Physical Sciences and Mathematics Commons^™

The Synthesis And Optimization Of Sulfide And Halide Solid Electrolytes For All Solid-State Batteries, Teerth Brahmbhatt

Doctoral Dissertations

Countries and organizations around the world have established ambitious targets to transition away from fossil fuel-based energy sources and devices. The transition is focused on cleaning up power generation by converting coal, natural gas, and oil-based power generation to renewables and nuclear energy. Decarbonizing other sectors of energy use, transportation for example, will require broader electrification. To drive this move away from fossil fuel powered transportation will require portable energy storage devices. Conventional lithium-ion batteries are a popular candidate to lead this shift. However, these batteries often rely on flammable liquid electrolytes and carbon anodes that suffer from low energy …

Heat Pump Integrated Thermal Storage For Building Demand Response And Decarbonization, Sara Sultan

Doctoral Dissertations

This work presents a novel thermal energy storage (TES) integrated with existing residential heat pump (HP). The research focuses on controls and configuration for energy, demand, cost and carbon emissions savings for residential buildings’ energy consumption. This work will be significant in developing a framework especially for reduced energy demand and carbon emissions associated with space heating and cooling in residential buildings. Since buildings account for about 40% primary energy consumption in U.S. and half of that is associated with HP.

An existing air source HP in integrated with a phase change material (PCM) based TES via active configuration where …

Precipitation Variability And Predictability Over The Arabian Peninsula, Central Southwest Asia, And Southern Africa, Matthew Francis Horan

Doctoral Dissertations

The Northern Hemisphere winter is the main rainy season for the Arabian Peninsula (AP), Central Southwest Asia (CSWA), and Southern Africa (SF), where precipitation predictability is limited or understudied. This dissertation research focuses on improving our understanding of these regions' wet-season precipitation characteristics and predictability.

First, I have identified the AP's key moisture sources through a Lagrangian back-trajectory algorithm. Mid-latitude land and water bodies, such as the Mediterranean and Caspian Seas, are the primary moisture sources in the northern region. Areas further south rely on moisture transport from the Western Indian Ocean and the African continent. A significant drying trend …

Hashed Coordinate Sparse Tensor Storage With Matlab, Jama Meili Charles

Doctoral Dissertations

Tensors, or n-way arrays, are incredibly useful for storing indexable data in an arbitrary number of dimensions. Interest in tensor analysis using tensor decomposition has expanded to a variety of fields, including data mining, signal processing, computer vision, and machine learning. Tensors modelling interesting data may also be sparse, where the majority of its values are zero. These tensors can be extremely large and contain millions of entries that cannot be stored explicitly. To address this problem, various formats have arisen in the past decade to compress and compact such massive data. However, most of these existing structures are …

Redox-Active Polymerization Catalysts And Their Applications, Nicholas M. Shawver

Masters Theses

Traditional catalyst systems are reliable means to produce polymers with well-defined architectures and thermomechanical properties; however, they are often limited by a narrow monomer scope and their ability access few, if any, advanced polymer architectures. To address this limitation, a new class of catalysts have recently emerged that feature redox-active moieties that may access advanced architectures through catalyst electronic modulation that arises from redox events occurring on the ligand scaffold or at the active metal center itself. For example, researchers have explored the ability of redox-active catalysts to impart “on-off” kinetic control during ring-opening polymerizations and their ability to access …

Numerical And Experimental Constraints On Trace Element Fractionation During Lunar Magma Ocean Solidification, Dian Ji

Masters Theses

Traditional lunar magma ocean (LMO) theory suggests the anorthositic lunar crust formed by floating of buoyant plagioclase, one of the major products of LMO solidification, on the surface of LMO. To test this model, after applying experimentally determined LMO solidification sequences, we compared calculated Rare Earth Element (REE) concentrations of lunar plagioclase to plagioclase in Apollo ferroan anorthosites and lunar anorthositic meteorites. Several initial LMO compositions, and lunar-relevant mineral-melt partition coefficient predictive models were tested (where the partition coefficient is the concentration ratio of a specific element between two phases). Compared with plagioclase in the natural samples, modeled plagioclase directly …

Expression And Purification Of Polyketide Synthase Domains To Investigate Protein-Protein Interactions In Polyketide Biosynthetic Pathways, Mujeeb Adeyinka Wakeel

Masters Theses

Polyketide synthases (PKSs) are multienzyme proteins catalyzing the production of the polyketide class of natural products with vast structural diversity. Type II PKSs catalyze polyketide biosynthesis using discrete (standalone) enzymes (domains), while type I PKSs use covalently linked enzymes arranged in a module to catalyze polyketide production. It is hypothesized that type II PKSs are the precursors to type I PKSs, proposing that the genes encoding individual discrete enzymes in type II PKSs fused to give the multienzyme modules of type I PKSs. We reasoned that the intramolecular-like reactions occurring in type I PKS modules might be a driving force …

Exploring Skyrmions Dynamics And Structure Using Neutron Scattering, W-L-Namila Chandula Liyanage

Doctoral Dissertations

Magnetic skyrmions are topologically protected chiral spin textures with great potential for next-generation consumer technologies. These magnetic structures can be described as spins continuously wrapping into a closed coplanar loop, featuring a core and fencing perimeter with opposite out-of-plane orientations. While conventional depictions of magnetic skyrmions use a two-dimensional projection, recent research underscores the importance of their three-dimensional structure in determining their topology and stability. Magnetic skyrmions typically emerge just below the curie temperature of a magnetic material, creating what is known as a skyrmion pocket. In most materials the stability pocket is at low temperatures and finite fields, however …

An Exploration Of Absolute Minimal Degree Lifts Of Hyperelliptic Curves, Justin A. Groves

Doctoral Dissertations

For any ordinary elliptic curve E over a field with non-zero characteristic p, there exists an elliptic curve E over the ring of Witt vectors W(E) for which we can lift the Frobenius morphism, called the canonical lift. Voloch and Walker used this theory of canonical liftings of elliptic curves over Witt vectors of length 2 to construct non-linear error-correcting codes for characteristic two. Finotti later proved that for longer lengths of Witt vectors there are better lifts than the canonical. He then proved that, more generally, for hyperelliptic curves one can construct a lifting over …

Morphologic Analyses Of Paleozoic Rhombiferan Echinoderm Stems, Aidan R. Sweeney

Doctoral Dissertations

During the Paleozoic, echinoderms exhibited a diverse array of morphologies. This work specifically deals with an extinct stemmed group called glyptocystitoid rhombiferans. The goal of this work is to investigate functional morphology of the stem in this enigmatic group. Abnormalities in form are addressed herein by a brief literature review of teratologic features and in the description of a new species of pleurocystitid Pleurocystites? scylla. Morphologic specialization is discussed in the investigation of the internal structure and morphometrics of the mesotem of Brockocystis. Linear morphometrics, multiple imputation, and multivariate statistics were used to describe the variability exhibited in …

Reducing Communication In The Solution Of Linear Systems, Neil S. Lindquist

Doctoral Dissertations

There is a growing performance gap between computation and communication on modern computers, making it crucial to develop algorithms with lower latency and bandwidth requirements. Because systems of linear equations are important for numerous scientific and engineering applications, I have studied several approaches for reducing communication in those problems. First, I developed optimizations to dense LU with partial pivoting, which downstream applications can adopt with little to no effort. Second, I consider two techniques to completely replace pivoting in dense LU, which can provide significantly higher speedups, albeit without the same numerical guarantees as partial pivoting. One technique uses randomized …

The G_2-Hitchin Component Of Triangle Groups: Dimension And Integer Points, Hannah E. Downs

Doctoral Dissertations

The image of $\PSL(2,\reals)$ under the irreducible representation into $\PSL(7,\reals)$ is contained in the split real form $G_{2}^{4,3}$ of the exceptional Lie group $G_{2}$. This irreducible representation therefore gives a representation $\rho$ of a hyperbolic triangle group $\Gamma(p,q,r)$ into $G_{2}^{4,3}$, and the \textit{Hitchin component} of the representation variety $\Hom(\Gamma(p,q,r),G_{2}^{4,3})$ is the component of $\Hom(\Gamma(p,q,r),G_{2}^{4,3})$ containing $\rho$.

This thesis is in two parts: (i) we give a simple, elementary proof of a formula for the dimension of this Hitchin component, this formula having been obtained earlier in [Alessandrini et al.], \citep{Alessandrini2023}, as part of a wider investigation using Higgs bundle techniques, …

Insights Into The Application Of Deep Reinforcement Learning In Healthcare And Materials Science, Benjamin R. Smith

Doctoral Dissertations

Reinforcement learning (RL) is a type of machine learning designed to optimize sequential decision-making. While controlled environments have served as a foundation for RL research, due to the growth in data volumes and deep learning methods, it is now increasingly being applied to real-world problems. In our work, we explore and attempt to overcome challenges that occur when applying RL to solve problems in healthcare and materials science.

First, we explore how issues in bias and data completeness affect healthcare applications of RL. To understand how bias has already been considered in this area, we survey the literature for existing …

Multidimensional Investigation Of Tennessee’S Urban Forest, Jillian L. Gorrell

Doctoral Dissertations

Preserving existing trees in urban areas and properly cultivating urban forest conservation and management opportunities is valuable to the ever-growing urban environment and necessary for creating optimal experiences and educational tools to meet the needs of increasing urban populations. This dissertation contains studies investigating several facets of the urban forest, including environmental effects of deforestation and urbanization, tree equity, and urban forest facility management and accessibility. Community education and outreach at arboreta about the importance of the tree canopy can help promote environmental stewardship. A digital questionnaire was electronically distributed to representatives of arboreta certified through the Tennessee Division of …

Sub-Chandrasekhar Type Ia Supernovae Scenarios With Increased Pathways For Neutronization, Fernando Hernan Rivas

Doctoral Dissertations

Type Ia supernovae are thermonuclear explosions of white dwarfs (WD), electron-degenerate cores of old intermediate mass stars(under 8$M_{\odot}$). Reaching energies of $10^{51}$\si{\erg}, they outshine whole galaxies as they synthesize and distribute most of the iron group elements (IGE; V, Cr, Mn, Fe, Co, Ni) into the interstellar medium, thus being one of the main agents in cosmic chemical evolution. Also, given their notably homogeneous lightcurves, they form the last step in the cosmic distance ladder outdistancing Cepheid variables by orders of magnitude. Though calibration of said lightcurves is dependent on a high number of confirmed events, the limits of statistical …

Synthesizing, Purifying, And Characterizing Molten Chloride Salts, Phillip W. Halstenberg

Doctoral Dissertations

Molten chloride salts have vast potential as heat transfer fluids with both nuclear and concentrated solar power applications. For application in energy systems, the characteristics that govern these systems must be well understood. This work focuses on inorganic molten chloride salts with a special emphasis on the experimental aspect of chemical research. Chapter 2 covers the synthetic approaches for the formation of molten chloride mixtures. Many salts can be purchased from industrial suppliers, but most must be purified therefore, Chapter 3 evaluates various methodology developed for removal of impurities in salt mixtures. Once the salt of proper content and purity …

Mechanochemical Synthesis Of Task-Specific Conjugated Porous Networks Towards Enhanced Energy Storage, Juntian Fan

Doctoral Dissertations

Conjugated scaffolds with high electronic conductivity, high surface area, etc. are promising materials for diverse technological applications, especially in the electrochemical field. However, the current synthesis methods are still limited to the traditional solution-based method or the ionothermal method, which always require an inert atmosphere shield, large amounts of organic solvents, noble catalysts, long reaction time up to days, and high temperatures, etc. Therefore, there is a common goal of developing conjugated scaffolds through facile, green, straightforward pathways. Mechanochemistry, which is an efficient, sustainable, solvent-free methodology, could provide a unique reaction environment to synthesize this kind of functionalized materials, resulting …

Space-Angle Discontinuous Galerkin Finite Element Method For Radiative Transfer Equation, Hang Wang

Doctoral Dissertations

Radiative transfer theory describes the interaction of radiation with scattering and absorbing media. It has applications in neutron transport, atmospheric physics, heat transfer, molecular imaging, and others. In steady state, the radiative transfer equation is an integro-differential equation of five independent variables, which are 3 dimensions in space and 2 dimensions in the angular direction. This high dimensionality and the presence of the integral term present serious challenges when solving the equation numerically. Over the past 50 years, several techniques for solving the radiative transfer equation (RTE) have been introduced. These include, but are certainly not limited to, Monte Carlo …

Utilizing Ultra-Performance Chromatography High-Resolution Mass Spectrometry To Investigate Fatty Acid Mediated Antibiotic Tolerance, Brittni Woodall

Doctoral Dissertations

The lipid membrane is the first component necessary to sustain life. To maintain homeostasis, segregate cellular machinery, provide protection from the environment, and reproduce, an organism must establish a boundary in which the processes can occur. Throughout the last two decades, research has propelled our knowledge of lipid membranes much beyond original hypotheses. Once thought of to be static and uniform, the understanding of the lipid membrane has evolved to encompass a structure that is responsive, unique, and intricately constructed by the organism itself. By chance or by choice, organisms adapt the lipid membrane according to the environment for which …

Fabrication, Measurements, And Modeling Of Semiconductor Radiation Detectors For Imaging And Detector Response Functions, Corey David Ahl

Doctoral Dissertations

In the first part of this dissertation, we cover the development of a diamond semiconductor alpha-tagging sensor for associated particle imaging to solve challenges with currently employed scintillators. The alpha-tagging sensor is a double-sided strip detector made from polycrystalline CVD diamond. The performance goals of the alpha-tagging sensor are 700-picosecond timing resolution and 0.5 mm spatial resolution. A literature review summarizes the methodology, goals, and challenges in associated particle imaging. The history and current state of alpha-tagging sensors, followed by the properties of diamond semiconductors are discussed to close the literature review. The materials and methods used to calibrate the …

Path Integral Monte Carlo For Entanglement In Bosonic Lattices At T = 0, Emanuel Casiano-Diaz

Doctoral Dissertations

Path-Integral Monte Carlo Worm Algorithm is one of many Quantum Monte Carlo (QMC) methods that serve as powerful tools for the simulation of quantum many-body systems. Developed in the late 90’s, this algorithm has been used with great success to study a wide array of physical models where exact calculation of observables is not possible due to the exponential size of the Hilbert space. One type of systems that have eluded PIMC-WA implementation are lattice models at zero temperature, which are of relevance in experimental settings, such as in optical lattices of ultra-cold atoms. In this thesis, we develop a …

Pointing Control And Stabilization Of The High-Energy Uv Laser For Laser-Assisted Charge Exchange, Martin Joseph Kay

Doctoral Dissertations

Laser-Assisted Charge Exchange (LACE) is an experimental method of charge exchange injection into a proton accumulator ring that is being developed at the Spallation Neutron Source (SNS) in Oak Ridge National Laboratory (ORNL) as an alternative to hazardous injection foils. The current scheme of LACE requires a high-energy, low-repetition-rate UV (355 nm) laser beam (140 mJ pulses at 10 Hz) to be transported over 65 meters to the laser-particle interaction point (IP) in a high-radiation area of the accelerator. Thermal effects and other disturbances along the free-space laser transport line cause the beam to slowly drift away from the IP …

Total Absorption Spectroscopy Of Mo-106 And Tc-106, Michael Cooper

Doctoral Dissertations

Total absorption spectroscopy is a method of gamma-ray spectroscopy that has gained prominence in the past several decades, as nuclear data revisions are performed on older nuclear data, which is often incomplete. A strong understanding of underlying nuclear data, particularly fission and beta decay data, is essential for nuclear reactors and nuclear fuel decay heat. This PhD work involves the analysis of fission fragments 106Mo [Mo-106] and 106Tc [Tc-106]. These neutron rich isotopes contribute upwards of 6% of the cumulative fission yield of 241Pu [Pu-241] fission, and 4% of 239Pu [Pu-239] fission. Prior data for these two fission fragments only …

Large-Scale Volcanism On The Terrestrial Planets, Keenan Ben Golder

Doctoral Dissertations

Evidence for mafic volcanism has been found on each planet in the inner Solar System. Lava flows on these planets range in size from 10s to 1000s of kilometers in extent. I investigated large-scale lava flows on Mercury, Earth, and Mars throughout the chapters in this dissertation. Each of these lava flows provides an avenue to study the emplacement and evolution of lava on various planets and under differing conditions, the factors that affect their overall extent, and potential source areas.

Chapter One investigates large-scale lava flows in the Cerberus region on Mars, specifically to understand their emplacement history, material …

The Novel Chlorination Of Zirconium Metal And Its Application To A Recycling Protocol For Zircaloy Cladding From Spent Nuclear Fuel Rods, Breanna K. Vestal

Doctoral Dissertations

A novel protocol has been developed for the chemical removal of zirconium alloy (Zircaloy) cladding from spent nuclear fuel rods and subsequent isolation and purification of nuclear-grade zirconium chloride derived therefrom. This protocol is based on the chemistry developed from two new scientific findings.

First, two new oxidative chlorination reactions have been discovered for zirconium metal. In both solvents, zirconium can be quantitatively chlorinated at temperatures less than 150°C, with the operative equations seen below. In sulfur monochloride, the reaction is completed in 2 – 4 hours via surface etching, exhibiting 0^th order kinetic behavior. The elemental sulfur byproduct …

Mapping Past Land Use Changes And Modeling Future Urbanization Patterns In A Mid-Sized American City, Duncan P. Mccurry

Masters Theses

On a global scale, humans have been moving from rural to urban areas at an increasingly fast rate in a process called urbanization. It is crucial to understand and predict the impacts of urbanization because city expansion encroaches on farmland and woodland, reducing regional ecosystem services. Therefore, urbanization must be well planned in a forecasting manner. The objective of this study is to map the land use change in Knox County, Tennessee, from 2001-2019 to identify the urbanization trends and understand the dynamic geospatial relationships between the urban and rural areas. The geospatial mapping was done using USGS land use …

Survey Of Input Modalities In The Western World, John Ezat Sadik

Masters Theses

Having your account compromised can lead to serious complications in your life. One
way accounts become compromised is through the security risks associated with weak
passwords and reused passwords [22,23]. In this thesis, we seek to understand how
entering passwords on non-PC devices contributes to the problems of weak and reused
passwords. To do so, we conducted a survey that was distributed to people in the
the Western World. In our survey results, we found that users commented about
how the current password model was not created with a variety of device types in
mind, which created frustrations and complexity …

Climatological Analysis Of Tropical Cyclone Occurrence Dates And Landfall Characteristics In The North Atlantic And Eastern North Pacific, Nicholas Sava Grondin

Doctoral Dissertations

Tropical cyclones (TCs) are significant hazards to coastal and inland regions across the globe, especially in North America. North America is affected by TCs from two basins, the North Atlantic (NATL) and eastern North Pacific (ENP), with the former being the predominate focus of past research. In this dissertation, I present three studies that directly compare TCs in the NATL and ENP by using the same methods for each basin in studying occurrence dates and intraseasonal variability, effects of environmental parameters on occurrence dates and seasonal forecasting, and the behavior of TCs during the final 36 hours before landfall in …

Unlocking The Potential Of Machine Learning In The Derivation Of Low-Energy Models For Metallic Magnets, Vikram Sharma

Doctoral Dissertations

Condensed matter physics often grapples with complex many-particle problems lacking definitive closed-form solutions, necessitating approximation strategies to investigate low-energy sectors of the Hilbert space. Perturbation theory, though widely used for this purpose, is limited when expansion terms diverge. This work introduces a machine learning (ML) assisted protocol to extract effective low-energy models for lattice models of fermions interacting with classical fields, specifically focusing on the Kondo Lattice Model (KLM).

Skyrmions, featuring whirling spin texture and topological protection, are promising candidates for future spintronic devices. Materials featuring conduction electrons coupled to localized $f$-electrons' net moment are ideal for realizing skyrmions and …

Neutrino Physics At A Research Reactor: Backgrounds And Analysis, Blaine Alexander Heffron

Doctoral Dissertations

The field of neutrino physics has a rich history and is currently the subject of much active research. The discovery of neutrino oscillations led to the conclusion that neutrinos have mass which was in contradiction to the Standard Model. Now researchers are investigating a number of open questions regarding neutrino properties such as their mass values or the existence of CP violation in the weak interaction. In order to answer these questions experimental and analytical techniques of neutrino detection are becoming more advanced, entering into an era of precision neutrino detection.

Nuclear reactors as a source of antineutrinos have played …