Physical Sciences and Mathematics Commons^™

Timing And Spectroscopy Requirements For A Plastic Scintillating Fiber Bundle Time-Of-Flight Neutron Spectrometer, Paul A. Clement

Theses and Dissertations

The design parameters of a Time-of-Flight (TOF) neutron spectrometer composed of BCF-12 plastic scintillating fibers were investigated. A GEANT4 transport model was developed for analyzing the interaction of 2.5 MeV neutrons with a 14 x 14 BCF-12 fiber bundle. The bundle simulation demonstrated that 0.359% of all neutrons incident on the bundle will double scatter. The timing and data collection e efficiencies of a Tektronix DPO7104 series digital oscilloscope were examined to determine the signal processing requirements for future fiber bundle measurements. The minimum detectable neutron energy was computed by taking into account the bundle scintillation e efficiency, light collection …

Counting Threshold Graphs And Finding Inertia Sets, Christopher Abraham Guzman

Theses and Dissertations

This thesis is separated into two parts: threshold graphs and inertia sets. First we present an algorithmic approach to finding the minimum rank of threshold graphs and then progress to counting the number of threshold graphs with a specific minimum rank. Second, we find an algorithmic and more automated way of determining the inertia set of graphs with seven or fewer vertices using theorems and lemmata found in previous papers. Inertia sets are a relaxation of the inverse eigenvalue problem. Instead of determining all the possible eigenvalues that can be obtained by matrices with a specific zero/nonzero pattern we restrict …

Synthesis, Structural Variations And Trends In The Properties Of Unique Dinuclear And Polynuclear Complexes Of Bis(Pyrazolyl)Methane Ligands In Solid State And Solution, Andrea Eva Pascui

Theses and Dissertations

The semi-rigid ligands, p-[CH(pz)₂]₂C₆H₄, L_p, m-[CH(pz)₂]₂C₆H₂, L_m, and m-[CH(3,5-Me₂pz)₂]₂C₆H₄, L_m* (pz = pyrazolyl ring), link two bis(pyrazolyl)methane units into a single molecule by a rigid phenylene spacer and are used to study the structural variations and magnetic interactions in self-assembled first row, divalent transition metal complexes in polymeric, dinuclear and dinuclear metallacyclic settings. The formation of these architectures highly depend on the geometry of these ligands: anti, the …

Real Time Monitoring Of Surface Chemical Events By Streaming Potentials In Microfluidic Channels, Kenji Nokura

Theses and Dissertations

Zeta potential is one of the tools to measure the surface charge of materials, and Alvarez et al. have developed a microchannel device to measure zeta potentials in real time for label-free sensing using immobilized receptors on microchannel surfaces. However, the challenge has been the charge interference of surface modifiers on analyte detection. Therefore, it was necessary to find the best strategy to regenerate minimal surface charge after modifying the channel with polymer films that would anchor the affinity groups for the analyte. It was demonstrated that adsorption of positively and negatively charged analytes were monitored via real time zeta …

Synthesis, Characterization, And Application Of High Surface Area, Mesoporous, Stabilized Anatase Tio2 Catalyst Supports, Rebecca Elizabeth Olsen

Theses and Dissertations

Nanomaterials have attracted substantial attention in the area of catalysis due to the unique properties they exhibit such as high surface areas, intricate pore networks and unique morphologies. TiO2 has attracted attention as a catalyst since the discovery of its high photocatalytic activity by Fuishima and Honda in 1972. Given its high thermal stability, low cost, low environmental impact, and versatility, TiO2 is a widely used commercial catalyst and catalyst support. TiO2 is used in many applications such as photocatalysis is also an excellent support material for noble metals in a number of oxidative synthesis and pollution-control reactions. Though TiO2 …

Geology Of The Birdseye 7.5-Minute Quadrangle, Utah County, Utah:Â Implications For Mid-Cenozoic Extension And Deposition Of The Moroni Formation, Don L. Bagshaw

Theses and Dissertations

Geologic structures within the Birdseye 7.5 minute quadrangle Utah County, Utah have been related by previous workers to both the Jurassic Arapien Shale diapirism and to the mid-Cenozoic extensional collapse of the Charleston-Nebo Thrust. Whichever model proves valid, it will have implications for oil exploration and interpretation of the subsurface geologic structure in the region. A detailed map of the quadrangle was constructed to better constrain which mechanism was responsible for the deformation. Exposures of Arapien Shale near, and within the Birdseye quadrangle show no evidence of diapiric movement. Arapien involvement in the deformation of Tertiary rocks in the center …

Development And Validation Of An Automated Directivity Acquisition System Used In The Acquisition, Processing, And Presentation Of The Acoustic Far-Field Directivity Of Musical Instruments In An Anechoic Space, Nicholas J. Eyring

Theses and Dissertations

A high spatial resolution acoustic directivity acquisition system (ADAS) has been developed to acquire anechoic measurements of the far field radiation of musical instruments that are either remote controlled or played by musicians. Building upon work performed by the BYU Acoustic Research Group in the characterization of loudspeaker directivity, one can rotate a musical instrument with sequential azimuthal angle increments under a fixed semicircular array of microphones while recording repeated notes or sequences of notes. This results in highly detailed and instructive directivity data presented in the form of high-resolution balloon plots. The directivity data and corresponding balloon plots may …

Nonlinear Spectroscopic Investigation Of Adsorption To C-18 Model Stationary Phase, Anthony D. Peterson

Theses and Dissertations

Reversed-phase liquid chromatography (RPLC) is a commonly used separation technique in chemistry. Nevertheless, the mechanistic interactions at the molecular level among the eluent, analyte, and the stationary phase are not fully understood. Because of this limited understanding, optimization of the separation must be done experimentally. Learning more about molecular interactions should aid in improving separations. We are currently using second-harmonic generation (SHG) spectroscopy to investigate how analytes adsorb to the surface. SHG is a spectroscopic technique that produces signal only at places of non-isotropic symmetry; this typically occurs at surfaces. SHG can be used to produce surface isotherms of test …

Record Linkage, Stasha Ann Bown Larsen

Theses and Dissertations

This document explains the use of different metrics involved with record linkage. There are two forms of record linkage: deterministic and probabilistic. We will focus on probabilistic record linkage used in merging and updating two databases. Record pairs will be compared using character-based and phonetic-based similarity metrics to determine at what level they match. Performance measures are then calculated and Receiver Operating Characteristic (ROC) curves are formed. Finally, an economic model is applied that returns the optimal tolerance level two databases should use to determine a record pair match in order to maximize profit.

Accelerating Computational Algorithms, Michael Risley

Theses and Dissertations

Mathematicians and computational scientists are often limited in their ability to model complex phenomena by the time it takes to run simulations. This thesis will inform interested researchers on how the development of highly parallel computer graphics hardware and the compiler frameworks to exploit it are expanding the range of algorithms that can be explored on affordable commodity hardware. We will discuss the complexities that have prevented researchers from exploiting advanced hardware as well as the obstacles that remain for the non-computer scientist.

Synthesis, Characterization, And Functionalization Of Magnetic Iron Nanoparticles For Enhanced Biological Applications, Christopher Warren

Theses and Dissertations

The transition metal ferrites of composition MFe2O4 where M is Fe, Co, or Ni are well established materials for various biological applications due to their interesting magnetic properties. Their elemental and stochiometric composition can be easily manipulated which allows further tuning of their ferrimagnetic properties. By changing the identity of M and by changing the crystallite size of the ferrites, nanocrystals with diverse magnetic properties can be systematically produced. Furthermore, ferrites are more stable in diverse chemical environments, as compared to metallic nanoparticles, which make ferrites particularly useful for a broad range of biomedical applications, especially in the field of …

Analysis Of Mathematical Models Of The Human Lung, Cooper Racheal

Theses and Dissertations

The processes of lung ventilation and perfusion, diffusion, and gas transport make up the system of breathing and tissue oxygenation. Here, we present several mathematical formulations of the essential processes that contribute to breathing. These models aid in our understanding and analysis of this complex system and can be used to form treatments for patients on ventilators. With the right analysis and treatment options, patients can be helped and money can be saved. We conclude with the formulation of a mathematical model for the exchange of gasses in the body based on basic reaction kinetics.

Multi-Column Multi-Layer Computational Model Of Neocortex, Beata Strack

Theses and Dissertations

We present a multi-layer multi-column computational model of neocortex that is built based on the activity and connections of known neuronal cell types and includes activity-dependent short term plasticity. This model, a network of spiking neurons, is validated by showing that it exhibits activity close to biology in terms of several characteristics: (1) proper laminar flow of activity; (2) columnar organization with focality of inputs; (3) low-threshold-spiking (LTS) and fast-spiking (FS) neurons function as observed in normal cortical circuits; and (4) different stages of epileptiform activity can be obtained with either increasing the level of inhibitory blockade, or simulation of …

Digital Outcrop Model And Paleoecology Of The Eight-Foot Rapid Algal Field (Middle Pennsylvanian Lower Ismay Sequence), Paradox Basin, Utah, Colton Lynn Goodrich

Theses and Dissertations

Although phylloid algal mounds have been studied for 50 year, much remains to be determined concerning the ecology and sedimentology of these Late Paleozoic carbonate buildups. Herein we perform a digital outcrop study of the well-known Middle Pennsylvanian Lower Ismay mound interval in the Paradox Basin because outcropping mounds along the San Juan River are cited as outcrop analogs of reservoir carbonates in the Paradox Basin oil province of Utah and adjacent states. The principal field area is the Eight Foot algal field located at river mile 19.2 on the San Juan River, approximately 14 miles SSW of Bluff, Utah. …

Minimum Rank Problems For Cographs, Nicole Andrea Malloy

Theses and Dissertations

Let G be a simple graph on n vertices, and let S(G) be the class of all real-valued symmetric nxn matrices whose nonzero off-diagonal entries occur in exactly the positions corresponding to the edges of G. The smallest rank achieved by a matrix in S(G) is called the minimum rank of G, denoted mr(G). The maximum nullity achieved by a matrix in S(G) is denoted M(G). For each graph G, there is an associated minimum rank class, MR(G) consisting of all matrices A in S(G) with rank A = mr(G). Although no restrictions are applied to the diagonal entries of …

Optimization And Spatial Queueing Models To Support Multi-Server Dispatching Policies With Multiple Servers Per Station, Sardar Ansari

Theses and Dissertations

In this thesis, we propose novel optimization and spatial queueing models that expand the currently existing methods by allowing multiple servers to be located at the same station and multiple servers to be dispatched to a single call. In particular, a mixed integer linear programming (MILP) model is introduced that determines how to locate and dispatch ambulances such that the coverage level is maximized. The model allows multiple servers to be located at the same station and balances the workload among them while maintaining contiguous first priority response districts. We also propose an extension to the approximate Hypercube queueing model …

The Design And Synthesis Of Magnetic Nanocomposites, Daniel Hudgins

Theses and Dissertations

Magnetism lies at the core of modern technology and can be found in industries such as oil refining, automotive, telecommunications, personal electronics, and power generation that are integral to our day to day lives. This permeation into everyday life has been enhanced in the past several decades with improvements in material design based upon the principles of nanotechnology leading to smaller, faster, and more efficient devices. The presented research will discuss the synthesis and processing of multiple magnetic nanoparticle structures designed for the enhancement of various, application specific, properties. In the first experiments a tunable core/shell structure was developed with …

Zinc Environment In Proteins: The Flexible And Reactive Core Of Hiv-1 Ncp7 And The Inhibitory Site Of Caspase-3, A. Gerard Daniel

Theses and Dissertations

Zinc is an essential cofactor of several proteins. The roles of zinc in these proteins are classified as catalytic, structural or regulatory. Zinc present in structural sites is considered to be a chemically inert, static structural element. On the contrary, previous studies on a C2H2 type zinc finger model compound and the C3H type HIV-1 NCp7 C-terminal zinc knuckle have shown that zinc at these sites can undergo coordination sphere expansion under the influence of a Pt based electrophile. The pentacoordination observed around zinc in these experiments raises an important question: are the structural zinc motifs found in the proteins …

Formation And Analysis Of Zinc Oxide Nanoparticles And Zinc Oxide Hexagonal Prisms And Optical Analysis Of Cadmium Selenide Nanoparticles, Jared M. Hancock

Theses and Dissertations

In this dissertation, methods to synthesize ZnO are reported. First, zinc oxide nanoparticles were synthesized with small amounts of transition metal ions to create materials called dilute magnetic semiconductors (DMS). We employed a low temperature sol-gel method that produces ZnO nanoparticles of reproducible size and incorporates cobalt, nickel, and manganese ions into the nanoparticles. Conditions were controlled such that a range of amounts of Co, Ni, and Mn were incorporated. The incorporation was tracked by color changes in the white ZnO powder to blue for Co, green for Ni and yellow for Mn. XRD measurements showed the nanoparticles were on …

Data Mining Revision Controlled Document History Metadata For Automatic Classification, Dustin Maass

Theses and Dissertations

Version controlled documents provide a complete history of the changes to the document, including everything from what was changed to who made the change and much more. Through the use of cluster analysis and several sets of manipulated data, this research examines the revision history of Wikipedia in an attempt to find language-independent patterns that could assist in automatic page classification software. Utilizing two sample data sets and applying the aforementioned cluster analysis, no conclusive evidence was found that would indicate that such patterns exist. Our work on the software, however, does provide a foundation for more possible types of …

Structure And Function Of Proteins Investigated By Crystallographic And Spectroscopic Time-Resolved Methods, Namrta Purwar

Theses and Dissertations

Biomolecules play an essential role in performing the necessary functions for life. The goal of this thesis is to contribute to an understanding of how biological systems work on the molecular level. We used two biological systems, beef liver catalase (BLC) and photoactive yellow protein (PYP). BLC is a metalloprotein that protects living cells from the harmful effects of reactive oxygen species by converting H2O2 into water and oxygen. By binding nitric oxide (NO) to the catalase, a complex was generated that mimics the Cat-H2O2 adduct, a crucial intermediate in the reaction promoted by the catalase. The Cat-NO complex is …

Wind Turbine Controls For Farm And Offshore Operation, Zhongzhou Yang

Theses and Dissertations

Development of advanced control techniques is a critical measure for reducing the cost of energy for wind power generation, in terms of both enhancing energy capture and reducing fatigue load. There are two remarkable trends for wind energy. First, more and more large wind farms are developed in order to reduce the unit-power cost in installation, operation, maintenance and transmission. Second, offshore wind energy has received significant attention when the scarcity of land resource has appeared to be a major bottleneck for next level of wind penetration, especially for Europe and Asia. This dissertation study investigates on several wind turbine …

Deformation And Fluid Interactions In The Mineral Fork Diamictites, Antelope Island, Utah, Kimberly Rose Johnson

Theses and Dissertations

ABSTRACT

DEFORMATION AND FLUID INTERACTIONS IN THE MINERAL FORK DIAMICTITES,

ANTELOPE ISLAND, UTAH

by

Kimberly R. Johnson

The University of Wisconsin-Milwaukee, 2013

Under the Supervision of Professor Dyanna Czeck

Diamictite from the Mineral Fork Formation on Antelope Island, Utah was deformed to various degrees on the footwall of the Willard Thrust Fault during the Sevier Orogeny. The diamictite contains clasts of differing strength resulting in quartzite clasts deformed the least, pink granitic clasts deformed to a greater degree, and softer green gneissic clasts deformed the most. The pink granitic and green gneissic clasts have similar compositions, but deform differently. This …

Transcending Microbial Source Tracking Techniques Across Geographic Borders: An Examination Of Human And Animal Microbiomes And The Integration Of Molecular Approaches In Pathogen Surveillance In Brazil And The United States, Amber Mae Koskey

Theses and Dissertations

Waterborne illnesses, attributed to the ingestion or contact with contaminated water, present a significant global health concern. Surface water sources can be impacted by wide array of pollution inputs, but fecal pollution generates the most significant and acute threat to human health. Therefore, the detection of fecal bacteria in surface water sources remains an important public health objective. Current surface water monitoring employs the use of fecal indicator bacteria (FIB) including E. coli and enterococci as proxies for pathogenic organisms carried in fecal pollution. These traditional indicators, detected by culture-based microbiological methods, do not discriminate fecal sources from another. New …

Extracting The Structure And Conformations Of Biological Entities From Large Datasets, Ali Dashti

Theses and Dissertations

In biology, structure determines function, which often proceeds via changes in conformation. Efficient means for determining structure exist, but mapping conformations continue to present a serious challenge. Single-particles approaches, such as cryogenic electron microscopy (cryo-EM) and emerging "diffract & destroy" X-ray techniques are, in principle, ideally positioned to overcome these challenges. But the algorithmic ability to extract information from large heterogeneous datasets consisting of "unsorted" snapshots - each emanating from an unknown orientation of an object in an unknown conformation - remains elusive.

It is the objective of this thesis to describe and validate a powerful suite of manifold-based algorithms …

Aplikimi I Cms Për Krijimin E Portal: Përdorimi I Dotnetnuke Për Ndërtimin E Portal Dhe Website, Mentor Qorri

Theses and Dissertations

Në dekadën e fundit popullariteti në rritjen e World Wide Web ka çuar në një rritje eksponenciale të numrit të faqeve dhe portaleve që janë në dispozicion në Web. Ky numër kaq i madh i Web faqeve dhe portaleve e bën më se të vështirë për shfrytëzuesit e Internetit gjetjen e informacionit të nevojshëm. E tëra kjo është si pasojë e mos aplikimit të disa fazave të caktuara në zhvillimin e Web aplikacioneve, por edhe të aplikacioneve në përgjithësi. E tëra kjo është si përgjigje, ndaj zhvillimit të hershëm kaotik të Web sajteve te ndryshme dhe të aplikacioneve në përgjithësi, …

A Two-Echelon Location-Inventory Model For A Multi-Product Donation-Demand Driven Industry, Milad Khajehnezhad

Theses and Dissertations

This study involves a joint bi-echelon location inventory model for a donation-demand driven industry in which Distribution Centers (DC) and retailers (R) exist. In this model, we confine the variables of interest to include; coverage radius, service level, and multiple products. Each retailer has two classes of product flowing to and from its assigned DC i.e. surpluses and deliveries. The proposed model determines the number of DCs, DC locations, and assignments of retailers to those DCs so that the total annual cost including: facility location costs, transportation costs, and inventory costs are minimized. Due to the complexity of problem, the …

Evaluation Of Vdr-Coactivator Inhibitors Using Biochemical And Cell-Based Assays, Athena Marie Baranowski

Theses and Dissertations

ABSTRACT

EVALUATION OF VDR–COACTIVATOR INHIBITORS USING BIOCHEMICAL AND CELL–BASED ASSAYS

by

Athena Baranowski

The University of Wisconsin–Milwaukee, 2013

Under the Supervision of Dr. Alexander Arnold

The vitamin D receptor (VDR) is a ligand–dependent transcription factor, which belongs to the nuclear receptor superfamily. VDR–mediated gene regulation is governed by coregulators (coactivators and corepressors). VDR coregulator binding inhibitors (CBIs), which were discovered using high throughput screening (HTS), were evaluated using cell–based assays and biochemical assays to determine their ability to inhibit the interaction between VDR and steroid receptor coactivator–2 (SRC–2). Determining their ability to inhibit the VDR–SRC–2 interaction can lead to the …

Examining Spring And Autumn Phenology In A Temperate Deciduous Urban Woodlot, Rong Yu

Theses and Dissertations

This dissertation is an intensive phenological study in a temperate deciduous urban woodlot over six consecutive years (2007-2012). It explores three important topics related to spring and autumn phenology, as well as ground and remote sensing phenology. First, it examines key climatic factors influencing spring and autumn phenology by conducting phenological observations four days a week and recording daily microclimate measurements. Second, it investigates the differences in phenological responses between an urban woodlot and a rural forest by employing comparative basswood phenological data. Finally, it bridges ground visual phenology and remote sensing derived phenological changes by using the Normalized Difference …

Sediment Microbial Fuel Cell As Sustainable Power Resource, Ananta Kothapalli

Theses and Dissertations

This research demonstrates that Ceratophyllum demersum a root less non vascular aquatic plant has negatively affected the power generation from a Sediment Microbial Fuel cell (SMFC). In SMFC the reduced organic matter in the sediment in water produces electrons, which reduces oxygen. Whereas in Plant SMFC continuous supply of organic matter to the anode is done by rhizodeposition (root exudates). Six SMFCs were run for more than 3 months to see the effect of plants, pH and temperature on power generation. Out of six only two SMFC showed stable data. The maximum power density 18 ± 1mW/m3 was generated from …