Physical Sciences and Mathematics Commons^™

Perturbed Hamiltonian System Of Two Parameters With Several Turning Points, Myeong Joon Ann

Dissertations

No abstract provided.

Electron Emission Following The Interaction Of Slow Highly Charged Ions With Solids, Joseph W. Mcdonald

Dissertations

The interaction of highly-charged ions with surfaces involves many excitation processes of the surface atoms and the bulk material. One such process, the emission of electrons from surfaces due to the potential energy of the incident ions has been studied. The experimental results presented here confirm that the majority of electrons emitted as a result of highly-charged ions interacting with a solid surface have energies of about 20 eV. Auger processes contribute a smaller fraction of the total emitted electrons with increasing Z o f the projectile. This contribution to the total electron emission yield is found to be less …

A Method For The Determination Of Purity Of Pnu-10483 Bulk Drug By Capillary Zone Electrophoresis, Gavin Gibson

Honors Theses

In this investigation, a method was developed for the determination of purity of the drug PNU-10483 using the technique of capillary zone electrophoresis (CZE). CZE was seen as a potential alternative to the formerly used procedure of ion-pair reversed phase highperformance liquid chromatography (HPLC). Nearly five years earlier, a similar study was performed, in which an attempt was made to develop a method that used CZE to determine the purity of bulk drug and the potency of drug tablets. While this development was mostly successful, sporadically unpredictable results reduced the method's overall viability. These outliers were thought to be caused …

A Paleoclimatic Study Of The Midwestern United States From The Stable Isotope Records In Lake Sediments, Norman Alan Lovan

Dissertations

No abstract provided.

Groundwater Hydraulics And Slope Stability Analysis: Elements For Prediction Of Shoreline Recession, William W. Montgomery

Dissertations

Studies documenting the roles that geologic materials and groundwater play in Great Lakes bluff recession are rare. This study reports findings concerning relationships between bluff lithology, bluff hydrology, and bluff recession along a 10-mile stretch of eastern Lake Michigan shoreline in heterogeneous Pleistocene deposes. According to a newly-developed, field-tested, GIS-based methodology, bluffs in the study area can be characterized lithologically as sand, clay, or mixed sand/clay, and can be characterized hydrologically as exhibiting either high head or low head.

Geotechnical analysis indicates that Atterberg limits, index properties, consolidation state, and drainage conditions affect the shear strength of bluff materials. Silty …

Implementation Of The Graphical User Interface Of The Parint Package In Java, Gwowen Fu

Masters Theses

The graphical user interface (GUI) of the ParInt interface package provides a convenient and efficient way for users to integrate multivariate functions on a parallel system or a network.

This thesis introduces basic structure of the GUI and gives a detailed description of each class of how the classes communicate with each other and how the connection with the parallel program is made.

Factors Governing The Rate Of Appearance Of Fuels In Monitoring Wells, Bradley A. Green

Masters Theses

Delays in the appearance of free product (e.g. fuels) in groundwater monitoring wells often cause costly delays in site evaluation. Little is known about how monitoring well design and installation affect this rate of appearance. This study examined the effects of well screen open area, filter pack grain size and wettability, and well development methods on the rate of appearance and subsequent thickness of free product in wells.

Laboratory and field results indicate that free product appears faster in hydrophilic filter packs than in hydrophobic filter packs. Hydrophobic filter packs with a finer grain size than the "industry standard", seem …

Vertical Resistivity Electrode Arrays For Detecting Hydrocarbon Movement And Content In Sands, Kirt Elliott

Masters Theses

In many contamination sites where hydrocarbon is involved an accurate thickness of the contaminant can not be achieved through the most commonly used methods. The purpose of this study is to find an alternate method of determining a precise thickness and monitor the contaminant movement in conjunction with the current methods. Vertical resistivity electrode arrays were tested in a lab environment on singular probes and between probes. The arrays tested were the Wenner, dipole dipole, gradient, parallel and down-hole 3-arrays. Electrode pipes were constructed and placed into a sand tank where the hydrocarbon thickness and the water level could be …

Sm-Nd Systematics As Indicators Of Displaced Plutons: A Test In The Idaho Batholith-Boulder Batholith Region, Christine J. Brand

Masters Theses

In east-central Idaho and western Montana a 400km-long Cretaceous and Tertiary magmatic corridor extends from the Wallowa-Seven Devils terrane to the Helena Salient. Three basement provinces underlie this area: Archean basement to the east, Permo-Triassic basement to the west, and Proterozoic basement in-between. Ideally, if Cretaceous plutons were decapitated and translated eastward along thrusts over a different basement province, then the Cretaceous pluton and the in-place Tertiary pluton would show different isotopic signatures. Pluton samples from locations evenly spaced throughout the magmatic corridor were analyzed for ε⁰_Nd, ε^t_Nd, and ¹⁴⁷Sm/¹⁴³Nd model ages …

A Generic Multi-Electrode Automated/Semi-Automated Field Resistivity System, Douglas D. Werkema

Masters Theses

Geophysical field exploration using electrical resistivity typically employs the use of four electrodes which are progressively relocated to positions that differ from a few meters to hundreds of meters. Consequently, field operations are tiresome and often lead to imprecise locations of electrodes and poor data quality. This project develops an automated field resistivity system.

This automation of resistivity measurements is accomplished by using multiple sets of field electrodes, a programmable switch box, remotely controlling the acquisition instrument and digitally storing the results. Controlling the process is the Acquisition Control^©software, for Windows 95^© .The prototype switch box has …

A Comparison Study Of Water Well Grouting Materials, Sherry L. Callaway

Masters Theses

To prevent contamination from occurring in water wells, and thereby groundwater, the annulus between the well casing and borehole wall must be sealed with a grout that is capable of maintaining a proper seal. Several factors and properties determine the integrity of the grout and the seal formed by that grout.

A field study discovered limitations in all of the tested grout types. Most grouts were found to vary greatly in thickness surrounding the well casing. Bentonite slurry grouts settled excessively. Cement and bentoni tecement grouts did not adhere to PVC well casing. Bentonite-cement grout fractured. The granulated bentonite was …

Collision Spectroscopy Of Low Energy Capture By Multiply Charged Ions From Atomic Targets, Kadir Akgungor

Dissertations

State-selective differential cross sections for single-electron capture processes in very slow collisions of Ar^q+ (q = 4 - 6) ions with Ne, and Ar^6+ ions with He have been studied experimentally at laboratory collision energies between 15 and 100 qeV, and at scattering angles between 0° and 8° by means of translational energy-gain spectroscopy technique. The translational energy spectra show that only a few final states are populated depending on the charge state of the projectile, the projectile laboratory scattering angle, and the collision energy. These measurements also show that the dominant reaction channels are due to capture into excited …

Laboratory Comparison Of Trench Design Options For Recovering Spilled Oil, Renuka Fernando

Masters Theses

The research goal was to improve the performance of drainage trenches used to recover spilled oil in the subsurface. Different trench designs were compared in two laboratory experiments. The first laboratory experiment clearly demonstrates that the performance of a oil recovering drainage trench could be improved by replacing the standard gravel pack sand used around the drain pipe with mixtures of teflon and sand. The effectiveness of a downgradient impermeable 'backstop' also was studied in the first experiment.

In experiment two, four trench designs were compared: perforated drain pipe; wire-wrapped horizontal well screen; perforated sheet pile; and gravel fill with …

A Large Scintillation Detector For Nuclear Physics Experiments At Indiana University Cyclotron Facility, Apurva Pathak

Masters Theses

A new, large, scintillation detector, called the "K" detector has been designed and built for use in a series of nuclear physics experiments being performed at the Indiana University Cyclotron Facility (IUCF). This project describes the design, construction and testing of this scintillation detector. The K detector was designed to augment an existing detector stack at IUCF, and will serve to increase the energy range of previous studies of neutral pion production in proton-proton collisions near threshold. The test data for the current project came from a proton-proton scattering experiment, during which several runs were carried out between the bombarding …

Lithologic And Stratigraphic Analysis Of Glacial Diamictons, Sturgis, Michigan, R. Christopher Gardner

Masters Theses

Seven diamictons are identified in the subsurface glacial drift near Sturgis, Michigan using textural analyses and x-ray diffraction of clay minerals. The clay mineral content is quantified by comparing the 7-A/10- A peak height ratios from x-ray diffraction diffractograms of oriented clay-size particle (< 2um) mounts. Two diamictons occur at the base of the drift. Unit 1 is gray , resembling the shale it overlies. The texture of Unit 1 is sandy clay loam to loam and average 7-A/10-A peak height clay mineral ratios of 0.446 ±0.069. Unit 2 is a yellowish-brown diamicton, it overlies Unit 1, and is a sandy loam to loam with average 7-A/10-A clay mineral ratio of 0.657 ±0.151. Diamicton Units 4 and 5 overlie a thick unit of sand and gravel on top of Unit 2. Units 4 and 5 have similar color and texture, however the 7-A/10-A ratios are 1.059 ±0.090 and 0.810 ±0.072 respectively. Unit 6 is a thin diamicton unit, leached of calcite, and x-ray diffraction suggests that there is a range of weathering horzins between borings. Unit 7 is loamy, whereas Unit 8 generally ranges from sandy clay loam to sandy loam with average 7-A/10-A ratios of 0.865 ±0.090 and 1.195 ±0.189.

Pan, Ppn And Mpan Measurements And The Systematic Relationship Between Mpan And Macr At A Semi-Rural Site In Tennessee, George Nouaime

Masters Theses

Simultaneous measurements of peroxymethacryloyl nitrate (MPAN) and its primary and secondary precursors, methacarolein (MACR) and isoprene, were carried out for the first time in July 1995 at a semi-rural site southeast of Nashville. In addition to these compounds, peroxyacetyl nitrate (PAN), peroxypropionyl nitrate (PPN), other volatile organic compounds (VOCs) and supporting measurements were also collected in collaboration with other research groups. The mean concentrations of PAN, PPN, MPAN and MACR were found to be 485 pptv, 50 pptv, 30 pptv and 0.290 ppbv respectively. MP AN levels, which closely tracked those of MACR during the day, peaked and dropped earlier …

Elucidation Of The Pathway Required For The Stimulation Of G6pdh Gene Expression By Insulin And Its Mimetics, Asavari Wagle

Masters Theses

Insulin, an anabolic hormone, exquisitely controls cellular physiology and metabolism by modulating the activity of key proteins which regulate metabolic and mitogenic events. Insulin activates several cytosolic proteins via a phosphorylation cascade, but only some of these proteins are required for its specific action. We have elucidated the insulin signal transduction cascade in primary rat hepatocytes, and outlined some of the events that are required for the insulin induced stimulation of glucose-6-phosphate dehydrogenase (G6PDH) gene expression. Using well-characterized and structurally different inhibitors, we show that insulin stimulation of the gene requires the IRS-1/P13K pathway and not the RAS/RAF/MAPK pathway. Gene …

Geology Newsletter- 1997, Department Of Geology

Geological and Environmental Sciences News

Vol. 1, No. 22

• Dear Alumni and Friends
• Faculty News
• Awards and Scholarships
• Alumni News
• Geology Development and Scholarship Donations
• Advisory Council News

Systematics Of Stable Isotopes And Radionuclides In Precipitation At Kalamazoo, Michigan, Usa, Madhav V. Machavaram

Dissertations

Precipitation samples were collected at Kalamazoo from June 1992 to March 1995. The samples were analyzed for their 8D and 8lgO values. The 5D - 5I80 relationship is comparable to that of Meteoric Water Line (MWL). The monthly mean isotopic values in precipitation exhibited strong seasonality, being higher in summer and lower in winter months. This behavior is apparently a direct consequence of the temperature effect on isotope fractionation.

The summer precipitation at Kalamazoo is derived predominantly from the water vapor originated in the Gulf of Mexico. A box model calculation showed that a Rayleigh type distillation with Gulf moisture …

Extraction Of Premafloxacin Radiolabeled With Carbon Fourteen From Loam Soil, Steven Gregory Staskiewicz

Masters Theses

Premafloxacin is a fluoroquinolone antibiotic being developed by Pharmacia & Upjohn for veterinary indications. Since the parent drug and possibly metabolites will be applied to soil through the deposition of animal excreta, many regulatory agencies will require environmental assessment testing. In order to determine if ¹⁴C-premafloxacin would biodegrade in the soil, loam soil was extracted with solvents and C18 solid phase columns were used to isolate the compound after three weeks of incubation. In addition to extracting the soil, production of ¹⁴CO₂ was monitored by trapping the degradation by-product in 2 N NaOH. Liquid scintillation counting of …

Reservoir Characterization Of Crystal Field And Analysis Of The Tow#1-3 Hd-1 Well, Montcalm County, Michigan, Heidi Wines

Masters Theses

The goal of this project was to characterize the Dundee reservoir of Crystal oil field using the newly drilled Tow #1-3 well data in conjunction with historical well records to evaluate heterogeneity of facies and their controls on oil production.

From the Tow# 1-3 HD-1 well, three major facies were identified in the reservoir. A non-fractured intertidal grainstone facies provides storage of fluids with its uniform permeability and excellent intercrystalline porosity. The supratidal fractured micrites and open marine fractured biomicrites are interbedded with the grainstone facies providing conduits for fluid migration between the facies. Facies are important controls on oil …

Geophysical Characterization Of A Jp-4 (Lnapl) Contaminated Site At The Wurtsmith, Air Force Base, Oscoda, Michigan, Kristina C. Sprietzer

Masters Theses

The detection of hydrocarbon contamination in the subsurface using geophysical techniques has been based on the known physical properties of high electrical resistivities (ρa) (low conductivities). However, geophysical field investigations at uncontrolled spill sites yield measurements of low resistivity (high conductivity). The purpose of this study is to test that in the natural environment some hydrocarbon spills (in the case of LNAPLs), can exhibit changes with time due to biodegradation, from electrically resistive to conductive. Since time is an important factor, this hypothesis was tested at a site where the time when a hydrocarbon release occurred is known and where …

Link/Loop/Node Networks, Mark E. Gilbert

Honors Theses

This document is really two separate documents that have been appended together. The first is Link/Loop/Node Networks. This document describes the theory behind link/loop/node networks (LLN), as well as the basic operating instructions for the LLN Simulator (LLNS). The second document is LLN Simulator Technical Reference. This second document describes how the LLNS was constructed using Microsoft Access 2.0, as well as how the LLNS simulates LLN.

Localization And Transport Effects In The Disordered Materials, Vladislav Malyshkin

Dissertations

No abstract provided.

A Robust Estimate For An Autoregressive Time Series, Jeffrey Terpstra

Dissertations

A weighted rank-based estimate for estimating the parameter of an auto-regressive time series is considered. When the weights are constant, the estimate is equivalent to using Jaeckel’s estimate and Wilcoxon scores. The estimate can be shown to be asymptotically normal at rate y/n. In a linear regression setting this estimate has the desired properties of a continuous totally bounded influence function and a positive breakdown point. It is shown via examples and Monte Carlo that these properties are preserved in an autoregressive time series setting.

Groundwater-Kalamazoo River Interaction Near The Parchment City Wellfield, Parchment, Michigan, W. Richard Laton

Dissertations

A detailed hydrogeologic study of the Kalamazoo River and its interaction with the groundwater was completed near Parchment, Michigan. The Kalamazoo River between Portage Creek and Allegan Dam is a Federal superfund site due to PCB contamination trapped in its sediments. The City of Parchment pumps all of its drinking water from a glacial aquifer 850 feet from the Kalamazoo River. This study focused on the hydrogeology and groundwater/surface interaction of the area through the use of surface and downhole geophysics, installation of monitoring wells and peizometers, seepage meters and chemical sampling. It was determined that the Kalamazoo River is …

Domination In Digraphs, Lisa Hansen

Dissertations

No abstract provided.

Synthesis Of Biologically Active Substituted Chalcones, Kiel Steven Hoff

Masters Theses

Two different synthetic routes to poly-hydroxylated chalcones are investigated. The wittig synthesis and protection of the hydroxyl functionalities by forming the methyl ether followed by the base catalyzed Claissen-schmidt reaction and then deprotection were investigated. It was demonstrated that the protection-condensation- deprotection route was more efficient. The antiviral activity of 2,2', 4' - trihydroxychalcone against the HIV virus is also presented.

Changes In Channel Morphology And Flood-Plain Ecosystems Of The Green River Between The Flaming Gorge Dam, Utah And The Gates Of Lodore, Colorado, Gloria Christine Celeste Britton

Masters Theses

Closure of Flaming Gorge Dam in 1962 reduced the flow rate and variability of discharge on the Green River below this dam. These changes, coupled with the decreased sediment load due to stilling and sporadic peaking in response to demand for hydroelectric power and controlled releases of up to 4500 cfs to cope with snowmelt have impacted the channel morphology and ecosystems of the main stem Green River between the Dam and the Gates of Lodore. Detailed comparative analysis of channel shape and riparian ecosystems or pre-dam and post-dam aerial photographs revealed that significant changes occurred after closure. Channel width …

Bandwidth, Edgesum And Profile Of Graphs, Yung-Ling Lai

Dissertations

No abstract provided.