Physical Sciences and Mathematics Commons^™

Synthesis And Characterization Of A New Cyano-Substituted Tris(Pyrazolyl)Borate And Its Thallium(I) Complex, Bozumeh Som

Electronic Theses and Dissertations

A new cyanoscorpionate - tris(4-cyano-3,5-diphenylpyrazolyl)borate (Tp^Ph2,4CN) has been synthesized and characterized. The thallium complex of this ligand TlTp^Ph2,4CN has also been prepared and characterized by FT-IR, ¹H NMR, and single-crystal X-ray-diffraction. The complex TlTp^Ph2,4CN crystalized in the monoclinic space group C2/c with unit cell a = 14.6697(10) Å, b = 13.9493(10) Å, c = 19.3347(12) Å, and b= 91.761(2)°. Structural comparison of TlTp^Ph2,4CN with analogous complexes demonstrated the effects of both steric and electron-withdrawing substituents on coordination geometry and the electronic properties of the metal ion. There were short contacts between the cyano groups …

Synthesis And Characterization Of 2,2-Cis-[Rh2(Nphcoch3)4]•Ncc6h4r Where R = H, 2-Ch3, 3-Ch3, 4-Ch3 And [Rh2(O2cch3)(Nphcocf3)3], Fredricka F. Quarshie

Electronic Theses and Dissertations

Five novel compounds were synthesized and characterized. Crystal structures were determined using Rigaku Mercury 375/MCCD(XtaLAB mini) diffractometer with graphite monochromated MoKα radiation. The crystal structures of [Rh₂(NPhCOCH₃)₄•xNCC₆H₄R where x = 1 or 2 and R=H, 2-CH₃,3-CH₃ and 4-CH₃ were solved to an R₁ value of less than 5 (R₁= Σ||F_o| - |F_c|| / Σ |F_o|). In each of the nitrile complexes, the rhodium is five or six coordinate and possesses pseudo D_4h symmetry. The complexes were …

Extremal Results For Peg Solitaire On Graphs, Aaron D. Gray

Electronic Theses and Dissertations

In a 2011 paper by Beeler and Hoilman, the game of peg solitaire is generalized to arbitrary boards. These boards are treated as graphs in the combinatorial sense. An open problem from that paper is to determine the minimum number of edges necessary for a graph with a fixed number of vertices to be solvable. This thesis provides new bounds on this number. It also provides necessary and sufficient conditions for two families of graphs to be solvable, along with criticality results, and the maximum number of pegs that can be left in each of the two graph families.

Co2 Capture On Porous Adsorbents Containing Surface Amino Groups, Odette Amana Esam

Electronic Theses and Dissertations

The potential impact of carbon dioxide as a major source of global warming has led to extensive research in order to mitigate the greenhouse effect. In this work, four adsorbents were synthesized and studied. The adsorbents were obtained by grafting and sol-gel of amino-containing molecules such as bis[3-(trimethoxysilyl)propyl]amine as monoamine and [3-(2-aminoethylamino)propyl]- trimethoxysilane as diamine on the surface of silica gel. CO2 passed through adsorbents at room temperature for its capture, then desorbed at moderate heating, and stored in the form of insoluble BaCO3. The adsorbent synthesized by sol-gel synthesis was found to be more efficient due to its high …

A Model Study Of The Copper River Plume And Its Effects On The Northern Gulf Of Alaska, Yuan Wang

Electronic Theses and Dissertations

Using a three-level nested Regional Ocean Modeling System coupled with the Carbon, Silicate, Nitrogen Ecosystem model, this study examined the seasonal evolution of the Copper River (CR) plume and how it influences the along- and across-shore transport in the northern Gulf of Alaska (NGoA). A passive tracer was introduced in the model to delineate the growth and decay of the plume and to diagnose the spread of the CR discharge in the shelf, into Prince William Sound (PWS) and offshore. Furthermore, a model experiment with doubled discharge was conducted to investigate potential impacts of accelerated glacier melt in future climate …

Developing An Acoustic Method For Reducing North Atlantic Right Whale (Eubalaena Glacialis) Ship Strike Mortality Along The United States Eastern Seaboard, Kaitlyn Allen Mullen

Electronic Theses and Dissertations

North Atlantic right whales (Eubalaena glacialis) are among the world’s most endangered cetaceans. Although protected from commercial whaling since 1949, North Atlantic right whales exhibit little to no population growth. Ship strike mortality is the leading known cause of North Atlantic right whale mortality. North Atlantic right whales exhibit developed auditory systems, and vocalize in the frequency range that dominates ship acoustic signatures. With no behavioral audiogram published, current literature assumes these whales should be able to acoustically detect signals in the same frequencies they vocalize. Recorded ship acoustic signatures occur at intensities that are similar or higher to those …

Identifying Productive Resources In Secondary School Students' Discourse About Energy, Benedikt Walter Harrer

Electronic Theses and Dissertations

A growing program of research in science education acknowledges the beginnings of disciplinary reasoning in students’ ideas and seeks to inform instruction that responds productively to these disciplinary progenitors in the moment to foster their development into sophisticated scientific practice. This dissertation examines secondary school students’ ideas about energy for progenitors of disciplinary knowledge and practice. Previously, researchers argued that students’ ideas about energy were constrained by stable and coherent conceptual structures that conflicted with an assumed unified scientific conception and therefore needed to be replaced. These researchers did not attend to the productive elements in students’ ideas about energy. …

Contextual Analysis Of Large-Scale Biomedical Associations For The Elucidation And Prioritization Of Genes And Their Roles In Complex Disease, Jeremy J. Jay

Electronic Theses and Dissertations

Vast amounts of biomedical associations are easily accessible in public resources, spanning gene-disease associations, tissue-specific gene expression, gene function and pathway annotations, and many other data types. Despite this mass of data, information most relevant to the study of a particular disease remains loosely coupled and difficult to incorporate into ongoing research. Current public databases are difficult to navigate and do not interoperate well due to the plethora of interfaces and varying biomedical concept identifiers used. Because no coherent display of data within a specific problem domain is available, finding the latent relationships associated with a disease of interest is …

Physical Security Assessment Of A Regional University Computer Network, Nathan H. Timbs

Electronic Theses and Dissertations

Assessing a network's physical security is an essential step in securing its data. This document describes the design, implementation, and validation of PSATool, a prototype application for assessing the physical security of a network's intermediate distribution frames, or IDFs (a.k.a. "wiring closets"). PSATool was created to address a lack of tools for IDF assessment. It implements a checklist-based protocol for assessing compliance with 52 security requirements compiled from federal and international standards. This checklist can be extended according to organizational needs.

PSATool was validated by using it to assess physical security at 135 IDFs at East Tennessee State University. …

Long-Term Recovery Of South Indian Creek Following Interstate Construction, Clara Mcclure

Electronic Theses and Dissertations

The expansion of Interstate 26 from Erwin, TN to the North Carolina border was a project that potentially adversely impacted South Indian Creek because of the steep landscapes and potential for erosion. Several studies have shown the short-term, negative effects of road construction on the water quality of nearby water bodies. Non-point source pollution is the major source of water pollution in the United States. The primary objective of this research is to evaluate the long-term effects of the construction of Interstate 26 on South Indian Creek to see if there has been any ecological recovery. The Environmental Health Sciences …

Synthesis Of Resveratrol Ester Derivatives, Daniel Ressler

Electronic Theses and Dissertations

The goal of this research project was to synthesize derivatives of transresveratrol. In order for resveratrol to be activated and used by the body it needs to bind to Human Serum Albumin (HSA), a protein in blood plasma. The derivatives were synthesized to improve the ability of resveratrol to enter cells as well as improve their ability to bind to HSA. The three derivatives that were synthesized have converted one of the hydroxyl groups on resveratrol to an ether with a methylene chain terminated by a carboxylic acid. By varying the lengths of the methylene chain we varied the water …

Synthesis And Characterization Of Three New Tetrakis(N-Phenylacetamidato) Dirhodium(Ii) Nitrile Complexes, Nkongho Atem-Tambe

Electronic Theses and Dissertations

Three new tetrakis [Rh₂(PhNCOCH₃)₄·xNCR] (R = {2-CH₃}C₆H₄ (x=2), R = {3-CH₃}C₆H₄ (x=1), R = (3-CN)C₆H_4∞ (x=1)) complexes have been synthesized and characterized. These complexes were characterized by IR and ¹H NMR spectroscopies and X-ray crystallography which solved with R₁<0.05.

[Rh₂(PhNCOCH₃)₄·2NC{2-CH₃}C₆H₄] was triclinic (a=9.79Å, b=14.79Å, c=16.36Å, α=103.84⁰, β=99.17⁰, γ=99.77⁰, P-1(#2), μCN=2227.78cm^-1, Rh-Rh=2.42Å, N-C=1.13Å, 1.14Å, Rh-N=2.34Å, 2.35Å, Rh-N-C=151.6⁰, 152.5⁰, Rh-Rh-N=173.0⁰, 174.6⁰).

[Rh₂(PhNCOCH₃)_{4 …}

Defects And Dark Current In Organic Photovoltaics And Impacts On Device Physics, Xin Jiang

Electronic Theses and Dissertations

In this dissertation, we discussed the shape, energy level and density of defects in Organic Photovoltaic (OPV) devices by both theoretical and experimental methods. The energy band structure and intrinsic junctions of general standard and inverted OPV devices are investigated in detail. Transportation of separated holes and electrons in both structures are well analyzed. In chapter II, we developed a Monte-Carlo model to simulate charge transport process in organic materials. Marcus theory is applied to calculate the carrier transfer rate to build up hopping process in ideal lattices. Results of this model showed several properties of carriers regarding mobility, reorganization …

Development Of A Biosensor For Investigating Membrane Curvature Sorting, Joshua C. Black

Electronic Theses and Dissertations

The physical structure of cellular membranes plays a critical role in lipid and protein sorting. A novel biosensor was developed to probe the influence of curvature on sorting. This biosensor mimics large, two-dimensional membranes in dynamic equilibrium, achieves high spatial resolution between curvature and molecules of interest, and has high sensitivity, enough for single particle detection. The biosensor consists of continuous supported lipid bilayer formed over nanoparticles (40 to 200 nm diameter) deposited on a glass substrate. The nanoparticles determine the extent of curvature. This biosensor is the first to observe large-scale 2-dimensional diffusion of biomolecules on a supported lipid …

Geochemical Tracers Linking Submarine Groundwater Discharge To Hypoxia Formation In Long Bay, South Carolina, Usa, Sarah Lynn Chappell

Electronic Theses and Dissertations

Long Bay, South Carolina has experienced hypoxic conditions (<2mg/L dissolved oxygen) in the nearshore environment, not fully attributed to traditional formation mechanisms. Past research suggested physical, biological, and/or anthropogenic influences on low dissolved oxygen levels. This project aimed to determine the contribution of submarine groundwater discharge (SGD) to hypoxia formation. We measured activities of 222Rnxs, 224Raxs, 223Ra, 228Ra, and 226Ra (3.8d, 3.6d, 11.5d, 5.8yr, 1600yr half-lives, respectively) in nearshore bottom waters from April 2012 through April 2013. Radium activities observed during a hypoxic event on 16-Aug-2012 were up to an order of magnitude higher than those seen during oxic conditions and the highest ever observed in the open ocean, to our knowledge. We determined that a hypoxic water mass, comprised heavily of offshore anoxic SGD, migrated inshore due to physical conditions constraining mixing over a two week time period. High groundwater content suggests that observed hypoxic conditions in nearshore Long Bay may be independent of biological influence once offshore SGD occurs.

A Glyptosaurine Lizard From The Eocene (Late Uintan) Of San Diego, California, And Implications For Glyptosaurine Evolution And Biogeography, David Moscato

Electronic Theses and Dissertations

Glyptosaurinae is an extinct subfamily of lizards of the family Anguidae. Glyptosaurine lizards are known exclusively from the Paleogene of North America and Eurasia, reaching their peak of diversity and distribution in the Eocene. In North America these lizards are largely restricted to the intermontane basins along the Rocky Mountain range, with only sparse, indeterminately-identified skeletal elements known from outside of this region. Glyptosaurine lizards are split into two tribes: the monophyletic Glyptosaurini and paraphyletic “Melanosaurini”. Within Glyptosaurini, the most common and widespread genus is Glyptosaurus. In this study I describe a new specimen assignable to G. sylvestris, …

Packings And Coverings Of Complete Graphs With A Hole With The 4-Cycle With A Pendant Edge, Yan Xia

Electronic Theses and Dissertations

In this thesis, we consider packings and coverings of various complete graphs with the 4-cycle with a pendant edge. We consider both restricted and unrestricted coverings. Necessary and sufficient conditions are given for such structures for (1) complete graphs K_v, (2) complete bipartite graphs K_m,n, and (3) complete graphs with a hole K(v,w).

X-Ray Crystal Structures Of: [Rh2(N-{2,4,6-Ch3}C6h2)Coch3)4]•2ncc6h4 And Ba1.5[Fe(C10h13n2o7)][Co(Cn)6]•9h2o; Two Crystallographic Challenges, Kenneth K. Kpogo

Electronic Theses and Dissertations

The novel compound, [Rh₂(N-{2,4,6-CH₃}C₆H₂)COCH₃)₄] was synthesized. Crystal structures of [Rh₂(N-{2,4,6-CH₃}C₆H₂)COCH₃)₄]·2NCC₆H₅ and Ba_1.5[Fe(C₁₀H₁₃N₂O₇)][Co(CN)₆]·9H₂O were determined employing a Rigaku Mercury375R/M CCD (XtaLAB mini) diffractometer with graphite monochromated Mo-Kα radiation. For [Rh₂(N-{2,4,6-CH₃}C₆H₂)COCH₃)₄]·2NCC₆H₅, the space group was P-421c(#114) with unit cell dimensions: a =11.0169(14)Å, c =21.499(3)Å, V …

Synthesis Of Ester Derivatives Of Resveratrol As Potential Anti-Cancer Drugs, Parasmani Pageni

Electronic Theses and Dissertations

Resveratrol is a naturally occurring phytoalexin of the stilbene family produced by various plants in response to stress, UV radiation, and fungal attack. It is primarily found in peanuts, berries, grape skin, and red wine. Resveratrol has been found to exhibit anti-cancer, anti-inflammatory, anti-aging, and anti-oxidant properties. Research indicates that diets enriched with resveratrol containing substances result in less incidence of cancer. Unfortunately, the low bioavailability and solubility has been a huge setback for its potential prospects. As a result, efforts have been made to synthesize derivatives of resveratrol with increased solubility and bioavailability. Three triester novel resveratrol derivatives 3, …

Human Action Recognition Via Fused Kinematic Structure And Surface Representation, Salah R. Althloothi

Electronic Theses and Dissertations

Human action recognition from visual data has remained a challenging problem in the field of computer vision and pattern recognition. This dissertation introduces a new methodology for human action recognition using motion features extracted from kinematic structure, and shape features extracted from surface representation of human body. Motion features are used to provide sufficient information about human movement, whereas shape features are used to describe the structure of silhouette. These features are fused at the kernel level using Multikernel Learning (MKL) technique to enhance the overall performance of human action recognition. In fact, there are advantages in using multiple types …

Mixture Of Poisson Distributions To Model Discrete Stock Price Changes., Rasitha Rangani Jayasekare Kodippuli Thanthillage Dona

Electronic Theses and Dissertations

An application of a mixture of Poisson distributions is proposed to model the discrete changes in stock price based on the minimum price movement known as `tick-size'. The parameters are estimated using the Expectation-Maximization (EM) algorithm with a constant mixing probability as well as mixing probabilities which depend on order size. The model is evaluated using simulations and real data. Both the simulated and real data show reasonable estimates. Several adjustments are made to the model implementation to improve the efficiency with user written codes for the Newton Raphson algorithm and also implementing one of the most recent versions of …

A Paleoenvironmental Investigation Of Eolian Influx In Lacustrine Sediments Of The Southern Rocky Mountain Region, Rebecca L. Brice

Electronic Theses and Dissertations

Potential indications of long-term trends in paleoclimate, specifically winds, in the Southern Rocky Mountain region of the United States were tested using lacustrine sediment from South Blue Lake in the Wet Mountains of Colorado. This study builds upon existing eolian and lacustrine research, and investigates paleowind in a location not yet studied in this manner. Variability in sediment laminae, particle size, and mineralogy show similar patterns during the mid-Holocene warm period (ca. 5500 cal. yr BP - ca. 6000 cal. yr BP). These patterns indicate a warmer, drier, windier period that is contrasted by a less variable period in the …

Systematics, Climate, And Ecology Of Fossil And Extant Nyssa (Nyssaceae, Cornales) And Implications Of Nyssa Grayensis Sp. Nov. From The Gray Fossil Site, Northeast Tennessee, Nathan R. Noll

Electronic Theses and Dissertations

The Late Hemphillian (latest Miocene or earliest Pliocene, 7-4.5 Ma) Gray Fossil Site in northeastern Tennessee is interpreted to represent a lacustrine paleokarst fed by a river or stream. This research focuses on the morphological and systematic relations of Nyssa endocarps (fruit pits) from the fossil site to extinct and extant Nyssa species. A combination of metric and nonmetric traits allows recognition of a new species: Nyssa grayensis sp. nov. This fossil species shares the most similarities with the extant Nyssa ogeche Bartram ex Marshall from southeast North America and the Eocene fossil Nyssa eolignitica Berry from western Tennessee. Affinities …

Loops And Their Permutation Groups, Mark Greer

Electronic Theses and Dissertations

This dissertation uses the connections between loops and their associated permutation groups to study certain varieties of loops. We first define a variety of loops generalizing commutative automorphic loops and show this new variety is power associative. We show a correspondence to Bruck loops of odd order and use this correspondence to give structural results for our new variety, which in turn hold for commutative automorphic loops. Next, we study a variety of loops that generalize both Moufang and Steiner loops. We extend on known results for Moufang loops and then extend two different doubling constructions for creating Moufang and …

Using Hydrologic Measurements To Investigate Free Phase Gas In A Maine Peatland, Usa, Christiaan Bon

Electronic Theses and Dissertations

Northern Peatlands cover more than 350 million ha (~3 percent of Earth’s surface) and are an important source of methane (CH4) and other biogenic gases contributing to climate change. Free phase gas (FPG) accumulation and episodic release has recently been recognized as an important mechanism for biogenic gas flux from peatlands. It is likely that gas production and groundwater flow are interconnected in peatlands: groundwater flow influences gas production by regulating geochemical conditions and nutrient supply available for methanogenesis while FPG influences groundwater flow through a reduction in peat permeability and by creating excess pore fluid pressures. Water samples collected …

Very Cost Effective Partitions In Graphs, Inna Vasylieva

Electronic Theses and Dissertations

For a graph G=(V,E) and a set of vertices S, a vertex v in S is said to be very cost effective if it is adjacent to more vertices in V -S than in S.

A bipartition pi={S, V- S} is called very cost effective if both S and V- S are very cost effective sets. Not all graphs have a very cost effective bipartition, for example, the complete graphs of odd order do not. We consider several families of graphs G, including Cartesian products and cacti graphs, to determine whether G has a very cost effective bipartition.

Study Of Immobilizing Cadmium Selenide Quantum Dots In Selected Polymers For Application In Peroxyoxalate Chemiluminescence Flow Injection Analysis, Christopher S. Moore

Electronic Theses and Dissertations

Two batches of CdSe QDs with different sizes were synthesized for immobilizing in polyisoprene (PI), polymethylmethacrylate (PMMA), and low-density polyethylene (LDPE). The combinations of QDs and polymer substrates were evaluated for their analytical fit-for-use in applicable immunoassays. Hydrogen peroxide standards were injected into the flow injection analyzer (FIA) constructed to simulate enzyme-generated hydrogen peroxide reacting with bis-(2,4,6-trichlorophenyl) oxalate.

Linear correlations between hydrogen peroxide and chemilumenscent intensities yielded regression values greater than 0.9750 for hydrogen peroxide concentrations between 1.0 x 10^-4 M and 1.0 x 10^-1 M. The developed technique’s LOD was approximately 10 ppm. Variability of the prepared …

A Comparison Of Leading Database Storage Engines In Support Of Online Analytical Processing In An Open Source Environment, Gabriel Tocci

Electronic Theses and Dissertations

Online Analytical Processing (OLAP) has become the de facto data analysis technology used in modern decision support systems. It has experienced tremendous growth, and is among the top priorities for enterprises. Open source systems have become an effective alternative to proprietary systems in terms of cost and function. The purpose of the study was to investigate the performance of two leading database storage engines in an open source OLAP environment. Despite recent upgrades in performance features for the InnoDB database engine, the MyISAM database engine is shown to outperform the InnoDB database engine under a standard benchmark. This result was …

Peg Solitaire On Trees With Diameter Four, Clayton A. Walvoort

Electronic Theses and Dissertations

In a paper by Beeler and Hoilman, the traditional game of peg solitaire is generalized to graphs in the combinatorial sense. One of the important open problems in this paper was to classify solvable trees. In this thesis, we will give necessary and sufficient conditions for the solvability for all trees with diameter four. We also give the maximum number of pegs that can be left on such a graph under the restriction that we jump whenever possible.

Analysis Of The Blancan Procyonids Of Florida, Laura S. Gilmore

Electronic Theses and Dissertations

Procyonids are well known biologically but knowledge of their fossil record is comparatively sparse. This study seeks to describe a sample of late Blancan procyonid fossils composed mostly of postcranial and dental material. Fossils are analyzed using linear and 2D geometric morphometrics and compared with a large sample of modern specimens from a wide geographic area to understand the range of intraspecific variation. The large Procyon species is described as a new taxon based on morphology of the postcrania and lower dentition, while another Procyon species is also described as new due to an apomorphy in the upper dentition. A …