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Full-Text Articles in Physical Sciences and Mathematics

Table Of Contents, The Editors Apr 2024

Table Of Contents, The Editors

Coal Geology & Exploration

No abstract provided.

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Response Mechanism Characteristics Of Mining-Induced Fault Activation, Sun Wenbin, Hao Jianbang, Dai Xianzheng, Kong Lingjun Apr 2024

Response Mechanism Characteristics Of Mining-Induced Fault Activation, Sun Wenbin, Hao Jianbang, Dai Xianzheng, Kong Lingjun

Coal Geology & Exploration

In the process of coal mining, mining-induced stress perturbation is a key factor leading to fault activation, which is a primary challenge faced by safe coal mining. Fault activation is prone to induce geological disasters such as rock bursts and floor water inrushes of coal mines. Furthermore, it poses a serious threat to mining safety. Using the Flac3D software for numerical simulations and similar material simulation experiments, this study established a model for faults’ stress-displacement responses under coal mining to analyze the mechanisms behind the evolution of fault structure zones in the process of coal mining. Key findings are …

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Prediction Of Mine Water Inflow Along Mining Faces Using The Ssa-Cg-Attention Multifactor Model, Ding Yingying, Yin Shangxian, Lian Huiqing, Liu Wei, Li Qixing, Qi Rongrong, Bu Changsen, Xia Xiangxue, Li Shuqian Apr 2024

Prediction Of Mine Water Inflow Along Mining Faces Using The Ssa-Cg-Attention Multifactor Model, Ding Yingying, Yin Shangxian, Lian Huiqing, Liu Wei, Li Qixing, Qi Rongrong, Bu Changsen, Xia Xiangxue, Li Shuqian

Coal Geology & Exploration

Predicting mine water inflow plays an important role in ensuring mine safety, optimizing resource allocation, and improving work efficiency. This study aims to improve the accuracy and stability of the predicted mine water inflow. Given their strong correlations with water inflow, borehole water level and microseismic energy were chosen as multifactor characteristic variables. Using these variables, this study developed the SSA-CG-Attention multifactor prediction model for mine water inflow along mining faces. The new model extracted effective nonlinear local features of data utilizing a new network structure, which was formed by integrating a convolutional neural network (CNN) based on the time …

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Three-Dimensional Forward Modeling Using The Transient Electromagnetic Method Under Complex Terrains And The Analysis Of Terrain Effects, Qu Shaobo, Zhu Jiao, Jiang Zhihai, Li Maofei, He Zhilong Apr 2024

Three-Dimensional Forward Modeling Using The Transient Electromagnetic Method Under Complex Terrains And The Analysis Of Terrain Effects, Qu Shaobo, Zhu Jiao, Jiang Zhihai, Li Maofei, He Zhilong

Coal Geology & Exploration

The ground-based transient electromagnetic method (TEM), with unique advantages, has been extensively applied for hydrogeological exploration in coal mines. However, in field exploration, complex terrains tend to cause variations in geometric shapes of transmitting sources and deviations in signals received, reducing exploration accuracy. Hence, by integrating theoretical analysis and numerical simulations with the analysis of actual terrain data, this study systematically investigated the response characteristics of electrical- and magnetic-source TEM fields under complex terrains. Using the vector finite-element electromagnetic forward modeling technique based on second-order backward Euler discretization, this study delved into the laws of influence of peak and valley …

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Research On Path Planning Methods For Underground Roadheader Robots, Zhang Xuhui, Zheng Xili, Yang Wenjuan, Li Yuyang, Ma Bing, Dong Zheng, Chen Xin Apr 2024

Research On Path Planning Methods For Underground Roadheader Robots, Zhang Xuhui, Zheng Xili, Yang Wenjuan, Li Yuyang, Ma Bing, Dong Zheng, Chen Xin

Coal Geology & Exploration

In order to solve the problems of difficulty and low efficiency in the movement of robotic roadheaders under conditions of non-full-section roadways in coal mines, the characteristics of unstructured environments in coal mines and the motion characteristics of robotic roadheaders were analyzed, and a path planning method for robotic roadheaders based on deep reinforcement learning was proposed. The tunnel environment was constructed in real time using depth cameras, a virtual model for detecting roadheader-tunnel collisions was established, collision detection was performed in a virtual environment using the hierarchical bounding box method, and an obstacle avoidance strategy under the restrictions of …

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Exploring The Detection Performance Of Different Array Configurations For Multi-Electrode Resistivity Method Tomography Using A 2.5d Finite Element Method, Zhao Rongchun, Lyu Yuzeng, Zhang Zhi, Wei Liuye, Pan Hongxu Apr 2024

Exploring The Detection Performance Of Different Array Configurations For Multi-Electrode Resistivity Method Tomography Using A 2.5d Finite Element Method, Zhao Rongchun, Lyu Yuzeng, Zhang Zhi, Wei Liuye, Pan Hongxu

Coal Geology & Exploration

Multi-electrode resistivity method is equipped with various electrode array configurations. Due to their different electrode arrangements, various electrode array configurations tend to exhibit significantly varying detection effects under different survey environments. Hence, to achieve satisfactory detection effects using high-resolution electrical resistivity tomography, it is necessary to explore the strategy for choosing appropriate array configurations targeting different objects in practical work. Given the high applicability of the method, its forward and inversion calculations remain a critical task. Based on the differential equations to be satisfied by the point source potential in a three-dimensional structure, this study derived the variational problem to …

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Intelligent Identification Method For Overburden Three Zones Of A Goaf, Li Jianwen, Zhao Wen, Wu Zhenkun, Xu Xiaobing, Wang Qingtao, Duan Longchen Apr 2024

Intelligent Identification Method For Overburden Three Zones Of A Goaf, Li Jianwen, Zhao Wen, Wu Zhenkun, Xu Xiaobing, Wang Qingtao, Duan Longchen

Coal Geology & Exploration

In this paper, an intelligent identification method was proposed to ascertain overlying strata failure types and fracture development in the overlying strata of a goaf, and identify three zones (sagging zone, fractured zone and caving zone) quickly and accurately. This method is expected to be a basis in later development of goaf treatment plans. A coal mine goaf in Shandong Province was introduced for case study, where the Bayesian Online Changepoint Detection (BOCD) algorithm was employed to analyze the changes and response characteristics of the drilling fluid loss and drilling rate over the drilling process at the boundaries of three …

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Exploring Dynamic Parameters And Tooth Structure Of Self-Propelled Borehole Repairing Drill Bits, Liu Yong, Li Yang, Wei Jianping, Yuan Yongwang, Dai Shuo, Li Linyu Apr 2024

Exploring Dynamic Parameters And Tooth Structure Of Self-Propelled Borehole Repairing Drill Bits, Liu Yong, Li Yang, Wei Jianping, Yuan Yongwang, Dai Shuo, Li Linyu

Coal Geology & Exploration

Self-propelled borehole repairing drill bits provide an effective technique for repairing long boreholes that have failed. In order to further improve the borehole repair speed and gas drainage efficiency, based on the theory of jet recoil, the relationship between the jet recoil force and nozzle parameters was analyzed, and a theoretical model was established for rotational mechanics of self-propelled borehole repairing drill bits. Subsequently, the coal-breaking processes of drill bits with different tooth structures were simulated using LS-DYNA, the failure modes in coal mass broken by cutting teeth and the rules of variation in the volume of coal broken by …

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Research On Tar-Rich Coals: Progress And Prospects, Wang Shuangming, Bao Yuan, Hao Yonghui, Wang Shengquan, Shi Qingmin, Li Dan, Hu Yiliang Apr 2024

Research On Tar-Rich Coals: Progress And Prospects, Wang Shuangming, Bao Yuan, Hao Yonghui, Wang Shengquan, Shi Qingmin, Li Dan, Hu Yiliang

Coal Geology & Exploration

Tar-rich coals are a coal-based oil and gas resource that integrates the properties of coal, oil, and gas. Given China's energy endowment of abundant coal resources but limited oil and gas reserves, exploiting tar-rich coals plays a significant role in alleviating China's tight supply of oil and gas resources and achieving green development and low-carbon utilization of coals. Using tar-rich coals as the keyword, we searched the CNKI and Web of Science databases for academic articles and patents published from 1985 to the end of 2023. Based on the search results, we statistically analyzed the process and main aspects of …

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Mechanism And Application Of Cross-Interface Fracturing For Permeability Enhancement Through The Roof Blasting Of Tectonic Coal Seams, Gao Kui, Wang Youwei, Qiao Guodong, Tian Yu, Fu Shigui Apr 2024

Mechanism And Application Of Cross-Interface Fracturing For Permeability Enhancement Through The Roof Blasting Of Tectonic Coal Seams, Gao Kui, Wang Youwei, Qiao Guodong, Tian Yu, Fu Shigui

Coal Geology & Exploration

Deep coal mining is challenging due to deteriorating geological conditions. After undergoing multiphase tectonic movements, primary coals have evolved into soft tectonic coal seams with low permeability and high gas content, complicating drilling in coal seams. In this case, the blasting-induced fractures are not well-developed and are prone to be re-compacted. So far, no fundamental breakthrough has been achieved in the key technology of fracturing for permeability enhancement technology through the roof blasting of tectonic coal seams. Given this, this study established test models for similar simulation tests and numerical analysis on the roof blasting of coal seams. By monitoring …

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Preliminarily Exploring The Theories And Technologies For Coalbed Methane Production Using Horizontal Wells: Comparison Of Conditions For Coalbed Methane And Shale Gas Exploitation, Wang Hongyan, Duan Yaoyao, Liu Honglin, Zhao Qun, Chen Shangbin, Lu Haibing, Shi Zhensheng, Sun Qinping, Chen Zhenhong, Zhou Shangwen, Yang Mingwei, Wang Cong Apr 2024

Preliminarily Exploring The Theories And Technologies For Coalbed Methane Production Using Horizontal Wells: Comparison Of Conditions For Coalbed Methane And Shale Gas Exploitation, Wang Hongyan, Duan Yaoyao, Liu Honglin, Zhao Qun, Chen Shangbin, Lu Haibing, Shi Zhensheng, Sun Qinping, Chen Zhenhong, Zhou Shangwen, Yang Mingwei, Wang Cong

Coal Geology & Exploration

Through 30 years of unremitting explorations, coalbed methane (CBM) wells in China have gradually transitioned from vertical to horizontal wells. However, the lack of basic theories on CBM production using horizontal wells is the main challenge to current CBM development. Compared to shales, coal seams exhibit heterogeneity and a minor presence of foliations and brittle minerals, hindering the formation of volumetric fracture networks. Nevertheless, the roofs and floors of coal seams have high sealing capacities and mechanical strength, creating excellent conditions for hydraulic fracturing. Some fractures in coals are filled with calcite, rendering acidification conducive to the improvement of reservoir …

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Accumulation Characteristics And Exploration Prospects Of Deep Coalbed Methane In The Longtan Formation Of The Nanchuan Block On The Southeastern Margin Of The Sichuan Basin, Guo Tao, Jin Xiaobo, Wu Didi, Xie Fei, Liu Jinxian Apr 2024

Accumulation Characteristics And Exploration Prospects Of Deep Coalbed Methane In The Longtan Formation Of The Nanchuan Block On The Southeastern Margin Of The Sichuan Basin, Guo Tao, Jin Xiaobo, Wu Didi, Xie Fei, Liu Jinxian

Coal Geology & Exploration

Vertical well Y2 in the Nanchuan bloc on the southeastern margin of the Sichuan Basin has yielded daily production of natural flowing gas of 13000 m3, signifying a strategic breakthrough in deep coalbed methane (CBM) exploration on the margin. This study aims to systematically reveal the enrichment and high-yield patterns of CBM in the Nanchuan block. Using data on the regional geology, tests, assays, and production, this study investigated the accumulation characteristic and conducted exploration potential evaluation for deep CBM in the Nanchuan block from the perspective of the quality, pore and fissure characteristics, gas content, and fracability …

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Fracture Propagation Mechanism In Directional Perforation And Hydraulic Fracturing Of Coal Seam Horizontal Wells, Pang Tao, Jiang Zaibing, Hui Jiangtao, Jia Bingyi Apr 2024

Fracture Propagation Mechanism In Directional Perforation And Hydraulic Fracturing Of Coal Seam Horizontal Wells, Pang Tao, Jiang Zaibing, Hui Jiangtao, Jia Bingyi

Coal Geology & Exploration

Horizontal well perforation and fracturing in complex coal-bearing strata are key to increasing coal seam permeability and enhancing gas extraction efficiency, with the formation structure and perforation location determining fracture propagation. Considering the characteristics of formation structure and perforation locations, a fracturing geological model is established. Based on the finite element method, a numerical model is constructed to study the effects of perforation location, formation conditions, and the difference between vertical stress and horizontal stress on fracture perforation. Engineering verification is conducted, and construction suggestions are proposed. Key findings are as follows: There are three scenarios for the perforation locations: …

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An Intelligent Water Source Discrimination Method For Water Inrushes From Coal Seam Roofs In The Inner Mongolia-Shaanxi Border Region, Wang Hao, Sun Junqing, Zeng Yifan, Shang Hongbo, Wang Tiantian, Qiao Wei Apr 2024

An Intelligent Water Source Discrimination Method For Water Inrushes From Coal Seam Roofs In The Inner Mongolia-Shaanxi Border Region, Wang Hao, Sun Junqing, Zeng Yifan, Shang Hongbo, Wang Tiantian, Qiao Wei

Coal Geology & Exploration

Water hazard on the coal seam proof induced by high-intensity coal mining are increasingly prominent in the Inner Mongolia-Shaanxi border region. The effective, accurate water-source discrimination of the water inrushes is the key to water hazard prevention. This study investigated three typical mines in the Inner Mongolia-Shaanxi border region. To this end, principal component analysis (PCA) was employed to extract principal components from 80 groups of groundwater samples. Then, with inorganic indicators K++Na+, Ca2+, Mg2+, Cl−, SO4 2−, HCO3 − and TDS and organic indicators UV254 …

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Sulphate Contamination In An Abandoned Coal Mine In Light Of Mining Effects, Qi Yueming, Zhou Pei, Zhou Lai, Jiang Dan, Yang Yuqing, Liu Yanzhuo Apr 2024

Sulphate Contamination In An Abandoned Coal Mine In Light Of Mining Effects, Qi Yueming, Zhou Pei, Zhou Lai, Jiang Dan, Yang Yuqing, Liu Yanzhuo

Coal Geology & Exploration

Abandoned high-sulfur coal mines will become deeply buried acid-producing contamination sites, posing hazards to adjacent aquifers and surrounding environments. Furthermore, mining effects and the complex spatial distribution of abandoned mines complicate the assessment of the contamination processes and degrees in adjacent aquifers. Focusing on a certain abandoned coal mine, this study examined the migration characteristics of SO4 2− pollution in acid mine drainage using numerical simulations by taking sulfate (SO4 2−) as the characteristic contaminant and considering the effects of the fractures formed by the mining of multiple coal seams on the aquifer structure. Furthermore, it analyzed …

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Experimental Study Of The Thermal Cracking Mechanism Of Limestones During Burning, Zhang Weiqiang, Cao Zhicheng, Zhou Qizhong, Wang Zuoquan, Wu Yun Apr 2024

Experimental Study Of The Thermal Cracking Mechanism Of Limestones During Burning, Zhang Weiqiang, Cao Zhicheng, Zhou Qizhong, Wang Zuoquan, Wu Yun

Coal Geology & Exploration

Spontaneous combustion of coal seams will cause different degrees of structural damage to surrounding rocks at different high temperatures, significantly altering their physical and mechanical properties and engineering geological effects. To delve into the structural evolution patterns of rocks during burning, this study investigated the limestones from the floor of a coal mine in Xuzhou. It conducted thermal cracking experiments under different temperatures, exploring the thermal cracking patterns of rocks on multiple scales. Furthermore, this study revealed the genetic mechanism of thermal cracking by combining numerical simulations and microstructure tests. Key findings are as follows: (1) The thermal cracking temperature …

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Edge Detection Of Low Illumination Image In Cutting Unit Of Shearer, Jia Pengtao, Jin Luwei, Wang Bin, Guo Fengjing, Li Na Apr 2024

Edge Detection Of Low Illumination Image In Cutting Unit Of Shearer, Jia Pengtao, Jin Luwei, Wang Bin, Guo Fengjing, Li Na

Coal Geology & Exploration

In this paper, a fractional differentiation-based edge detection algorithm named Lif is proposed to address the edge detection problems of missing edge and fuzzy details in the cutting unit of shearers working in low-light underground environments. First, the initial fractional mask operator was built using a larger detection template according to the Grünwald-Letnikov definition of the fractional derivative. Then, the weight coefficients at various positions of the mask operator were determined according to the theory of Pascal’s triangle, and the mask operator was extended to four different directions. Finally, the mask operator was convolved with the image, and the local …

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Development Of A New Nanosensor For The Determination Of Food Coloring Sunset Yellow In Powder Drinks Using L-Cysteine Coated Copper Nanoclusters, Mehmetcan Bi̇lkay, Büşra Karataş, Hayri̇ye Eda Şatana Kara Apr 2024

Development Of A New Nanosensor For The Determination Of Food Coloring Sunset Yellow In Powder Drinks Using L-Cysteine Coated Copper Nanoclusters, Mehmetcan Bi̇lkay, Büşra Karataş, Hayri̇ye Eda Şatana Kara

Turkish Journal of Chemistry

Sunset Yellow (SY), which is an artificial azo dye, is preferable for its high stability and low cost. The determination of SY in foods is extremely important for human health because excessive consumption of SY has harmful effects, such as hyperactivity disorder and cancer. In this method, L-cysteine ​​coated copper nanoclusters (CuNCs) were used as a fluorescence probe. L-cysteine ​​has been used as both a reducing and stabilizing agent. One-step green hydrothermal synthesis of CuNCs was made. L-cysteine-coated CuNCs have been characterized using several of methods. CuNCs quenching mechanism is static and inner filter effect (IFE). The linear range is …

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Sensitive And Accurate Determination Of Oil-Soluble And Water-Soluble Organosulfur Compounds In Garlic Matrix Using Reversed Phase-High Performance Liquid Chromatography, Ümmügülsüm Polat Korkunç, Buse Tuğba Zaman, Sezgi̇n Bakirdere, Emine Karakuş Apr 2024

Sensitive And Accurate Determination Of Oil-Soluble And Water-Soluble Organosulfur Compounds In Garlic Matrix Using Reversed Phase-High Performance Liquid Chromatography, Ümmügülsüm Polat Korkunç, Buse Tuğba Zaman, Sezgi̇n Bakirdere, Emine Karakuş

Turkish Journal of Chemistry

Garlic is in the family Liliaceae and has many different constituents such as organic sulfur compounds, amino acids, carbohydrates, minerals, and vitamins. In this work, a simple, sensitive, and accurate analytical method was developed for the determination of selected organosulfur compounds (OSCs) in garlic bulbs using reversed phase-high performance liquid chromatography (RP-HPLC). Oil-soluble and water-soluble OSCs were extracted from the garlic samples via acetonitrile and deionized water, respectively. The OSCs were separated on a Phenomenex C18 (250 mm, 4 mm, 5mm) column and the monitoring was performed with a UV detector at 220 nm. An isocratic mobile phase comprising of …

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Phosphorus And Nitrogen-Containing Soybean Oil Polyols: Effect On The Mechanical Properties And Flame Retardancy Of Polyurethane Foam, Deni̇z Öztaşkin, Lütfullah Yusuf Yi̇vli̇k, İlayda Acaroğlu Degitz, Tarik Eren Apr 2024

Phosphorus And Nitrogen-Containing Soybean Oil Polyols: Effect On The Mechanical Properties And Flame Retardancy Of Polyurethane Foam, Deni̇z Öztaşkin, Lütfullah Yusuf Yi̇vli̇k, İlayda Acaroğlu Degitz, Tarik Eren

Turkish Journal of Chemistry

In recent years, there has been an increasing interest in producing new materials that use renewable resources and halogen-free flame retardants with nonleaching properties. This research focuses on designing and synthesizing phosphorus-nitrogen-based biopolyols for use in polyurethane (PU) foam production. Polyol (ESBO-DYM) with dual functionalities, renewability, and nonflammability is synthesized through the epoxy ring-opening reaction of epoxidized soybean oil with phosphorus and nitrogen-containing tetraol products (DYM). The mechanical and flame retardant properties of PU foams with the addition of an ESBO-DYM were investigated. Increasing the amount of phosphorus in the PU foams increased the thermal stability properties. Using 100% ESBO-DYM …

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Improving The Water Solubility Of Cannabidiol Using A Peptide Carrier, Melek Parlak Khalily Apr 2024

Improving The Water Solubility Of Cannabidiol Using A Peptide Carrier, Melek Parlak Khalily

Turkish Journal of Chemistry

Cannabidiol (CBD), nonpsychotropic cannabinoid found in Cannabis sativa, is a very promising drug candidate offering many differential effects such as sedative, antiinflammatory, antioxidant, and neuroprotective properties. Nevertheless, the therapeutic use of CBD is hindered by its lack of water solubility and relatively low bioavailability. Various carriers have been used to address the solubility issues of CBD and other highly lipophilic drugs so far. However, self-assembled peptide nanostructures as carrier have not been used to improve the water solubility of CBD yet. In this study, a self-assembling peptide micelle was demonstrated to be an effective vehicle for encapsulation of CBD and …

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Computational Drug Repurposing Effort For Identifying Novel Hits For The Treatment Of Diseases Such As Endometriosis, Uterine Fibroids, And Prostate Cancer, Ahmet Buğra Ortaakarsu, Hi̇lal Medetali̇beyoğlu Apr 2024

Computational Drug Repurposing Effort For Identifying Novel Hits For The Treatment Of Diseases Such As Endometriosis, Uterine Fibroids, And Prostate Cancer, Ahmet Buğra Ortaakarsu, Hi̇lal Medetali̇beyoğlu

Turkish Journal of Chemistry

This research aimed to identify potential drug compounds from the ZINC15 molecule database that could effectively treat GnRH1R-related diseases. The study utilized molecular docking and molecular dynamics methods to achieve this goal, which is crucial in drug repurposing research. The virtual screening process involved analyzing known drug compounds using molecular docking. Additionally, molecular dynamics simulations and MM-GBSA were employed to evaluate the stability of the complexes and determine the interactions between the compounds and protein structure. As a result, this study provides significant insights for treating diseases such as endometriosis, uterine fibroids, and prostate cancer related to GnRH1R. The study …

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Hummers’ Method-Assisted Liquid-Phase Exfoliation Enables The Fabrication Of Few-Layer Borophene From Bulk Boron, Mehmet Semih Bingöl, Mehmet Yilmaz, Ahmet Emre Kasapoğlu Apr 2024

Hummers’ Method-Assisted Liquid-Phase Exfoliation Enables The Fabrication Of Few-Layer Borophene From Bulk Boron, Mehmet Semih Bingöl, Mehmet Yilmaz, Ahmet Emre Kasapoğlu

Turkish Journal of Chemistry

The fabrication of few-layer borophene (BP) from bulk boron (b-B) is of great importance and still a scientific challenge due to the complex structure and crystallinity of b-B. Herein, we propose a novel technique to prepare a few-layer BP on a large scale with a large lateral size in a well-controlled manner. For this, we employed the Hummers’ method-assisted liquid-phase exfoliation. In the first step, the chemical exfoliation of the b-B as a precursor was performed by the modified Hummers’ method. After chemical exfoliation, mechanical delamination was employed by using an immersion sonicator. Finally, BP sheets were collected with dimensions …

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Supramolecular Solvent-Based-Vortex-Assisted-Dispersive Liquid Liquid Microextraction Of Sudan Black B In Food Samples Prior To Spectrophotometric Detection, Fi̇gen Erek, Mustafa Tüzen Apr 2024

Supramolecular Solvent-Based-Vortex-Assisted-Dispersive Liquid Liquid Microextraction Of Sudan Black B In Food Samples Prior To Spectrophotometric Detection, Fi̇gen Erek, Mustafa Tüzen

Turkish Journal of Chemistry

A new, simple and rapid spectrophotometric method was developed for determination of Sudan Black B in food products by supramolecular solvent-based-vortex-assisted-dispersive liquid liquid microextraction (SUPRAS-VA-DLLME). Extraction solvent type, volume of solvent, pH, volume of THF, centrifugation time, vortex time, and sample volume were investigated as optimization parameters of the developed method. Under the optimum conditions, limit of detection and limit of quantification, preconcentration factor and enhancement factor of the developed method were calculated to be 9.01 µg L–1, 29.73 µg L–1, 20, and 55, respectively. The developed microextraction method was successfully applied to food samples for the determination of Sudan …

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Evaluation Of P(Hema-Co-Nipam) Hydrogels For Removal Of Methylene Blue From Aqueous Solution:Isotherm, Kinetic, And Thermodynamic Studies, Hayri̇ye Mi̇ne Antep, Müni̇re Nalan Demi̇r, Cevher Gündoğdu Hizliateş, Si̇mge Öztürk, Eli̇f Esen Apr 2024

Evaluation Of P(Hema-Co-Nipam) Hydrogels For Removal Of Methylene Blue From Aqueous Solution:Isotherm, Kinetic, And Thermodynamic Studies, Hayri̇ye Mi̇ne Antep, Müni̇re Nalan Demi̇r, Cevher Gündoğdu Hizliateş, Si̇mge Öztürk, Eli̇f Esen

Turkish Journal of Chemistry

In this study, a novel adsorbent material, poly (2-hydroxyethyl methacrylate-co-N-isopropyl acrylamide) (p(HEMA-co-NIPAM) hydrogel, was synthesized for the purpose of removing methylene blue (MB) from aqueous media. The synthesis of hydrogel was carefully conducted, and its properties were thoroughly examined using techniques such as Fourier-transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), and thermogravimetric analysis (TGA). The adsorption experiments conducted revealed a remarkable affinity of p(HEMA-co-NIPAM) hydrogel towards MB. The highest adsorption was observed when 0.05 g of the adsorbent were utilized, with optimal conditions at a pH of 6.0 and a temperature of 15 °C. This underscores the importance of …

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Investigation Of Benzoic Acid And Sorbic Acid Concentrations In Tomato Paste, Pepper Paste, Ketchup, Mayonnaise, And Barbeque Sauce Samples By Headspace Gas Chromatography-Mass Spectrometry, Orhan Destanoğlu Apr 2024

Investigation Of Benzoic Acid And Sorbic Acid Concentrations In Tomato Paste, Pepper Paste, Ketchup, Mayonnaise, And Barbeque Sauce Samples By Headspace Gas Chromatography-Mass Spectrometry, Orhan Destanoğlu

Turkish Journal of Chemistry

In this study, it was aimed at investigating benzoic acid (BA) and sorbic acid (SoA) concentrations in tomato paste, pepper paste, ketchup, mayonnaise, and barbeque sauce samples by a validated static headspace gas chromatography–mass spectrometry (GC-MS) method. Salicylic acid (SalA) was used as internal standard and the measurements were conducted in the wide linear concentration ranges of BA and SoA which were 2.5–5000 and 12.5–5000, respectively. The limit of detections (LODs) were determined to be 1.5 and 4.5 mg/kg while the limit of quantifications (LOQs) were 2.5 and 12.5 mg/kg for BA and SoA, respectively. The average recovery% values of …

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Construction Of Hyperbranched Imprinted Nanomaterials For Selective Adsorption Of Cadmium (Ii), Sheng Nan Hu, Xinyu Zhang, Ming Guo, Shengchun Wu, Wenjun Lu Apr 2024

Construction Of Hyperbranched Imprinted Nanomaterials For Selective Adsorption Of Cadmium (Ii), Sheng Nan Hu, Xinyu Zhang, Ming Guo, Shengchun Wu, Wenjun Lu

Turkish Journal of Chemistry

A hyperbranched ion-imprinted polymer (IIP) material containing multiple selective adsorption sites was synthesized using halloysite nanotubes, methyl acrylate, and ethylenediamine in the presence of a template ion [i.e. Cd (II) heavy metal]. The successful preparation of the Cd-IIP composition was confirmed by FT-IR, XRD, TEM, TGA, and elemental analysis. The polymers exhibited good adsorption of Cd (II) with a maximum adsorption capacity of 64.37 mg·g–1. The imprinting factor (α) for Cd (II) was 2.62 and the selection factor (β) was 1.78, indicating a specific adsorption of Cd (II) ion. The selection coefficients of Cd-IIP for Cd (II)/Pb (II), Cd (II)/Cu …

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Transdermal Delivery System To Release Phthalocyanine Photosensitizers For The Potential Treatment Of Skin Cancer With Pdt, Meryem Çamur Demi̇r, Fatma Kurşun Baysak, Caner Yahya Boyar, Ali̇han Toksoy, Fati̇h Algi Apr 2024

Transdermal Delivery System To Release Phthalocyanine Photosensitizers For The Potential Treatment Of Skin Cancer With Pdt, Meryem Çamur Demi̇r, Fatma Kurşun Baysak, Caner Yahya Boyar, Ali̇han Toksoy, Fati̇h Algi

Turkish Journal of Chemistry

This research aims to examine the transdermal release of water-soluble indium and zinc metallo phthalocyanine (InPc and ZnPc) compounds from the poly(vinyl alcohol) (PVA) membrane and the cytotoxicity effect of these Pcs on normal mouse fibroblasts (L929 fibroblast) and human melanoma (SK-MEL-30) cells. For this purpose, the effects of temperature, pH, drug concentration and membrane thickness on transdermal release were investigated in order to obtain the optimum transdermal release profile by preparing PVA membranes with different thicknesses and crosslinked by heat treatment. Optimum drug release was found to be 85.36% using 6 µm thick PVA membrane at 37 ± 0.5 …

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Graphene Aerogels: Part 2 - Derived From Commercial Graphene And Chemically Reduced Graphene Oxide Via Supercritical Carbon Dioxide Drying, Meryem Samanci, Ayşe Bayrakçeken Apr 2024

Graphene Aerogels: Part 2 - Derived From Commercial Graphene And Chemically Reduced Graphene Oxide Via Supercritical Carbon Dioxide Drying, Meryem Samanci, Ayşe Bayrakçeken

Turkish Journal of Chemistry

Graphene aerogels (GAs), the most important class of carbonaceous aerogels, have attracted attention of many researchers due to their superior physical and chemical properties. In this study, commercial graphene (GR) and chemically reduced graphene oxide (RGO) were used as graphene-based precursor materials, unlike graphene oxide (GO), which is widely used in the literature in GA synthesis. GAs were synthesized using the sol-gel technique and dried with supercritical carbon dioxide (SCCO2). In addition, graphene-based materials were used in different ratios and their distribution in the aerogel matrix and its effect on surface properties were investigated. In addition, the synthesized GAs were …

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Performance Test Of Zn-Astaxanthin Complex-Sensitized Solar Cell: Effect Of Light Intensity On Open-Circuit Voltage And Short-Circuit Current Values, Septiani Septiani, Winda Rahmalia, Thamrin Usman Apr 2024

Performance Test Of Zn-Astaxanthin Complex-Sensitized Solar Cell: Effect Of Light Intensity On Open-Circuit Voltage And Short-Circuit Current Values, Septiani Septiani, Winda Rahmalia, Thamrin Usman

Turkish Journal of Chemistry

The sensitizer is one of the most essential dye-sensitized solar cell (DSSC) components. In the present research, a Zn-astaxanthin complex was investigated as a sensitizer, compared to pure astaxanthin. The complex with a 1:1 mole ratio between astaxanthin and Zn2+ was synthesized in a reflux reactor at 37–60 °C. The product was analyzed using Proton Nuclear Resonance (1H-NMR), which indicates the presence of chelate formation between Zn2+ with two atoms of oxygen on the terminal cyclohexane ring of astaxanthin. The interaction of sensitizers (astaxanthin and Zn-astaxanthin) on the photoelectrode surface in this study was analyzed using a Fourier Transform Infra-Red …

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