Physical Sciences and Mathematics Commons^™

Ethical Ambivalence In Local Television Weathercasting: A Rossian Analysis, Vernon Keith Thompson

Masters Theses

Today’s television weathercasters are being called upon increasingly to go beyond benign weather prognostications to become the “newsroom experts” for science topics. The expectation to act as both scientists and journalists can cause ethical ambivalence (EA), a sociological condition in which, faced with conflicting norms, the subject feels that he/she is being pulled psychologically in two different directions (Jansen & Von Glinow, 1985). This thesis presents a Rossian analysis of climate change in weathercasting, a topic that captures the most important ethical tensions arising from conflicting duties within the weathercaster role, specifically: a) how might the duties of the television …

Integrating Depositional Facies And Sequence Stratigraphy In Characterizing Unconventional Reservoirs: Eagle Ford Shale, South Texas, Seth Jordan Workman

Masters Theses

The Mid-to-Late Cretaceous Eagle Ford Shale of South Texas is a mixed siliciclastic/carbonate, unconventional resource play with considerable oil and natural gas. Characterization of Eagle Ford reservoir quality and potential is made difficult by complex, small-scale heterogeneities.

The limited availability of subsurface data constrains previous subsurface Eagle Ford investigations. As a result, the internal variability of depositional facies and reservoir attributes remain poorly understood for these Eagle Ford rocks.

This investigation incorporates a representative group of four Eagle Ford cores, and core data, from within the current play area in order to: 1) determine facies successions, 2) establish a hierarchal …

Creating Sustainable Economic And Ecological Growth In The Congo Basin: Bushmeat Consumption And Biodiversity Protection, Richelle Lynn Warnock

Masters Theses

This research examines the economic and ecological sustainability of bushmeat hunting in the Congo Basin, specifically the Democratic Republic of Congo and the Republic of Congo. Although bushmeat hunting has provided short term gain for individuals in the region, long term solutions focusing on micro and macro level interventions may provide community wide benefits, while protecting Congo Basin wildlife. Research shows that a focus on the development of key economic sectors such as agriculture, mineral resources and hydroelectricity, as well as the growth of infrastructure may provide viable economic gain for the Congo Basin. Ecotourism and improvements to forest management …

Development And Evaluation Of An Inquiry-Based Unit For Teaching About Paleoclimate And Climate Change, Steven Barone

Masters Theses

The purpose of this action research study is to develop and evaluate a sequence of four lessons for an introductory earth science course taken by future elementary teachers. Action research is a reflective process of data collection and analysis used by teachers to improve their classroom practice. This study’s goal is to produce a series of lessons that align with the course philosophy of student-driven learning through guided-inquiry and are effective at improving students’ understanding of climate change.

Three data sets were used to evaluate the lessons: 1) student knowledge gains on an objective pre- and post-test, 2) students’ self-reported …

Study Of The Insulin Mimetic Sodium Orthovanadate In Glucosamine Induced Insulin Resistnace In Primary Rat Hepatocytes, Kalan Mcpherson

Masters Theses

Insulin resistance and type II diabetes is a disease state characterized by a lack of sensitivity of insulin to provoke a proper response in insulin sensitive tissues. Currently, we utilize glucosamine to increase flux through the Hexosamine Biosynthetic Pathway (HBP) to induce an insulin resistance like state in primary rat hepatocytes. We tested the effectiveness of the insulin mimetic sodium orthovanadate to determine if it could elicit an insulin-like response under these conditions. Mixed results were obtained on the effectiveness of vanadate as an insulin mimetic in this insulin resistant model.

Effectiveness Of Flipping The Classroom In A Honors Level, Mechanics-Based Physics Class, Stephen J. Zownorega

Masters Theses

Concentration in Physical Science

The idea behind "flipping the classroom" is that standard lecture can be sent home with students to view and take notes. Class time that had traditionally been used for presenting lecture information can then be used by the teacher for different teaching methods in class. These teaching methods support what was seen in a video (i.e., screencast) and allows students an opportunity to develop a better understanding of the concepts viewed the night before. During class time the teacher can work individually with students, thus increasing personal contact time between teacher and student. Videos also allow …

Studies Of The Structural Boundaries Of Solid-State Photodimerization Reactions Via Isocoumarins And Heteromeric Assemblies, Mihiri S. Weerasinghe

Masters Theses

The study of molecules in crystals has gained considerable attention in the field of structural chemistry. Much interest has focused on the use of molecular crystals for the construction of materials with specific functional properties. Because the design of such materials requires a critical understanding of intermolecular interactions, use of the building-block approach continues to offer an important strategy to multimolecular frameworks. Though the use of template and metal-ligand interactions has provided successful opportunities to organize chemical reactions in solids, these methods require secondary molecules and are limited to achiral starting materials. As such, exploring chiral synthesis with simplified precursors …

Is Ethanol A Potential Solution To Reducing U.S. Foreign Oil Dependence?, Jasmina N. Patel

Masters Theses

In this study, we estimated the impact of increasing ethanol production on net imports of crude oil in the United States. We also examined whether factors such as com production, population, gross fixed capital formation and the Energy Policy Act of 2005 contributed to an increase in ethanol production. Using time series data from 1981 to 2012, the results of multiple regression models showed that ethanol production was a significant variable and had an inverse relation to net imports of crude oil. Our study also showed that the implementation of the 2005 Act and an increase in com production contributed …

From Half-Rotaxanes To Poly-Rotaxane Architectures, Heather Renee Schoonover

Masters Theses

The host-guest abilities of macrocyclic compounds made them important players in the field of supramolecular chemistry, especially those studying mechanical bonds. Rotaxanes and catenanes are among the most well-known examples of mechanically interlocked molecules. Our approach in the synthesis of poly-rotaxane systems involves the preparation of pseudorotaxanes with donor capabilities and then use metallic centers to assemble the poly-rotaxane architectures.

A pyridine-based half-rotaxane has been synthesized and the subsequent solution studies revealed a large association constant. ¹H-NMR studies show that these interlocked species exhibit a slow exchange on the NMR timescale. Using the single point method and VT-NMR several …

The Effects Of Chemical Treatment And Light Exposure On Pah Concentrations In Biochar, Fathima Nadheesha Muhammed Khalid

Masters Theses

A series of experiments quantifying extractable polycyclic aromatic hydrocarbons (PAHs) in biochar before and after various treatments were conducted. The analytical approach included solvent extraction of PAHs with toluene, further isolation and column cleanup before gas chromatography mass spectroscopy (GC-MS) analysis. The treatment methods include exposing biochar samples to sunlight and UV radiation with and without additives and reacting with hydrogen peroxide.

Two biochar samples from the Eastern Illinois University bench-type gasifier and commercial biochar were analyzed. Analyzing of three biochar types revealed that plant biochar has lower total PAH concentration than wood (W) biochar or wood and plant (giant …

The Effect Of Electrochemical Modification On The Surface Topography And Chemical Make-Up Of Strontium Titanate, Kelly J. Harmon

Masters Theses

Previous research into the oxidation and reduction of strontium titanate and the changes that result from this has been carried out. The oxidation and reduction of strontium titanate at high temperatures and high pressures has been investigated for the effect that it has upon the surface topography of strontium titanate and the chemical makeup of the strontium titanate. Research into the electrochemical oxidation of perovskites, similar in structure to that of strontium titanate, have even provided evidence pointing to the identity of the oxygen species being incorporated into the strontium titanate.

This research seeks to investigate what changes occur to …

Security Analysis Of A Cyber Physical System : A Car Example, Jason Madden

Masters Theses

"Deeply embedded Cyber Physical Systems (CPS) are infrastructures that have significant cyber and physical components that interact with each other in complex ways. These interactions can violate a system's security policy, leading to the leakage of rights and unintended information flow. This thesis will explore information flow as it uses a public channel. In order to exemplify the use of the public channel, a vehicle being composed of the computer system and its operators will show how information is disclosed to an observer. The example is made up of a vehicle traveling across some terrain with an observer watching the …

Immersed Finite Element Method For Interface Problems With Algebraic Multigrid Solver, Wenqiang Feng

Masters Theses

"This thesis is to discuss the bilinear and 2D linear immersed finite element (IFE) solutions generated from the algebraic multigrid solver for both stationary and moving interface problems. In contrast to the body-fitting mesh restriction of the traditional finite element methods or finite difference methods for interface problems, a number of numerical methods based on structured meshes independent of the interface have been developed. When these methods are applied to the real world applications, we often need to solve the corresponding large scale linear systems many times, which demands efficient solvers. The algebraic multigrid (AMG) method is a natural choice …

Search-Based Model Summarization, Lokesh Krishna Ravichandran

Masters Theses

"Large systems are complex and consist of numerous components and interactions between the components. Hence managing such large systems is a cumbersome and time consuming task. Large systems are usually described at the model level. But the large number of components in such models makes it difficult to modify. As a consequence, developers need a solution to rapidly detect which model components to revise. Effective solution is to generate a model summary. Although existing techniques are powerful enough to provide good summaries based on lexical information (relevant terms), they do not make use of structural information (component structure) well. In …

Secure Design Defects Detection And Correction, Wenquan Wang

Masters Theses

"Bad design and software defects often make source codes hard to understand and lead to maintenance difficulties. In order to detect and fix such defects, researchers have systematically investigated these issues and designed different effective algorithms to tackle the problems. However, most of these methods need source codes/models for defect detection and correction. Commercial companies, like banks, may not be willing to provide their source models due to data security. Therefore, it is a huge challenge to detect software detects by a consulting company as well as to keep source models confidential. This thesis analyze security issues in existing approaches …

Lexis In Chemical Engineering Discourse: Analyzing Style In Chemical Engineering Research Articles Through A Rhetorical Lens, David Lamar Young

Masters Theses

"This study examines the style of chemical engineering research articles to discover stylistic trends that may be applicable to authors looking to publish their own research. Rhetorical stylistic analysis was used as a research method to allow for thorough analysis of all articles in the sample. Ten research articles from the two prominent chemical engineering journals were chosen using specific criteria to constitute a sample of articles that could most accurately represent the population of chemical engineering research articles. Each article was then analyzed line by line to identify markers of chemical engineering research article style, including the following: ▬Use …

Wetting And Drying Cycles And The Fungal Communities On Leaf Litter In Streams, Kele Qwinn Thrailkill

Masters Theses

"Leaf litter is a major source of energy for streams in deciduous forests. Fungi play a critical role by converting the leaves into nutritional material for the rest of the food web. The breakdown of leaf litter and associated biota, including invertebrates and fungi, have been proposed as measures of stream health in systems affected by anthropogenic activity. Rates of leaf breakdown can be depressed in streams affected by acidity, metals, organic contaminants, and other stressors. Climate change may lead to alterations in stream hydrology such that streams experience more frequent floods as well as drying episodes. Fungal communities can …

Role Of Nicotine In Oxidative Stress, Rakesh Kacham

Masters Theses

"Nicotine, a major alkaloid, is present in tobacco products as well as in smaller amounts in potatoes, tomatoes, and eggplants. Although it is the addictive compound in cigarettes, nicotine is believed to play a protective role in neurodegenerative disorders such as Parkinson's disease. Researchers have found that the short-term administration of nicotine may help improve the memory process by reducing oxidative stress in the brain. Our studies have shown that, by blocking Fenton's reaction, nicotine is able to inhibit free radical generation, so this research has focused on the antioxidant properties of nicotine. The cell lines of the alveoli, blood …

Statistical Analysis Of Microarray Data In Sleep Deprivation, Stephanie Marie Berhorst

Masters Theses

"Microarray technology is a useful tool for studying the expression levels of thousands of genes or exons within a single experiment. Data from microarray experiments present many challenges for researchers since costly resources often limit the experimenter to small sample sizes and large amounts of data are generated. The researcher must carefully consider the appropriate statistical analysis to use that aligns with the experimental design employed. In this work, statistical issues are investigated and addressed for a microarray experiment that examines how expression levels change over time as individuals are sleep deprived. Over the course of 48 hours of sleep …

Part I: Increased Leaching Of Arsenic, Selenium, Molybdenum, And Vanadium From High Calcium Coal Ash Containing Trona Reaction Products. Part Ii: Using Agricultural Byproduct Rice Hull As Biosorbent To Remove And Recover Metal Ions In Water, Yongbo Dan

Masters Theses

"Part I. The trona is being injected to control SO_x emission from coal-fired power plants. The results showed that trona ash leached significantly more As, Se, Mo, and V than the control fly ash did, especially under the natural pH condition. In addition, trona ash had a significantly greater soluble fraction than the control ash. Further investigation indicated that greater amounts of the studied anionic elements in the trona ash were associated with the soluble, trona reaction products. Moreover, the insoluble fraction of the trona ash lost its capability to adsorb these elements under the natural pH condition. The …

Sybil Detection In Vehicular Networks, Muhammad Ibrahim Almutaz

Masters Theses

"A Sybil attack is one where an adversary assumes multiple identities with the purpose of defeating an existing reputation system. When Sybil attacks are launched in vehicular networks, an added challenge in detecting malicious nodes is mobility that makes it increasingly difficult to tie a node to the location of attacks. In this thesis, we present an innovative protocol for Sybil detection in vehicular networks. Considering that vehicular networks are cyber-physical systems integrating cyber and physical components, our technique exploits well grounded results in the physical (i.e., transportation) domain to tackle the Sybil problem in the cyber domain. Compared to …

Balanced Cross Section Of The Northeast Of Adiyaman, Turkey, Mustafa Tuncer

Masters Theses

"Deformation during closure of an ocean basin and continent-continent collision in southeast Anatolia Turkey during the Late Cretaceous to Middle Miocene was investigated by construction of a geologic map, structural cross-section and retrodeformed palinspastically restored cross-section. The area of study is a N-S transect across the Bitlis Suture Zone of Northeast of Adiyaman. The study area is situated in the southeast Anatolian orogenic belt which includes, from south to north, the Arabian platform, the zone of Imbrication, and the zone of Nappes. A geologic map of this region was prepared in order to construct balanced and restored cross sections from …

A Structural Analysis Of The El Kasr Structure In The Western Desert Of Egypt, Trevor Charles Ellis

Masters Theses

"The El Kasr structure was studied in order to investigate the origins and evolution of the enigmatic Desert Eyes structures of the Western Desert due to its accessibility and uniqueness among the structures. The El Kasr structure, an elongate structural basin with low limb dips, is unique among the "Desert Eyes" structures in that it: 1) occurs in isolation in otherwise horizontal sedimentary rock, 2) the long dimension of the basin is oriented NNW, 3) it is closely spatially associated with the less common NNW fault zones, and 4) is composite in nature. The structure was investigated using remote sensing …

Comparative Evaluation Of N-Acetylcysteine And N-Acetylcysteine Amide In Acetaminophen-Induced Oxidative Stress, Ahdab Naeem Khayyat

Masters Theses

"Acetaminophen (APAP) is the most widely used pharmaceutical analgesic-antipyretic agent in the world, but its toxicity is a common cause of drug-induced hepatotoxicity. With APAP toxicity, cellular glutathione (GSH) is depleted. This results in the availability of N-acetyl-p-benzoquinone imine (NAPQI), is a toxic metabolite of APAP that binds to cellular macromolecules, which leads to cell necrosis. N-acetyl cysteine (NAC), a GSH precursor, is the only approved antidote for an acetaminophen overdose. It is a negatively charged molecule that diminishes its penetration into the cells, thereby requiring fairly high doses that increase the severity of side effects. In addition, oral and …

Shopping Alone Online Vs. Co-Browsing: A Physiological And Perceptual Comparison, Ceren Topaloglu

Masters Theses

"Although shopping is a social activity frequently performed with friends and family members, most online shopping is done alone. With the development of Web 2.0 technologies and the increasing popularity of social networking sites, online social shopping has emerged as a new phenomenon that allows more social interaction, participation, and satisfaction for customers while shopping online. Therefore, companies have started to use social shopping tools in their e-commerce websites to facilitate online social shopping. Co-browsing is one of the more recent online social shopping tools available, enabling users to shop or browse together by offering synchronized web views and chat …

Production Of 1,3-Propanediol From Glycerol Under Haloalkaline Conditions By Halanaerobium Hydrogeniformans, Daniel William Roush

Masters Theses

"With increased demands around the world to make modern lifestyles more environmentally friendly, the chemical commodity market has rapidly shifted. Through new technologies in chemical production, certain high value products have oversaturated the market and have become high-volume, low value waste products. The expansion of biodiesel production offers a prime example; high volumes of glycerol byproduct from this process have shifted glycerol from a high priced commodity to a common waste product. A number of microorganisms are known to synthesize the polymeric precursor 1,3-propanediol from glycerol; however, crude glycerol from biodiesel production creates a harsh environment for most microbes, and …

Women Authors Of Technical Writing Textbooks From 1923 To 1973, Melissa Nicole Wampler

Masters Theses

"The published histories of technical writing textbooks do not usually include many women-authored textbooks. To find out why women-authored textbooks have been marginalized in these pedagogical histories, I selected seven women-authored textbooks and four men-authored textbooks published from 1923 to 1973, investigated the backgrounds of the authors and key features of their textbooks, and used the collected data to compare the women-authored textbooks to the men-authored textbooks. I was not able to find any reason why the women-authored textbooks have been or should be marginalized in histories of technical writing textbooks; however, my study had several limitations. My thesis begins …

Chemical Transformations Of Arylsulfonamide Molecular Crystals, Rajan Giri

Masters Theses

The pursuit of chemical specificity and efficiency of chemical reaction in molecular crystals has attracted considerable attention over the last decade. The successful control of molecular alignment prior to such transformations continues to provide opportunities for near quantitative yields of new materials. This thesis reports the predictable self-assembly of aryl sulfonamide materials constructed from cinnamic acid and phenylpentadienoic acid fragments capable of forming supramolecular dimers that undergo unique photocyclization reactions. Use of racemic and enantiopure single-component building-blocks provides access to enantiocontrolled [2+2] photodimerized products.

Solid-state reaction precursors were prepared using conventional solution-based synthetic organic techniques. Component chirality (racemic or homochiral) …

Determination Of Structural Stabilities Of Metal-Free Porphyrin Cytochrome C, Zinc Cytochrome C, And Cobalt Cytochrome C, Usha K. Tottempudi

Masters Theses

No abstract provided.

Internet Accessible Remote Real-Time Laboratory For Computer Networking Curriculum, Oyindamola Idowu

Masters Theses

Despite the availability of equipment required to teach hands-on laboratory practices in a computer networking curriculum, educators are faced with the challenge of extending such practices to students in remote locations. Distance learning has become a substantial part of the current education system, requiring institutes of learning adjusting from traditional face-to-face courses to content that can be carried out over the internet so that students can complete part or all the requirements for certain courses in an online modality. Unfortunately, traditional networking laboratories were designed with the assumption students will be physically present. This research is aimed to provide at …