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Full-Text Articles in Physical Sciences and Mathematics

Synthesis Of Pyridine Nucleosides By Cycloaddition Reactions And Synthesis And Condensation Reactions Of 4-Aryl-2-Oxytetronimides, Glenn L. Heise Dec 1985

Synthesis Of Pyridine Nucleosides By Cycloaddition Reactions And Synthesis And Condensation Reactions Of 4-Aryl-2-Oxytetronimides, Glenn L. Heise

Masters Theses

Experiment 1: The reaction of various glutaconaldehyde salts (Na+ or K+) with glycosyl isothiocyanates has resulted in the formation of a novel class of compounds. Relatively mild conditions were utilized for the synthesis which occurs in four steps, and in good yield, starting from glucpseptentaacetate. These reactions were found to be regiospecific. The unique physical and spectral properties of the model compound 1-(2,3,4,6-tetra-0-acetyl-β-D-glycopranosyl)-2-thiono-3-pyridine carboxaldehyde are also discussed.

Experiement 2: Early synthetic methodologies have recently been utilized in the synthesis of 4-aryl-2-oxytetronimides. These compounds have been found to participate in condensation reactions with various substituted o-phenylene diamines. A …


Reactivity Of Some Nitrogen-Containing Compounds At Supercritical Water Conditions, David M. Tiffany Apr 1985

Reactivity Of Some Nitrogen-Containing Compounds At Supercritical Water Conditions, David M. Tiffany

Masters Theses

The use of water at cuperctirical conditions to remove nitrogen from several nitrogen-containing compounds was studied with the purpose of exploring the use of supercritical water as a method of removing nitrogen from the extraction products of coal. Quinoline and isoquinolone were the primary model compounds used with benzonitrile and carbazole also being examined briefly. Reaction conditions varied in temperature (350-500°C), pressure (3500-5200 psi), and water density (0.170-.0.426g/cc). The major products formed by isoquinoline were benzene, toluene, ethylbenzene, and o-xylene as well as nonvolatile tar and char. Quinoline produced aniline and toluidine in addition to those obtained from isoquinoline. Most …


Preparation Of Methyl-Substituted Dienols By The Hydromethylation Of Ene-Yn-Ol Substrates With Titanium Tetrachloride And Trimethylaluminum, Terry James Zitzelberger Jan 1985

Preparation Of Methyl-Substituted Dienols By The Hydromethylation Of Ene-Yn-Ol Substrates With Titanium Tetrachloride And Trimethylaluminum, Terry James Zitzelberger

Dissertations, Theses, and Masters Projects

No abstract provided.


The Irreversible Inhibition Of D-Amino Acid Oxidase With Trans-3-Bromoacrylic Acid And Four Others Halo-Vinylic Acids, Christopher D. Kontos Jan 1985

The Irreversible Inhibition Of D-Amino Acid Oxidase With Trans-3-Bromoacrylic Acid And Four Others Halo-Vinylic Acids, Christopher D. Kontos

Dissertations, Theses, and Masters Projects

No abstract provided.


Search For New Membrane Active Substances: Synthesis Of 3-Tropanols With Alkyl, Alkenyl And Alkenynyl Group At The Bridgehead, Ramalinga Murty Dharanipragada Jan 1985

Search For New Membrane Active Substances: Synthesis Of 3-Tropanols With Alkyl, Alkenyl And Alkenynyl Group At The Bridgehead, Ramalinga Murty Dharanipragada

Graduate Theses, Dissertations, and Problem Reports

In recent years, Witkop and coworkers have isolated several structurally unique alkaloids from the colombian frog belonging to the genera Dendrobates. These alkaloids, which occur in the defensive skin secretions of the frog have been found to be highly active venoms as well as mucosal tissue irritants towards both mammals and reptiles. Among them are three important alkaloids histrionicotoxin, isodihydrohistronicotoxin and octahydrohistronicotoxin.