surface self-coating of cathode materials using segregation of doping elements and their electrochemical properties is still very rare. The LiFePO₄ particles with rich-Al on the surface were synthesized by one step solvothermal route. TEM results demonstrated that the surface of the obtained LiFePO₄ particles was well-covered by the amorphous coating. The soft X-ray absorption spectroscopy (XAS) and Auger electron spectroscopy (AES) component analyses revealed that the amorphous coating was composed of LiFe_1-xAl_xPO …

Effect Of Vanadium Substitution On Structure Of Li2Fesio4/C Composites, Yang Hong, Zhang Ying, Cheng Xuan

Journal of Electrochemistry

The carbon coated lithium iron silicate (Li₂FeSiO₄/C) composites were prepared using less expansive iron starting material of soluble ferric nitrate through sol-gel process and solid state reaction. The theoretically calculated amounts of 5, 10, 15, 20, 25, 30, and 50% of vanadium (V) were introduced using NH₄VO₃ to obtain V-substituted Li₂FeSiO₄/C composites. It was found that the pure Li₂FeSiO₄/C composite exhibited a good crystallinity with P2₁/n and nearly no impurities being detected, while the V-substituted Li₂FeSiO₄/C composites showed major …

Preparation And Electrochemical Properties Of Amorphous Znsno3/C By Hydrothermally Carbonization Method, Guo-Qing Fang, Rui-Xue Zhang, Wei-Wei Liu, Bing-Bo Xia, Hong-Dan Sun, Hai-Bo Wang, Jing-Jing Wu, Shinko Kaneko, De-Cheng Li

Journal of Electrochemistry

The amorphous ZnSnO₃@C composite was synthesized via a simple glucose hydrothermal and subsequent carbonization approach. The structure, morphology and electrochemical property of the composite were characterized by XRD, TEM and electrochemical measurements. Compared to bare ZnSnO₃, the ZnSnO₃/C composite exhibited markedly enhanced lithium storage property and cycle performance, delivering a reversible capacity of 659 mAh·g^-1 after 100 cycles at a current density of 100 mA·g^-1.

Synthesis And Electrochemical Property Of Li2Fesio4/C Cathode Material By Solid State Method, Jiao-Li Sun, Zhi-Jiao Chen, Yi-Xiao Li, Hu Cheng

Journal of Electrochemistry

Li₂FeSiO₄/C cathode material was synthesized using Li₂SiO₃ and FeC₂O₄ as raw materials by solid state method. The structure and morphology of the material were characterized by XRD and SEM. The electrochemical properties of the material were studied by constant-current cyclic testing. The results show that Li₂FeSiO₄/C has a good electrochemical performance. The first discharge capacity of Li₂FeSiO₄/C cathode material at 30oC reached 167 mAh∙g^-1 when cycled at 10 mA∙g^-1 between 1.5 and 4.8 V.

Aqueous Solution-Evaporation Route Synthesis And Phase Structural Research Of The Li-Rich Cathode Li1.23Ni0.09Co0.12Mn0.56O2 By In-Situ Xrd, Chong-Heng Shen, Shou-Yu Shen, Zhou Lin, Xiao-Mei Zheng, Hang Su, Ling Huang, Jun-Tao Li, Shi-Gang Sun

Journal of Electrochemistry

The Li-rich Li_1.23Ni_0.09Co_0.12Mn_0.56O₂ material was synthesized via aqueous solution-evaporation route. The structure and morphology of the material were characterized by means of XRD and SEM. The results indicated that the single particle of the product was polygonal with the size of 330 nm and the structure was layered solid solution with a certain amount of Li₂MnO₃. Electrochemical tests showed that the first discharge capacity of the Li-rich layered material was 250.8 mAh·g^-1 at 0.1C, the capacity retention was 86.5% after 40 cycles. Through in-situ XRD study …

Primary Care-Based Educational Interventions To Decrease Risk Factors For Metabolic Syndrome For Adults With Major Psychotic And/Or Affective Disorders: A Systematic Review, Cynthia Nover, Sarah S. Jackson

Epidemiology Faculty Publications

Background

Individuals with major psychotic and/or affective disorders are at increased risk for developing metabolic syndrome due to lifestyle- and treatment-related factors. Numerous pharmacological and non-pharmacological interventions have been tested in inpatient and outpatient mental health settings to decrease these risk factors. This review focuses on primary care-based non-pharmacological (educational or behavioral) interventions to decrease metabolic syndrome risk factors in adults with major psychotic and/or affective disorders.

Methods

The authors conducted database searches of PsychINFO, MEDLINE and the Cochrane Database of Systematic Reviews, as well as manual searches and gray literature searches to identify included studies.

Results

The authors were …

Amino Acid Region 1000–1008 Of Factor V Is A Dynamic Regulator For The Emergence Of Procoagulant Activity, Joesph R. Wiencek, Mahesheema Na, Jamila Hirbawi, Michael Kalafatis

Chemistry Faculty Publications

Single chain factor V (fV) circulates as an Mr 330,000 quiescent pro-cofactor. Removal of the B domain and generation of factor Va (fVa) are vital for procoagulant activity. We investigated the role of the basic amino acid region 1000-1008 within the B domain of fV by constructing a recombinant mutant fV molecule with all activation cleavage sites (Arg(709)/Arg(1018)/Arg(1545)) mutated to glutamine (fV(Q3)), a mutant fV molecule with region 1000-1008 deleted (fV(ΔB9)), and a mutant fV molecule containing the same deletion with activation cleavage sites changed to glutamine (fV(ΔB9/Q3)). The recombinant molecules along with wild type fV (fV(WT)) were transiently expressed …

Volatization Of Extraterrestrial Materials As Determined By Zinc Isotopic Analysis, Randal Christopher Paniello

All Theses and Dissertations (ETDs)

None

Timing And Spectroscopy Requirements For A Plastic Scintillating Fiber Bundle Time-Of-Flight Neutron Spectrometer, Paul A. Clement

Theses and Dissertations

The design parameters of a Time-of-Flight (TOF) neutron spectrometer composed of BCF-12 plastic scintillating fibers were investigated. A GEANT4 transport model was developed for analyzing the interaction of 2.5 MeV neutrons with a 14 x 14 BCF-12 fiber bundle. The bundle simulation demonstrated that 0.359% of all neutrons incident on the bundle will double scatter. The timing and data collection e efficiencies of a Tektronix DPO7104 series digital oscilloscope were examined to determine the signal processing requirements for future fiber bundle measurements. The minimum detectable neutron energy was computed by taking into account the bundle scintillation e efficiency, light collection …

Efficient And Long-Time Accurate Second-Order Methods For The Stokes-Darcy System, Wenbin Chen, Max Gunzburger, Dong Sun, Xiaoming Wan

Mathematics and Statistics Faculty Research & Creative Works

We propose and study two second order in time implicit-explicit methods for the coupled Stokes-Darcy system that governs flows in karst aquifers and other subsurface flow systems. the first method is a combination of a second-order backward differentiation formula and the second order Gear's extrapolation approach. the second is a combination of the second-order Adams-Moulton and second-order Adams-Bashforth methods. Both algorithms only require the solution of decoupled Stokes and Darcy problems at each time-step. Hence, these schemes are very efficient and can be easily implemented using legacy codes. We establish the unconditional and uniform in time stability for both schemes. …

Understanding Human Learning Using A Multiagent Based Unified Learning Model Simulation, Vlad T. Chiriacescu

School of Computing: Dissertations, Theses, and Student Research

Within cognitive science, computational modeling based on cognitive architectures has been an important approach to addressing questions of human cognition and learning. Modeling issues such as limited expressivity in representing knowledge and lack of appropriate selection of model structure represent a challenge for existing architectures. Furthermore, latest research shows that the concepts of long-term memory, motivation and working memory are critical cognitive aspects but a unifying cognitive paradigm integrating those concepts hasn’t been previously achieved.

Derived from a synthesis of neuroscience, cognitive science, psychology, and education, the Unified Learning Model (ULM) provides this integration by merging a statistical learning mechanism …

U.S. Drought Monitor, December 24, 2013, Matthew Rosencrans

United States Agricultural Commodities in Drought Archive

Drought map of U.S. for December 24, 2013 (12/24/13) plus: U.S. crop areas experiencing drought (map), Approximate percentage of crop located in drought, by state (bar graph), Percent of crop area located in drought, past 52 weeks (line graph) for: Hay, Cattle, Winter wheat.

Table Of Contents, Michele Harmon

Journal of the South Carolina Academy of Science

No abstract provided.

Multi-State Models For Natural History Of Disease, Amy Laird, Rebecca A. Hubbard, Lurdes Y. T. Inoue

UW Biostatistics Working Paper Series

Longitudinal studies are a useful tool for investigating the course of chronic diseases. Many chronic diseases can be characterized by a set of health states. We can improve our understanding of the natural history of the disease by modeling the sequence of visited health states and the duration in each state. However, in most applications, subjects are observed only intermittently. This observation scheme creates a major modeling challenge: the transition times are not known exactly, and in some cases the path through the health states is not known.

In this manuscript we review existing approaches for modeling multi-state longitudinal data. …

A Search For Enhanced Very High Energy Gamma-Ray Emission From The 2013 March Crab Nebula Flare, P. T. Reynolds, Et Al

Physical Sciences Publications

In 2013 March, a flaring episode from the Crab Nebula lasting ~2 weeks was detected by Fermi-LAT (Large Area Telescope on board the Fermi Gamma-ray Space Telescope). The Very Energetic Radiation Imaging Telescope Array System (VERITAS) provides simultaneous observations throughout this period. During the flare, Fermi-LAT detected a 20 fold increase in flux above the average synchrotron flux >100 MeV seen from the Crab Nebula. Simultaneous measurements with VERITAS are consistent with the non-variable long-term average Crab Nebula flux at TeV energies. Assuming a linear correlation between the very high energy flux change >1 TeV and the flux …

Determining The 7li(N,Gamma) Cross Section Via Coulomb Dissociation Of 8li, R. Izsak, A. Horvath, A. Kiss, Z. Seres, A. Galonsky, C. A. Bertulani, Zs Fueloep, T. Baumann, D. Bazin, K. Ieki, C. Bordeanu, N. Carlin, M. Csanád, F. Deák, Paul A. Deyoung, N. Frank, T. Fukuchi, A. Gade, D. Galaviz, C. R. Hoffman, W. A. Peters, H. Schelin, M. Thoennessen, G. I. Veres

Faculty Publications

The applicability of Coulomb dissociation reactions to determine the cross section for the inverse neutron capture reaction was explored using the reaction Li-8(gamma,n)Li-7. A 69.5 MeV/nucleon Li-8 beam was incident on a Pb target, and the outgoing neutron and Li-7 nucleus were measured in coincidence. The deduced (n,gamma) excitation function is consistent with data for the direct capture reaction Li-7(n,gamma) Li-8 and with low-energy effective field theory calculations.

C4a-Hydroperoxyflavin Formation In N -Hydroxylating Flavin Monooxygenases Is Mediated By The 2′-Oh Of The Nicotinamide Ribose Of Nadp⁺, Reeder Robinson, Somayesadat Badieyan, Pablo Sobrado

Chemistry Faculty Research & Creative Works

Flavin-dependent monooxygenases must stabilize a C4a-hydroperoxyflavin intermediate to hydroxylate their respective substrates. Formation and decay of the C4a-hydroperoxyflavin were monitored under rapid reaction kinetic conditions in SidA, an N-hydroxylating monooxygenase involved in siderophore biosynthesis. Solvent kinetic isotope effect studies of flavin oxidation indicate that both hydrogen peroxide elimination and water elimination occur via abstraction of hydrogen from the N5 of the flavin. Kinetic isotope effect and density functional theory results are consistent with the transfer of a proton from the 2′-OH of the nicotinamide ribose of nicotinamide adenine dinucleotide phosphate (NADP+) to the C4a-peroxyflavin to form the C4a-hydroperoxyflavin. This represents …

Students' Perceived Utility Of Precision Taught Calculus, Rebecca-Anne Dibbs, David Glassmeyer, Wafa Yacoub

Faculty Articles

The last decade of calculus research has showed students learn best when lecture is supplemented with thoughtful use of technology and group work; however, educators are given little direction of how they are to balance the already full first semester calculus class. Precision teaching is an instructional model that employs formative assessment to provide information on what topics are understood by students as well as indicate troublesome concepts. With this information, the instructor can adjust class time accordingly by incorporating supplemental activities most beneficial to students. The purpose of this interview study was to explore the perceived utility of precision …

Long Term Observations Of B2 1215+30 With Veritas, E. Aliu, S. Archambault, T. Arlen, T. Aune, M. Beilicke, W. Benbow, R. Bird, A. Bouvier, J. H. Buckley, V. Bugaev, A. Cesarini, L. Ciupik, M. P. Connolly, W. Cui, J. Dumm, M. Errando, A. Falcone, S. Federici, Q. Feng, J. P. Finley, P. Fortin, L. Fortson, A. Furniss, N. Galante, L. Gerard, G. H. Gillanders, S. Griffin, J. Grube, G. Gyuk, D. Hanna, J. Holder, G. Hughes, T. B. Humensky, P. Kaaret, M. Kertzman, Y. Khassen, D. Kieda, H. Krawczynski, F. Krennrich, M. J. Lang, A. S. Madhavan, G. Maier, P. Majumdar, S. Mcarthur, A. Mccann, P. Moriarty, R. Mukherjee, D. Nieto, A. O’Faolain De Bhroithe, P. T. Reynolds, Et Al

Physical Sciences Publications

We report on VERITAS observations of the BL Lac object B2 1215+30 between 2008 and 2012. During this period, the source was detected at very high energies (VHEs; E > 100 GeV) by VERITAS with a significance of 8.9σ and showed clear variability on timescales larger than months. In 2011, the source was found to be in a relatively bright state and a power-law fit to the differential photon spectrum yields a spectral index of 3.6 ± 0.4stat ± 0.3syst with an integral flux above 200 GeV of (8.0 ± 0.9stat ± 3.2syst) × 10−12 cm−2 s−1. No short term variability …

Categorization Of Large Corpora Of Malicious Software, Deekshit Kura

LSU New Orleans Theses and Dissertations

Malware is computer software written by someone with mischievous or, more usually, malicious and/or criminal intent and specifically designed to damage data, hosts or networks. The variety of malware is increasing proportionally with the increase in computers and we are not aware of newly emerging malware. Tools are needed to categorize families of malware, so that analysts can compare new malware samples to ones that have been previously analyzed and determine steps to detect and prevent malware infections.

In this thesis, I developed a technique to catalog and characterize the behavior of malware, so that malware families, the level of …

High Resolution X-Ray Diffraction Analysis Of Cb1 Receptor Antagonists As A Means To Explore Binding Affinity, Steven P. Fournet

LSU New Orleans Theses and Dissertations

Abstract

Charge density studies have been conducted on ten CB₁ cannabinoid receptor antagonists via high resolution x-ray crystallography. Bond critical point values and various other properties derived from these studies including the electrostatic potential were analyzed in correlation to the affinity of each compound with the CB₁ receptor. Correlation/anti-correlation was found between several properties and K_i. The data was also interpreted by principal component analysis with three principal components accounting for 85% of the data variation. Data mining was limit due to the low sample count and the requirements set for the inclusion of correlated/anti-correlated variables …

Synthesis Of Novel Azetidines, Amber Thaxton

LSU New Orleans Theses and Dissertations

Azetidine is a four-membered nitrogen-containing heterocyclic ring that has recently received a great deal of attention as a molecular scaffold for the design and preparation of biologically active compounds. Structure-activity studies employing functionalized azetidines have led to the development of variety of drug molecules and clinical candidates encompassing a broad spectrum of biological activities.

Herein, the synthesis a novel series of 3-aryl-3-arylmethoxyazetidines is described. Selected 3-aryl-3-arylmethoxyazetidines were evaluated for their binding affinity to multiple monoaminergic transporters for the potential treatment of methamphetamine addiction. It was discovered that this scaffold exhibits high binding affinity (nM) for both the serotonin and dopamine …

A Study On The Integration Of A Novel Absorption Chiller Into A Microscale Combined Cooling, Heating, And Power (Micro-Cchp) System, Scott J. Richard

LSU New Orleans Theses and Dissertations

This study explores the application of micro-CCHP systems that utilize a 30 kW gas microturbine and an absorption chiller. Engineering Equation Solver (EES) is used to model a novel single-effect and double-effect water-lithium bromide absorption chiller that integrates the heat recovery unit and cooling tower of a conventional CCHP system into the chiller’s design, reducing the cost and footprint of the system. The results of the EES model are used to perform heat and material balances for the micro-CCHP systems employing the novel integrated chillers, and energy budgets for these systems are developed. While the thermal performance of existing CCHP …

4d Evolution Of Fluvial System And Channel-Fill Architecture Of The Cretaceous Blackhawk Formation, Wasatch Plateau, Utah: An Integrated Fluvial Rock Record Analysis, Hiranya Sahoo

LSU New Orleans Theses and Dissertations

Using an integrated dataset comprising outcrop, core, GPR and LiDAR data, this study targets a high-quality outcrop "window" of the upper Cretaceous Blackhawk Formation in the eastern Wasatch Plateau in central Utah, spanning a fairly large spatial (~30 km² area comprising eight contiguous, and vertical cliff faces) and temporal (~4 my) range. This research provides field-validation and -calibration of a wider range of fluvial heterogeneity: 1) large-scale heterogeneity (10’s of m vertically and 100’s of m laterally), 2) intermediate-scale heterogeneity (1’s of m vertically and 10’s of m laterally), and 3) small-scale heterogeneity (10’s of cm vertically and 1’s …

Wave Transformation At A Saltmarsh Edge And Resulting Marsh Edge Erosion: Observations And Modeling, Kevin J. Trosclair

LSU New Orleans Theses and Dissertations

This study examines wind generated waves during winter storms, their transformation/attenuation near the marsh edge, and the resulting saltmarsh edge erosion. A simple numerical model for wave generation, transmission and marsh edge erosion was developed and validated against observations from Lake Borgne, Louisiana. Results suggest that meteorological conditions modify the local water depth via wind or wave setup and atmospheric pressure, thus exerting a first order control on the location of wave attack, which in turn determines the type of wave forces (shear vs. impact) that dominate the erosion process. Scarp failure follows, at a location determined by water level, …