Physical Sciences and Mathematics Commons^™

A Study Of Integral Equations For Computing Radial Distribution Functions, Zainuriah Hassan

Masters Theses

Integral equation T (a two parameter equation of the Ornstein-Zernike form) is studied for computing the radial distribution functions of simple classical fluids interacting pairwise according to the Lennard-Jones 6-12 potential function. Numerical calculations are done on a computer for the system in the gas and liquid phases. At a high temperature, equation T results are found to agree very well with equation C when the parameters are chosen in a similar way. At a temperature slightly above the critical temperature, results from other sources over a wide density range. In equation T, by varying two of the parameters, the …

A Water Quality Element For The Extension Of The Salt Ponds Special Area Management Plan To Quonochontaug, Winnapaug (Brightmans) And Maschaug Ponds, Clarkson A. Collins

Theses and Major Papers

The Salt Ponds Project scientific research and management efforts were designed to address the management issues typical to barrier beach-lagoon systems. It was anticipated that the finds of the project would be applied to the management of similar estuarine systems in Rhode Island and elsewhere. This paper presents findsings and recommendations relating to water quality and land use for the watersheds of Quonochontaug Pond, Winnapaug Pond, and Maschaug Ponds. With the inclusion of these waterbodies into the SAM Plan framework, all of the barrier beach-coastal lagoon ecosystems of the south shore will come under a plan specifically designed to protect …

Predicting Success In High School Computer Programming, John C. Gevedon

Graduate Theses and Dissertations

There are great differences in performance among students taking high school programming courses, and instructors debate over what elements contribute to these differences. Some students develop logical thinking abilities and problem solving techniques, while others fail to develop skills beyond memorization of specific terms and procedures. It is not known whether these differences are causally related to the specific educational environment or student backgrounds. Without more information, the factors that actually contribute to the success of high school students in computer programming courses cannot be accurately determined. It was the purpose of this study then to isolate certain student characteristics …

Electronic Absorption Spectra Of Ni (Ii) In Sodium Phosphate And Sodium Fluorophosphate Glasses, Tarek Mostafa Sami Genena

Archived Theses and Dissertations

No abstract provided.

Development Of An On-Line Computer System For Cyclic Voltammetry Studies, Tai-Lee Leo Huo

Chemistry & Biochemistry Theses & Dissertations

An Apple II Plus microcomputer was interfaced to a PAR 174A Polarographic Analyser, an HP 7O4OA X-Y recorder and a three-electrode system. This on-line computer system was applied to Cyclic Voltammetry (CV) studies. The interfacing involved both hardware and software development. Various hardware components were used to amplify and transmit the analog signal both going into the computer and coming from the computer. Software programs were written for staircase waveform generation, data acquisition, and plotting the voltammograms obtained.

A package was designed for CV experiments to be used by the students in the instrumental analysis laboratory. This package contains several …

The Apparent Dissociation Constants Of Carbonic Acid In Low Salinity Waters, Ching-Hui Hsu

OES Theses and Dissertations

The first and second apparent dissociation constants of carbonic acid in artificial seawater and diluted artificial seawater, K₁ ' and K₂ 1 were determined at selected combinations of temperatures and salinities between 2 to 30° C and 0 to 35 o/oo with special attentions to waters with salinities below 20 o/oo at atmospheric pressure by measuring K₁ ' and the product of K₁ ' and K₂.

The results can be expressed as functions of temperature and salinity by the following equations, pK₁ '=3360.206T^-1 +0. 033331 T-14.8303-0.09633x (Cl^1/2) pK₂ '=14911.671 …

Minimal Norm Constrained Interpolation, Larry Dean Irvine

Mathematics & Statistics Theses & Dissertations

In computational fluid dynamics and in CAD/CAM a physical boundary, usually known only discreetly (say, from a set of measurements), must often be approximated. An acceptable approximation must, of course, preserve the salient features of the data (convexity, concavity, etc.) In this dissertation we compute a smooth interpolant which is locally convex where the data are locally convex and is locally concave where the data are locally concave.

Such an interpolant is found by posing and solving a minimization problem. The solution is a piecewise cubic polynomial. We actually solve this problem indirectly by using the Peano kernel theorem to …

Algebraic Grid Generation Using Tensor Product B-Splines, Bonita Valerie Saunders

Mathematics & Statistics Theses & Dissertations

In general, finite difference methods are more successful if the accompanying grid has lines which are smooth and nearly orthogonal. This thesis discusses the development of an algorithm which produces such a grid when given the boundary description.

Topological considerations in structuring the grid generation mapping are discussed. In particular, this thesis examines the concept of the degree of a mapping and how it can be used to determine what requirements are necessary if a mapping is to produce a suitable grid.

The grid generation algorithm uses a mapping composed of bicubic B-splines. Boundary coefficients are chosen so that the …

Copper Electrodeposition In A Magnetic Field, Hiroshi Takeo

Dissertations and Theses

The effect of a magnetic field on copper electrodeposition was investigated. Copper was electrodeposited onto square copper cathodes 1 sq cm in area from an aqueous solution (0.5 M CuSO₄, 0.5 M H₂SO₄. A glass cell was placed between the pole pieces of an electromagnet, and the magnetic fields applied were in the range from 0 to 12.5 kG. The current density was in the range from 80 mA/sq cm to 880 mA/sq cm. In each of the experiments, cell current, cell voltage, and cell temperature were monitored with a microcomputer. The weight …

Dynamics Of Clastic Sedimentation And Watershed Evolution Within A Low-Relief Karst Drainage Basin, Mammoth Cave Region, Kentucky, John D. Pickle

Earth and Planetary Sciences ETDs

The hydrology and sedimentology of the Mill Hole drainage basin, a low-relief karst system in the Mammoth Cave Region, Kentucky, depend upon the interactions of surface and groundwater drainages and the distribution of lithologies within the basin. This basin is characterized by sinking streams in the headwaters (Glasgow Uplands) draining into cave rivers beneath the sinkhole-pocked plain (sinkhole plain), which, in turn, flow beneath a sandstone-capped upland (Chester Cuesta) and emerge at base-level springs. Karst windows expose the subterranean drainage within the Chester Cuesta.

Confinement Of Electron Orbits And The Interaction Between The Electron Beam And Cavity Modes In The Orbitron Maser, Wlodzimierz Nakonieczny

Doctoral Dissertations

The Orbitron maser, developed over recent years in the University of Tennessee Plasma Laboratory, is an alternative microwave source, capable of producing microwave radiation up to the submillimeter range. It operates on the basis of interaction between an electrostatically confined electron cloud and electromagnetic field in the Orbitron resonator. Good confinement of the cloud is very important for an efficient operation of the Orbitron, and is directly related to the shape of electron orbits in the device. It appears that the radial confinement can be determined by two simple criteria concerning the electron's angular momentum L and energy E. The …

Detection And Analysis Of Carbonyl Compounds In Rural Cloudwater, Steven Bart Bertman

Honors Theses

A new technique for aqueous determination of aldehydes and ketones was field tested along with a new technique for ambient air analysis. The work was done during the summer of 1984 on Whiteface Mountain in Wilmington, NY. Both techniques utilized carbonyl derivitization as their 2,4-dinitrophenyl hydrazones and subsequent analysis by reversed phase HPLC. Analysis of the blank levels for the ambient air method shows the levels found to be non-detectable. The aqueous method worked well. Formaldehyde, acetaldehyde, and acetone were the only species found in cloud water. They were generally present in concentrations between .5 uM and 4 uM. Little …

Fluvial, Tidal And Storm Sedimentation In The Chilhowee Group (Lower Cambrian), Northeastern Tennessee, Mary R. Cudzil

Masters Theses

The Lower Cambrian Chilhowee Group of northeastern Tennessee consists of the Unicoi, Hampton and Erwin Formations and is divided into four facies. Facies G occurs only within the lower 200 m of measured section (the Unicoi Formation) and consists of fine-grained to pebbly quartz wacke with rare thin beds of laminated siltstone. Subfacies Gh consist of low-angle to horizontally laminated, fine-grained sandstone with laminae and lenses of granules and pebbles. Subfacies Gh represents upper flow-regime, overbank deposition within a braided stream system that was proximal to a coastline. Subfacies Gmr consists of medium-scale, planar-tabular cross-stratified conglomerate in which megaripple bedforms …

The Syntheses Of Benzo-(2.2)-Paracyclophane, 2, 15-Dithia-(3.3)-Napthalenophane, And Hexamethylbenzene Dichloride, David Gene Barrett

Honors Theses

The purpose of this study was the preparation by a novel approach of benzo-(2.2)-paracyclophane. Also synthesized were the syn-and anti-isomers of 2,15-dithia (3.3)- napthalenophane. The results of these syntheses are supported by spectral studies. In preparation for future study of the ruthenium complexes of these cyclophanes, hexamethylbenzeruthenium dichloride was also synthesized.

Determination Of The Equilibrium Constant For The Acetaldehyde-Bisulfite Addition Compound, Mark B. Richard

Honors Theses

Synthesis of the addition compounds of formaldehyde, acetaldehyde, acetone, and propionaldehyde with sodium bisulfite was achieved using the method of Stewart and Donnally. Recognition of a water comtamination led to a method for determining purity using the integrations from NMR spectrometry. An equilibrium constant for the acetaldehyde-bisulfite addition compound was determined using the method of Dasgupta. A value of 6.3 x 10-5 was determined at a ph of 4.7. This value correlates well in magnitude when compared to the value of 1.56 x 10-5 for the formaldehyde-bisulfite addition compound at pH 5.0 determined by Dasgupta and also with Stewart and …

A Study Of Chemiluminescence Via Flash Photolysis, Craig Lawrence Shalmi

Honors Theses

We are interested in understanding the mechanistic details of photo-initiated chemiluminescent reactions. Currently, we are examining reactions which lead to luminescent from electronically excited nitric oxide. Stedman has reported observing NO gamma-band emission in the thermal reaction of hydrazoic acid, HN3 with O(3P). The rate constant for the production of NO* is low and, consequently, the emission intensity is weak. We are endeavoring to generate excited NO from HN3 and O(1D), the later produced in the flash photolysis of ozone. It is hoped that a greater population of NO* will be produced yielding a greater chemiluminescent intensity. By observing the …

Reaction Of Atomic Hydrogen With Chloroform In A Discharge Flow Reactor, Wan-Kuen Jo

Theses

The reactions of atomic hydrogen with chloroform were studied in a tubular flow reactor both in a 4 cm i.d. and 2.6 i.d. discharge flow reactor at pressure of 2.22 to 2.82 mmHg and room temperature using GC and GC/MS for analysis of the reaction. The hydrogen atom concentration at the reaction flame was measured by Chemiluminescence titration with nitrogen dioxide. The hydrogen concentrations are in the 2.48 x 10⁺¹⁴ to 4.83 x 10⁺¹⁴ atoms/cc range at six different hydrogen flow rates. Evidence was found for the formation of atomic carbon intermediate in the reaction, but methane was …

Random Genetic Drift Diffusion Model And Deterministic And Stochastic Models Of Epidemics, Norman W. Loney

Theses

In the Random Genetic Drift Diffusion model two approaches are taken. First we examined a discrete model that represent a relatively idealised version of the phenomena. Hefurther make the assumption that the Population reproduces itself and then dies, thus maintaining a finite population size at all times. If at a given locus there are two possible allels A and B and if X(t) is the number of A type in the genetic pool of size 2N, then 2N-X(t) is the number of B type. We then proceed to obtain a probability density function of X( t) by an Exact method …

The Mechanics Of Low Orbiting Satellites Implications In Communication, Lane Brostrom

Undergraduate Honors Capstone Projects

Low orbiting satellite communication networks will be competing with geosynchronous satellites for a share of the communications market. In world-wide communications that do not require immediate real time transmissions, low orbiting satellites are competitive with geosynchronous satellites because the system is reliable and low in cost.

Since satellites are a clear example of Newtonian laws, the distinct patterns they make in their orbiting process are predictable. Newton's law states that an object will remain in uniform motion unless acted upon by a force: a satellite remains in motion around the earth because there is no atmosphere to slow it down. …

Applications Of A Direct Fast Field/Reflectivity Method To Wave Propagation Modeling In Underwater Acoustic And Solid Earth Seismic Environments, Gerard Joseph Tango

University of New Orleans Theses and Dissertations

A new method is discussed for exact rapid computation of the depth-dependent Green's function occuring in full integral solutions to the acoustic and elastic Helmholtz wave equation, allowing calculations of underwater acoustic propagation loss and full wavefield synthetic seismograms, in range-independent plane stratified media.

Spring Flow In A Portion Of Grand Canyon National Park, Arizona, David Bruce Goings

UNLV Theses, Dissertations, Professional Papers, and Capstones

Hermit, Monument, Salt, and Horn Creeks flow through four side canyons of the Colorado River within the Grand Canyon. They lie just west of Grand Canyon Village on the south side of the canyon. Each of these creeks is fed by at least one spring.

Comparisons of flow at each of these springs for a 14 month period, and precipitation on the south rim show a close correlation. The lag period between recharge at the rim and discharge at the springs is less than one month for Hermit Creek and between one and two months for the other three creeks. …

Pollution In The Mediterranean: A Regional Response, Antony O. Heimer

Theses and Major Papers

Pollution of the Mediterranean Sea has been an issue of significant political, economic and environmental concern for more than a decade. It has more recently become a regional issue with politically diverse coastal states and a wide variety of international agencies implementing cooperative programs of scientific research, education and training, planning, and treaty drafting. Being a regional issue, the pollution problem has facilitated discussions between nations on several levels and governments have found it politically advantageous to use the issue for a variety of purposes.This paper will provide an overview of the Mediterranean pollution problem, covering the nature of the …

Approaches To Development And Extension Of Capture Technologies For Developing Small Scale Fisheries, Stephen C. Drew

Theses and Major Papers

Over half the world's supply of fish for human consumption is produced by small scale fisheries. In recent years, increasing attention has been focused on improvement of small scale fisheries in developing countries. In spite of substantial investments, and the arduous labor of many competent, well-intentioned people, the success rates of small scale fisheries development projects have not been encouraging. This paper will discuss two types of project approaches which have been used in small scale fisheries development, with examples of the challenges and problems they have encountered. A description of the Appropriate Technology Adaptive Research, Development, and Extension (ATARDE) …

The Seasonal Pattern Of Shipping Freight Rates, Wathanachai Raunglerdpanyagul

Theses and Major Papers

This paper reviews the behavior of shipping freight rate by using the freight index as an proxy variable. A proxy variable is the one that is a substitute to the intended one because it is difficult to obtain. It was found that a seasonal pattern in the freight rate exists, but no specific estimated pattern of the seasonal variation was found. Generally, tramp freight rates rise above average level from February or March to June or July, and from September or October to December or January. The tanker freight rate, which differs from the tramp freight rate, has only one …

The Feasibility Of A Zone Of Peace, P. R. Kendrick

Theses and Major Papers

Starting in 1964 there has been a movement to declare the Indian Ocean a "Zone of Peace." In an age when many in the world feel threatened by the potential of nuclear holocaust this is not striking in and of itself. What the Zone of Peace proposal provides is more valuable than the actual resolution. Empirically, it is obvious that nuclear free zones and peace zones have little validity. Historically, the weak have been vanquished by the powerful; their proclaimed neutrality notwithstanding. Consequently, a study of the peace movement in the Indian ocean may be utilized to investigate why proclamations …

The Petrology And Mineralogy Of Tertiary(?) Olivine Trachyte In The Harrington Peak Quadrangle, Southeastern Idaho, Amanda Shearer-Fullerton

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

The Harrington Peak Quadrangle is located within the Caribou National Forest of southeast Idaho. Within this quadrangle are outcrops of olivine trachyte of Pliocene(?) age overlying sedimentary rocks of Mississippian to Tertiary age. The region contains thrust faults and later normal faults (generally trending north-south} formed during Basin and Range extension.

The Largest outcrop of olivine trachyte (approximately1 1/2 X 3 km) probably formed as the result of a fissure eruption. Two other outcrop areas show evidence of being sites of local extrusion.

Whole-rock chemical analyses revealed the olivine trachyte to have moderate amounts of SiO₂ and Al_{2O …}

Petrology And Mineralogy Of Tertiary(?) Volcanic Rocks Of Snowville Area, Utah, And Tertiary-Quaternary(?) Volcanic Rocks Of Table Mountain And Holbrook Areas, Idaho, Yunshuen Wang

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Basalt flows occur in the Snowville area of north-central Utah and the Table Mountain and Holbrook areas of south-central Idaho. All basalt flows are aphanitic in groundmass, and contain olivine, plagioclase, augite, and opaque oxides. They can be distinguished by texture. Snowville basalt has predominantly subophitic to intergranular textures. Table Mountain basalt is fine grained, with stumpy groundmass plagioclase and equant ilmenite crystals. Holbrook basalt has pilotaxitic to intergranular textures, with the presence of plagioclase phenocrysts and characteristic exsolution lamellae in Fe-Ti oxides. The olivine grains in Holbrook area are intensely oxidized to Fe-Ti oxides.

Snowville basalt contains olivine phenocrysts …

Sequential Thrusting Beneath The Willard Thrust Fault, Wasatch Mountains, Ogden, Utah, Tad William Schirmer

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

The downstructure of viewing geologic maps, balanced and cross sections, and hanging-wall-sequence diagrams are applied to produce the first comprehensive synthesis of the structure below the willard thrust sheet.

Development of the duplex beneath the Willard thrust may be explained with a "piggyback" thrust model where younger thrust slices form below and fold an older, overlying thrust sheet. Progressive failure of the footwall ramp of the Willard thrust sheet extended the sole thrust eastward and produced a duplex consisting of thrust slices (horses) which adhered to the overriding thrust sheet where it ramped from a lower sole thrust to an …

Geodesic Orbits About An Axisymmetric Mass Distribution, David J. Dean

Honors Theses

The General Theory of Relativity (GRT) gives rise to many interesting questions, one of which is a question about how test particles orbit various relativistic mass configurations. A test particle is defined as an electrically neutral particle small enough that its self gravitating energy, as calculated using standard Newtonian theory, can be neglected when compared with the particle's rest mass, ie. M/R << 1. (Here M is the mass of the particle in meters, and R is the radius of the particle again in meters. The mass of the sun in these units is 1.47 km.) For example, the earth, which can be considered a test particle for the sun, travels about the sun in an elliptic orbit. What would happen if the sun suddenly became a black-hole? How would the earth's orbit be affected? It is the purpose of this paper to answer these questions not only for the case of the spherical black-hole (which has been extensively studied), but also for the case of an axisymmetric mass distribution idealized by a long thin rod-like mass (which will henceforth be referred to as a line mass). The classical case and relativistic case concerning orbits about the line mass will be discussed, along with some interesting features of the relativistic line mass orbits. Some background information concerning GRT will be needed before the problem of line mass is approached.

Ion-Exchange And Surface Properties Of Titania Gels From Ti (111) Chloride Solutions, Suzan I Khairy Seleem

Archived Theses and Dissertations

No abstract provided.