Physical Sciences and Mathematics Commons^™

Crystal Structures Of Metal Sulfonates, Jon Lyle Obrecht

Masters Theses

Designing new materials with predictable chemical and physical properties has long been a goal of synthetic chemists. The functional properties of molecular compounds are intimately tied to the underlying chemical framework. In addition to atom selection and chemical connectivity, the spatial organization of the molecules often contributes to the function of materials. Because crystals are constructed of periodic arrays of components (i.e. atoms or molecules) with structures easily assessed via X-ray diffraction, crystalline materials offer ideal candidates to explore the relationship of component selection and crystal packing to material property.

One such property that has been extensively examined by …

Evaluating The Effectiveness Of The All Power Labs Power Pallet As A Training Tool For Biomass Gasification Education, Christopher Che Frederick

Masters Theses

The purpose of this study was to provide a better understanding of classroom training with regard to renewable energies. A lecture series and survey were developed by the principle researcher and presented to students in the Alternative and Renewable Energy Systems class and Machine Design class at Eastern Illinois University. The lecture series introduced students to biomass gasification and its application at Eastern Illinois University. The survey analyzed participant's level of knowledge of gasification technologies. The survey's pre and post test scores were used to validate the effectiveness of the training.

The All Power Labs Power Pallet was utilized as …

3d Seismic Data Interpretation Of Boonsville Field, Texas, Aamer Ali Alhakeem

Masters Theses

"The Boonsville field is one of the largest gas fields in the US located in the Fort Worth Basin, north central Texas. The highest potential reservoirs reside in the Bend Conglomerate deposited during the Pennsylvanian. The Boonsville data set is prepared by the Bureau of Economic Geology at the University of Texas, Austin, as part of the secondary gas recovery program. The Boonsville field seismic data set covers an area of 5.5 mi². It includes 38 wells data. The Bend Conglomerate is deposited in fluvio-deltaic transaction. It is subdivided into many genetic sequences which include depositions of sandy conglomerate representing …

Broad-Spectrum Antibacterial Properties Of Metal-Ion Doped Borate Bioactive Glasses For Clinical Applications, Megan Ottomeyer

Masters Theses

"Bioactive glasses with antimicrobial properties can be implemented as coatings on medical devices and implants, as well as a treatment for tissue repair and prevention of common hospital-acquired infections such as MRSA A borate-containing glass, B3, is also undergoing clinical trials to assess wound-healing properties. The sensitivities of various bacteria to B3, B3-Ag, B3-Ga, and B3-I bioactive glasses were tested. In addition, the mechanism of action for the glasses was studied by spectroscopic enzyme kinetics experiments, Live-Dead staining fluorescence microscopy, and luminescence assays using two gene fusion strains of Escherichia coli.

It was found that gram-positive bacteria were more …

Assessment Of An Enterprise Employee Portal Using Dashboard Monitoring System: A Case Study, Aditi Mishra

Masters Theses

"A portal is a browser-based application that provides a web platform for users to improve inter-department collaboration and customer service. Portals are classified either as internal facing portals or external public facing portals. This study addresses the problems facing an internal portal related to its contents, functions and usability and provides a list of essential contents and functions that it should include through integrating theories and industry best practices. The theory framework is based on literature review and the industry best practices are based on the analysis of a number of internal portals of companies used as case studies. These …

Hybridizing And Applying Computational Intelligence Techniques, Jeffery Scott Shelburg

Masters Theses

"As computers are increasingly relied upon to perform tasks of increasing complexity affecting many aspects of society, it is imperative that the underlying computational methods performing the tasks have high performance in terms of effectiveness and scalability. A common solution employed to perform such complex tasks are computational intelligence (CI) techniques. CI techniques use approaches influenced by nature to solve problems in which traditional modeling approaches fail due to impracticality, intractability, or mathematical ill-posedness. While CI techniques can perform considerably better than traditional modeling approaches when solving complex problems, the scalability performance of a given CI technique alone is not …

Efficient Integrity Verification Of Replicated Data In Cloud, Raghul Mukundan

Masters Theses

"The cloud computing is an emerging model in which computing infrastructure resources are provided as a service over the Internet. Data owners can outsource their data by remotely storing them in the cloud and enjoy on-demand high quality services from a shared pool of configurable computing resources. By using these data storage services, the data owners can relieve the burden of local data storage and maintenance. However, since data owners and the cloud servers are not in the same trusted domain, the outsourced data may be at risk as the cloud server may no longer be fully trusted. Therefore, data …

Physics Faculty Use Of Example Solutions In Teaching Introductory Physics, William O. Mamudi

Masters Theses

This study investigates how physics faculty perceive and use features of example problem solutions. Thirty physics instructors from diverse institutions participated in semi-structured interviews. In addition to open-ended questions, three example problem solution artifacts were used to focus on specific solution features. Data were analyzed to identify instructors’ goals for the use of example solutions and whether their goals were consistent with the solution features that they valued and used. The study concludes that many faculty have three major goals: keeping students cognitively involved, helping students become better problem solvers, and supporting students in learning physics. The study also found …

Characterizing The Internal Architecture Of Upper Bone Spring Limestone Turbidites And Mass-Transport Deposits (Mtds) Utilizing High-Resolution Image Log Technology, Jason J. Asmus

Masters Theses

Characterization of reservoir scale (less than 1 meter thick) turbidites and mass-transport deposits (MTDs) using conventional subsurface data is complex, due to millimeter-centimeter scale architectural heterogeneity exhibited by these deposits.

Limited studies of the Bone Spring carbonate turbidites and MTDs within the Delaware Basin subsurface emphasized the use of conventional wire-line log and seismic data to evaluate reservoir potential of such strata. As a result, limited resolution offered by these data sets do not allow for accurate characterization of reservoir, and sub-reservoir scale, architectural and compositional variations.

The present investigation integrates high-resolution (centimeter scale) electrical borehole image logs with conventional …

Stratigraphic Framework For Deposits Of The Saginaw Lobe, Barry And Calhoun Counties, Michigan, Usa, Stephanie K. Ewald

Masters Theses

Between 2006 and 2012, twelve rotasonic borings were drilled in Barry and Calhoun Counties, south central Michigan, as part of several Great Lakes Geological Mapping Coalition projects. Natural gamma ray logs were collected at every location and a detailed description and textural analysis was completed for seven of these cores. Five of the seven analyzed cores reached bedrock. Six of the seven borings were drilled north of the Kalamazoo Moraine of the Saginaw Lobe, which was constructed during retreat of the lobe after the Late Glacial Maximum. Five borings, drilled in tunnel valleys, indicate an increase in depth of tunnel …

Faunal Distribution And Relative Abundance In A Silurian (Wenlock) Pinnacle Reef Complex - Ray Reef, Macomb County, Michigan, Jennifer L. Trout

Masters Theses

Niagaran (Silurian) reefs are important sources of hydrocarbons in the Michigan Basin. In addition, some of these reservoirs have been used for gas storage and may be potential CO2 sequestration sites.

Despite extensive research on Niagaran reefs, most studies concerning faunal abundance and distribution have been qualitative studies conducted by paleontologists with an emphasis on taxonomy, paleoecology, and evolution.

This study is the first quantitative study of relative abundance and general distribution of fauna throughout a single Wenlock reef located in the southern trend of the Michigan Basin. This study will build on previous work done by WMU students and …

Privacy And Security Issues In Iot Healthcare Applications For The Disabled Users A Survey, Wassnaa Al-Mawee

Masters Theses

Aging of the population resulted in new challenges for the society and healthcare systems. Ambient Assisted Living (AAL) that depends on Internet of Things (IoT) provides assistance to the disabled people and supports their vital daily life activities. Affordability of and accessibility to AAL and the usage of IoT starts revolutionizing healthcare services. This Thesis is a survey of the privacy and security issues in IoT healthcare applications for the disabled users. Introduction includes definitions of privacy and security terms, and discusses their relationship. Then, it presents an overview of the IoT, including its architecture and components. Next, the Thesis …

The Effects Of Replacing Dispersed Trash And Recycling Bins With Integrated Waste Receptacles On The Accuracy Of Waste Sorting In An Academic Building, Katherine J. Binder

Masters Theses

Numerous researchers and theorists have attempted to explain the existence of the gap between the possession of environmental knowledge and awareness and the display of pro-environmental behavior (Glasser, 2007; Kollmuss & Agyeman, 2002). Behavior analysis is uniquely aligned to contribute to this discussion through its emphasis on the role of controlling variables in behavior change. A growing number of behavioral research studies address the challenges of group-contingencies in an effort to solve real-world gaps (Lehman & Geller, 2004). This study was designed as a continuation of the line of behavioral research designed to increase recycling rates and also as an …

Equipment Qualification Of Ion Mobility Spectrometry And Method Development And Validation For Pharmaceutical Equipment Cleaning Validation, Amy Lee Heiser

Masters Theses

Ion mobility spectrometry (IMS) instrumentation has been identified as a suitable technology for the detection and reporting of drug product and detergent residues from pharmaceutical manufacturing equipment. Ion mobility is not a new technology, but is entering the field of cleaning validation because of tightened requirements from the US Food and Drug Administration (FDA).

The purpose of this thesis is to outline a practical implementation of the analytical technique, Ion Mobility Spectrometry in a cleaning validation program. Ion Mobility Spectrometry (IMS) is fast and specific for the analysis of small organic molecules and has been gaining popularity in the pharmaceutical …

Direct Analysis Of Hops By Leaf Spray And Paper Spray Mass Spectrometry, Kari Blain

Masters Theses

The objective of this research is to develop a new and innovative method of hops analysis, which is much faster than standard testing methods, as well as reduce the amount of consumables and solvent used. A detailed discussion on the development of an ambient ionization mass spectrometry method called paper spray (PS-MS) and leaf spray (LS-MS) mass spectrometry will be presented. This research investigates the use of PS-MS and LS-MS techniques to determine the α- and β- acids present in hops. PS-MS and LS-MS provide a fast way to analyze hops samples by delivering data as rapidly as a UV-Vis …

The Dissemination And Effective Use Of Physics Education Research In Undergraduate Instruction, Trevor Stefanick

Masters Theses

Based on the results of a national survey of physics faculty, a set of interviews was conducted of 70 physics faculty from a diverse set of institutions. The interviews included questions about the dissemination and effective use of curricula and instructional strategies based on Physics Education Research (PER), focused to obtain recommendations to the PER community that might help to spread the use of these PER-based materials. Approximately half of the interviews (those with faculty who indicated knowledge about or use of Peer Instruction) have been previously analyzed. This project is the analysis of the 38 interviews that were conducted …

Reservoir Characterization And Enhanced Oil Recovery Potential In Middle Devonian Dundee Limestone Reservoirs, Michigan Basin, Usa, Abrahim Abduslam

Masters Theses

Middle Devonian Rogers City and subjacent Dundee Limestone formations have combined oil production in excess of 375 MMBO. In general, hydrocarbon production occurs in two distinct reservoir types: 1) bottom water drive, fractured dolomite reservoirs in the Rogers City and 2) gas expansion drive, depositional facies controlled limestone reservoirs of the Dundee.

The main objective of this study is to evaluate the enhanced oil recovery (EOR) potential in Dundee Limestone reservoirs on the basis of detailed geological reservoir characterization in several fields in the Michigan Basin. Seven main depositional facies were identified from core studies in six fields. Three of …

Synthesis Of 1,1-Dialkyhydrazines And Their Hydroxyl Radical Degradation In Aqueous Environments, Benjamin F. Strong

Masters Theses

Determination of hydroxyl radical rate constants are essential to ensure adequate degradation of contaminants in wastewater. Hydrazines are an important class of organic contaminants and are the focus of this research. Ten 1,1-dialkylhydrazines are synthesized by the zinc reduction of the corresponding N-nitrosamines. Their hydroxyl radical rate constants are determined using the linear accelerator at the Notre Dame Radiation Laboratory at pH 4, 7, and 10.

Their rate constants are found to depend on the protonation state of the molecule. At pH 4 the molecules are fully protonated and hydrogen atom abstraction is favored from the alkyl chains. At …

Geophysical And Remote Sensing Applications For A Better Understanding Of The Structural Controls On Groundwater Flow In The Lucerne Valley, California, Dale R. Dailey

Masters Theses

An integrated study was conducted in the Mojave Basin to investigate the potential role of faults and basement uplifts for groundwater flow in the Mojave Desert. Observations made include: 1) Very Low Frequency (VLF) measurements across mapped (using LIDAR and Geoeye-1 imagery) fault traces showed significant radio field dip angles indicative of presence of shallow sub-vertical, sheet-like conductors; many of the VLF tilt peaks coincided with changes in the magnetic profiles; 2) Vertical Electric Soundings indicate shallow basement west of, and parallel to, the Helendale Fault and deep saturated zones east of the fault/basement outcrop (F/B); and 3) isotopic analyses …

Integrating Depositional Facies And Stratigraphy In Characterizing Hydrothermal Dolomite Reservoirs: Trenton Group Of The Albion-Scipio Trend, Michigan, Marcel R. Robinson

Masters Theses

Reservoir characterization of carbonate rocks requires understanding the role of depositional and diagenetic parameters in reservoir distribution. This is especially true for the diagenetically-altered and structurally-influenced Trenton-Black River reservoirs of the Michigan Basin. Evaluating the depositional evolution and reservoir characteristics of component depositional facies through modeling and stratigraphic reconstruction would aid in exploration and characterization through providing a prediction tool for reservoir distribution, both within and outside of the Michigan Basin.

Results indicate that reservoir development is controlled by primary rock fabric related to depositional facies. Depositional and stratigraphic reconstructions show facies distribution trends occur consistently and therefore predictably away …

A Localized Investigation Of High Resolution Groundwater Flow Properties Of The Saginaw Aquifer Mason, Michigan, Amanda Hayden

Masters Theses

High resolution groundwater models can aid in better management of groundwater resources through more accurate characterization and quantification of aquifer systems. Detailed assessments of flow properties in the context of sedimentary facies can provide high quality data input for more accurate groundwater models.

The Pennsylvanian Grand River and Saginaw bedrock formations comprise the Saginaw Aquifer located in the Lansing, Michigan Tri-County region. The Saginaw Aquifer consists of a predominately shale and sandstone successions. These sandstone facies range up to 40 meters thick, and supply a significant amount water resources to the Lansing Tri-County area. Data used in this study was …

Evaluating The Effects Of Lithofacies And Thin Shales On The Lateral Distribution Of Hydrothermal Dolomite Reservoirs In The Michigan Basin, Peter J. Feutz

Masters Theses

The southern Michigan Basin contains numerous hydrothermal dolomite hydrocarbon fields, including the giant Albion-Scipio Field. The fields typically encompass narrow zones of faulting and fracturing which have been altered from a tight host limestone into a more porous and permeable dolomite by upward-moving hydrothermal fluids. Alternating layers of dolomite that spread laterally away from the main vertical fault conduits imply that structure alone may not define the resulting reservoir architectures within the region. A detailed analysis of primary depositional facies and thin shale seams suggests that secondary stratigraphic controls play a significant role in the development of reservoir rock within …

The Variation Of Hydrogen Concentration In Ni/Mgh Thin Film With Temperature, Rex Nyadaufe Taibu

Masters Theses

The thermal stability of Ni/MgH thin film deposited on Si substrate by Unbalanced Magnetron Physical Vapor Deposition has been investigated using Ion Beam analysis (DBA) techniques. Rutherford Backscattering Spectrometry (RBS) and Non-Rutherford Backscattering Spectrometry (NRBS) have been used to find the composition of Magnesium, Nickel and Oxygen. Elastic Recoil Detection Analysis (ERDA) has been used to determine the concentration of hydrogen at each level of heating. Heating was done in the Ultra High Vacuum (UHV) environment using a non gassy button heater. Ni/MgH sample had lost most of its hydrogen after being heated to a temperature of about 125°C in …

Dibenzimidazolium Salts And Their Interactions With 1,5-Dinaphtho-38-Crown-10, David B. Bernthal

Masters Theses

The use of imidazolium salts in mechanically interlocked molecules, like pseudorotaxanes, is of interest because they can be functionalized with side arms that allow for coordination chemistry. It has been previously shown that tetraakylbenzobisimidazolium salts successfully thread through crown ethers, such as 15DN38C10 or BPP34C10, to form pseudorotaxanes. As an extension of the results that were gathered about this novel template, it was our goal to explore the degree to which larger imidazolium salts interact with such crown ethers. This research focused on the interactions between 15DN38C10 and dibenzimidazolium cations that were tetra-substituted with methyl groups, butyl groups, and benzyl …

Internal Motion In Weakly Bound Halomethane Complexes, Amelia J. Thomas

Masters Theses

A complementary blend of computational and spectroscopic methods has been used to analyze three halomethane complexes which exhibit different types of internal motion. In CH2FrCO2, the CH2F2 undergoes a "rocking" motion which inverts the dipole moment component along the c axis. For thjs complex, the spectra of six isotopologues were measured and an experimental structure was determined (see figure). The barrier to inversion was 142(3) cm·1 based on an experimental AE (AE is the energy difference between v=0+ and v=ff), which is in good agreement with the ab imtio ZPE-corrected barrier of 122 cm •1 . Upon comparison with similar …

An Application Of Optical Tweezers, Patrick W. Swanson

Masters Theses

Oxycyte is a perfluorocarbon-based material that can mimic the oxygen carrying capabilities of hemoglobin and is in the testing stages of acting for use as a blood substitute. However, a problem associated with using Oxycyte as a blood substitute is that it clumps together too easily and does not coagulate. An approach for studying the problem uses optical tweezers to help model the forces between Oxycyte particles. Elements of optical tweezers, including laser beams, microscopes, and operation by trapping particles with light will be outlined. An experimental system created to study the forces between particles is presented. Experimental issues and …

Educational Technology: Podcasts, Vodcasts, And Blogs In The Science Classroom, Danielle N. Thompson

Masters Theses

Junior-level Chemistry students at De Soto High School, Missouri, were introduced to educational technology in the form of podcasts, vodcasts, and blogs to facilitate learning outside of the traditional four walls of the classroom. Educational technology was utilized to see if content knowledge could be delivered from the teacher to the students as well as from the students to the teacher. Students were surveyed eight weeks after educational technology was introduced in the classroom to see if participation, attitudes, and interests in science were influenced by the use of educational technology in addition to traditional pedagogical methods.

Robust Evolutionary Algorithms, Brian Wesley Goldman

Masters Theses

"Evolutionary Algorithms (EAs) have shown great potential to solve complex real world problems, but their dependence on problem specific configuration in order to obtain high quality performance prevents EAs from achieving widespread use. While it is widely accepted that statically configuring an EA is already a complex problem, dynamic configuration of an EA is a combinatorially harder problem. Evidence provided here supports the claim that EAs achieve the best results when using dynamic configurations. By designing methods that automatically configure parts of an EA or by changing how EAs work to avoid configurable aspects, EAs can be made more robust, …

Under Pressure: A Psychophysiological Analysis Of The Effect Of Temporal Constraints On Information Processing And Decision Making, Nagaratna Krishna Sneha Pochinapeddi

Masters Theses

"In recent times, decision making under time pressure has become more common than ever and hence, it has become a hot topic for behavioral researchers. This research studies the effects of temporal constraints on users' decision quality and decision strategy. The paper primarily addresses two research questions: (i) Does time pressure affect decision quality? (ii) Does time pressure affect decision strategy? The decision accuracy and decision strategy of the participants were measured for three time-pressure conditions namely, No time pressure, Reasonable time pressure and Extreme time pressure. Research results from the past revealed that, Cognitive style is also observed to …

Palynomorph And Palynofacies Assemblages Of Neutral-Alkaline And Acid Lakes South Of Norseman, Southern Western Australia, Lutfia Grabel

Masters Theses

"The Yilgarn Craton in Western Australia hosts hundreds of shallow ephemeral hypersaline lakes, the majority of which have acid to neutral pH values. As part of a multidisciplinary study of the evolution of hypersalinity and acidity in the region, three drill cores were studied for their palynofacies and palynomorph contents in order to characterize palynofloral response to environmental changes. Drill cores from two acid lakes, Prado Lake (PL1-09 and PL2-09) and Twin Lake West (TLW1-09), and the neutral-alkaline Gastropod Lake (GLE1-09) south of Norseman recovered Miocene to Holocene sediments of the Revenge and Polar Bear formations. Transmitted light microscopy was …