Physical Sciences and Mathematics Commons^™

Interactive Feature Selection And Visualization For Large Observational Data, Jingyuan Wang

Doctoral Dissertations

Data can create enormous values in both scientific and industrial fields, especially for access to new knowledge and inspiration of innovation. As the massive increases in computing power, data storage capacity, as well as capability of data generation and collection, the scientific research communities are confronting with a transformation of exploiting the advanced uses of the large-scale, complex, and high-resolution data sets in situation awareness and decision-making projects. To comprehensively analyze the big data problems requires the analyses aiming at various aspects which involves of effective selections of static and time-varying feature patterns that fulfills the interests of domain users. …

Scattering Amplitudes In Flat Space And Anti-De Sitter Space, Savan Kharel

Doctoral Dissertations

We calculate gauge theory one-loop amplitudes with the aid of the complex shift used in the Britto- Cachazo-Feng-Witten (BCFW) recursion relations of tree amplitudes. We apply the shift to the integrand and show that the contribution from the limit of infinite shift vanishes after integrating over the loop momentum, with a judicious choice of basis for polarization vectors. This enables us to write the one-loop amplitude in terms of on-shell tree and lower-point one-loop amplitudes. Some of the tree amplitudes are forward amplitudes. We show that their potential singularities do not contribute and the BCFW recursion relations can be applied …

Social Fingerprinting: Identifying Users Of Social Networks By Their Data Footprint, Denise Koessler Gosnell

Doctoral Dissertations

This research defines, models, and quantifies a new metric for social networks: the social fingerprint. Just as one's fingers leave behind a unique trace in a print, this dissertation introduces and demonstrates that the manner in which people interact with other accounts on social networks creates a unique data trail. Accurate identification of a user's social fingerprint can address the growing demand for improved techniques in unique user account analysis, computational forensics and social network analysis.

In this dissertation, we theorize, construct and test novel software and methodologies which quantify features of social network data. All approaches and methodologies are …

Investigations Into Ambient Ionization Mechanisms: Electrospray Ionization And Direct Analysis In Real Time Mass Spectrometry, Stephen Colin Gibson

Doctoral Dissertations

Mass spectrometry (MS) is an important tool for chemical analyses. Despite the MS requirement for generation of analyte gas-phase ions, many ion source designs afford little-to-no fragmentation, allowing characterization of intact molecules. However, this does not assure that detected ions are representative of the analytes’ natural state. Ionization mechanisms are generally complex and rarely fully understood. Fundamental research into these mechanisms provides greater insight into the relationship between solution chemistry and mass spectra. Work herein addresses aspects of two ambient ionization mechanisms: electrospray ionization (ESI) and Direct Analysis in Real Time (DART).

Ions produced by ESI are dispersed into a …

Elucidating Fundamental Mechanisms In Focused Electron- And Ion-Beam Induced Synthesis, Carlos M. Gonzalez

Doctoral Dissertations

A focused electron beam deposition process (FEBID) coupled with in-situ infrared pulsed laser assist (LA-EBID) has been implemented for higher purity tungsten nanowires using W(CO)₆ [tungsten hexacarbonyl] as parent precursor gas. Nanowires made of Co from Co₂(CO)₈ [dicobalt octacarbonyl] and Pt from MeCpPtIVMe₃ [trimethyl methylcyclopentadienyl platinum] have also been realized by using inert focused ion beams of helium and helium and neon, respectively. In all cases, higher electrical conductivities, higher purities and larger grain sizes have been obtained when compared with preceding traditional additive edit techniques. These new approaches will make possible successful nanoscale direct-write …

Comparisons Of Point And Average Capillary Pressure - Saturation Functions For Porous Media, Samuel Clark Cropper

Doctoral Dissertations

The relationship between the volume of water occupying pores in soil or rock and its energy state is called the capillary pressure–saturation function. This is an important hydrogeologic property needed for modeling multiphase flow and transport. Standard methods used to determine capillary pressure–saturation behavior produce volume averaged functions rather than point functions. Average functions can produce erroneous simulations in flow models. Analytical expressions permit extraction of point functions from average functions, and predictions of average functions from point function parameters. These concepts are discussed in Chapter I.

Chapter II compares average and point functions from centrifugation of Berea sandstone, glass …

Neutron Scattering Studies Of Phosphate Proton Conductors, Amal Bajes Al-Wahish

Doctoral Dissertations

Proton ceramic fuel cells operating in the intermediate temperature range of 300-500 °C offer potentially revolutionary advantages over existing fuel cells because expensive noble metal catalysts would not be needed, and in situ reforming of liquid bio-fuels such as ethanol or methanol would be possible.The chief obstacle facing intermediate fuel cells is the lack of a suitable electrolyte in the operating temperature range. A good electrolyte is thermally and chemically stable, inexpensive, environmentally friendly, and has a proton conductivity on the order of 10^-2 S cm^-1 [Siemens per centimeter] at 400 °C. Acceptor-doped lanthanum orthophosphate is an …

Synthesis And Thermodynamic Analysis Of Volatile Beta-Diketone Complexes Of Select Lanthanides Via Gas-Phase Separations, Daniel Hanson

Doctoral Dissertations

Rapid separation techniques for fission and activation products have long been desired to supplant the slow solution-based methodologies currently used. In this work, rare earth elements were derivatized with β [beta]-diketones to synthesize rare earth complexes with high volatility suitable for gas-phase separations. Rare earth elements samarium and dysprosium were combined with hfac (1,1,1,5,5,5-hexafluoro-2,4-pentadione) and fod (6,6,7,7,8,8,8-heptafluoro-2,2-dimethyl-3,5-octanedione) and analyzed using a gas-phase separation technique. Rare earth elements praseodymium and europium were combined with dpm (2,2,6,6-tetra-methyl-3,5-heptanedione) and similarly analyzed. Employing the data from the separations, the entropy (Δ [delta] S) and enthalpy (Δ [delta] H) of adsorption were evaluated mathematically based …

Nonlocal Polarization Interferometry And Entanglement Detection, Brian P. Williams

Doctoral Dissertations

At present, quantum entanglement is a resource, distributed to enable a variety of quantum information applications such as quantum key distribution, superdense coding, and teleportation. Necessarily, the distribution and characterization of entanglement is fundamental to its application. This dissertation details three research efforts to enable nonlocal entanglement detection, distribution, and characterization. Foremost of these efforts, we present the theory and demonstration of a nonlocal polarization interferometer capable of detecting entanglement and identifying Bell states statistically. This is possible due to the interferometer’s unique correlation dependence on the anti-diagonal elements of the density matrix, which have distinct bounds for separable states …

Photo-Switchable Control Of Membrane Properties Of Liposomes And Biochemical Processes, Andrew Michael Bayer

Doctoral Dissertations

Liposomes are promising agents for drug delivery. They have the ability to encapsulate therapeutic drugs, resulting in decreased toxicity and prolonged circulation time. However, many obstacles to achieving broad utility in liposomal drug delivery still exist, including the ability to control release of therapeutic drugs and modulate surface reactivity. A primary focus of this dissertation involves the development of synthetic photocleavable lipids for controlled release from membranes.

Phosphatidylcholine (PC) is a natural lipid that comprises the majority of structural membranes. It contributes heavily to the formation of lipid bilayers in cell membranes, and modifications to the bilayer can induce membrane …

Computational Studies For Optimization And Design Of Extracting Agents For Separation Of Lanthanides And Actinides, Deborah Andrea Penchoff

Doctoral Dissertations

Rare earths and actinides are of great interest given their varied applications in energy conversion and storage, such as in catalysis and batteries, and for advanced technological applications related to optical and magnetic properties (including electronics and automotive), amongst others. Many of the rare earth elements are considered endangered species due to their unique properties which have no clear alternatives that will maintain performance for important applications. The optimal approach is to find readily available alternatives for critical materials to ensure a certain standard of living and quality of life for future generations, but it is very likely that reusing …

Hi-Fidelity Simulation Of The Self-Assembly And Dynamics Of Colloids And Polymeric Solutions With Long Range Interactions, Mahdy Malekzadeh Moghani

Doctoral Dissertations

Modeling the equilibrium properties and dynamic response of the colloidal and polymeric solutions provides valuable insight into numerous biological and industrial processes and facilitates development of novel technologies. To this end, the centerpiece of this research is to incorporate the long range electrostatic or hydrodynamic interactions via computationally efficient algorithms and to investigate the effect of these interactions on the self-assembly of colloidal particles and dynamic properties of polymeric solutions. Specifically, self-assembly of a new class of materials, namely bipolar Janus nano-particles, is investigated via molecular dynamic simulation in order to establish the relationship between individual particle characteristics, such as …

Detecting Tropical Cyclone Signals In Tree Rings Of Longleaf Pine (Pinus Palustris Mill.), Valdosta, Georgia, U.S.A., Savannah Anne Collins

Masters Theses

The study of past hurricanes to help interpret the patterns of current and future tropical storms is vital to our economy, society, and infrastructure. Understanding how hurricanes are influenced by a warm climate is critical, and hurricane reconstructions from former periods of the Holocene (the last ~11,500 yr) will be beneficial. Paleotempestology is the study of past tropical cyclones and uses historical, biological, and geological proxies to reconstruct tropical cyclone activity to create a record of historical hurricane patterns. A tropical cyclone (TC) is a chaotic weather event that is influenced by several elements, including warm ocean waters from which …

Metamorphic Evolution Of Eastern Blue Ridge Calc-Silicates In Southwestern North Carolina, Northeastern Georgia, And Northwestern South Carolina, Gina Brianne Smith

Masters Theses

Calc-silicate rocks in the eastern Blue Ridge of SW North Carolina, NE Georgia, and NW South Carolina are products of contact and regional metamorphism. Two types of calc-silicates occur in this area: Type A rocks occur as contact metamorphosed xenoliths in the ~336 Ma Rabun Granodiorite batholith, and Type B rocks occur as mappable thin, elongate, ribbon-like units in the Tallulah Falls Formation east of the Rabun batholith. Petrographic and geochemical data confirm similar composition for both types and mineral assemblages that includes amphibole, garnet, epidote, diopside, quartz, and plagioclase with accessory zircon, sphene, and opaque minerals. Calcite, however, is …

Design And Model Of The Frame For Hagrid (Hybrid Array Of Gamma Ray Detectors), Santiago Munoz

Masters Theses

Transfer reactions in inverse kinematics have provided critical information in the study of exotic nuclei. However, transfer reactions with charged particles suffer from poor resolution. The measurement of gamma-rays offers several advantages: they provide not only good resolution in measurements but also other information about the nuclei like lifetimes of unstable states. The combination of these two methods would be the ideal situation to gather information about nuclear structure.

HAGRiD, which stands for The Hybrid Array of Gamma Ray Detectors, is a LaBr3(Ce) [lanthanum bromide crystal with a cerium activator] scintillation array to measure gamma rays from transfer reactions and …

Investigating The Effects Of Urbanization On Residual Forest Soils In Knox Co., Tennessee, Benjamin Lee Reichert

Masters Theses

As the process of urbanization advances across the country, so does the importance of urban forests, which include both trees and the soils in which they grow. Soil microbial biomass, which plays a critical role in nutrient transformation in urban ecosystems, is affected by factors such as soil type and the availability of water, carbon, and nitrogen. However, the microbial dynamics of urban forest soils remain largely unknown. A key mechanistic link between plant species diversity and ecosystem function is heterotrophic microbial communities that inhabit the soil and mediate principal processes that control ecosystem carbon (C) and nitrogen (N) cycling. …

Structural And Metamorphic Evolution Of The Haimanta Group: Insights From P-T-T-D Path Modeling Of Rocks Near The Leo Pargil Dome, Nw India, Kyle Vincent White

Masters Theses

The metasedimentary rocks of the Haimanta Group in the upper Sutlej Valley, NW India, record an extensive history of Himalayan deformation and metamorphism. Situated beneath the low-grade metasediments of the Tethyan Sedimentary sequence in the hanging wall of the South Tibetan detachment system (STDS), these poly-deformed rocks record Eocene–Oligocene burial metamorphism, crustal thickening and shortening, decompression and mid-crustal melting in the early Miocene, and exhumation along extensional shear zones related to the orogen-parallel exhumation of the Leo Pargil dome (LPD). Low-pressure assemblages (cordierite + sillimanite + quartz) overgrow Barrovian porphyroblasts in Haimanta Group rocks in the NE portion of Sutlej …

Laser-Induced Breakdown Spectroscopy For Analysis Of High Density Methane-Oxygen Mixtures, Matthew Dackman

Masters Theses

The applicability of laser-induced breakdown spectroscopy (LIBS) toward greater than atmospheric density combustion diagnostics is examined. Specifically, this involves ascertaining the feasibility of measuring chemical equivalence ratios directly from atomic emission spectra at high density. The need for such measurement arises from the desire to quantify real time, localized combustion performance in weakly mixed flows. Insufficiently mixed flows generally result in unwanted byproducts, possess the propensity for overall combustion instability, and are increasingly likely to experience localized flame extinction.

We simulate methane/oxygen combustion in ambient pressures ranging 1 to 4 atmospheres, demonstrating these results to be analogous to what would …

Estimating Streambank Erosion Using Gps-Based Watershed-Scale Video Mapping And Usepa Bancs For The Development Of Sediment Tmdls, Kelsey Jo Hensley

Masters Theses

According to the United States Environmental Protection Agency (USEPA), sediment is one of the most common water pollutants in the nation’s rivers. Consequently, the identification of streambank locations with high erosion potential is important in reducing sediment input via management and monitoring practices. Furthermore, the estimation of erosion rates and sediment loads can assist in the development of Total Maximum Daily Loads (TMDLs). The objective of this study was to integrate two USEPA-recommended approaches with the Streambank Video Mapping System (SVMS) in order to predict site-specific Total Daily Sediment Loads (TDSLs) and calculate sediment TMDLs for streambank erosion over several …

Transport Of Fecal Pollution Indicators: Impacts From The Land Spreading Of Liquid Manure On Water Quality, Derek Lee Street

Masters Theses

This thesis is a case study to determine if groundwater and/or drainage tiles are important pathways for fecal migration to streams resulting from the application of liquid manure to cropland at a small dairy farm, the Little River Animal and Environmental Unit, near Townsend, TN. Traditional biological indicators, coliforms and E.coli, were used in conjunction with a bovine specific Bacteroides assay to measure fecal microbes. Total nitrates, turbidity, and other chemical parameters for water quality also were used to identify related fecal contamination. This thesis covers three separate manure applications. The first manure application occurred in May 2013, the …

Synthesis And Characterization Of Ln[Hfac]X And Ln[Fod]X Complexes For Thermochromatographic Separations, Matthew L. Marsh

Chancellor’s Honors Program Projects

No abstract provided.

The Phenomenon Of Outbound Medical Tourism In The United States, Tanner Douglas Cabbage

Chancellor’s Honors Program Projects

No abstract provided.

Pressure-Induced Magnetic Crossover Driven By Hydrogen Bonding In Cuf2(H2o)2(3-Chloropyridine), Kenneth R. O'Neal, Tatiana V. Brinzari, Joshua B. Wright, Chunli Ma, Santanab Giri, John A. Schlueter, Qian Wang, Puru Jena, Zhenxian Liu, Janice L. Musfeldt

Chemistry Publications and Other Works

Hydrogen bonding plays a foundational role in the life, earth, and chemical sciences, with its richness and strength depending on the situation. In molecular materials, these interactions determine assembly mechanisms, control superconductivity, and even permit magnetic exchange. In spite of its long-standing importance, exquisite control of hydrogen bonding in molecule-based magnets has only been realized in limited form and remains as one of the major challenges. Here, we report the discovery that pressure can tune the dimensionality of hydrogen bonding networks in CuF2(H2O)2(3-chloropyridine) to induce magnetic switching. Specifically, we reveal how the development of exchange pathways under compression combined with …

Evidence For Divisome Localization Mechanisms Independent Of The Min System And Slma In Escherichia Coli, Matthew W. Bailey, Paola Bisicchia, Boyd T. Warren, David J. Sherratt, Jaan Mannik

Physics and Astronomy Publications and Other Works

Cell division in Escherichia coli starts with assembly of FtsZ protofilaments into a ring-like structure, the Z-ring. Positioning of the Z-ring at midcell is thought to be coordinated by two regulatory systems, nucleoid occlusion and the Min system. In E. coli, nucleoid occlusion is mediated by the SlmA proteins. Here, we address the question of whether there are additional positioning systems that are capable of localizing the E. coli divisome with respect to the cell center. Using quantitative fluorescence imaging we show that slow growing cells lacking functional Min and SlmA nucleoid occlusion systems continue to divide preferentially at …

Growth, Structure, Electronic And Transport Properties Of Yttrium Disilicide Nanowires, Saban Mustafa Hus

Doctoral Dissertations

The electronic properties of low-dimensional materials deviate significantly from their bulk counterparts. Especially in quasi one-dimensional (1D) materials, a small number of structural defects can lead to strong electron localization. Electrons may also display unusual collective behavior in 1D. As integrated circuits continue to shrink in size, there is an increasing need for understanding and possibly manipulating electronic transport in quasi 1D materials. Here, we focus on electrical transport in self-assembled YSi₂ [yttrium disilicide] nanowires on Si(001). Being just a few atoms wide, these nanowires are one of the closest experimental realizations of a 1D conductor. YSi₂ nanowires …

Composition Dependence Of The Flory-Huggins Interaction Parameter In Polymer Blends: Structural And Thermodynamic Calculations, Travis H. Russell

Doctoral Dissertations

Flory-Huggins Theory has been the basis for understanding polymer solvent and blended polymer thermodynamics for much of the last 60 years. Within this theory, a parameter (χ) [chi] was included to quantify the enthalpic energy of dispersion between distinct components. Thin film self-assembly of polymer melts and block copolymers depends critically on this parameter, and in application, χ has generally been assumed to be independent of the concentrations of the individual components of the system. However, Small-Angle Neutron Scattering data on isotopic polymer blends, such as polyethylene and deuterated polyethylene, have shown a roughly parabolic concentration dependency for …

Predicting High-Stakes Tests Of Math Achievement Using A Group-Administered Rti Instrument: Validating Skills Measured By The Monitoring Instructional Responsiveness: Math, Jeremy Thomas Coles

Doctoral Dissertations

Three universal screeners and nine progress monitoring probes from the Monitoring Instructional Responsiveness: Math (MIR:M), a silent, group-administered math assessment designed for implementation with an RTI Model, were administered to 223 fifth-grade students. The growth parameters of the overall MIR:M composite and two global composites (math calculation and math reasoning) identified significant variation in student growth, within significant linear and quadratic trajectories. However, there were significant differences in the nature of the growth trajectories that have applied educational implications. In addition, growth parameters across the three composites provided significant predictive potential when using the Tennessee Comprehensive Assessment Program (TCAP) Achievement …

Examining The Process Of Identification In The Mathematics Classroom And The Role Of Students’ Academic Communities, Richard J. Robinson

Doctoral Dissertations

The primary purpose of this research was to provide insight into the identities students develop as they interact in a high school mathematics classroom. A normative divide developed which eventually split the classroom into two distinct academic factions: those who resisted the emerging local definition of what it meant to do mathematics and those who did not resist (i.e. complied or identified). A secondary purpose of this research was to understand the role of students’ academic communities in mathematics identity development. Student narratives helped uncover mathematical spaces outside the classroom that each developed their own unique definition of what it …

Exploring Martian Magmas: From The Mantle To The Regolith, Arya Sigrid Waltraud Udry

Doctoral Dissertations

The planet Mars is geologically more similar to Earth than to other planets of the solar system. For the past 50 years, new rovers, orbital spacecraft, and new martian meteorites have helped us to understand the geological processes that occurred on Mars. In this dissertation, I investigate a wide range of martian igneous compositions, such as shergottite and nakhlite meteorites, Gusev and Gale surface basalts, and the Northwest Africa (NWA) 7034 breccia. I attempt to better understand magmatic processes that occurred in the martian mantle and crust as well as surficial processes using various petrologic and geochemical tools.

As shown …

Impacts Of Climate Change On The Evolution Of The Electrical Grid, Melissa Ree Allen

Doctoral Dissertations

Maintaining interdependent infrastructures exposed to a changing climate requires understanding 1) the local impact on power assets; 2) how the infrastructure will evolve as the demand for infrastructure changes location and volume and; 3) what vulnerabilities are introduced by these changing infrastructure topologies. This dissertation attempts to develop a methodology that will a) downscale the climate direct effect on the infrastructure; b) allow population to redistribute in response to increasing extreme events that will increase under climate impacts; and c) project new distributions of electricity demand in the mid-21^st century.

The research was structured in three parts. The first …