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- Chemical and Biochemical Engineering Faculty Research & Creative Works (13)
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Articles 1 - 20 of 20
Full-Text Articles in Physical Sciences and Mathematics
Highly Efficient Dopamine Sensing With A Carbon Nanotube-Encapsulated Metal Chalcogenide Nanostructure, Harish Singh, Jiandong Wu, Kurt A.L. Lagemann, Manashi Nath
Highly Efficient Dopamine Sensing With A Carbon Nanotube-Encapsulated Metal Chalcogenide Nanostructure, Harish Singh, Jiandong Wu, Kurt A.L. Lagemann, Manashi Nath
Chemical and Biochemical Engineering Faculty Research & Creative Works
Carbon nanotube-encapsulated nickel selenide composite nanostructures were used as nonenzymatic electrochemical sensors for dopamine detection. These composite nanostructures were synthesized through a simple, one-step, and environmentally friendly chemical vapor deposition method, wherein the CNTs were formed in situ from pyrolysis of a carbon-rich metallo-organic precursor. The composition and morphology of these hybrid NiSe2-filled carbon nanostructures were confirmed by powder X-ray diffraction, Raman, X-ray photoelectron spectroscopy, and high-resolution transmission electron microscopy images. Electrochemical tests demonstrated that the as-synthesized hybrid nanostructures exhibited outstanding electrocatalytic performance toward dopamine oxidation, with a high sensitivity of 19.62 μA μM-1 cm-2, low detection limit, broad linear …
Repeated Low-Level Blast Exposure Alters Urinary And Serum Metabolites, Austin Sigler, Jiandong Wu, Annalise Pfaff, Olajide Adetunji, Paul Ki-Souk Nam, Donald James, Casey Burton, Honglan Shi
Repeated Low-Level Blast Exposure Alters Urinary And Serum Metabolites, Austin Sigler, Jiandong Wu, Annalise Pfaff, Olajide Adetunji, Paul Ki-Souk Nam, Donald James, Casey Burton, Honglan Shi
Chemistry Faculty Research & Creative Works
Repeated exposure to low-level blast overpressures can produce biological changes and clinical sequelae that resemble mild traumatic brain injury (TBI). While recent efforts have revealed several protein biomarkers for axonal injury during repetitive blast exposure, this study aims to explore potential small molecule biomarkers of brain injury during repeated blast exposure. This study evaluated a panel of ten small molecule metabolites involved in neurotransmission, oxidative stress, and energy metabolism in the urine and serum of military personnel (n = 27) conducting breacher training with repeated exposure to low-level blasts. The metabolites were analyzed using HPLC—tandem mass spectrometry, and the Wilcoxon …
Transport And Plugging Performance Evaluation Of A Novel Re-Crosslinkable Microgel Used For Conformance Control In Mature Oilfields With Super-Permeable Channels, Adel Alotibi, T. Song, Baojun Bai, Thomas P. Schuman
Transport And Plugging Performance Evaluation Of A Novel Re-Crosslinkable Microgel Used For Conformance Control In Mature Oilfields With Super-Permeable Channels, Adel Alotibi, T. Song, Baojun Bai, Thomas P. Schuman
Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works
Preformed particle gels (PPG) have been widely applied in oilfields to control excessive water production. However, PPG has limited success in treating opening features because the particles can be flushed readily during post-water flooding. We have developed a novel micro-sized Re-crosslinkable PPG (micro-RPPG) to solve the problem. The microgel can re-crosslink to form a bulk gel, avoiding being washed out easily. This paper evaluates the novel microgels' transport and plugging performance through super-permeable channels. Micro-RPPG was synthesized and evaluated for this study. Its storage moduli after fully swelling are approximately 82 Pa. The microgel characterization, self-healing process, transportation behavior, and …
Establishing Pteridine Metabolism In A Progressive Isogenic Breast Cancer Cell Model – Part Ii, Lindsey Rasmussen, Zachary Foulks, Jiandong Wu, Casey Burton, Honglan Shi
Establishing Pteridine Metabolism In A Progressive Isogenic Breast Cancer Cell Model – Part Ii, Lindsey Rasmussen, Zachary Foulks, Jiandong Wu, Casey Burton, Honglan Shi
Chemistry Faculty Research & Creative Works
Introduction: Determining the biological significance of pteridines in cancer development and progression remains an important step in understanding the altered levels of urinary pteridines seen in certain cancers. Our companion study revealed that several folate-derived pteridines and lumazines correlated with tumorigenicity in an isogenic, progressive breast cancer cell model, providing direct evidence for the tumorigenic origin of pteridines. Objectives: This study sought to elucidate the pteridine biosynthetic pathway in a progressive breast cancer model via direct pteridine dosing to determine how pteridine metabolism changes with tumorigenicity. Methods: First, MCF10AT breast cancer cells were dosed individually with 15 pteridines to determine …
An Efficient Multicomputer Algorithm For The Solution Of Chemical Process Flowsheeting Equations, Fikret Ercal, Neil L. Book, S. Pait, J. J. Fielding
An Efficient Multicomputer Algorithm For The Solution Of Chemical Process Flowsheeting Equations, Fikret Ercal, Neil L. Book, S. Pait, J. J. Fielding
Computer Science Faculty Research & Creative Works
This paper presents a parallel solution method of large sparse systems of linear equations arising in the context of a chemical process flowsheeting application on a message passing multicomputer. To maximize the performance, the algorithm uses a novel matrix decomposition and solution method, called parallel two-phased LU decomposition, which schedules the concurrent tasks in a maximally overlapping manner, and at the same time, tries to minimize the interprocessor data dependencies and obtain optimal load balancing. The forward elimination step is performed concurrently with the parallel two-phased LU decomposition step and backward substitution is parallelized in a piecewise manner. Implementation results …
Orientation Induced Scattering Asymmetry, Jee-Ching Wang, Ronald E. Olson
Orientation Induced Scattering Asymmetry, Jee-Ching Wang, Ronald E. Olson
Chemical and Biochemical Engineering Faculty Research & Creative Works
Projectile angular scattering is investigated following electron capture by protons from circular Rydberg atoms oriented along a quantization axis perpendicular to the incident projectile direction. We find strong left-right scattering asymmetry as a function of the orientation angle at collision speeds comparable to the electron orbital speed. The capture cross section is dramatically enhanced due to velocity matching when the angular momenta of the proton and the electron are aligned. The scattering asymmetry exhibits characteristic impact parameter dependencies suitable for studying three-body dynamics influenced by both long and short range forces of comparable strength. © 1994 IOP Publishing Ltd.
Dominance Of The Thomas Mechanism For Electron Capture From Orientated Rydberg Atoms, Jee-Ching Wang, Ronald E. Olson
Dominance Of The Thomas Mechanism For Electron Capture From Orientated Rydberg Atoms, Jee-Ching Wang, Ronald E. Olson
Chemical and Biochemical Engineering Faculty Research & Creative Works
We investigate electron capture from initially oriented circular Rydberg atoms by proton impact at collision speeds comparable to the electron orbital speed. The Thomas double scattering mechanism is observed even at these low relative speeds. Furthermore, we find evidence for the dominance of a quasi Thomas capture mechanism in the form of not a single peak, but a double-peaked structure in the differential cross section when the plane of the circular orbit is nearly perpendicular to the incident direction of the projectile. © 1994 The American Physical Society.
Final State Distributions For Electron Capture From Orientated Rydberg Atoms, Jee-Ching Wang, Ronald E. Olson
Final State Distributions For Electron Capture From Orientated Rydberg Atoms, Jee-Ching Wang, Ronald E. Olson
Chemical and Biochemical Engineering Faculty Research & Creative Works
Final state nim distributions are studied for electron capture from orientated circular Rydberg atoms. Strong orientation effects are found for all quantum numbers at collision speeds comparable to the electron orbital speed. Predominant population of large m states is observed when the plane of the circular orbit is nearly perpendicular to the incident direction of the projectile. The Ini distributions show structures due to quasi-Thomas scattering even at low relative collision velocities. © 1993 IOP Publishing Ltd.
Ionic Charge Dependence Of The Zero Degree Binary Encounter Peak For Partially Stripped Heavy Ions, W. Wolff, H. E. Wolff, J. L. Shinpaugh, Jee-Ching Wang, Ronald E. Olson, D. Fainstein, S. Lencinas, U. Bechthold, R. Herrmann, H. Schmidt-Bocking
Ionic Charge Dependence Of The Zero Degree Binary Encounter Peak For Partially Stripped Heavy Ions, W. Wolff, H. E. Wolff, J. L. Shinpaugh, Jee-Ching Wang, Ronald E. Olson, D. Fainstein, S. Lencinas, U. Bechthold, R. Herrmann, H. Schmidt-Bocking
Chemical and Biochemical Engineering Faculty Research & Creative Works
We report on the measurements of double differential cross sections, at zero degree, for the production of secondary electrons from the collision of 0, 6 MeV amu-1 Cu5+, I7+, Au11+, U13+, Cu19+, t23+ and Au29+ projectiles with H2 and He. The shapes and positions of the observed binary encounter electron peaks are compared with continuum distorted wave-eikonal initial state (CDW-EIS), impulse approximation and classical trajectory Monte Carlo calculations, as well as with predictions from an adiabatic resonant tunnelling model recently proposed by Fainstein and co-workers. The …
Dependence Of Binary Encounter Electron Production On The Charge State Of The Recoil Ion, Jee-Ching Wang, Ronald E. Olson, H. Wolf, J. Shinpaugh, W. Wolff, H. Schmidt Böcking
Dependence Of Binary Encounter Electron Production On The Charge State Of The Recoil Ion, Jee-Ching Wang, Ronald E. Olson, H. Wolf, J. Shinpaugh, W. Wolff, H. Schmidt Böcking
Chemical and Biochemical Engineering Faculty Research & Creative Works
We study the dependence of the production of binary encounter electrons on the charge state of recoil ions for 2.4 MeV u-l Xe21+ on He and Ar. Doubly differential cross sections of electron emission are calculated with the ncrMC method. We find that the contributions to the binary electron cross section from various recoil ion charge states reach a maximum near Ar5+ for the Ar target. In the case of the He target; double ionization dominates over single ionization for alt ejected electron energies above 100 eV. However, an unexpected local drop of double ionization in the …
Diffraction In The Binary Encounter Electron Peak Observed In Collisions Of 0.6 Mev Amu⁻¹ I7+, I23+ And Au11+ Projectiles With He And Ar, W. Wolff, J. L. Shinpaugh, H. E. Wolff, Ronald E. Olson, Jee-Ching Wang, S. Lencinas, D. Piscevic, R. Herrmann, H. Schmidt-Böcking
Diffraction In The Binary Encounter Electron Peak Observed In Collisions Of 0.6 Mev Amu⁻¹ I7+, I23+ And Au11+ Projectiles With He And Ar, W. Wolff, J. L. Shinpaugh, H. E. Wolff, Ronald E. Olson, Jee-Ching Wang, S. Lencinas, D. Piscevic, R. Herrmann, H. Schmidt-Böcking
Physics Faculty Research & Creative Works
Relative double differential cross sections for electron emission from collisions of 0.6 MeV amu-1I7+and I23+ projectiles with Ar and Au11+projectiles with He were measured for electron energies from 100 eV to 2000 eV and for angles from 0° to 50°. Experimentally observed sudden shifts of the position of the binary encounter peak were interpreted as resulting from quantum interference in the scattering of target electrons from the partially stripped projectile ion. To this end calculations for the elastic scattering of free electrons initially at rest in the laboratory reference frame from the screened …
Plasma Polymerization Of Tetrafluoroethylene. Iii. Capacitive Audio Frequency (10 Khz) And Ac Discharge, N. (Nicholas) C. Morosoff, H. Yasuda, E. S. Brandt, C. N. Reilley
Plasma Polymerization Of Tetrafluoroethylene. Iii. Capacitive Audio Frequency (10 Khz) And Ac Discharge, N. (Nicholas) C. Morosoff, H. Yasuda, E. S. Brandt, C. N. Reilley
Chemical and Biochemical Engineering Faculty Research & Creative Works
The plasma polymerization of tetrafluoroethylene (TFE) is studied in a capacitively coupled system with internal electrodes using a 10 kHz (af) and a 60 Hz (ac) source. The emphasis is on identifying conditions that are compatible with continuous coating of plasma polymer on a substrate moving through the center of the interelectrode gap. Operation at a pressure below 100 mTorr is most favorable for deposition of a substantial portion of the plasma polymer on this substrate. Plasma polymer deposited in this way is characterized by ESCA and by deposition rate data and compared to that deposited using rf power in …
Plasma Polymerization Of Tetrafluoroethylene. Ii. Capacitive Radio Frequency Discharge, N. (Nicholas) C. Morosoff, H. Yasuda, E. S. Brandt, C. N. Reilley
Plasma Polymerization Of Tetrafluoroethylene. Ii. Capacitive Radio Frequency Discharge, N. (Nicholas) C. Morosoff, H. Yasuda, E. S. Brandt, C. N. Reilley
Chemical and Biochemical Engineering Faculty Research & Creative Works
The plasma polymerization of tetrafluoroethylene (TFE) is studied in a capacitively coupled system with internal electrodes using radio frequency (13.56 MHz) power. The emphasis is on identifying conditions that are compatible with continuous coating of plasma polymer on a substrate moving through the center of the interelectrode gap. At high pressure (500 mTorr), deposition of plasma polymer is primarily on the electrodes rather than on a substrate placed midway between electrodes. Glow is observed in only part of the interelectrode gap at low powers and fills the gap only at high power levels. The use of a magnetic field effects …
Plasma Polymerization Of Tetrafluoroethylene. I. Inductive Radio Frequency Discharge, H. Yasuda, N. Morosoff, E. S. Brandt, C. N. Reilley
Plasma Polymerization Of Tetrafluoroethylene. I. Inductive Radio Frequency Discharge, H. Yasuda, N. Morosoff, E. S. Brandt, C. N. Reilley
Chemistry Faculty Research & Creative Works
The plasma polymerization of tetrafluoroethylene in an inductively coupled radio frequency glow discharge, using a flow system, was studied. A simple long tube reactor, with the coupling coil placed at the middle of the tube and gas entrance and exit at the respective ends, was used. Deposition rates and the chemical nature of the polymer (as revealed by ESCA spectra and surface energy studies) are obtained as a function of location in the reactor tube with respect to the coupling coil and of applied energy per unit mass of tetrafluoroethylene (W/FM). It was found that a fluorine poor polymer, containing …
Film Formation On Anodically Polarized Lead, H. Vaidyanathan, Ram A. Narasagoudar, Thomas J. O'Keefe, William Joseph James, James W. Johnson
Film Formation On Anodically Polarized Lead, H. Vaidyanathan, Ram A. Narasagoudar, Thomas J. O'Keefe, William Joseph James, James W. Johnson
Materials Science and Engineering Faculty Research & Creative Works
No abstract provided.
Handlos And Baron Model: Short Contact Times, J. Patel, Robert M. Wellek
Handlos And Baron Model: Short Contact Times, J. Patel, Robert M. Wellek
Chemical and Biochemical Engineering Faculty Research & Creative Works
No abstract provided.
The Anodic Dissolution Of Cadmium, James W. Johnson, E. Deng, S. C. Lai, William Joseph James
The Anodic Dissolution Of Cadmium, James W. Johnson, E. Deng, S. C. Lai, William Joseph James
Chemical and Biochemical Engineering Faculty Research & Creative Works
The anodic dissolution of cadmium has been studied in aqueous solutions containing Cl−, Br−, I−, Ac−, SO4=, and NO3− ions. The normal valence (+2) was found in all solutions with the exception of NO3−. The apparent valence (calculated) of cadmium ions in nitrate solutions varied from 1.2 to 2.0 and was found to be a function of NO3− concentration, current density, and temperature. An anodic dissolution mechanism has been proposed involving local corrosion and disintegration of the anode which is consistent with the experimental results. © 1967, The Electrochemical Society, Inc. All rights reserved.
Radial Pressure Gradient In Turbulent Pipe Flow, Gary Kent Patterson, Walter J. Ewbank, Virgil A. Sandborn
Radial Pressure Gradient In Turbulent Pipe Flow, Gary Kent Patterson, Walter J. Ewbank, Virgil A. Sandborn
Chemical and Biochemical Engineering Faculty Research & Creative Works
Measurements made with a Prandtl static pressure probe have demonstrated that a radial pressure gradient does exist in turbulent pipe flow with approximately the magnitude predicted by Sandborn from hot-wire anemometry measurements.
The Mechanism Of The Electrooxidation Of Acetylene On Gold, James W. Johnson, J. L. Reed, William Joseph James
The Mechanism Of The Electrooxidation Of Acetylene On Gold, James W. Johnson, J. L. Reed, William Joseph James
Chemical and Biochemical Engineering Faculty Research & Creative Works
Acetylene has been oxidized anodically in aqueous solutions at 80 °C on gold electrodes. It was found that the partial oxidation to CO2 was accompanied by a polymer formation. Effects of potential, acetylene partial pressure, pH, and temperature on the rate (current) were measured. A discontinuity in the Tafel curves was noted that indicated a change in the reaction mechanism with potential. The discontinuity was also pH dependent. A mechanism involving the discharge of H2O and/or OH− has been proposed that is consistent with the experimental results. © 1967, The Electrochemical Society, Inc. All rights reserved.
The Effect Of Concentration On The Viscosities Of Solutions Of Linear Flexible High Polymers, Lung Yu Chou, Jacques L. Zakin
The Effect Of Concentration On The Viscosities Of Solutions Of Linear Flexible High Polymers, Lung Yu Chou, Jacques L. Zakin
Chemical and Biochemical Engineering Faculty Research & Creative Works
Viscosity-concentration results in the moderately concentrated range for four samples of polyisobutylene (molecular weights of 1.3 x 104 to 1.0 x 106) in cyclohexane (concentrations up to 4.7 g./dl.) and in benzene (concentrations up to 7.0 g./dl.) at 24°C. (a theta solvent) showed molecular weight and goodness of solvent dependencies similar to those reported earlier for three other polymers. For polyisobutylene, polystyrene, and a copolymer of styrene and methyl methaerylate in good solvents, viscosity-concentration data plotted as ηsp. C[η] vs. k′[η]C fit a single curve. The linear region of this curve suggests that the Huggins equation is useful to C[η] …