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Articles 271 - 300 of 7311

Full-Text Articles in Physical Sciences and Mathematics

Comparative Nitrene-Transfer Chemistry To Olefins Mediated By First-Row Transition Metal Catalysts Supported By A Pyridinophane Macrocycle With N4 Ligation, Himanshu Bhatia, Lillian P. Adams, Ingrid Cordsiemon, Suraj Kumar Sahoo, Amitava Choudhury, Thomas R. Cundari, Pericles Stavropoulos Aug 2025

Comparative Nitrene-Transfer Chemistry To Olefins Mediated By First-Row Transition Metal Catalysts Supported By A Pyridinophane Macrocycle With N4 Ligation, Himanshu Bhatia, Lillian P. Adams, Ingrid Cordsiemon, Suraj Kumar Sahoo, Amitava Choudhury, Thomas R. Cundari, Pericles Stavropoulos

Chemistry Faculty Research & Creative Works

A 12-membered pyridinophane scaffold containing two pyridine and two tertiary amine residues is examined as a prototype ligand (tBuN4) for supporting nitrene transfer to olefins. The known [(tBuN4)MII(MeCN)2]2+ (M = Mn, Fe, Co, and Ni) and [(tBuN4)CuI(MeCN)]+ cations are synthesized with the hexafluorophosphate counteranion. The aziridination of para-substituted styrenes with PhI=NTs (Ts = tosyl) in various solvents proved to be high yielding for the Cu(I) and Cu(II) reagents, in contrast to the modest efficacy of all other metals. For α-substituted styrenes, aziridination is accompanied by products of aziridine …

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Visceral, Neural, And Immunotoxicity Of Per- And Polyfluoroalkyl Substances: A Mini Review, Pietro Martano, Samira Mahdi, Tong Zhou, Yasmin Barazandegan, Rebecca Iha, Hannah Do, Joel Burken, Paul Ki-Souk Nam, Qingbo Yang, Ruipu Mu Aug 2025

Visceral, Neural, And Immunotoxicity Of Per- And Polyfluoroalkyl Substances: A Mini Review, Pietro Martano, Samira Mahdi, Tong Zhou, Yasmin Barazandegan, Rebecca Iha, Hannah Do, Joel Burken, Paul Ki-Souk Nam, Qingbo Yang, Ruipu Mu

Chemistry Faculty Research & Creative Works

Per- and polyfluoroalkyl substances (PFASs) have gained significant attention due to their widespread distribution in the environment and potential adverse health effects. While ingestion, especially through contaminated drinking water, is considered the primary route of human exposure, recent research suggests that other pathways, such as inhalation and dermal absorption, also play a significant role. This review provides a concise overview of the toxicological impacts of both legacy and emerging PFASs, such as GenX and perfluoro butane sulfonic acid (PFBS), with a particular focus on their effects on the liver, kidneys, and immune and nervous systems, based on findings from recent …

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Mantle Flow And Crustal Deformation Revealed By Seismic Anisotropy In The Subduction Zone Beneath Myanmar, Enbo Fan, Mingming Jiang, Yinshuang Ai, Stephen S. Gao, Kelly H. Liu, Yumei He, Yiming Bai, Guangbing Hou, Yuan Ling, Chit Thet Mon, Myo Thant, Kyaing Sein Aug 2025

Mantle Flow And Crustal Deformation Revealed By Seismic Anisotropy In The Subduction Zone Beneath Myanmar, Enbo Fan, Mingming Jiang, Yinshuang Ai, Stephen S. Gao, Kelly H. Liu, Yumei He, Yiming Bai, Guangbing Hou, Yuan Ling, Chit Thet Mon, Myo Thant, Kyaing Sein

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

The oblique convergence of the Indian and Eurasian plates drives significant deformation in the crust and mantle beneath Myanmar. However, the crustal deformation in the Indo-Burman Ranges (IBR) and mantle flow beneath Myanmar and adjacent areas remain unclear due to limited studies. We utilized data from the newly deployed second phase of the China-Myanmar Geophysical Survey of the Myanmar Orogen array to perform shear wave splitting analysis of PKS, SKKS, and SKS (XKS) phases. Our results, together with previous findings, provide new insights into mantle flow and crustal deformation across central Myanmar. In the IBR, we observed a transition from …

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Squeezing Information From Radio Surveys To Probe The Primordial Universe, Dionysios Karagiannis, Roy Maartens, Shun Saito, José Fonseca, Stefano Camera, Chris Clarkson Aug 2025

Squeezing Information From Radio Surveys To Probe The Primordial Universe, Dionysios Karagiannis, Roy Maartens, Shun Saito, José Fonseca, Stefano Camera, Chris Clarkson

Physics Faculty Research & Creative Works

A major goal of cosmology is to understand the nature of the field(s) which drove primordial Inflation. Through future observations, the statistics of large-scale structure will allow us to probe primordial non-Gaussianity of the curvature perturbation at the end of Inflation. We show how a new correlation statistic can significantly improve these constraints over conventional methods. Next-generation radio telescope arrays are under construction which will map the density field of neutral hydrogen to high redshifts. These telescopes can operate as an interferometer, able to probe small scales, or as a collection of single dishes, combining signals to map the large …

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“Silent Is Not Actually Silent”: An Investigation Of Toxicity On Bug Report Discussion, Mia Mohammad Imran, Jaydeb Sarker Jul 2025

“Silent Is Not Actually Silent”: An Investigation Of Toxicity On Bug Report Discussion, Mia Mohammad Imran, Jaydeb Sarker

Computer Science Faculty Research & Creative Works

Toxicity in bug report discussions poses significant challenges to the collaborative dynamics of open-source software development. Bug reports are crucial for identifying and resolving defects, yet their inherently problem-focused nature and emotionally charged context make them susceptible to toxic interactions. This study explores toxicity in GitHub bug reports through a qualitative analysis of 203 bug threads, including 81 toxic ones. Our findings reveal that toxicity frequently arises from misaligned perceptions of bug severity and priority, unresolved frustrations with tools, and lapses in professional communication. These toxic interactions not only derail productive discussions but also reduce the likelihood of actionable outcomes, …

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Llput: Investigating Large Language Models For Bug Report-Based Input Generation, Alif Al Hasan, Subarna Saha, Mia Mohammad Imran, Tarannum Shaila Zaman Jul 2025

Llput: Investigating Large Language Models For Bug Report-Based Input Generation, Alif Al Hasan, Subarna Saha, Mia Mohammad Imran, Tarannum Shaila Zaman

Computer Science Faculty Research & Creative Works

Failure-inducing inputs play a crucial role in diagnosing and analyzing software bugs. Bug reports typically contain these inputs, which developers extract to facilitate debugging. Since bug reports are written in natural language, prior research has leveraged various Natural Language Processing (NLP) techniques for automated input extraction. With the advent of Large Language Models (LLMs), an important research question arises: how effectively can generative LLMs extract failure-inducing inputs from bug reports? In this paper, we propose LLPut, a technique to empirically evaluate the performance of three open-source generative LLMs-LLaMA, Qwen, and Qwen-Coder-in extracting relevant inputs from bug reports. We conduct an …

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Deformation And Earthquake Potential On The North America - Caribbean - Cocos Triple Junction In Guatemala, Jeremy Maurer, Andreas Eckert, Qiaoqi Sun, Jonathan Obrist-Farner Jul 2025

Deformation And Earthquake Potential On The North America - Caribbean - Cocos Triple Junction In Guatemala, Jeremy Maurer, Andreas Eckert, Qiaoqi Sun, Jonathan Obrist-Farner

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

The triple junction between the Cocos (CO), North American (NA), and Caribbean (CA) tectonic plates in Guatemala is a region of high seismic risk and includes many large faults and historic earthquakes. Previous analyses of the tectonic system have been overly simplified, resulting in discrepancies between geologically derived and geodetic models of fault slip rate. This study leverages available geodetic, seismic, and geologic data to develop new strain rate maps and faulting models for the region. We find that locking on the regional faults matches historic reports of large earthquakes and that multiple minor fault segments are active and accommodate …

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Qder: Query-Specific Document And Entity Representations For Multi-Vector Document Re-Ranking, Shubham Chatterjee, Jeff Dalton Jul 2025

Qder: Query-Specific Document And Entity Representations For Multi-Vector Document Re-Ranking, Shubham Chatterjee, Jeff Dalton

Computer Science Faculty Research & Creative Works

Neural IR has advanced through two distinct paths: entity-oriented approaches leveraging knowledge graphs and multi-vector models capturing fine-grained semantics. We introduce QDER, a neural re-ranking model that unifies these approaches by integrating knowledge graph semantics into a multi-vector model. QDER's key innovation lies in its modeling of query-document relationships: rather than computing similarity scores on aggregated embeddings, we maintain individual token and entity representations throughout the ranking process, performing aggregation only at the final scoring stage-an approach we call "late aggregation." We first transform these fine-grained representations through learned attention patterns, then apply carefully chosen mathematical operations for precise matches. …

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Orbital Modulation Of Gamma Rays Up To 100 Tev From Ls 5039, R. Alfaro, M. Araya, J. C. Arteaga-Velázquez, D. Avila Rojas, H. A. Ayala Solares, R. Babu, P. Bangale, E. Belmont-Moreno, A. Bernal, K. S. Caballero-Mora, T. Capistrán, A. Carramiñana, S. Casanova, U. Cotti, J. Cotzomi, S. Coutiño De León, D. Depaoli, P. Desiati, N. Di Lalla, R. Diaz Hernandez, B. L. Dingus, M. A. Duvernois, K. Engel, T. Ergin, C. Espinoza, K. L. Fan, K. Fang, J. A. Garcia-Gonzalez, H. Goksu, A. Gonzalez Munoz, J. A. Gonzalez, M. M. Gonzalez, J. A. Goodman, S. Groetsch, J. P. Harding, S. Hernandez-Cadena, I. Herzog, J. Hinton, D. Huang, F. Hueyotl-Zahuantitla, P. Huntemeyer, S. Kaufmann, D. Kieda, A. Lara, J. Lee, H. Leon Vargas, J. T. Linnemann, A. L. Longinotti, G. Luis-Raya, K. Malone, O. Martinez, J. Martinez-Castro, J. A. Matthews, P. Miranda-Romagnoli, J. A. Morales-Soto, E. Moreno, M. Mustafa, M. Najafi, L. Nellen, M. U. Nisa, N. Omodei, E. Ponce, Y. Perez Araujo, E. G. Perez-Perez, C. D. Rho, A. Rodriguez Parra, D. Rosa-Gonzalez, M. Roth, H. Salazar, D. Salazar-Gallegos, A. Sandoval, M. Schneider, G. Schwefer, J. Serna-Franco, A. J. Smith, Y. Son, R. W. Springer, O. Tibolla, K. Tollefson, I. Torres, R. Torres-Escobedo, R. Turner, E. Varcla, Xiaojie Wang, Z. Wang, I. J. Watson, H. Wu, S. Yu, S. Yun-Carcamo, H. Zhou, C. De Leon Jul 2025

Orbital Modulation Of Gamma Rays Up To 100 Tev From Ls 5039, R. Alfaro, M. Araya, J. C. Arteaga-Velázquez, D. Avila Rojas, H. A. Ayala Solares, R. Babu, P. Bangale, E. Belmont-Moreno, A. Bernal, K. S. Caballero-Mora, T. Capistrán, A. Carramiñana, S. Casanova, U. Cotti, J. Cotzomi, S. Coutiño De León, D. Depaoli, P. Desiati, N. Di Lalla, R. Diaz Hernandez, B. L. Dingus, M. A. Duvernois, K. Engel, T. Ergin, C. Espinoza, K. L. Fan, K. Fang, J. A. Garcia-Gonzalez, H. Goksu, A. Gonzalez Munoz, J. A. Gonzalez, M. M. Gonzalez, J. A. Goodman, S. Groetsch, J. P. Harding, S. Hernandez-Cadena, I. Herzog, J. Hinton, D. Huang, F. Hueyotl-Zahuantitla, P. Huntemeyer, S. Kaufmann, D. Kieda, A. Lara, J. Lee, H. Leon Vargas, J. T. Linnemann, A. L. Longinotti, G. Luis-Raya, K. Malone, O. Martinez, J. Martinez-Castro, J. A. Matthews, P. Miranda-Romagnoli, J. A. Morales-Soto, E. Moreno, M. Mustafa, M. Najafi, L. Nellen, M. U. Nisa, N. Omodei, E. Ponce, Y. Perez Araujo, E. G. Perez-Perez, C. D. Rho, A. Rodriguez Parra, D. Rosa-Gonzalez, M. Roth, H. Salazar, D. Salazar-Gallegos, A. Sandoval, M. Schneider, G. Schwefer, J. Serna-Franco, A. J. Smith, Y. Son, R. W. Springer, O. Tibolla, K. Tollefson, I. Torres, R. Torres-Escobedo, R. Turner, E. Varcla, Xiaojie Wang, Z. Wang, I. J. Watson, H. Wu, S. Yu, S. Yun-Carcamo, H. Zhou, C. De Leon

Physics Faculty Research & Creative Works

Gamma-ray binaries are luminous in gamma rays, composed of a compact object orbiting a massive companion star. The interaction between these two objects can drive relativistic outflows, either jets or winds, in which particles can be accelerated to energies reaching hundreds of teraelectronvolts (TeV). However, it is still debated where and under which physical conditions particles are accelerated in these objects and ultimately whether protons can be accelerated up to PeV energies. Among the well-known gamma-ray binaries, LS 5039 is a high-mass X-ray binary with an orbital period of 3.9 days that has been observed up to TeV energies by …

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Domain-Adaptive Diagnosis Of Lewy Body Disease With Transferability Aware Transformer, Xiaowei Yu, Jing Zhang, Tong Chen, Yan Zhuang, Minheng Chen, Chao Cao, Yanjun Lyu, Lu Zhang, Li Su, Tianming Liu, Dajiang Zhu Jul 2025

Domain-Adaptive Diagnosis Of Lewy Body Disease With Transferability Aware Transformer, Xiaowei Yu, Jing Zhang, Tong Chen, Yan Zhuang, Minheng Chen, Chao Cao, Yanjun Lyu, Lu Zhang, Li Su, Tianming Liu, Dajiang Zhu

Computer Science Faculty Research & Creative Works

Lewy Body Disease (LBD) is a common yet understudied form of dementia that imposes a significant burden on public health. It shares clinical similarities with Alzheimer’s disease (AD), as both progress through stages of normal cognition, mild cognitive impairment, and dementia. A major obstacle in LBD diagnosis is data scarcity, which limits the effectiveness of deep learning. In contrast, AD datasets are more abundant, offering potential for knowledge transfer. However, LBD and AD data are typically collected from different sites using different machines and protocols, resulting in a distinct domain shift. To effectively leverage AD data while mitigating domain shift, …

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Coordinating Instruments For Multi-Messenger Astrophysics, Daisy Wang, Ye Htet, Marion Sudvarg, Roger Chamberlain, Jeremy Buhler, James Buckley Jul 2025

Coordinating Instruments For Multi-Messenger Astrophysics, Daisy Wang, Ye Htet, Marion Sudvarg, Roger Chamberlain, Jeremy Buhler, James Buckley

Computer Science Faculty Research & Creative Works

In multi-messenger astrophysics, signals of multiple types (e.g., gravitational waves, neutrinos, electromagnetic waves) are combined in an effort to learn more about the observed phenomena of interest. The Advanced Particle-astrophyics Telescope (APT) is a mission concept for a space-borne instrument that detects gammaray bursts (GRBs) omnidirectionally, facilitating multi-messenger observations by identifying and localizing celestial events of interest. Here, we describe the on-instrument computations for APT and its Antarctic Demonstrator (ADAPT) as well as techniques for follow-up observations of transient events.

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Retraction: A Database Of Teleseismic Shear-Wave Splitting Measurements For The Ordos Block And Adjacent Areas(Seismological Research Letters (2022), 93, 5, (2731–2739), 10.1785/0220210310), Lin Liu, Stephen S. Gao, Kelly H. Liu, Tu Xue, Yan Jia, Sanzhong Li Jul 2025

Retraction: A Database Of Teleseismic Shear-Wave Splitting Measurements For The Ordos Block And Adjacent Areas(Seismological Research Letters (2022), 93, 5, (2731–2739), 10.1785/0220210310), Lin Liu, Stephen S. Gao, Kelly H. Liu, Tu Xue, Yan Jia, Sanzhong Li

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

An earlier version of this article (Liu et al., 2022) included private data from the Himalayan-III program which should not have been made public. The authors acknowledge and regret their negligence during the selection of the measurements. The impacted data represent only 2.7% of the total data published in this article, and after review, the authors and the editors agree that this unintentional error has no bearing on the work's scientific conclusions. Therefore, we are retracting the impacted data and have made corrections to remove any Himalayan-III program data from the article's text, figures, and supplemental tables.

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Investigating The Thixotropy Of Fresh Struvite Cement-Based Composite: Insights On Mechanisms Of The Pastes’ Thixotropic Behavior, Ugochukwu Ewuzie, Abdulkareem O. Yusuf, Damilola Daramola, Monday Uchenna Okoronkwo Jul 2025

Investigating The Thixotropy Of Fresh Struvite Cement-Based Composite: Insights On Mechanisms Of The Pastes’ Thixotropic Behavior, Ugochukwu Ewuzie, Abdulkareem O. Yusuf, Damilola Daramola, Monday Uchenna Okoronkwo

Chemical and Biochemical Engineering Faculty Research & Creative Works

Struvite (ST) recovered during wastewater treatment has been sparsely applied in cement-based composites. This study systematically evaluated the thixotropic behavior of cement-struvite (CST) pastes, a mix of 5–20 % ST by mass of cement, and proposed the interaction mechanisms leading to the pastes' thixotropy. The hysteresis loop area was used to establish the pastes' thixotropy and investigate its relationship with increased ST content, temperature, and yield stress. In the thixotropic behavior model used, the equilibrium shear stress was employed to examine the CST pastes' irreversible change; the characteristic time of deflocculation was used to study the flocs destruction process; and …

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Deciphering A Quantitative Relationship Between Rifting And Crustal Melt Fraction: Insights From The Incipient Okavango Rift Zone, Tuo Wang, Ling Chen, Stephen S. Gao, Kelly H. Liu Jun 2025

Deciphering A Quantitative Relationship Between Rifting And Crustal Melt Fraction: Insights From The Incipient Okavango Rift Zone, Tuo Wang, Ling Chen, Stephen S. Gao, Kelly H. Liu

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Rifting and magmatism are fundamental geological processes in the evolution of the lithosphere; however, quantitative investigations of their relationship are rare. The Okavango Rift Zone (ORZ) is in the early stages of rifting and magmatic activity and thus is an ideal locale to study this relationship. We examine the relationship using two primary crustal structure parameters: crustal thickness and average Vp/Vs ratio obtained from receiver functions. Our large Vp/Vs estimates indicate the existence of melts within the crust of the ORZ. Comparing our results with those of other continental rifts, we identify a quantitative relationship between rifting and crustal melt …

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A Promising Statistical Approach For Studying The Collisional Excitation Induced By Co: Application To The Cs-Co System, Amélie Godard Palluet, Richard Dawes, Ernesto Quintas-Sánchez, Adrian Batista-Planas, François Lique Jun 2025

A Promising Statistical Approach For Studying The Collisional Excitation Induced By Co: Application To The Cs-Co System, Amélie Godard Palluet, Richard Dawes, Ernesto Quintas-Sánchez, Adrian Batista-Planas, François Lique

Chemistry Faculty Research & Creative Works

The calculations of rate coefficients for the interpretation of molecular spectra are a recognized computationally expensive task. This is particularly true for media like comets, where the dominant species (CO, CO2, and H2O) have relatively high masses. Currently, no clear methodology exists to treat the collisional excitation of heavy species at low temperatures, thus limiting the number of collisional studies on such species. We present here a promising statistical approach to determine collisional rate coefficients of heavy systems as an alternative to fully quantum calculations when heavy projectiles such as CO are considered. This is illustrated …

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Ceno: Non-Uniform, Segment And Parallel Zero-Knowledge Virtual Machine, Tianyi Liu, Zhenfei Zhang, Yuncong Zhang, Wenqing Hu, Ye Zhang Jun 2025

Ceno: Non-Uniform, Segment And Parallel Zero-Knowledge Virtual Machine, Tianyi Liu, Zhenfei Zhang, Yuncong Zhang, Wenqing Hu, Ye Zhang

Mathematics and Statistics Faculty Research & Creative Works

In this paper, we explore a novel Zero-knowledge Virtual Machine (zkVM) framework leveraging succinct, non-interactive zero-knowledge proofs for verifiable computation over any code. Our approach divides the proof of program execution into two stages. In the first stage, the process breaks down program execution into segments, identifying and grouping identical sections. These segments are then proved through data-parallel circuits that allow for varying amounts of duplication. In the subsequent stage, the verifier examines these segment proofs, reconstructing the program's control and data flow based on the segments' duplication number and the original program. The second stage can be further attested …

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Maximizing Edge Connectivity In Graph Partitioning Using Hotspots, Isam A. Alobaidi, Hiba G. Fareed, Jennifer L. Leopold, Andrea E. Smith Jun 2025

Maximizing Edge Connectivity In Graph Partitioning Using Hotspots, Isam A. Alobaidi, Hiba G. Fareed, Jennifer L. Leopold, Andrea E. Smith

Computer Science Faculty Research & Creative Works

Graphs have long been used to model relationships between entities. For some applications, a single graph is sufficient; for other problems, a collection of graphs may be more appropriate to represent the underlying data. Many contemporary problem domains, for which graphs are an ideal data model, contain an enormous amount of data (e.g., social networks). Hence, researchers frequently employ parallelized or distributed processing. The graph data must first be partitioned and assigned to the multiple processors in a way that the workload is balanced and inter-processor communication is minimized. The latter problem may be complicated by the existence of edges …

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Performance Evaluation Of Aminated Multi-Walled Carbon Nanotubes Incorporated With Green Synthesized Iron Nanoparticles For Toxic Dyes Sequestration From Textile Wastewater, Titus Chinedu Egbosiuba, Cynthia Chukwuemeka, Jonah Chukwudi Umeuzuegbu, Nwanneka Chibuzo Mmonwuba, Ugochukwu Ewuzie, Monday Uchenna Okoronkwo, Valentine Chikaodili Anadebe, Saheed Mustapha, Ambali Saka Abdulkareem, Jimoh Oladejo Tijani, Ashish Patel, Virendra Kumar Yadav Jun 2025

Performance Evaluation Of Aminated Multi-Walled Carbon Nanotubes Incorporated With Green Synthesized Iron Nanoparticles For Toxic Dyes Sequestration From Textile Wastewater, Titus Chinedu Egbosiuba, Cynthia Chukwuemeka, Jonah Chukwudi Umeuzuegbu, Nwanneka Chibuzo Mmonwuba, Ugochukwu Ewuzie, Monday Uchenna Okoronkwo, Valentine Chikaodili Anadebe, Saheed Mustapha, Ambali Saka Abdulkareem, Jimoh Oladejo Tijani, Ashish Patel, Virendra Kumar Yadav

Chemical and Biochemical Engineering Faculty Research & Creative Works

This study evaluates the performance of aminated multi-walled carbon nanotubes (AM-MWCNTs) integrated with zerovalent iron nanoparticles (ZVI) synthesized using cashew leaf (Anacardium occidentale) extract (AM-MWCNTs@ZVI) for the removal of Congo Red (CR) and Methylene Blue (MB) dyes from textile industrial wastewater. The nanocomposite was characterized using FTIR, XRD, BET, HRSEM, and HRTEM analyses, confirming its functional groups, crystalline structure, and enhanced surface area of 1050.4 m2/g. The ecological risk degree of the textile pollutants was assessed to determine the percentage concentrations of crystal violet, Congo red, methyl orange, methylene blue and rhodamine B. Batch adsorption experiments identified optimal …

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The Influence Of Black Soldier Fly Residue On Watermelon Growth And The Properties Of A Coarse-Textured Ultisol, Benedict Onyebuchi Unagwu, Chidiebere Fransica Odu, Chinedu Felix Amuji, Michael Onyedika Eze, Nancy Ekene Ebido, Chidike Ude Abara, Chioma Rosita Igboka, Uchechukwu Paschal Chukwudi Jun 2025

The Influence Of Black Soldier Fly Residue On Watermelon Growth And The Properties Of A Coarse-Textured Ultisol, Benedict Onyebuchi Unagwu, Chidiebere Fransica Odu, Chinedu Felix Amuji, Michael Onyedika Eze, Nancy Ekene Ebido, Chidike Ude Abara, Chioma Rosita Igboka, Uchechukwu Paschal Chukwudi

Chemistry Faculty Research & Creative Works

Improving the fertility status of nutrient-depleted soils is critical to achieving food security. The negative effects of chemical fertilizers on soils necessitate the global quest for eco-friendly, effective, and sustainable alternatives. This work assessed the effect of black soldier fly (BSF) residue application on soil properties and watermelon growth. The study was set up in a completely randomized design with six replications. The treatments were BSF1 (BSF applied at 10 t ha−1), BSF2 (20 t ha−1), BSF3 (30 t ha−1), and control. The plant data collected in this study were vine length, leaf width, …

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Investigation Of Retention And Dehydration Of Preformed Particle Gel For Conformance Control In Fractured Carbonates, Abdulaziz A. Almakimi, Abdullah O. Almansour, Junchen Liu, Baojun Bai, Ibnelwaleed A. Hussein Jun 2025

Investigation Of Retention And Dehydration Of Preformed Particle Gel For Conformance Control In Fractured Carbonates, Abdulaziz A. Almakimi, Abdullah O. Almansour, Junchen Liu, Baojun Bai, Ibnelwaleed A. Hussein

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Preformed particle gel (PPG) treatment has proved to be among the most effective methods to reduce excessive water production in fractured reservoirs. The blocking ability of PPGs to fractures or fracture-like features is highly dependent on injected gel properties and volume. Gel dehydration during extrusion through fracture is common and has a considerable effect on gel properties, transport, and plugging efficiency. As the gel particles propagate through the fracture, continuous dehydration is often associated and causes the gel to concentrate and require high-pressure gradients to move. Dehydration might be desirable to a certain limit because it can help to form …

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Collision Kinematics For Fast Positron Impact Ionization Of Argon, Robert D. Dubois, Károly Tőkési Jun 2025

Collision Kinematics For Fast Positron Impact Ionization Of Argon, Robert D. Dubois, Károly Tőkési

Physics Faculty Research & Creative Works

Classical trajectory Monte Carlo calculations for 1 keV positron impact ionization of argon are presented. A combination of energy-weighted triple differential cross-sections is shown to provide good to excellent agreement compared with experimental data, depending on the ejected electron azimuthal angular acceptance range used to define in-plane scattering. For ejected electron energies less than 100 eV, information about the influence of pre- (the impact parameter) and post-(the direction of scattering) collision kinematics on the triple differential level is obtained. An overall picture of these kinematic properties is also presented for single differential cross-sections as a function of ejected electron energy …

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A Selective Discontinuous Galerkin Implicit Particle-In-Cell Method For Plasma Simulation With Improved Interpolation, Siyu Wu, Yang Li, Hongtao Liu, Xiaoming He, Yong Cao May 2025

A Selective Discontinuous Galerkin Implicit Particle-In-Cell Method For Plasma Simulation With Improved Interpolation, Siyu Wu, Yang Li, Hongtao Liu, Xiaoming He, Yong Cao

Mathematics and Statistics Faculty Research & Creative Works

This article dynamically incorporates multiple ideas into the existing direct implicit particle-in-cell (DIPIC) method for plasma simulation, in order to dramatically improve the DIPIC method for its local mesh refinement needs based on Cartesian meshes as well as its interpolation needs based on the locally refined meshes. One key tool is to utilize the selective discontinuous Galerkin method, which is based on the interior penalty discontinuous Galerkin formulation and the regular local finite element basis functions, as the electric field solver in the DIPIC simulation. This hybrid type finite element method combines the advantages of both continuous and discontinuous finite …

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The Nitrogen-Vacancy-Nitrogen Color Center: A Ubiquitous Visible And Near-Infrared-Ii Quantum Emitter In Nitrogen-Doped Diamond, Brett C. Johnson, Mitchell O. De Vries, Alexander J. Healey, Marco Capelli, Anjay Manian, Giannis Thalassinos, Amanda N. Abraham, Harini Hapuarachchi, Tingpeng Luo, Vadym N. Mochalin, Jan Jeske, Jared H. Cole, Salvy Russo May 2025

The Nitrogen-Vacancy-Nitrogen Color Center: A Ubiquitous Visible And Near-Infrared-Ii Quantum Emitter In Nitrogen-Doped Diamond, Brett C. Johnson, Mitchell O. De Vries, Alexander J. Healey, Marco Capelli, Anjay Manian, Giannis Thalassinos, Amanda N. Abraham, Harini Hapuarachchi, Tingpeng Luo, Vadym N. Mochalin, Jan Jeske, Jared H. Cole, Salvy Russo

Chemistry Faculty Research & Creative Works

Photoluminescent defects in diamond, such as the nitrogen-vacancy (NV) color center, are at the forefront of emerging optical quantum technologies. Most emit in the visible and near-infrared spectral region below 1000 nm (NIR-I), limiting their applications in photonics, fiber communications, and biology. Here, we show that the nitrogen-vacancy-nitrogen (N2V) center, which emits in the visible and near-infrared-II (NIR-II, 1000-1700 nm), is ubiquitous in as-synthesized and processed nitrogen-doped diamond, ranging from bulk samples to nanoparticles. We demonstrate that N2V is also present in commercially available state-of-the-art NV diamond sensing chips made via chemical vapor deposition (CVD). In high-pressure high-temperature (HPHT) diamonds, …

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Predicting Battery Levels Of Sensor Nodes Using Reinforcement Learning In Harsh Underground Mining Environments, Manish Anand Yadav, Mohamed Elmahallawy, Sanjay Madria, Samuel Frimpong May 2025

Predicting Battery Levels Of Sensor Nodes Using Reinforcement Learning In Harsh Underground Mining Environments, Manish Anand Yadav, Mohamed Elmahallawy, Sanjay Madria, Samuel Frimpong

Computer Science Faculty Research & Creative Works

Underground mining is a hazardous environment, with frequent accidents leading to significant loss of life each year. To enhance safety, sensor nodes monitor key environmental factors such as temperature, toxic gases, and miners' locations, as well as transmit critical messages. Miners interact with these sensors, which track their movements, enabling their location to be determined even without GPS signals. Therefore, predicting the battery life of these sensors is essential for: (i) rerouting miners during emergencies, (ii) ensuring timely maintenance, and most importantly (iii) identifying sensors that need energy harvesting to maintain vital communication within the mine. In this work, we …

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Beyond Boundaries: A Comprehensive Survey Of Transferable Attacks On Ai Systems, Guangjing Wang, Ce Zhou, Yuanda Wang, Bocheng Chen, Hanqing Guo, Qiben Yan May 2025

Beyond Boundaries: A Comprehensive Survey Of Transferable Attacks On Ai Systems, Guangjing Wang, Ce Zhou, Yuanda Wang, Bocheng Chen, Hanqing Guo, Qiben Yan

Computer Science Faculty Research & Creative Works

As Artificial Intelligence (AI) systems increasingly underpin critical applications, from autonomous vehicles to biometric authentication, their vulnerability to transferable attacks presents a growing concern. These attacks, designed to generalize across instances, domains, models, tasks, modalities, or even hardware platforms, pose severe risks to security, privacy, and system integrity. This survey delivers the first comprehensive review of transferable attacks across seven major categories, including evasion, backdoor, data poisoning, model stealing, model inversion, membership inference, and side-channel attacks. We introduce a unified six-dimensional taxonomy: cross-instance, cross-domain, cross-modality, cross-model, cross-task, and cross-hardware, which systematically captures the diverse transfer pathways of adversarial strategies. Through …

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Extended Tev Halos May Commonly Exist Around Middle-Aged Pulsars, A. Albert, R. Alfaro, C. Alvarez, J. C. Arteaga-Velázquez, D. Avila Rojas, H. A. Ayala Solares, R. Babu, E. Belmont-Moreno, A. Bernal, K. S. Caballero-Mora, T. Capistrán, A. Carramiñana, S. Casanova, U. Cotti, J. Cotzomi, S. Coutiño De León, E. De La Fuente, C. De León, D. Depaoli, P. Desiati, N. Di Lalla, R. Diaz Hernandez, B. L. Dingus, M. A. Duvernois, J. C. Diaz-Velez, K. Engel, C. Espinoza, K. L. Fan, K. Fang, N. Fraija, J. A. Garcia-Gonzalez, F. Garfias, H. Goksu, M. M. Gonzalez, J. A. Goodman, S. Groetsch, J. P. Harding, S. Hernandez-Cadena, I. Herzog, D. Huang, F. Hueyotl-Zahuantitla, A. Iriarte, S. Kaufmann, D. Kieda, J. Lee, H. Leon Vargas, J. T. Linnemann, A. L. Longinotti, G. Luis-Raya, K. Malone, O. Martinez, J. Martines-Castro, J. A. Matthews, P. Miranda-Romagnoli, J. A. Morales-Soto, E. Moreno, M. Mostafa, L. Nellen, M. U. Nisa, N. Omodei, Y. Perez Araujo, E. G. Perez-Perez, C. D. Rho, D. Rosa-Gonzalez, E. Ruiz-Velasco, H. Salazar, D. Salazar-Gallegos, A. Sandoval, M. Schneider, J. Serna-Franco, Y. Son, R. W. Springer, O. Tibolla, K. Tollefson, I. Torres, R. Tores-Escobedo, R. Turner, F. Urena-Mena, E. Varela, L. Villasenor, Xiaojie Wang, E. Wilcox, H. Wu, H. Zhou May 2025

Extended Tev Halos May Commonly Exist Around Middle-Aged Pulsars, A. Albert, R. Alfaro, C. Alvarez, J. C. Arteaga-Velázquez, D. Avila Rojas, H. A. Ayala Solares, R. Babu, E. Belmont-Moreno, A. Bernal, K. S. Caballero-Mora, T. Capistrán, A. Carramiñana, S. Casanova, U. Cotti, J. Cotzomi, S. Coutiño De León, E. De La Fuente, C. De León, D. Depaoli, P. Desiati, N. Di Lalla, R. Diaz Hernandez, B. L. Dingus, M. A. Duvernois, J. C. Diaz-Velez, K. Engel, C. Espinoza, K. L. Fan, K. Fang, N. Fraija, J. A. Garcia-Gonzalez, F. Garfias, H. Goksu, M. M. Gonzalez, J. A. Goodman, S. Groetsch, J. P. Harding, S. Hernandez-Cadena, I. Herzog, D. Huang, F. Hueyotl-Zahuantitla, A. Iriarte, S. Kaufmann, D. Kieda, J. Lee, H. Leon Vargas, J. T. Linnemann, A. L. Longinotti, G. Luis-Raya, K. Malone, O. Martinez, J. Martines-Castro, J. A. Matthews, P. Miranda-Romagnoli, J. A. Morales-Soto, E. Moreno, M. Mostafa, L. Nellen, M. U. Nisa, N. Omodei, Y. Perez Araujo, E. G. Perez-Perez, C. D. Rho, D. Rosa-Gonzalez, E. Ruiz-Velasco, H. Salazar, D. Salazar-Gallegos, A. Sandoval, M. Schneider, J. Serna-Franco, Y. Son, R. W. Springer, O. Tibolla, K. Tollefson, I. Torres, R. Tores-Escobedo, R. Turner, F. Urena-Mena, E. Varela, L. Villasenor, Xiaojie Wang, E. Wilcox, H. Wu, H. Zhou

Physics Faculty Research & Creative Works

Extended gamma-ray emission around isolated pulsars at TeV energies, also known as TeV halos, have been found around a handful of middle-aged pulsars. The halos are significantly more extended than their pulsar wind nebulae but much smaller than the particle diffusion length in the interstellar medium. The origin of TeV halos is unknown. Interpretations invoke either local effects related to the environment of a pulsar or generic particle transport behaviors. The latter scenario predicts that TeV halos would be a universal phenomenon for all pulsars. We searched for extended gamma-ray emission around 36 isolated middle-aged pulsars identified by radio and …

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Variable Selection In Mixture Cure Models Using Elastic Net Penalty: Application To Covid-19 Data, Aluwani Ramalata, Akim Adekpedjou, Maseka Lesaoana May 2025

Variable Selection In Mixture Cure Models Using Elastic Net Penalty: Application To Covid-19 Data, Aluwani Ramalata, Akim Adekpedjou, Maseka Lesaoana

Mathematics and Statistics Faculty Research & Creative Works

In survival analysis, it is often assumed that all individuals will eventually experience the event of interest if followed long enough. However, in many real-world scenarios, a subset of individuals remains event-free indefinitely. For instance, in clinical studies, some patients never relapse and are considered cured rather than censored. Traditional survival models are inadequate for capturing this heterogeneity. Mixture cure models address this limitation by distinguishing between cured and susceptible individuals while modeling the survival of the latter. A key challenge in mixture cure modeling is selecting relevant covariates, particularly when dealing with time-varying effects. This study develops a penalized …

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A Pure Rotational Spectroscopic Study Of Two Nearly-Equivalent Structures Of Hexafluoroacetone Imine, (Cf3)C=Nh, Daniel A. Obenchain, Beppo Hartwig, Daniel J. Frohman, Garry S. Grubbs, B. E. Long, Wallace C. Pringle, Stewart E. Novick, S. A. Cooke May 2025

A Pure Rotational Spectroscopic Study Of Two Nearly-Equivalent Structures Of Hexafluoroacetone Imine, (Cf3)C=Nh, Daniel A. Obenchain, Beppo Hartwig, Daniel J. Frohman, Garry S. Grubbs, B. E. Long, Wallace C. Pringle, Stewart E. Novick, S. A. Cooke

Chemistry Faculty Research & Creative Works

Rotational spectra for hexafluoroacetone imine, the singly substituted 13C isotopologues, and the 15N isotopologue, have been recorded using both cavity and chirped pulse Fourier transform microwave spectrometers. The spectra observed present as being doubled with separations between each pair of transitions being on the order of a few tens of kilohertz which is consistent with a large amplitude motion producing two torsional substates. The observed splitting is most likely due to the combined motions of the CF3 groups, for which the calculated barrier is small. However, no transitions between states could be observed and, similarly, no Coriolis coupling parameters …

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Unraveling The Causal Influences Of Drought And Crop Production On Groundwater Levels Across The Contiguous United States, Nitin K. Singh, Sheila M. Saia, Ruchi Bhattacharya, Hoori Ajami, David M. Borrok May 2025

Unraveling The Causal Influences Of Drought And Crop Production On Groundwater Levels Across The Contiguous United States, Nitin K. Singh, Sheila M. Saia, Ruchi Bhattacharya, Hoori Ajami, David M. Borrok

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Groundwater depletion in agricultural-dominated regions is attributed to climate and irrigation withdrawals that support crop production. However, despite decades of effort, knowledge gaps remain in understanding the relative influence of drought and crop production on groundwater levels at the continental scale. Here, utilizing empirical observations, we simultaneously track how long-term trajectories of groundwater levels, crop production of seven crops, and drought have evolved over time, and then integrate these observations with a causality-based attribution framework to unravel the relative impact of drought and crop production on groundwater levels across the contiguous United States (CONUS). We find a dominant pattern of …

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Comprehensive Global Data Set Of Uniformly Processed Shear-Wave Splitting Measurements, Jonathan Wolf, Thorsten W. Becker, Edward Garnero, Kelly H. Liu, John D. West May 2025

Comprehensive Global Data Set Of Uniformly Processed Shear-Wave Splitting Measurements, Jonathan Wolf, Thorsten W. Becker, Edward Garnero, Kelly H. Liu, John D. West

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Seismic anisotropy can inform us about convective flow in the mantle. Shear waves traveling through azimuthally anisotropic regions split into fast and slow pulses, and measuring the resulting shear-wave splitting provides some of the most direct insights into Earth's interior dynamics. Shear-wave splitting is a constraint for path-averaged azimuthal anisotropy and is often studied regionally. Global compilations of these measurements also exist. Such compilations include measurements obtained using different data processing methodologies (e.g., filtering), which do not necessarily yield identical results, and reproducing a number of studies can be challenging given that not all provide the required information, for example, …

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