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Missouri University of Science and Technology

2022

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Articles 1 - 30 of 212

Full-Text Articles in Physical Sciences and Mathematics

Predicting Convection Configurations In Coupled Fluid-Porous Systems, Matthew Mccurdy, Nicholas J. Moore, Xiaoming Wang Dec 2022

Predicting Convection Configurations In Coupled Fluid-Porous Systems, Matthew Mccurdy, Nicholas J. Moore, Xiaoming Wang

Mathematics and Statistics Faculty Research & Creative Works

A ubiquitous arrangement in nature is a free-flowing fluid coupled to a porous medium, for example a river or lake lying above a porous bed. Depending on the environmental conditions, thermal convection can occur and may be confined to the clear fluid region, forming shallow convection cells, or it can penetrate into the porous medium, forming deep cells. Here, we combine three complementary approaches - linear stability analysis, fully nonlinear numerical simulations and a coarse-grained model - to determine the circumstances that lead to each configuration. the coarse-grained model yields an explicit formula for the transition between deep and shallow …

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Enhanced Neurologic Concept Recognition Using A Named Entity Recognition Model Based On Transformers, Sima Azizi, Daniel B. Hier, Donald C. Wunsch Dec 2022

Enhanced Neurologic Concept Recognition Using A Named Entity Recognition Model Based On Transformers, Sima Azizi, Daniel B. Hier, Donald C. Wunsch

Chemistry Faculty Research & Creative Works

Although Deep Learning Has Been Applied to the Recognition of Diseases and Drugs in Electronic Health Records and the Biomedical Literature, Relatively Little Study Has Been Devoted to the Utility of Deep Learning for the Recognition of Signs and Symptoms. the Recognition of Signs and Symptoms is Critical to the Success of Deep Phenotyping and Precision Medicine. We Have Developed a Named Entity Recognition Model that Uses Deep Learning to Identify Text Spans Containing Neurological Signs and Symptoms and Then Maps These Text Spans to the Clinical Concepts of a Neuro-Ontology. We Compared a Model based on Convolutional Neural Networks …

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It’S Time To Change Our Documentation Philosophy: Writing Better Neurology Notes Without The Burnout, Jorge M. Rodríguez-Fernández, Jeffrey A. Loeb, Daniel B. Hier Nov 2022

It’S Time To Change Our Documentation Philosophy: Writing Better Neurology Notes Without The Burnout, Jorge M. Rodríguez-Fernández, Jeffrey A. Loeb, Daniel B. Hier

Chemistry Faculty Research & Creative Works

Succinct Clinical Documentation is Vital to Effective Twenty-First-Century Healthcare. Recent Changes in Outpatient and Inpatient Evaluation and Management (E/M) Guidelines Have Allowed Neurology Practices to Make Changes that Reduce the Documentation Burden and Enhance Clinical Note Usability. Despite Favorable Changes in E/M Guidelines, Some Neurology Practices Have Not Moved Quickly to Change their Documentation Philosophy. We Argue in Favor of Changes in the Design, Structure, and Implementation of Clinical Notes that Make Them Shorter Yet Still Information-Rich. a Move from Physician-Centric to Team Documentation Can Reduce Work for Physicians. Changing the Documentation Philosophy from "Bigger is Better" to "Short But …

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Tau Kinetics In Alzheimer's Disease, Daniel B. Hier, Sima Azizi, Matthew S. Thimgan, Donald C. Wunsch Nov 2022

Tau Kinetics In Alzheimer's Disease, Daniel B. Hier, Sima Azizi, Matthew S. Thimgan, Donald C. Wunsch

Chemistry Faculty Research & Creative Works

The Cytoskeletal Protein Tau is Implicated in the Pathogenesis of Alzheimer's Disease Which is Characterized by Intra-Neuronal Neurofibrillary Tangles Containing Abnormally Phosphorylated Insoluble Tau. Levels of Soluble Tau Are Elevated in the Brain, the CSF, and the Plasma of Patients with Alzheimer's Disease. to Better Understand the Causes of These Elevated Levels of Tau, We Propose a Three-Compartment Kinetic Model (Brain, CSF, and Plasma). the Model Assumes that the Synthesis of Tau Follows Zero-Order Kinetics (Uncorrelated with Compartmental Tau Levels) and that the Release, Absorption, and Clearance of Tau is Governed by First-Order Kinetics (Linearly Related to Compartmental Tau Levels). …

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Conservative Unconditionally Stable Decoupled Numerical Schemes For The Cahn–Hilliard–Navier–Stokes–Darcy–Boussinesq System, Wenbin Chen, Daozhi Han, Xiaoming Wang, Yichao Zhang Nov 2022

Conservative Unconditionally Stable Decoupled Numerical Schemes For The Cahn–Hilliard–Navier–Stokes–Darcy–Boussinesq System, Wenbin Chen, Daozhi Han, Xiaoming Wang, Yichao Zhang

Mathematics and Statistics Faculty Research & Creative Works

We propose two mass and heat energy conservative, unconditionally stable, decoupled numerical algorithms for solving the Cahn–Hilliard–Navier–Stokes–Darcy–Boussinesq system that models thermal convection of two-phase flows in superposed free flow and porous media. The schemes totally decouple the computation of the Cahn–Hilliard equation, the Darcy equations, the heat equation, the Navier–Stokes equations at each time step, and thus significantly reducing the computational cost. We rigorously show that the schemes are conservative and energy-law preserving. Numerical results are presented to demonstrate the accuracy and stability of the algorithms.

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Second-Order, Fully Decoupled, Linearized, And Unconditionally Stable Scalar Auxiliary Variable Schemes For Cahn–Hilliard–Darcy System, Yali Gao, Xiaoming He, Yufeng Nie Nov 2022

Second-Order, Fully Decoupled, Linearized, And Unconditionally Stable Scalar Auxiliary Variable Schemes For Cahn–Hilliard–Darcy System, Yali Gao, Xiaoming He, Yufeng Nie

Mathematics and Statistics Faculty Research & Creative Works

In this paper, we establish the fully decoupled numerical methods by utilizing scalar auxiliary variable approach for solving Cahn–Hilliard–Darcy system. We exploit the operator splitting technique to decouple the coupled system and Galerkin finite element method in space to construct the fully discrete formulation. The developed numerical methods have the features of second order accuracy, totally decoupling, linearization, and unconditional energy stability. The unconditionally stability of the two proposed decoupled numerical schemes are rigorously proved. Abundant numerical results are reported to verify the accuracy and effectiveness of proposed numerical methods.

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Transcriptional Regulatory Network Topology With Applications To Bio-Inspired Networking: A Survey, Satyaki Roy, Preetam Ghosh, Nirnay Ghosh, Sajal K. Das Nov 2022

Transcriptional Regulatory Network Topology With Applications To Bio-Inspired Networking: A Survey, Satyaki Roy, Preetam Ghosh, Nirnay Ghosh, Sajal K. Das

Computer Science Faculty Research & Creative Works

The advent of the edge computing network paradigm places the computational and storage resources away from the data centers and closer to the edge of the network largely comprising the heterogeneous IoT devices collecting huge volumes of data. This paradigm has led to considerable improvement in network latency and bandwidth usage over the traditional cloud-centric paradigm. However, the next generation networks continue to be stymied by their inability to achieve adaptive, energy-efficient, timely data transfer in a dynamic and failure-prone environment - the very optimization challenges that are dealt with by biological networks as a consequence of millions of years …

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Pattern Selection In The Schnakenberg Equations: From Normal To Anomalous Diffusion, Hatim K. Khudhair, Yanzhi Zhang, Nobuyuki Fukawa Nov 2022

Pattern Selection In The Schnakenberg Equations: From Normal To Anomalous Diffusion, Hatim K. Khudhair, Yanzhi Zhang, Nobuyuki Fukawa

Mathematics and Statistics Faculty Research & Creative Works

Pattern formation in the classical and fractional Schnakenberg equations is studied to understand the nonlocal effects of anomalous diffusion. Starting with linear stability analysis, we find that if the activator and inhibitor have the same diffusion power, the Turing instability space depends only on the ratio of diffusion coefficients (Formula presented.). However, smaller diffusive powers might introduce larger unstable wave numbers with wider band, implying that the patterns may be more chaotic in the fractional cases. We then apply a weakly nonlinear analysis to predict the parameter regimes for spot, stripe, and mixed patterns in the Turing space. Our numerical …

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Dtc: A Dynamic Transaction Chopping Technique For Geo-Replicated Storage Services, Ning Huang, Lihui Wu, Weigang Wu, Sajal K. Das Nov 2022

Dtc: A Dynamic Transaction Chopping Technique For Geo-Replicated Storage Services, Ning Huang, Lihui Wu, Weigang Wu, Sajal K. Das

Computer Science Faculty Research & Creative Works

Replicating data across geo-distributed datacenters is usually necessary for large scale cloud services to achieve high locality, durability and availability. One of the major challenges in such geo-replicated data services lies in consistency maintenance, which usually suffers from long latency due to costly coordination across datacenters. Among others, transaction chopping is an effective and efficient approach to address this challenge. However, existing chopping is conducted statically during programming, which is stubborn and complex for developers. In this article, we propose Dynamic Transaction Chopping (DTC), a novel technique that does transaction chopping and determines piecewise execution in a dynamic and automatic …

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Stable Matching Based Resource Allocation For Service Provider's Revenue Maximization In 5g Networks, Ajay Pratap, Sajal K. Das Nov 2022

Stable Matching Based Resource Allocation For Service Provider's Revenue Maximization In 5g Networks, Ajay Pratap, Sajal K. Das

Computer Science Faculty Research & Creative Works

5G technology is foreseen to have a heterogeneous architecture with the various computational capability, and radio-enabled service providers (SPs) and service requesters (SRs), working altogether in a cellular model. However, the coexistence of heterogeneous network model spawns several research challenges such as diverse SRs with uneven service deadlines, interference management, and revenue maximization of non-uniform computational capacities enabled SPs. Thus, we propose a coexistence of heterogeneous SPs and SRs enabled cellular 5G network and formulate the SPs' revenue maximization via resource allocation, considering different kinds of interference, data rate, and latency altogether as an optimization problem and further propose a …

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Further Comments On "Engineering Shape Anisotropy Of Fe3o4-Γ-Fe2o3hollow Nanoparticles For Magnetic Hyperthermia", Fernande Grandjean, Gary J. Long Oct 2022

Further Comments On "Engineering Shape Anisotropy Of Fe3o4-Γ-Fe2o3hollow Nanoparticles For Magnetic Hyperthermia", Fernande Grandjean, Gary J. Long

Chemistry Faculty Research & Creative Works

In their earlier paper, Niraula et al. (ACS Appl. Nano Mater. 2021, 4, 3148-3158) described the morphological, compositional, and magnetic properties of three different magnetite/maghemite or Fe3O4/γ-Fe2O3, hollow nanoparticles, referred to herein as nanorings, short-nanotubes, and long-nanotubes. Scanning electron microscopy indicates that these nanoparticles have lengths of 275 ± 51, 411 ± 92, and 515 ± 98 nm and outer diameters of 201 ± 55, 251 ± 46, and 229 ± 42 nm, respectively, dimensions that are all rather similar in view of their distributions, as is shown in a figure herein. …

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Origin Of The Second-Order Proton Catalysis Of Ferriin Reduction In Belousov-Zhabotinsky Reactions: Density Functional Studies Of Ferroin And Ferriin Aggregates With Outer Sphere Ligands Sulfate, Bisulfate, And Sulfuric Acid, Sara C. Mccauley, Rainer Glaser Oct 2022

Origin Of The Second-Order Proton Catalysis Of Ferriin Reduction In Belousov-Zhabotinsky Reactions: Density Functional Studies Of Ferroin And Ferriin Aggregates With Outer Sphere Ligands Sulfate, Bisulfate, And Sulfuric Acid, Sara C. Mccauley, Rainer Glaser

Chemistry Faculty Research & Creative Works

The detailed mechanisms of Belousov-Zhabotinsky oscillating reactions continue to present grand challenges, even after half a century of study. The origin of the pH dependence of the oscillation pattern had never been rigorously identified. In our recent kinetic study of one of the key Belousov-Zhabotinsky reactions, the iron-catalyzed bromate oxidation of malonic acid, compelling agreement between experiments and kinetic simulations was achieved only with the inclusion of second-order proton catalysis of the reduction of the [Fe(phen)3]3+ species. After exhausting all other avenues in search of an explanation of this proton catalysis, we considered the possibility that the …

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Coherent Enhancement Of Optical Remission In Diffusive Media, Nicholas Bender, Arthur Goetschy, Chia Wei Hsu, Hasan Yılmaz, Pablo Jara Palacios, Alexey Yamilov, Hui Cao Oct 2022

Coherent Enhancement Of Optical Remission In Diffusive Media, Nicholas Bender, Arthur Goetschy, Chia Wei Hsu, Hasan Yılmaz, Pablo Jara Palacios, Alexey Yamilov, Hui Cao

Physics Faculty Research & Creative Works

Remitted waves are used for sensing and imaging in diverse diffusive media from the Earth's crust to the human brain. Separating the source and detector increases the penetration depth of light, but the signal strength decreases rapidly, leading to a poor signal-to-noise ratio. Here, we show, experimentally and numerically, that wavefront shaping a laser beam incident on a diffusive sample enables an enhancement of remission by an order of magnitude at depths of up to 10 transport mean free paths. We develop a theoretical model which predicts the maximal remission enhancement. Our analysis reveals a significant improvement in the sensitivity …

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An Energy Efficient Smart Metering System Using Edge Computing In Lora Network, Preti Kumari, Rahul Mishra, Hari Prabhat Gupta, Tanima Dutta, Sajal K. Das Oct 2022

An Energy Efficient Smart Metering System Using Edge Computing In Lora Network, Preti Kumari, Rahul Mishra, Hari Prabhat Gupta, Tanima Dutta, Sajal K. Das

Computer Science Faculty Research & Creative Works

An important research issue in smart metering is to correctly transfer the smart meter readings from consumers to the operator within the given time period by consuming minimum energy. In this paper, we propose an energy efficient smart metering system using Edge computing in Long Range (LoRa). We assume that all appliances in a house are connected to a smart meter that is affixed with Edge device and LoRa node for processing and transferring the processed smart meter readings, respectively. The energy consumption of the appliances can be represented as an energy multivariate time series. The system first proposes a …

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Sum Rules For Energy Deposition Eigenchannels In Scattering Systems, Alexey Yamilov, Nicholas Bender, Hui Cao Oct 2022

Sum Rules For Energy Deposition Eigenchannels In Scattering Systems, Alexey Yamilov, Nicholas Bender, Hui Cao

Physics Faculty Research & Creative Works

In a random-scattering system, the deposition matrix maps the incident wavefront onto the internal field distribution across a target volume. The corresponding eigenchannels have been used to enhance the wave energy delivered to the target. Here, we find the sum rules for the eigenvalues and eigenchannels of the deposition matrix in any system geometry: including two- and three-dimensional scattering systems, as well as narrow waveguides and wide slabs. We derive a number of constraints on the eigenchannel intensity distributions inside the system as well as the corresponding eigenvalues. Our results are general and applicable to random systems of arbitrary scattering …

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Aircraft Engine Particulate Matter Emissions From Sustainable Aviation Fuels: Results From Ground-Based Measurements During The Nasa/Dlr Campaign Eclif2/Nd-Max, Tobias Schripp, Bruce E. Anderson, Uwe Bauder, Bastian Rauch, Joel C. Corbin, Greg J. Smallwood, Prem Lobo, Ewan C. Crosbie, Michael A. Shook, Richard C. Miake-Lye, Zhenhong Yu, Andrew Freedman, Philip D. Whitefield, Claire E. Robinson Oct 2022

Aircraft Engine Particulate Matter Emissions From Sustainable Aviation Fuels: Results From Ground-Based Measurements During The Nasa/Dlr Campaign Eclif2/Nd-Max, Tobias Schripp, Bruce E. Anderson, Uwe Bauder, Bastian Rauch, Joel C. Corbin, Greg J. Smallwood, Prem Lobo, Ewan C. Crosbie, Michael A. Shook, Richard C. Miake-Lye, Zhenhong Yu, Andrew Freedman, Philip D. Whitefield, Claire E. Robinson

Chemistry Faculty Research & Creative Works

The use of alternative jet fuels by commercial aviation has increased substantially in recent years. Beside the reduction of carbon dioxide emission, the use of sustainable aviation fuels (SAF) may have a positive impact on the reduction of particulate emissions. This study summarizes the results from a ground-based measurement activity conducted in January 2018 as part of the ECLIF2/ND-MAX campaign in Ramstein, Germany. Two fossil reference kerosenes and three different blends with the renewable fuel component HEFA-SPK (Hydroprocessed Esters and Fatty Acids Synthetic Paraffinic Kerosene) were burned in an A320 with V2527-A5 engines to investigate the effect of fuel naphthalene/aromatic …

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Control Of Dy 164 Bose-Einstein Condensate Phases And Dynamics With Dipolar Anisotropy, S. Halder, K. Mukherjee, Simeon I. Mistakidis, S. Das, P. G. Kevrekidis, P. K. Panigrahi, S. Majumder, H. R. Sadeghpour Oct 2022

Control Of Dy 164 Bose-Einstein Condensate Phases And Dynamics With Dipolar Anisotropy, S. Halder, K. Mukherjee, Simeon I. Mistakidis, S. Das, P. G. Kevrekidis, P. K. Panigrahi, S. Majumder, H. R. Sadeghpour

Physics Faculty Research & Creative Works

We Investigate The Quench Dynamics Of Quasi-One- And Two-Dimensional Dipolar Bose-Einstein Condensates Of Dy164 Atoms Under The Influence Of A Fast Rotating Magnetic Field. The Magnetic Field Thus Controls Both The Magnitude And Sign Of The Dipolar Potential. We Account For Quantum Fluctuations, Critical To Formation Of Exotic Quantum Droplet And Supersolid Phases In The Extended Gross-Pitaevskii Formalism, Which Includes The So-Called Lee-Huang-Yang Correction. An Analytical Variational Ansatz Allows Us To Obtain The Phase Diagrams Of The Superfluid And Droplet Phases. The Crossover From The Superfluid To The Supersolid Phase And To Single And Droplet Arrays Is Probed With Particle …

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Triple-Differential Cross Sections In Three-Dimensional Kinematics For Electron-Impact-Ionization Dynamics Of Tetrahydrofuran At 250-Ev Projectile Energy, Xiaorui Xue, Deepthy Maria Mootheril, Esam Ali, Maomao Gong, Shaokui Jia, Jiaqi Zhou, Enliang Wang, Jian Xing Li, Xiangjun Chen, Don H. Madison, Alexander Dorn, Xueguang Ren Oct 2022

Triple-Differential Cross Sections In Three-Dimensional Kinematics For Electron-Impact-Ionization Dynamics Of Tetrahydrofuran At 250-Ev Projectile Energy, Xiaorui Xue, Deepthy Maria Mootheril, Esam Ali, Maomao Gong, Shaokui Jia, Jiaqi Zhou, Enliang Wang, Jian Xing Li, Xiangjun Chen, Don H. Madison, Alexander Dorn, Xueguang Ren

Physics Faculty Research & Creative Works

We report a combined experimental and theoretical study of the ionization dynamics of tetrahydrofuran induced by 250 eV electron impact in which the highest occupied molecular orbital is ionized leading to the stable parent ion. Experimentally a reaction microscope was used, covering nearly the entire 4π solid angle for the ejected slow electron. We present the triple-differential cross sections for the projectile scattering angles of θ1 = -10∘ as a function of the emission angle of the ejected electrons with energies of E2=10, 15, and 20 eV, i.e., for asymmetric energy sharing between the scattered and ejected electrons. The measured …

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Dynamical Excitation Processes And Correlations Of Three-Body Two-Dimensional Mixtures, G. Bougas, Simeon I. Mistakidis, P. Giannakeas, P. Schmelcher Oct 2022

Dynamical Excitation Processes And Correlations Of Three-Body Two-Dimensional Mixtures, G. Bougas, Simeon I. Mistakidis, P. Giannakeas, P. Schmelcher

Physics Faculty Research & Creative Works

A Scheme Is Proposed To Dynamically Excite Distinct Eigenstate Superpositions In Three-Body Bose-Fermi Mixtures Confined In A Two-Dimensional Harmonic Trap. The System Is Initialized In A Noninteracting State With A Variable Spatial Extent, And The Scattering Lengths Are Subsequently Quenched Spanning The Regime From Weak To Strong Interactions. For Spatial Widths Smaller Than The Three-Body Harmonic Oscillator Length, A Superposition Of Trimers And Atom-Dimers Is Dynamically Attained, Otherwise Trap States Are Predominantly Populated, As Inferred From The Frequency Spectrum Of The Fidelity. Accordingly, The Tan Contacts Evince The Buildup Of Short-Range Two- And Three-Body Correlations In The Course Of The …

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Contact Process With Simultaneous Spatial And Temporal Disorder, Xuecheng Ye, Thomas Vojta Oct 2022

Contact Process With Simultaneous Spatial And Temporal Disorder, Xuecheng Ye, Thomas Vojta

Physics Faculty Research & Creative Works

We study the absorbing-state phase transition in the one-dimensional contact process under the combined influence of spatial and temporal random disorders. We focus on situations in which the spatial and temporal disorders decouple. Couched in the language of epidemic spreading, this means that some spatial regions are, at all times, more favorable than others for infections, and some time periods are more favorable than others independent of spatial location. We employ a generalized Harris criterion to discuss the stability of the directed percolation universality class against such disorder. We then perform large-scale Monte Carlo simulations to analyze the critical behavior …

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Efficient Data Collection In Iot Networks Using Trajectory Encoded With Geometric Shapes, Xiaofei Cao, Sanjay Kumar Madria Oct 2022

Efficient Data Collection In Iot Networks Using Trajectory Encoded With Geometric Shapes, Xiaofei Cao, Sanjay Kumar Madria

Computer Science Faculty Research & Creative Works

The mobile edge computing (MEC) paradigm changes the role of edge devices from data producers and requesters to data consumers and processors. MEC mitigates the bandwidth limitation between the edge server and the remote cloud by directly processing the large amount of data locally generated by the network of the internet of things (IoT) at the edge. An efficient data-gathering scheme is crucial for providing quality of service (QoS) within MEC. To reduce redundant data transmission, this paper proposes a data collection scheme that only gathers the necessary data from IoT devices (like wireless sensors) along a trajectory. Instead of …

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Laboratory Evaluation Of A Novel Self-Healable Polymer Gel For Co2 Leakage Remediation During Co2 Storage And Co2 Flooding, Tao Song, Zhanmiao Zhai, Junchen Liu, Yugandhara Eriyagama, Mohamed Ahdaya, Adel Alotibi, Ze Wang, Thomas P. Schuman, Baojun Bai Sep 2022

Laboratory Evaluation Of A Novel Self-Healable Polymer Gel For Co2 Leakage Remediation During Co2 Storage And Co2 Flooding, Tao Song, Zhanmiao Zhai, Junchen Liu, Yugandhara Eriyagama, Mohamed Ahdaya, Adel Alotibi, Ze Wang, Thomas P. Schuman, Baojun Bai

Chemistry Faculty Research & Creative Works

For CO2 storage in subsurface reservoirs, one of the most crucial requirements is the ability to remediate the leakage caused by the natural fractures or newly generated fractures due to the increasing pore pressure associated with CO2 injection. For CO2 Enhanced Oil Recovery (EOR), high conductivity features such as fractures and void space conduits can severely restrict the CO2 sweep efficiency. Polymer gels have been developed to plug the leakage and improve the sweep efficiency. This work evaluated a CO2 resistant branched self-healable preformed particle gel (CO2-BRPPG) for CO2 plugging purpose. This …

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Random Strain Induced Correlations In Materials With Intertwined Nematic And Magnetic Orders, W. Joe Meese, Thomas Vojta, Rafael M. Fernandes Sep 2022

Random Strain Induced Correlations In Materials With Intertwined Nematic And Magnetic Orders, W. Joe Meese, Thomas Vojta, Rafael M. Fernandes

Physics Faculty Research & Creative Works

Electronic nematicity is rarely observed as an isolated instability of a correlated electron system. Instead, in iron pnictides and in certain cuprates and heavy-fermion materials, nematicity is intertwined with an underlying spin-stripe or charge-stripe state. As a result, random strain, ubiquitous in any real crystal, creates both random-field disorder for the nematic degrees of freedom and random-bond disorder for the spin or charge ones. Here, we put forward an Ashkin-Teller model with random Baxter fields to capture the dual role of random strain in nematic systems for which nematicity is a composite order arising from a stripe state. Using Monte …

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Understanding The Effect Of Sodium Polyphosphate On Improving The Chemical Stability Of Ti3c2tz Mxene In Water, Shuohan Huang, Varun Natu, Jingyi Tao, Yumin Xia, Vadym Mochalin, Michel W. Barsoum Sep 2022

Understanding The Effect Of Sodium Polyphosphate On Improving The Chemical Stability Of Ti3c2tz Mxene In Water, Shuohan Huang, Varun Natu, Jingyi Tao, Yumin Xia, Vadym Mochalin, Michel W. Barsoum

Chemistry Faculty Research & Creative Works

Degradation of MXenes in aqueous environments severely limits the application and industrialization of this large family of two-dimensional (2D) materials. Hydrolysis and oxidation are now considered as two main degradation mechanisms and while significant efforts have been directed to prolonging the shelf-life of MXenes, separating and studying their degradation mechanisms have lagged behind. Herein, gas analysis via gas chromatography and Raman spectroscopy were used to investigate the effect of sodium polyphosphate, PP, on the degradation of Ti3C2Tz MXene. Transmission and scanning electron microscopies, as well as X-ray photoelectron spectroscopywere also used as complimentary techniques to …

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A Survey On Mobile Charging Techniques In Wireless Rechargeable Sensor Networks, Amar Kaswan, Prasanta K. Jana, Sajal K. Das Sep 2022

A Survey On Mobile Charging Techniques In Wireless Rechargeable Sensor Networks, Amar Kaswan, Prasanta K. Jana, Sajal K. Das

Computer Science Faculty Research & Creative Works

The recent breakthrough in wireless power transfer (WPT) technology has empowered wireless rechargeable sensor networks (WRSNs) by facilitating stable and continuous energy supply to sensors through mobile chargers (MCs). A plethora of studies have been carried out over the last decade in this regard. However, no comprehensive survey exists to compile the state-of-the-art literature and provide insight into future research directions. To fill this gap, we put forward a detailed survey on mobile charging techniques (MCTs) in WRSNs. In particular, we first describe the network model, various WPT techniques with empirical models, system design issues and performance metrics concerning the …

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Numerical Analysis Of A Second Order Ensemble Method For Evolutionary Magnetohydrodynamics Equations At Small Magnetic Reynolds Number, John Carter, Nan Jiang Sep 2022

Numerical Analysis Of A Second Order Ensemble Method For Evolutionary Magnetohydrodynamics Equations At Small Magnetic Reynolds Number, John Carter, Nan Jiang

Mathematics and Statistics Faculty Research & Creative Works

We study a second order ensemble method for fast computation of an ensemble of magnetohydrodynamics flows at small magnetic Reynolds number. Computing an ensemble of flow equations with different input parameters is a common procedure for uncertainty quantification in many engineering applications, for which the computational cost can be prohibitively expensive for nonlinear complex systems. We propose an ensemble algorithm that requires only solving one linear system with multiple right-hands instead of solving multiple different linear systems, which significantly reduces the computational cost and simulation time. Comprehensive stability and error analyses are presented proving conditional stability and second order in …

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Advanced Glycation End Products In Health And Disease, V. Prakash Reddy, Puspa Aryal, Emmanuel K. Darkwah Sep 2022

Advanced Glycation End Products In Health And Disease, V. Prakash Reddy, Puspa Aryal, Emmanuel K. Darkwah

Chemistry Faculty Research & Creative Works

Advanced glycation end products (AGEs), formed through the nonenzymatic reaction of reducing sugars with the side-chain amino groups of lysine or arginine of proteins, followed by further glycoxidation reactions under oxidative stress conditions, are involved in the onset and exacerbation of a variety of diseases, including diabetes, atherosclerosis, and Alzheimer's disease (AD) as well as in the secondary stages of traumatic brain injury (TBI). AGEs, in the form of intra- and interprotein crosslinks, deactivate various enzymes, exacerbating disease progression. The interactions of AGEs with the receptors for the AGEs (RAGE) also result in further downstream inflammatory cascade events. The overexpression …

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Polyphenols And Small Phenolic Acids As Cellular Metabolic Regulators, Mark Obrenovich, Yi Li, Moncef Tayahi, V. Prakash Reddy Sep 2022

Polyphenols And Small Phenolic Acids As Cellular Metabolic Regulators, Mark Obrenovich, Yi Li, Moncef Tayahi, V. Prakash Reddy

Chemistry Faculty Research & Creative Works

Polyphenols and representative small phenolic acids and molecules derived from larger constituents are dietary antioxidants from fruits, vegetables and largely other plant-based sources that have ability to scavenge free radicals. What is often neglected in polyphenol metabolism is bioavailability and the role of the gut microbiota (GMB), which has an essential role in health and disease and participates in co-metabolism with the host. The composition of the gut microbiota is in constant flux and is modified by multiple intrinsic and extrinsic factors, including antibiotics. Dietary or other factors are key modulators of the host gut milieu. In this review, we …

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Crystal Structure, Electronic Structure, And Optical Properties Of The Novel Li4cdge2s7, A Wide-Bandgap Quaternary Sulfide With A Polar Structure Derived From Lonsdaleite, Andrew J. Craig, Seung Han Shin, Jeong Bin Cho, Srikanth Balijapelly, Jordan C. Kelly, Stanislav S. Stoyko, Amitava Choudhury, Joon I. Jang, Jennifer A. Aitken, A. Sarjeant Sep 2022

Crystal Structure, Electronic Structure, And Optical Properties Of The Novel Li4cdge2s7, A Wide-Bandgap Quaternary Sulfide With A Polar Structure Derived From Lonsdaleite, Andrew J. Craig, Seung Han Shin, Jeong Bin Cho, Srikanth Balijapelly, Jordan C. Kelly, Stanislav S. Stoyko, Amitava Choudhury, Joon I. Jang, Jennifer A. Aitken, A. Sarjeant

Chemistry Faculty Research & Creative Works

The novel quaternary thiogermanate Li4CdGe2S7 (tetralithium cadmium digermanium heptasulfide) was discovered from a solid-state reaction at 750 °C. Single-crystal X-ray diffraction data were collected and used to solve and refine the structure. Li4CdGe2S7 is a member of the small, but growing, class of I4-II-IV2-VI7 diamond-like materials. The compound adopts the Cu5Si2S7 structure type, which is a derivative of lonsdaleite. Crystallizing in the polar space group Cc, Li4CdGe2S7 contains 14 crystallographically unique ions, all residing on …

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Fabrications And Applications Of Micro/Nanofluidics In Oil And Gas Recovery: A Comprehensive Review, Junchen Liu, Yandong Zhang, Mingzhen Wei, Xiaoming He, Baojun Bai Sep 2022

Fabrications And Applications Of Micro/Nanofluidics In Oil And Gas Recovery: A Comprehensive Review, Junchen Liu, Yandong Zhang, Mingzhen Wei, Xiaoming He, Baojun Bai

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Understanding fluid flow characteristics in porous medium, which determines the development of oil and gas oilfields, has been a significant research subject for decades. Although using core samples is still essential, micro/nanofluidics have been attracting increasing attention in oil recovery fields since it offers direct visualization and quantification of fluid flow at the pore level. This work provides the latest techniques and development history of micro/nanofluidics in oil and gas recovery by summarizing and discussing the fabrication methods, materials and corresponding applications. Compared with other reviews of micro/nanofluidics, this comprehensive review is in the perspective of solving specific issues in …

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