Physical Sciences and Mathematics Commons^™

Influence Of O-Phenylenediamine On The Catalysis At Hrp Enzyme Electrode In L,4-Dioxane, Hong Chen, Hui-Huang Wu

Journal of Electrochemistry

Horseradish peroxidase(HRP)was immobilized by crosslinkage on the glassycarbon electrode to prepare the enzyme electrede ,where the reduction of H_2O_2 was studied in l,4-dioxane media. It was shown that HRP electrode can catalyze the reduction of H_2O_2 without anymedintor,however, as an activator,o-phenylenediamine can promote the bio-catalysis. In thepresence of the activator,the parallel reactions occurred on the enzyme electrode. The workingcondition of the HRP electrede was investigated as the sensors for H_2O_2 and o-phenylenediamine,alsothe influence of water content in organic phase was discussed on the performance of the enzymeelectrode in organic phase.

Study Of The Action Mechanism Of A New Type Additive Sd-1 On The Electrodepositional Process Of Zinc, Huaqiang Wu, Yiqin Yan, Guangming Ni

Journal of Electrochemistry

The action mechanism of a new type additive SD-1 on the electrodepositionalprocess of zinc is reported.The results showed that the additive SD-1 is not electrochemistry activesubstane in the range of adsorption potential at rotating disk electrede surface。 The action of additiveSD-1 on the electredepositional process of zinc is considerated to be fitting in with the diffusion controlmechanism。

Application Of Electrochemistry In The Dyeing Of Fiber Textile, Bai Tong, Suzhen Gao, Zunze Wang, Jiling Wei

Journal of Electrochemistry

An electrochemical dyeing method of protein fiber-silk is presented,and aexperimental equation relating to the uptake a and trough voltage V is given. It is shown that theelectrochemical dyeing method can remarkably raise the uptake than common mtehod,reduce energyconsumption and cut down environment pollution. This is a new field for the application ofelectrochemistry.

Electrochemical Behaviors Of The Loaded Stainless Steel In Dilute Thiosulphate Solution, Changjian Lin, Zude Feng, Fuling Lin, Fayang Wang, Jianguang Tang, Yuanhui Wang

Journal of Electrochemistry

The electrochemical behavior of l8/8 stainless steel in dilute thiosulphate solutionduring strained loading was studied by various electrochemical techniques and scanning electronmicroscope.It is evidenced that the corrosion activity of stainless steel increased with strained loading.The dynamic process of repassivation ,which may datermine the initiation ,the cease and developmentof the stress corrosion cracking for stainless steel ,was strongly influenced by both electrochemical andloading conditions. Pitting corrosion may locate preferentially on the sites which was suffered mostloading.The propagation of pitting corrosion of stainless steel may induce stress corrosion crakingunder certain conditions.

Study On Properties Of Ti/Sno_2+Sb_2o_3/Pbo_2 Anode, Zhenhai Liang, Sen Wang, Yanping Sun, Wenlin Xu

Journal of Electrochemistry

A novel of anode-Ti/SnO_2+Sb_2O_3/PbO_2 was studied by means of SEM,EDS andXRD. The lifetime and kinetic parameters were determined in l mol/L H_2SO_4.The duel barrier modelwas used to interpret the results for the anode. The results show that the anode have better propertiesof electrochemistry and longer lifetime.

Coincidence Correlations Between Light Charged Particles In The Matched Reactions 905 And 1030 Mev121sb + 27al And 550 And 750 Mev 86kr + 63cu, Winifred E. Parker, Morton Kaplan, David J. Moses, John M. Alexander, Roy B. Lacey, Dalva M. De Castro Rizzo, J. Bolger, A. Narayanan, Graham F. Peaslee, D. G. Popescu

Faculty Publications

Coincidence measurements have been made between and a second particle () produced in the reactions 905 and 1030 MeV and 550 and 750 MeV . All four of the reactions lead to composite systems of 149Tb∗ or 148Gd∗ which facilitates comparisons of matched reactions. In the two reactions and the 550 MeV reaction, the particle-particle coincidences are dominated by processes that lead to evaporation residues. In the 750 MeV reaction, about half of the 1H and 4He are associated with evaporation residue production. These particle-particle coincidences arise from cross sections that are subsets of the total evaporation residue cross sections. …

Evidence For The Reducibility Of Multifragment Emission To An Elementary Binary Emission In Xe-Induced Reactions, K. Tso, L. Phair, A. Colonna, W. Skulski, G. J. Wozniak, L. G. Moretto, D. R. Bowman, M. Chartiet, C. K. Gelbke, W. G. Gong, W. C. Hsi, Y. D. Kim, M. A. Lisa, W. G. Lynch, Graham F. Peaslee, C. Schwarz, R. T. De Souza, M. B. Tsang, F. Zhu

Faculty Publications

Multifragmentation for 129Xe-induced reactions on several targets (natCu, 89Y, 165Ho, 197Au) has been studied at . The probability of emitting n intermediate mass fragments is shown to be binomial at each transversal energy and reducible to an elementary binary probability p. For each target and at each bombarding energy, p shows a thermal behavior as demonstrated by linear Arrhenius plots. A nearly universal linear Arrhenius plot is observed at each bombarding energy, independent of target. The sensitivity of p to the Zthreshold points to its physical significance and rules out auto-correlation effects.

53. Takeo Saegusa, Otto Vogl

Emeritus Faculty Author Gallery

No abstract provided.

53. Takeo Saegusa, Otto Vogl

Otto Vogl

No abstract provided.

A Magnetic, Neutron-Diffraction, And Mössbauer Spectral Study Of The Ce₂Fe₁₇₋ₓsiₓ Solid Solutions, D. P. Middleton, Sanjay R. Mishra, Gary J. Long, Oran Allan Pringle, Zhongbo Hu, William B. Yelon, Fernande Grandjean, K. H. J. Buschow

Chemistry Faculty Research & Creative Works

The magnetic properties of a series of Ce₂Fe_17-xSi_x solid solutions with x equal to 0.0, 0.23, 0.4, 0.6, 0.8, 1.02, 1.98, and 3.20 have been studied by magnetic measurements, neutron diffraction, and Mössbauer spectroscopy. An x-ray-diffraction study indicates that the compounds adopt the rhombohedral Th₂Zn ₁₇-type structure. The substitution of silicon for iron in Ce ₂Fe₁₇ leads to a contraction of the a axis by 0.2%, an expansion of the c axis by 0.2%, and a consequent reduction of the unit-cell volume by about 0.2% per substituted silicon. Magnetization studies …

Synthesis And Characterization Of Silicon Dioxide Thin Films By Plasma Enhances Chemical Vapor Deposition From Diethylsilane And Nitrous Oxide, Lan Chen

Theses

This study is focused on the synthesis and characterization of silicon dioxide thin films deposited on silicon wafers by plasma enhanced chemical vapor deposition(PECVD), using diethylsilane (DES) as a precursor and nitrous oxide (N₂O) as the oxidant. The process parameters, such as temperature, pressure and reactant gas composition have been systematically varied and their effects on the film growth rate and properties were investigated. The growth rate was found to be inversely proportional to the temperature in the examined range of 100-300°C. It increased with increasing N₂O/DES flow rate ratio as the total flow rate increased …

Factors Effecting Calcification Of Bioprosthetic Heart Valves, Sumei Yu

Theses

Calcification is the most frequent cause of clinical dysfunction of glutaraldehyde treated bioprosthetic heart valves. In this study, we compared calcification of bioprostheses of the No-ReactTM and the conventional glutaraldehyde treated pericardium by both in-vivo and in-vitro methods, and to further delineate the role of the host's inflammatory response in implant degeneration.

In the in-vitro study, the two types of pericardial samples were placed in individual polystyrene tubes containing physiological concentrations of calcium and phosphate and incubated for 21 days at 37°C. In the in-vivo study, the two types of pericardial samples were implanted subcutaneously in rats and subsequently retrieved …

Studies Of The Role Of Interfacial Molecular Structure To Adhesive Interaction, Cynthia Kraft, Mark Anderson

Mark R. Anderson

No abstract is currently available.

Electrochemical And Infrared Spectroscopic Study Of Electrodes Modified By Alkoxyalkanethiols, Jimin Huang, Mark Anderson

Mark R. Anderson

No abstract is currently available.

Understanding Proton Emission In Central Heavy-Ion Collisions, D. O. Handzy, W. Bauer, F. C. Daffin, S. J. Gaff, C. K. Gelbke, T. Glasmacher, E. Gualtieri, S. Hannuschke, M. J. Huang, G. J. Kunde, R. Lacey, T. Li, M. A. Lisa, W. J. Llope, W. G. Lynch, L. Martin, C. P. Montoya, R. Pak, Graham F. Peaslee, S. Pratt, C. Schwarz, N. Stone, M. B. Tsang, A. M. Vander Molen, G. D. Westfall, J. Yee, S. J. Yennello

Faculty Publications

Two-proton correlation functions for central collisions of 36Ar+45Sc at E/A=80, 120, and 160 MeV are compared to calculations with the Boltzmann-Uehling-Uhlenbeck (BUU) transport model. Agreement is found at E/A=80MeV, but the model predicts too large correlations at E/A=120 and 160 MeV. The discrepancy may be due to delayed emission of protons from particle-unstable states not modeled in BUU.

54. Burkart Philipp, Otto Vogl, Ch. Wandrey

Emeritus Faculty Author Gallery

No abstract provided.

Tunable Picosecond Infrared Laser System Based On Parametric Amplification In Ktp With A Ti:Sapphire Amplifier, D. E. Gragson, D. S. Alavi, G. L. Richmond

Chemistry and Biochemistry

A picosecond laser system that will generate high-power tunable IR pulses with bandwidths suitable for spectroscopic applications is discussed. The system is based on white-light continuum generation in ethylene glycol and optical parametric amplification in potassium titanyl phosphate. The nonlinear-optical processes are driven by a regeneratively amplified Ti:sapphire laser that produces 1.7-ps pulses at a repetition rate of 1 kHz. Energies as high as 40 and 12 µJ have been achieved over the signal (1.02–1.16-µm) and idler (2.6–3.7-µm) tuning ranges, respectively. The IR beam temporal and spatial characteristics are also presented.

Reply To ‘‘Comment On ‘Brillouin-Scattering Study Of The Elastic Constants Of Phenothiazine Through The Phase Transition’ ’’, J. Sartwell, Craig J. Eckhardt

Craig J. Eckhardt Publications

Disagreement in the ordering of relative magnitudes of the elastic constants of phenothiazine with those of Ecolivet et al. is resolved. Dubious methodologies and assumptions employed by Ecolivet et al. in their measurements, approximations, and arguments [C. Ecolivet et al., Phys. Rev. B 44, 4185 (1991)] are noted. Samples employed by these investigators in both their ultrasonic and Brillouin measurements are shown to exhibit properties consistent with impure samples and inconsistent with those of Sartwell and Eckhardt.

54. Burkart Philipp, Otto Vogl, Ch. Wandrey

Otto Vogl

No abstract provided.

Structure Factors Of Binary Fluids In A Dilute Gel, J.C. Lee

Faculty Publications

The statio and dynamic structure factors of binary fluids in a dilute gel are computed using a two-dimensional kinetic Ising model. The wetting effect of the gel strands is modeled with ''gel atoms'' which are distributed randomly among the spins and impose a field on their neighboring spins, all in the same direction. The result for the static structure factor shows the presence of adsorption clusters which mask the gel atoms. The result for the dynamic Structure factor shows an extremely slow relaxation-at late times which cannot be fitted in the form of the activated dynamic scaling known for random-field …

Three-Phase Intersection Points In Monolayers, John P. Hagen, Harden M. Mcconnell

Chemistry and Biochemistry

Some phospholipid/dihydrocholesterol Langmuir monolayers form coexisting liquid phases. Gas domains form at the interface between the phospholipid-rich and dihydrocholesterol-rich liquid phases when these monolayers undergo expansion to low surface pressure. Analysis of the domain shapes thus formed yields the relative line tensions of the gas/phospholipid, gas/dihydrocholesterol, and phospholipid/dihydrocholesterol phase interfaces.

55. Hermann Janeschitz-Kriegl, Otto Vogl, Anton Schausberger

Emeritus Faculty Author Gallery

No abstract provided.

55. Hermann Janeschitz-Kriegl, Otto Vogl, Anton Schausberger

Otto Vogl

No abstract provided.

Nutrient Limitation In A Southwestern Desert Reservoir: Eutrophication Of Las Vegas Bay, Lake Mead, Nevada, Davine M. Lieberman

Publications (WR)

Algal bioassay tests were conducted with Selenastrum capricornutum and natural algae on inner Las Vegas Bay, Lake Mead, Nevada, from December 1992 through September 1993, to identify any nutrient limitation in an area of the reservoir that has experienced problems associated with severe nutrient enrichment. Three areas were sampled based on a gradient of water quality conditions that existed in Las Vegas Bay (LVB). Disodium ethylenedinitrilotetraacetate (EDTA) significantly stimulated algal growth compared to non-EDTA treatment. Algal bioassays indicated that phosphorus (P) was the primary limiting nutrient at all stations for most of the test dates. Chl a response with EDTA …

Anisotropic Anharmonicity Of Lattice And Molecular Vibrations Of 1,2,4,5 Tetrabromobenzene Determined By Piezomodulated Raman Spectroscopy, K.M. White, Craig J. Eckhardt

Craig J. Eckhardt Publications

Strain-induced coupling constants for the anharmonicity of Raman-active lattice and certain molecular modes of vibration in 1,2,4,5-tetrabromobenzene (TBB) crystals have been determined using piezomodulated Raman spectroscopy. These constants, which are directly related to the first anharmonic term in the potential energy expansion for lattice dynamical calculations, are a quantitative measurement of the modal anharmonicities in the TBB molecular crystal. Application of uniaxial stress in the experiments permits the anisotropy of the anharmonicity to be determined as well as its magnitude. The TBB lattice modes are significantly coupled by the induced strains and the effects of coupling were observed to be …

Vr Projects, P.D. Quick

SWITCH

A description of three three projects having to do with virtual reality. The first is the Nanomanipulator, developed at the University of North Carolina Chapel Hill Department of Computer Science in conjunction with the UCLA Department of Chemistry in 1991. It is a machine that allows the user to interact with microscopic particles previously only visible in 2D from an electron microscope. The second project, The Augmented Reality Project, also developed at the Chapel Hill Department of Computer Science. This device used ultrasound images to be placed over a body allowing the user to see inside of it. The final …

Detection Of Alzheimer's Disease And Other Diseases Using An Improved Photoaffinity Labeling Method, Boyd E. Haley

Chemistry Faculty Patents

An improved method for diagnosing a disease comprising detecting a disease-specific biochemical marker macromolecule within a sample of extracted cerebral spinal fluid or serum is disclosed. In particular, a radioactively labeled photoaffinity probe is used to diagnose a disease. For instance, Alzheimer's disease can be diagnosed by detecting a disease-specific protein having a molecular weight of about 42,000 daltons, i.e., glutamine synthetase. Also included is a method for detecting other disease states, such as cancer, by detecting the presence or absence of specific nucleotide binding proteins.

Electrodeposition Of Cobalt And Rare Earth-Cobalt In Urea-Nabr-Kbr Melt, Qiqin Yang, Kairong Qiu, Derong Zhu, Lichang Sa

Journal of Electrochemistry

No abstract provided.

The Photoelectrochemical Studies Of Passive Films On Rebar Electrodes In Simulated Cement Pore Solution, Wei Chu, Yuanxiang Shi, Baoming Wei

Journal of Electrochemistry

The electronic properties of the passive film on REBAR electrodes in simulatedcement pore solution(pH=9.0～13.8)have been investigated using in-situ photoelectrochemicalmethods.The results show that the passive film is composed of mixed oxides of ferrum ,and it is anamorphous,n-type semiconductive film. Variations of pH values,ions in the solution and film-formation potentials can affect the composition of the films. There are two main stages in the growthof the film,with two rate functions characterized by linear relation between the film thickness and thelogarithm of time.The addition of inhibitor NaNO_2 changes the composition,structure and growthkinetics of the film,and therefore improves the resistance of pitting corrosion induced …

Study On The Surface States Of Zinc Sulfide Thin Film Doped With Erbium And Their Effect On The Relaxation Luminance, Yujiang Wang, Zhaohong Liu, Zhenxiang Chen

Journal of Electrochemistry

X-ray photoelectron spectrum and characteristics of the capacity,versus thevoltage of the thin film devices are measured to study the surface states of the zinc sulfide thin film.The transient electroluminescence excited by pulses shows the relaxation luminance peaks during anon-exponential decay process of the characteristic transitions activated by Er￣(3+) in the ZnS directcurrent thin film electroluminescence (DCTFEL) devices.The surface structures of ZnS:Cu,Cl,Erfilm with the absorption of oxygen,and the effect of the surface states on the relaxation luminance ofthe devices are discussed.