Physical Sciences and Mathematics Commons^™

Exploring Multimedia Storytelling As A Novel Tool To Inspire Americans To Participate In Wildlife Conservation, Megan Brief

Masters Theses

Human and nonhuman animal lives are intimately entangled. In the age of the Anthropocene, it is imperative to reexamine our proximity and kinship with nature. Human-wildlife conflict can evolve into coexistence through conservation efforts marked by creativity and compassion. To inspire conservation action among North American audiences, we must enact novel ways of disseminating scientifically technical concepts. Multimedia storytelling can encourage equitable involvement among lay participants in conservation spaces. When inclusive of Indigenous knowledges, and conscious of damage narratives, such innovative stories can empathetically communicate wildlife degradation and injustices, as well as animate vulnerable human and nonhuman communities.

Growing Quelites In The City: Exploration On Memory And Food Sovereignty In Mexico City, Paola Valeria Ramirez Ensastiga

Masters Theses

In Mexico, as in the world, the number of people living in urban areas is increasing. In addition, urbanization directly generates a fragmentation of the natural habitat and causes the loss of biodiversity. Native edible crops are also being threatened by a constant decline in biodiversity, causing negative ecological, economic and even cultural impact. Until now, the main guardians of the edible biodiversity have been indigenous peoples. Several authors agree that the way in which indigeous people relate to nature may shed some light on how to face the ecological and climate crisis that we are experiencing today. I argue …

Agricultural Irrigation Induced Evaporation In A Temperate Study Area: A Stable Isotope Approach, Lincoln Grevengoed

Masters Theses

In regions where groundwater is used for irrigation, significant water losses take place due to evaporation. Previous studies demonstrated the utility of stable oxygen and hydrogen isotopes in estimating evaporative water loss experienced during return flow back to an aquifer. Unlike arid regions where the other studies took place, this study examined the region around Kalamazoo, Michigan, the United States, which experiences a more temperate climate. Irrigation in the Kalamazoo area primarily uses center-pivot systems supplied by wells, unlike flood irrigation in previous study areas. Water samples were taken periodically from wells close to center-pivot irrigation systems. Water losses due …

Confronting Wicked Crypto: Wicked Problems, Encryption Policy, And Exceptional Access Technology, Kevin Nicholas Kredit

Masters Theses

Public debate has resumed on the topic of exceptional access (EA), which refers to alternative means of decryption intended for law enforcement use. The resumption of this debate is not a renege on a resolute promise made at the end of the 1990s “crypto war”; rather, it represents a valid reassessment of optimal policy in light of changing circumstances. The imbalance between privacy, access, and security in the context of constantly changing society and technology is a wicked problem that has and will continue to evade a permanent solution. As policymakers consider next steps, it is necessary that the technical …

Towards Development Of A Remote Charting System For Connected Healthcare, Alex Bodurka

Masters Theses

Health Care Providers play a crucial role in a patients well-being. While their primary role is to treat the patient, it is also vital to ensure that they can spend adequate time with the patient to create a unique treatment plan and build a personal relationship with their patients to help them feel comfortable during their treatment. Health Care Providers are frequently required to manually record patient data to track their healthcare progress during their hospital stay. However, with hospitals continuously trying to optimize their workflows, this crucial one-on-one time with the patient is often not practical.

As a solution, …

Assessing The Robustness And Versatility Of Nanojars For Anion Binding, Mia Lily Ann Jawor

Masters Theses

Supramolecular chemistry is a field in chemistry that focuses on intermolecular bonds in a “host-guest complex” or supramolecular assemblies. Nanojars are supramolecular assemblies of the formula [anion⊂{Cu(μ-OH)(μ-pz)}_n] (n = 27‒33) which incarcerate kosmotropic anions, such as carbonate (CO₃^2‒), sulfate (SO₄^2‒) and hydrogen phosphate (HPO₄^2‒). Nanojars consist of three [Cu(μ-OH)(μ-pz)]_x (x = 6‒14, except 11) rings that are assembled similarly to Matryoshka dolls, where the top and bottom rings act as guests for the central ring. The larger central ring is bound to the two smaller rings by multiple …

A Framework To Support Automatic Certification For Self-Adaptive Systems, Ioannis Nearchou

Masters Theses

Presently, cyber-physical systems are increasingly being integrated into societies, from the economic sector to the nuclear energy sector. Cyber-physical systems are systems that combine physical, digital, human, and other components, which operate through physical means and software. When system errors occur, the consequences of malfunction could negatively impact human life. Academic studies have relied on the MAPE-K feedback loop model to develop various system components to satisfy the self-adaptive features, such that violation of the safety requirements can be minimized. Assurance of system requirement satisfaction is argued through an industrial standard form, called an assurance case, which is usually applied …

Analysis Of Interdunal Wetlands And Ecosystem Dynamics Using Uas And Obia In Ludington State Park, Michigan, Claire Gilbert

Masters Theses

The Great Lakes sand dunes are the world's largest freshwater dune complex. There is a functional relationship between coastal wetlands and freshwater sand dune, referred to as interdunal wetlands. Interdunal wetland systems are highly dynamic and change dramatically seasonally and annually. Using geographic information systems (GIS) and unoccupied aerial systems (UAS), this thesis project is focused on understanding the spatial distribution of sparse and dense vegetation, and abiotic influence such as distance to coast, slope, and aspect influence interdunal wetland stability within a Great Lakes shoreline dune system. Object-based image analysis (OBIA) classification results extracted meaningful vegetation densities of growth …

Using Historical Maps For Contaminated Site Identification And Prediction, And Environmental Justice Implications: A Case Study In Grand Rapids, Michigan, Dana Heusinkveld

Masters Theses

As the production of synthetic chemicals has grown in the past centuries to increase production, lower costs, and generally make our lives more convenient, detecting and understanding the environmental impacts of these compounds has lagged significantly behind their mass production and wide-spread use. To combat this trend, sources of these contaminants, especially those that have been removed from the landscape, need to be quickly identified to make mitigation and remediation efforts more effective. In this study, historical Sanborn maps are used to extract and digitize historical site/land use in Grand Rapids during the early 1900s through the practical application of …

Distribution And Variability In Sulfur Isotopes Within Paleoproterozoic Metasedimentary Strata Of The Michigamme Formation, Upper Peninsula, Michigan, Beau J. Haag

Masters Theses

In the Upper Peninsula of Michigan, the Paleoproterozoic Michigamme Formation is composed of a thick package of metasedimentary rocks derived from foreland basin sediments which were deposited during the 1.8Ga Penokean Orogeny. These rocks contain significant, but variable amounts of texturally distinct sulfide minerals such as pyrrhotite and pyrite. We report a systematic relationship between δ³⁴S values from sulfide mineral occurrences, and their stratigraphic locations regardless of texture and mineral composition. We suggest the sulfide minerals within the Michigamme Formation have inherited δ³⁴S values from early sedimentarydiagenetic sulfides, therefore preserving primary isotopic signatures. The observed stratigraphic …

An Analysis Of Factors Influencing Chemistry Students’ Choice Of Major And Career, Jennifer Marie Ribble

Masters Theses

In recent years there has been a push to increase the number of STEM graduates in the United States in order for the nation to retain its position as a global leader in the sciences. If educators are to address recruitment and attrition issues in STEM fields it is important to understand student perspectives related to choosing both a major and a career in chemistry. The present study explores the decision-making process students utilize to choose chemistry as a major and as a career, their perception of what careers are available to someone with a degree in chemistry and what …

Field And Numerical Evaluation Of Nitrogen Transport From Septic Systems In Surfical Aquifer Systems To Charlotte Harbor, Florida, Tanten T. Buszka

Masters Theses

Shallow water tables in coastal surficial aquifers limit effective treatment of septic effluent which can result in excess nutrient loading into nearby surface water bodies. Approximately 45,000 septic systems in Charlotte County, Florida transmit effluent into an under studied surficial aquifer and contribute to harmful algal blooms and outbreaks of E. coli. An undeveloped field site was characterized using standard hydrogeologic methods, including a one-year duration natural gradient tracer test, to obtain representative lithology of the sandy surficial aquifer and estimates of groundwater velocity, flow directions, effective porosity and dispersion. These data were used to support the development of a …

An Analysis Of Large Displacement Pneumatic Slug Tests For The Characterization Of Aquifer Parameters – Guidelines For An Alternative Field Procedure, Madison E. Wayt

Masters Theses

Variations in hydraulic conductivity (K) between larger scale aquifer tests and smaller scale slug tests, and within individual aquifer tests, have been linked to method bias and aquifer heterogeneity. The impacts of varying slug sizes on K, which represents K dependence on a smaller scale, is not as well understood. To examine the relationship between K and slug size, a series of slug tests with a range of initial displacements were performed in three intermediate to high K, unconfined aquifers encompassing homogeneous, mildly heterogeneous, and moderate to highly heterogeneous conditions. Slug test estimated K values at Asylum Lake are compared …

Evaluation Of The Symbiotic Relation Between Endophyte And Poplar Trees Exposed To Landfill Leachate, Catalina Vega Hurtado

Masters Theses

“The contamination of soil and groundwater from leachate leakage from landfill has turned, nowadays, into a global public issue. One of the main concerns about this pollutant is the potential threat to human and ecosystem health. The current research studied endophyte bacteria in association with poplar trees (Populus sp.), as a method of bioremediation of landfill leachates. The objective of the project was to identify treatment strategies that may improve plant performance (survival rates, plant fitness, and degradation efficacy) with the purpose of being implemented in phytoremediation plots, aimed to intercept and treat landfill leachate, before the contamination of watershed. …

Values Of Artificial Intelligence In Marketing, Yingrui Xi

Masters Theses

“Artificial Intelligence (AI) is causing radical changes in marketing and emerging as a competent assistant supporting all areas of the marketing field. The influences and impacts AI has created in various marketing segments have aroused much interest among marketing professionals and academic scholars. Comprehensive and systematic studies on the values of AI in marketing, however, are still lacking and the existing literature fragmented. This research provides a comprehensive review of the existing literature in the relevant fields as well as a series of systematic interviews using the Value-Focused Thinking approach to understand the values of AI in marketing. This research …

Nanodiamonds And Carbon Nano-Onions Ceramic Composites And Their Applications, Ibrahim Munkaila Abdullahi

Masters Theses

"Luminescent nanodiamonds are photostable non-blinking fluorescent biocompatible, non-toxic, functional Zable materials made from high-pressure high temperature (HPHT) microcrystalline diamonds. For long, the scientific community has been investigating for a clean, efficient and cost-effective technique to reduce the size of fluorescent microcrystalline diamond into nanodiamonds. Their color center, responsible for the fluorescent properties are crucial for their applications, including biomedical imaging, nano sensing, quantum computing etc, and therefore should not be affected significantly by the method of size reduction applied. A novel size reduction technique that is based on explosive fragmentation was developed and the corresponding fragmented diamonds obtained were characterized …

Synthesis And Characterization Of Starburst Pseudorotaxanes And Their Metallic Derivatives, Shalini D. Kadinappulige

Masters Theses

Mechanically Interlocked Molecules (MIMs) are interlocked molecular architectures, characterized by the fact that they are linked through a mechanical bond. Catenanes, rotaxanes, molecular knots, and Borromean rings are typical examples for these molecules. Since MIMs are not connected by covalent bonds, hydrogen bonding, π- π stacking, and/or electrostatic interactions help bring the components together. Dialkyl-ammonium centers, bis(pyridinium)ethane dications, viologen species, and naphthalenediimide π-deficient groups are well known as recognition motifs for crown ethers. In the research described here, we have synthesized several pseudorotaxanes and their tricyclohexyltin metallic derivatives, based on benzobis(imidazolium) (BBI) salts as axles, in combination with the 15DN38C10 …

Attack Detection And Mitigation In Mobile Robot Formations, Arnold Fernandes

Masters Theses

"A formation of cheap and agile robots can be deployed for space, mining, patrolling, search and rescue applications due to reduced system and mission cost, redundancy, improved system accuracy, reconfigurability, and structural flexibility. However, the performance of the formation can be altered by an adversary. Therefore, this thesis investigates the effect of adversarial inputs or attacks on a nonholonomic leader-follower-based robot formation and introduces novel detection and mitigation schemes.

First, an observer is designed for each robot in the formation in order to estimate its state vector and to compute the control law. Based on the healthy operation of the …

Decoupled Finite Element Methods For General Steady Two-Dimensional Boussinesq Equations, Lioba Boveleth

Masters Theses

"This work presents two kinds of decoupled finite element methods for the steady natural convection problem in two dimensions. Firstly, the standard Galerkin finite element method is derived in detail stating algorithms needed for the realization in MATLAB. A numerical example verifies the error convergence. Secondly, using iteration, the Boussinesq equations are decoupled into the Navier-Stokes equations and a parabolic problem. The resulting problems are solved either in parallel or sequentially. Finally, the same numerical example as before is used to confirm the convergence and analyze the methods in terms of iteration performance. In addition to a higher flexibility and …

On Predicting Stopping Time Of Human Sequential Decision-Making Using Discounted Satisficing Heuristic, Mounica Devaguptapu

Masters Theses

“Human sequential decision-making involves two essential questions: (i) "what to choose next?", and (ii) "when to stop?". Assuming that the human agents choose an alternative according to their preference order, our goal is to model and learn how human agents choose their stopping time while making sequential decisions. In contrary to traditional assumptions in the literature regarding how humans exhibit satisficing behavior on instantaneous utilities, we assume that humans employ a discounted satisficing heuristic to compute their stopping time, i.e., the human agent stops working if the total accumulated utility goes beyond a dynamic threshold that gets discounted with time. …

Computer Vision Based Deep Learning Models For Cyber Physical Systems, Muhammad Monjurul Karim

Masters Theses

“Cyber-Physical Systems (CPSs) are complex systems that integrate physical systems with their counterpart cyber components to form a close loop solution. Due to the ability of deep learning in providing sensor data-based models for analyzing physical systems, it has received increased interest in the CPS community in recent years. However, developing vision data-based deep learning models for CPSs remains critical since the models heavily rely on intensive, tedious efforts of humans to annotate training data. Besides, most of the models have a high tradeoff between quality and computational cost. This research studies deep learning algorithms to achieve affordable and upgradable …

Determining Variable Depth To Bedrock Using Ert And Masw: A Geophysical Investigation In St. Louis, Mo, Justin James Clinton

Masters Theses

“The research involves a geophysical study in the Maremec River Valley in St. Louis County, Missouri. The geophysical methods described in this paper can provide a relatively quick, inexpensive, and accurate means in investigating the lithologic characteristics of the subsurface. Method selection is ultimately dependent of the type of investigation and site-specific characteristics. In this investigation, Electrical Resistivity Tomography (ERT) data and Mutli-Channel Analysis of Surface Waves (MASW) data were acquired to image the bedrock beneath the Maremec River to an approximate depth of 110 ft or an elevation of 300 ft for a proposed wastewater tunnel. Two overlapping dipole-dipole …

Characterization Of A Plasma Source Simulating Solar Wind Plasma In A Vacuum Chamber, Blake Anthony Folta

Masters Theses

"The United States has set an aggressive time line to not only return to the Moon, but also to establish a sustained human presence. In the Apollo missions dust was a significant factor, but the duration of those missions was short so dust and surface charging were problems, but they did not pose an immediate threat. For a long-term mission, these problems instead become incredibly detrimental. Because of this, research needs to be conducted to investigate these phenomena so that mitigation techniques can be developed and tested. To this end, this thesis serves to demonstrate the Gas and Plasma Dynamics …

Aquatic Plants And Their Application To Successful Floating Treatment Wetlands, Katherine May Mazanec

Masters Theses

“This research aims to mitigate eutrophication of freshwater habitats affected by urban stormwater runoff. Two highly impacted urban ponds near the Missouri S&T campus in Rolla were the focus of this research on the application of floating treatment wetlands (FTWs). An FTW consists of a man-made floating mat that is planted with emergent or floating macrophytes. The plants grow on the mat and their roots extend into the water column below the mat. Plant tissues, especially roots in direct contact with the water, take up nutrients, act as biofilm growth sites, and may facilitate precipitation of nutrients. With urbanization, ponds …

The Role Of Tectonic Inheritance, Plate-Reorganization, And Magma Flare-Ups In The Evolution Of The Sevier Orogeny, J. Daniel Quick

Masters Theses

"The temporal and spatial distribution of strain associated with the Sevier Orogeny in western North America is significantly different in the southern end of the belt, at the latitude of Las Vegas, than further to the north at the latitude of Salt Lake City. Until this study, reasons for these differences were speculative as a lack of thrust kinematic data in the intervening region hindered along strike correlation across the belt. A crystallization age of 100.18 ± 14 0.04 Ma was determined for zircons extracted from a recently recognized ash fall tuff near the base of the synorogenic Iron Springs …

The Application Of Machine Learning Models In The Concussion Diagnosis Process, Sujit Subhash

Masters Theses

“Concussions represent a growing health concern and are challenging to diagnose and manage. Roughly four million concussions are diagnosed every year in the United States. Although research into the application of advanced metrics such as neuroimages and blood biomarkers has shown promise, they are yet to be implemented at a clinical level due to cost and reliability concerns. Therefore, concussion diagnosis is still reliant on clinical evaluations of symptoms, balance, and neurocognitive status and function. The lack of a universal threshold on these assessments makes the diagnosis process entirely reliant on a physician’s interpretation of these assessment scores. This study …

Quantifying Effects Of Sleep Deprivation On Cognitive Performance, Quang Nghia Le

Masters Theses

“The most commonly used metric for evaluating alertness and vigilance is the Psychomotor Vigilance Test (PVT), previous studies have indicated that alertness and vigilance can be affected by the lack of sleep as a function of sleep loss. This study explores methods to predict median psychomotor vigilance reaction times. The data used in this study comes from a series of tests and surveys conducted on volunteer students. The data set contains many potential predictors of PVT and one aspect of the study was to identify variables that are useful in prediction. The performances of various prediction methods that allow for …

Strain Partitioning Across The Polochic-Motagua Fault System In Guatemala: Insight From Kinematic Modeling, Qiaoqi Sun

Masters Theses

”The Polochic-Motagua Fault System in Guatemala is the on-land segment of the sinistral transform plate boundary between the North American Plate and the Caribbean Plate. Three major seismically active strike-slip faults in this fault system pose significant earthquake threats to surrounding populated cities. The assessment of seismic hazard requires a better understanding of the kinematics of the fault system. GPS monitoring indicates that seventy-five percent of the ~20 mm/yr. plate motion is accommodated by the Motagua Fault and less than twenty-five percent is accommodated by the Polochic Fault. However, the Polochic Fault documents a lateral offset of ~132 ± 5 …

Mineral Compositions Of Meteorite Samples Alha 77005, Nwa 7397, Nwa 5480, And Ausson: Implications For Geodynamic Processes On Their Parent Bodies And Meteorite Reclassification, Kaylin Agnata Tunnell

Masters Theses

“This study investigates the major, minor, and trace element compositions of minerals from a series of meteorites which represent different stages of planetary evolution including two sample from Mars (ALHA 77005 and NWA 7397), one sample from Vesta (NWA 5480), and one ordinary chondrite (Ausson). The goal of this study is to investigate if petrogenetic tracers commonly employed to understand terrestrial samples can also be applied to extraterrestrial samples. The data presented here show that mineral trace element data allow for novel insight into the magmatic history of meteorite samples. For example, V/Sc and Fe/Mn ratios in olivine provide insight …

Design, Synthesis, And Characterization Of Chemical Tools To Study Peroxisomal Import, Jhalak N. Timilsena

Masters Theses

Peroxisomes are dynamic and interconnected single lipid membrane bound organelles found in the eukaryotic cells which are involved in various biochemical processes including the b-oxidation of very long chain and branched chain fatty acids, metabolism of reactive oxygen and nitrogen species, and reduction of hydrogen peroxide among others. These organelles are known to host numerous proteins and enzymes depending on the cellular environment. All of the proteins needed in the peroxisomes are encoded in the nucleus and synthesized in the cytosol which are then transported to the peroxisomes with the help of a sophisticated protein-transport machinery. Pex5 is one of …