Physical Sciences and Mathematics Commons^™

Photochemical Reactions Of Optically Active Chiral And Achiral Organic Materials, Nicie Conley Murphy

Doctoral Dissertations

Sodium chlorate, NaClO₃, which crystallizes in the space group P2₁3, forms optically active crystals upon crystallization although the molecule itself is achiral. NaClO₃, has been shown to produce an asymmetric distribution of (+) and (-) crystals when crystallized from water while stirring. It has been discovered that beta or positron radiation can also induce asymmetric crystallization in NaClO₃ solutions. Like NaClO₃, achiral 4,4’-dimethylchalcone crystallizes in enantiomeric forms in the space group P2₁3. Kondepudi et al. provided evidence that stirred crystallizations of 4,4’-dimethylchalcone can induce a bimodal distribution of …

Study Of The N = 77 Isotones Near The Proton-Drip Line; Isomeric Decays Of 140Eu, 142Tb, 144Ho, And 146Tm, Mohammed Noor Tantawy

Doctoral Dissertations

In this dissertation, the systematics of the [pi]h₁₁/₂ [tensor] [nu]h₁₁/₂ and [pi]h₁₁/₂ [tensor] [nu]s₁/₂ isomeric configurations were studied for the odd-Z, N = 77 isotones near the proton drip line. The isomeric decays in ¹⁴⁰Eu, ¹⁴²Tb, ¹⁴⁴Ho and ¹⁴⁶Tm were measured by means of X-ray, [gamma]-ray and charged particle spectroscopy at the Recoil Mass Spectrometer at the Holifield Radioactive Ion Beam Facility (HRIBF) at Oak Ridge National Laboratory (ORNL). The spin and parity of I[pi] = 8⁺ and 5⁻ were deduced for the isomers in ¹⁴⁰ Eu and ¹⁴²Tb. New decay schemes were established, and the half-lives of the 8⁺ …

Gravity In Extra Dimensions Of Infinite Volume, Chad Aaron Middleton

Doctoral Dissertations

In this thesis, we discuss various aspects of the Dvali-Gabadadze-Porrati (DGP) model in D-dimensions. Firstly, we generalize the DGP model, which consists of a delta-function type 3-brane embedded in an infinite volume bulk-space by allowing the 3-brane to have a finite thickness. We calculate the graviton propagator in the harmonic gauge both inside and outside the brane and discuss its dependence on the thickness of the brane. We obtain two infinite towers of massive modes and tachyonic ghosts. In the thin-brane limit, we recover the four-dimensional Einstein gravity behavior of the graviton propagator which was found in the delta-function treatment. …

The Ds/Cft Correspondence And Quasinormal Modes Of Black Holes, Scott Henry Ness

Doctoral Dissertations

In this thesis we discuss two aspects of quantum gravity and break it up in the following way. In part I, we discuss a scalar field theory living in de Sitter space-time. We may describe the infinite past or future as being boundaries of this space-time and, on these boundaries we construct a field theory. It has been shown by Strominger that there exists a correspondence between the bulk de Sitter space-time and the field theory living in the infinite past [1]. This may be described as a holographic principle, where information in the bulk de Sitter space-time corresponds to …

Interdisciplinary Approaches To New Chemical Analysis, David Lynn Rodman

Doctoral Dissertations

The primary focus of this dissertation is the development of new chemical analyses for inorganic, organic, and organometallic compounds. Interdisciplinary approaches combining analytical, polymer, inorganic, organic, and materials chemistry have been used to develop new analytical methods. Topics discussed in this dissertation include the development of a sol-gel based metal ion sensor, photochemical oxidation of a biomimetic Cr(III) complex, photochemical oxidation of organic ligands and other interferences in model Pd catalyst complexes, modified Fujiwara reactions for the detection of halogenated hydrocarbons, and the development of a controlled-release polymer for delivery of reagents needed for chemical sensing applications.

High Performance Parallel Approximate Eigensolver For Real Symmetric Matrices, Yihua Bai

Doctoral Dissertations

In the first-principles calculation of electronic structures, one of the most timeconsuming tasks is that of computing the eigensystem of a large symmetric nonlinear eigenvalue problem. The standard approach is to use an iterative scheme involving the solution to a large symmetric linear eigenvalue problem in each iteration. In the early and intermediate iterations, significant gains in efficiency may result from solving the eigensystem to reduced accuracy. As the iteration nears convergence, the eigensystem can be computed to the required accuracy.
Traditional real symmetric eigensolvers compute the eigensystem in three steps: 1) reduce a dense matrix to a symmetric tridiagonal …

Structural And Spectroscopic Studies Of Transition Metal Organometallic And Coordination Complexes With Reference To Catalysis, Megan Taliaferro Bragg

Doctoral Dissertations

Inorganic chemistry encompasses a variety of topics and in many ways, these advances affect a wider sphere of chemists than purely inorganic and progress in this field is interesting to many scientists. The developments presented in this dissertation are significant as they affect three issues: catalytic reactivity, ligand fluxionality, and catalyst development. Catalysis affects industrial profit, pharmaceutical development, agrochemical synthesis, spectroscopy, enzymatic activity, and polymerization.

Progress in certain areas such as the [Cp*Rh(TsDPEN)] (TsDPEN = p-toluenesulfonyldiphenylethylenediamine) has lead to a moiety that is a powerful and efficient catalyst for the reduction of C=N bonds. The precise mechanism of the …

The Development Of Building Block Methodologies To Produce Nanostructured Heterogeneous Catalysts By Design, Jason Curtis Clark

Doctoral Dissertations

Building block methods were successfully developed to demonstrate the potential of this approach to synthesizing nanostructured heterogeneous catalysts by design. The octa(trimethyltin) cuboctameric spherosilicate, Si₈O₂₀(SnMe₃)₈, was used as the building block for the synthesis of these materials. The solid state structure of this building block was characterized and compared to other solid state structures of Si₈O₁₂ containing compounds. These studies showed that this building block is composed of rigid tetrahedral units connect through a flexible siloxy bridge. The trimethyltin functionality present on this molecular precursor will react with metal …

Ac Loss And Thickness Dependence Of Critical Currents In Coated Conductors, Anota Oluwatoyin Ijaduola

Doctoral Dissertations

This program of research is directed toward understanding the physical properties of certain materials in superconductive “coated conductors.” Specifically investigated were Ni1−xWx alloys for use as substrate and thin films of YBa 2Cu3O7, a high- Tc superconductor with many attractive features. A study has been conducted on the magnetic properties of a series of biaxially textured Ni1−xWx materials with compositions x = 0, 3, 5, 6, and 9 at.% W. These materials are important as substrates for “RABiTS”-type coated conductors that incorporate high temperature superconductors for current transport. The quasi-static dc and ac …

Photo-Acoustic Analysis Of Dental Materials And Tissue, Pavlina Jetchkova Jeleva

Doctoral Dissertations

The goal of the presented study is the investigation of the feasibility of using optically generated acoustic waves for analysis of dental material below laser-ablation threshold.

The temperature rise of dental material and tissue has been modeled analytically and numerically, and measured experimentally. Following interactions with nano- and femto-second laser radiation the temperature rises at a rate of typically 1 ±C per J=cm2, along with the generation of an acoustical wave. The results from the models agree with the experiment. The acoustic measurements show differences in the acoustic signal strength and the frequency spectrum when the canal in the …

The Development Of Computational Tools For Halo Analysis And Study Of Halo Growth In The Spallation Neutron Source Linear Accelerator, Dirk A. Bartkoski

Masters Theses

The Spallation Neutron Source (SNS), being built at the Oak Ridge National Laboratory, utilizes a high intensity particle accelerator for neutron production. One of the challenges in SNS, as with all high intensity accelerators, is to minimize the amount of beam lost. High beam losses can cause costly damage and lead to residual activation of accelerator components, which complicates routine maintenance.

One of the key components in beam loss at SNS is the development and propagation of beam halo. Halo particles are those driven to large amplitudes by space charge forces between the beam particles or by mismatch between the …

Effect Of Surface Morphology On Adsorption-Induced Bending Of Microcantilevers, Ramya Desikan

Masters Theses

Microcantilevers undergo bending due to molecular adsorption when adsorption is confined to a single surface. The origin of the adsorption-induced force is assumed to be surface stress variation due to molecular adsorption. Single crystal silicon cantilevers were etched for a series of different time periods using two different types of Potassium Hydroxide solutions in order to obtain a rough and a smooth finish on the cantilever surface. Cantilevers that approximately had the same resonance frequency in the rough and smooth etched categories were chosen for comparison in the experiment. Liquid phase adsorption of 1-Do-decan-thiol on the cantilevers having a thin …

Unsaturated Flow And Transport Of 90Sr, Co(Ii)Edta, And U(Vi) In Undisturbed Cores From The Hanford Formation, Hanford, Wa, Mary Fairfax Nichols-Pace

Doctoral Dissertations

At the U.S. Department of Energy’s Hanford Site in Richland, WA nuclear processing wastes, such as Sr-90, organic chelating agents such as EDTA, Co-60, and U(VI) have been detected in the vadose zone beneath the underground storage tanks. There is concern that waste released to the vadose zone could reach the groundwater and eventually flow into the Columbia River. The goal of this paper is to provide an improved understanding of coupled hydrologic and geochemical mechanisms that influence contaminant transport in the Handford vadose zone. Disturbed sediment and undisturbed sediment cores were collected from the Environmental Restoration Disposal Facility (ERDF) …

Applications Of Genetic Algorithms To A Variety Of Problems In Physics And Astronomy, Kevin Richard Williams

Masters Theses

Genetic algorithms are search techniques that borrow ideas from the biological process of evolution. By means of natural selection, genetic algorithms can be employed as robust numerical optimizers on problems that would normally be extremely problematic due to ill-behaved search spaces. The genetic algorithm has an advantage in that it is a global optimization strategy, as opposed to more conventional methods, which will often terminate at local maxima.

The success and resourcefulness of genetic algorithms as problem-solving strategies are quickly gaining recognition among researchers of diverse areas of study. In this thesis I elaborate on applications of a genetic algorithm …

Stratigraphic And Structural Relationships Of The Ocoee Supergroup, Southern Appalachians: Implications For Neoproterzoic Rift Basin Architecture And Paleozoic Collisional Orogenesis, James Ryan Thigpen

Masters Theses

The late Proterozoic-Early Cambrian Ocoee Supergroup (OSG)is the dominant lithostratigraphic sequence of the western Blue Ridge (WBR) province in southeast Tennessee, southwest North Carolina, and northern Georgia. The OSG is divided into the basal Snowbird Group (SG) that nonconformably overlies Grenvillian basement, the thick Great Smoky Group (GSG) that is usually in fault contact with the Snowbird Group, and the Walden Creek Group (WCG) that directly underlies the Cambrian Chilhowee Group and conformably overlies both the Snowbird and Great Smoky Groups. Traditional interpretations suggest that the OSG was deposited during late Neoproterozoic-Early Cambrian rifting along the southeast Laurentian margin, initially …

Universal Geometric Camera Calibration With Statistical Model Selection, Chistopher Paul Broaddus

Masters Theses

We propose a new universal camera calibration approach that uses statistical information criteria for automatic camera model selection. It requires the camera to observe a planar pattern from different positions, and then closed-form estimates for the intrinsic and extrinsic parameters are computed followed by nonlinear optimization. In lieu of modeling radial distortion, the lens projection of the camera is modeled, and in addition we include decentering distortion. This approach is particularly advantageous for wide angle (fisheye) camera calibration because it often reduces the complexity of the model compared to modeling radial distortion. We then apply statistical information criteria to automatically …

Virus Transport During Transient Unsaturated And Steady-State Saturated Flow Conditions In Memphis Aquifer Sand, Andrew Boruff Kenst

Masters Theses

The overall goal of this research was to determine the effect of transient unsaturated flow conditions on the transport of a virus in aquifer material. It was hypothesized that viruses would be transported at the same rate and over the same distance as the migration of the wetting front and that virus retention during transient unsaturated flow would be similar to that during steady-state saturated flow. Virus transport during transient unsaturated horizontal flow was experimentally compared with its behavior under steady-state saturated vertical flow. In the transient flow experiment, virus (ΦX174) suspension was introduced into an initially air-dry repacked Memphis …

Deciphering Eustatic And Tectonic Influences During Parasequence Development In The Mesoprotozoic Helena/Wallace Formation, Belt Supergroup, Montana And Idaho, Stephen Alan Welch

Masters Theses

The stratigraphic architecture of sedimentary basins results from a combination of changes in relative sea-level and tectonism, and resulting changes in sediment supply. The Helena/Wallace formations, Mesoproterozoic Belt Supergroup, Montana and Idaho, consists of >500 meters of stacked meter-scale cycles (parasequences) that record in situ carbonate deposition as well as siliciclastic deposition from both the Laurentian craton and an unknown (tectonically active?) western source. In this study, statistical methods and 2-D forward modeling are combined with geochemical provenance analysis to examine parasequence stacking patterns and decipher the relative eustatic and tectonic controls on sequence development.

Helena/Wallace parasequences are typically composed …

Pedologic Investigations In The Red River Region Of Eastern Kentucky: Relationship Of Soil Properties To Lithology, Slope Aspect, And Soil Quality To Prehistoric Indigenous Food Plot Locations, Jason D. Windingstad

Masters Theses

ABSTRACT

Part I

The Red River Valley of Eastern Kentucky contains cultural remains that point to the independent development of agriculture during the Late Archaic cultural period. The objective of this study is to gather quantitative data through the chemical and physical analysis of soils collected within a valley transect to gain insights into landscape processes and soil quality that may have played a role in the development of plant domestication. National Cooperative Soil Survey standards were used for field descriptions and the chemical and physical analysis of all samples. Soil quality values such as ECEC (ammonium acetate pH 7), …

A Reliability Case Study On Estimating Extremely Small Percentiles Of Strength Data For The Continuous Improvement Of Medium Density Fiberboard Product Quality, Weiwei Chen

Masters Theses

The objective of this thesis is to better estimate extremely small percentiles of strength distributions for measuring failure process in continuous improvement initiatives. These percentiles are of great interest for companies, oversight organizations, and consumers concerned with product safety and reliability. The thesis investigates the lower percentiles for the quality of medium density fiberboard (MDF). The international industrial standard for measuring quality for MDF is internal bond (IB, a tensile strength test). The results of the thesis indicated that the smaller percentiles are crucial, especially the first percentile and lower ones.

The thesis starts by introducing the background, study objectives, …

Parity Theorems For Combinatorial Statistics, Mark A. Shattuck

Doctoral Dissertations

A q-generalization Gn(q) of a combinatorial sequence Gn which reduces to that sequence when q = 1 is obtained by q-counting a statistic defined on a sequence of finite discrete structures enumerated by Gn. In what follows, we evaluate Gn(−1) for statistics on several classes of discrete structures, giving both algebraic and combinatorial proofs. For the latter, we define appropriate sign-reversing involutions on the associated structures. We shall call the actual algebraic result of such an evaluation at q = −1 a parity theorem (for the …

Structural And Stratigraphic Investigations Of The Bays Mountain Synclinorium, Parrottsville And A Portion Of Cedar Creek 7.5-Minute Quadrangles, East Tennessee, Neil E. Whitmer

Masters Theses

The southern Valley and Ridge foreland fold-thrust belt is comprised of a wedge of Lower Cambrian through Pennsylvanian sedimentary rocks that were folded and faulted during the late stages of the Alleghanian orogeny. Within one of the eastern thrust sheets lies the Bays Mountain synclinorium. Rocks as young as Middle Ordovician are preserved in the core of the synclinorium and record the evolution of a Taconian (Blountian) Sevier tectonic basin.

The Parrottsville and Cedar Creek 7.5-minute quadrangles are located on the southeastern flank of the Bays Mountain synclinorium of East Tennessee and contain rocks belonging to the Conasauga, Knox, and …

Development Of A Dilatant Damage Zone Along A Thrust Relay In A Low-Porosity Quartz Arenite, Jennie E. Cook

Masters Theses

A damage zone developed along a backthrust fault system in well-cemented quartz arenite of the Tuscarora Sandstone in the Alleghanian foreland thrust system consists of a network of NW-dipping thrusts that are linked by multiple higher-order faults and bound a zone of intense extensional fractures and breccias. The damage zone is unusual in that it preserves porous brittle fabrics despite formation at >5km depth. The damage zone developed at an extensional step-over between two independent, laterally propagating backthrusts. Continued displacement resulted in breaching of the relay and formation of faultbounded horses, and favored the formation of extensional fractures. The presence …

Obtaining High Precision Results From Low Precision Hardware, Adam Donald Graham

Masters Theses

This document describes an attempt at acheiving high precision matrix multiplication results from the Lenslet EnLight256 Optical Signal Processor (OSP), which on its own can only produce results which are hardware limited to 8-bit signed integers. Due to it’s low precision, it’s has only limited applicability to real world problems, and if higher precision results were possible from the machine it could be used for more applications. A C library is developed for this thesis to allow high-precision results from the EnLight256. The library is described and results are given. Finally an implementation of the Jacobi Method on the EnLight256 …

Detection Of Enteric Viruses In East Tennessee Public Ground Water Systems, Trisha Baldwin Johnson

Masters Theses

A two-part study was conducted by University of Tennessee-Knoxville, the U.S. Geological Survey, and the U.S. Environmental Protection Agency-National Exposure Research Laboratory to (1) develop, validate, and test a real-time reverse transcription-polymerase chain reaction (real-time RT-PCR) assay for enteroviruses in ground water samples and to (2) perform the first survey of enteric viral occurrence in the karst aquifers of East Tennessee. Karst aquifers are expected to have a high susceptibility to viral contamination because of the rapid flow (100’s of m/day) and frequent occurrence of fecal indicator bacteria typically observed in these systems.

Real-time RT-PCR primers and probes specific for …

Development Of A Dilatant Damage Zone Along A Thrust Relay In A Low-Porosity Quartz Arenite, Jennie E. Cook

Masters Theses

A damage zone developed along a backthrust fault system in well-cemented quartz arenite of theTuscarora Sandstone in the Alleghanian foreland thrust system consists of a network of NW-dipping thrusts that are linked by multiple higher-order faults and bound a zone of intense extensional fractures and breccias. The damage zone is unusual in that it preserves porous brittle fabrics despite formation at >5km depth. The damage zone developed at an extensional step-over between two independent, laterally propagating backthrusts. Continued displacement resulted in breaching of the relay and formation of faultbounded horses, and favored the formation of extensional fractures. The presence of …

Seasonal Forage Availability And Diet Of Reintroduced Elk In The Cumberland Mountains, Tennessee, Jason Lee Lupardus

Masters Theses

The Tennessee Wildlife Resources Agency (TWRA) reintroduced elk (Cervus elaphus manitobensis) into the Cumberland Mountains, Tennessee over a 3-year period beginning in December 2000. We radio-collared 160 elk and monitored them by aerial telemetry from February 2001 to June 2003. Locations (n = 1450) were used in a geographic information system (GIS) to develop a core herd home range (789-ha sampling area) to assess elk seasonal forage use and availability. We monitored diet and resource availability from November 2003 to October 2004 by vegetation sampling and microhistological analysis of feces. Tall fescue (Festuca arundinacea; 35.1%) dominated …

Synthesis Of 123-Iodine Labeled Rofecoxib Analogues: Potential Nuclear Medicine Imaging Agents, Brandy U. Belue

Masters Theses

Single photon emission computed tomography (SPECT) is a medical imaging technique which provides three-dimensional images ofliving systems after introduction ofa radiolabeled pharmaceutical. Rofecoxib (4-[ 4-methylsulphonylphenyl]-3phenylfuran-2(SH)-one) is an inhibitor of the cycloxygenase-2 enzyme, an enzyme which has been found to promote cancer cell growth. The synthesis of a no-carrier-added iodine-123 labeled rofecoxib derivative is potentially of value for the detection of cancer utilizing SPECT.

Iodine-123 labeled -(3-Iodophenyl)-4-(methanesulfonylphenyl)-SH furan-2-one, 1, and 3-(4-Iodophenyl)-4-(methanesulfonylphenyl)-5H-furan-2-one, 2, were prepared from the respective potassium organotrifluoroborate salts. The trifluoroborates were prepared from a simple six step pathway.

Identification Of Terrestrial Alkalic Rocks Using Thermal Emission Spectroscopy: Applications To Martian Remote Sensing, Tasha Laurrelle Dunn

Masters Theses

We present a detailed study examining the use of laboratory thermal emission spectra (5-25 μm at 2 cm^-1 spectral sampling) for identification and classification of alkalic volcanic rocks. Modal mineralogies and derived bulk rock chemistries of a suite of terrestrial alkali basalts, trachyandesites, trachytes, and rhyolites were determined using linear spectral deconvolution. Model-derived mineral modes were compared to modes measured using an electron microprobe mapping technique to access the accuracy of linear deconvolution in determining mineral abundances. Standard deviations of 1σ of absolute differences between measured and modeled mineral abundances range from 0.68 to 15.02 vol %, with …

Cross Sections Fall 2005, Department Of Physics And Astronomy

Cross Sections

No abstract provided.