Engineering Commons^™

Hydrodynamics Of Trickle Bed Reactors (Tbrs) Packed With Industrial Catalyst Using Advanced Measurement Techniques, Mohammed Jaber Al-Ani

Doctoral Dissertations

"The impacts of the packing characteristics on the hydrodynamics od a trickle bed reactor (TBR) have been investigated using advanced measurements techniques of Gamma-ray densitometry (GRD) and Optical fiber probe and conventional measurement techniques of high-frequency differential pressure transducer and load cell. Two different reactor sizes of bench and pilot plant scale were used. Bench-scale TBR carried out the experiments to assess phase distribution and catalyst utilization with 1.18 cm inside diameter and 72 cm length at ambient pressure and temperature. The mixture of catalyst and fine particles displayed considerable improvements in the phase distribution, liquid holdup profile, and catalyst …

Microstructural Evolution Of Zirconium Carbide (Zrcₓ) Ceramics Under Irradiation Conditions, Raul Florez

Doctoral Dissertations

A comprehensive understanding of the microstructural evolution of Zirconium Carbide (ZrC₂) ceramics under irradiation conditions is required for their successful implementation in advanced Gen-IV gas-cooled nuclear reactors. The research presented in this dissertation focusses on elucidating the ion and electron irradiation response of ZrC₂ ceramics. In the first part of the research, the microstructural evolution was characterized for ZrC₂ ceramics irradiated with 10 MeV Au³⁺ ions up to doses of 30 displacement per atom (dpa) at 800 ºC. Coarsening of the defective microstructure, as a function of dose, was revealed by transmission electron microscopy analysis. …

Reactor Configurations To Support Advanced Material Research, Thaqal Mazyad Alhuzaymi

Doctoral Dissertations

"The research goal is to configure a research reactor with multi-spectral capability for advance material research. This required the consideration of high and low-power levels alongside advanced fuel with high physical density and low enriched ²³⁵U. Selected fuel was U-10Mo with 19.75% ²³⁵U enrichment. The fuel and control rods system geometries were adopted from Missouri S&T Reactor (MSTR).

A high-power configuration (HPC) at 2 megawatts and low-power configuration (LPC) at 200 kilowatts were considered. Neutronic performances of the configurations were modeled using Monte Carlo N-particle (MCNP) transport code, version 6. Thermal-hydraulic analysis was performed with ANSYS Fluent. The …

Novel Insights Into Low Salinity Water Flooding Enhanced Oil Recovery In Sandstone Reservoirs, Hasan N. Al-Saedi

Doctoral Dissertations

"Ever growing global energy demand and the natural decline in oil production from mature oil fields have been the main incentives to search for methods to increase recovery efficiency for several decades. Water flooding is extensively applied worldwide to improve oil recovery. The recent drop in oil prices has turned the oil industry to the cheapest improved oil recovery (IOR) techniques, such as low salinity (LS) waterflooding. Also, the reduction in reservoir energy and the friendly environmental aspects of low salinity water flooding (LSWF) provide additional incentives for its use. That LS water requires decreasing only the active divalent cations …

Development Of Stage-I Tempered High Strength Cast Steel For Ground Engaging Tools, Viraj Ashok Athavale

Doctoral Dissertations

"Ground Engaging Tools (GET) are the expendable replacement parts used in heavy machinery used with mining or construction equipment. GET’s protect the expensive machine components from the wear and tear found common in high-impact or high-abrasion environments. The goal of this project is to develop advanced next-generation alloy choices that outperforms the existing GET materials. A method of predicting tempered hardness of mixed microstructures was formulated. Using this model, two alloy series viz. Cr-Ni-Mo and Mn-Si-Mo-V were proposed and experimented with the goal of obtaining a high strength and impact resistant cast steel. Cast iterations of Cr-Ni-Mo alloy series were …

Investigating The Performance Of High Viscosity Friction Reducers Used For Proppant Transport During Hydraulic Fracturing, Mohammed Salem Ba Geri

Doctoral Dissertations

"Over the last few recent years, high viscosity friction reducers (HVFRs) have been successfully used in the oil and gas industry across all premier shale plays in North America including Permian, Bakken, and Eagle Ford. However, selecting the most suitable fracture fluid system plays an essential role in proppant transport and minimizing or eliminating formation damage.

This study investigates the influence of the use of produced water on the rheological behavior of HVFRs compared to a traditional linear guar gel. Experimental rheological characterization was studied to investigate the viscoelastic property of HVFRs on proppant transport. In addition, the successful implication …

Applications Of Machine Learning In Nuclear Imaging And Radiation Detection, Shaikat Mahmood Galib

Doctoral Dissertations

"The main focus of this work is to use machine learning and data mining techniques to address some challenging problems that arise from nuclear data. Specifically, two problem areas are discussed: nuclear imaging and radiation detection. The techniques to approach these problems are primarily based on a variant of Artificial Neural Network (ANN) called Convolutional Neural Network (CNN), which is one of the most popular forms of 'deep learning' technique.

The first problem is about interpreting and analyzing 3D medical radiation images automatically. A method is developed to identify and quantify deformable image registration (DIR) errors from lung CT scans …

Characterization Of A Green Electric Solid Propellant For Electric Propulsion, Matthew Scott Glascock

Doctoral Dissertations

"Electric solid propellants are advanced solid chemical rocket propellants that can be controlled (ignited, throttled and extinguished) through the application and removal of an electric current. These propellants are also being considered for use in ablative pulsed plasma thruster and multimode systems. In this work, the behavior and performance of a novel green electric solid propellant operating in an electrothermal ablation-fed pulsed plasma thruster was investigated. Using an inverted pendulum micro-Newton thrust stand, the impulse bit and specific impulse of the device using the electric solid propellant were measured for short-duration and long-duration runs to end-of-life, at energy levels of …

Deep Understanding Of Degradation In Lithium Ion Batteries Through Experimental And First-Principles Study, Yufang He

Doctoral Dissertations

"The growing interests in Lithium-ion Batteries (LIBs) have significantly accelerated the development of active materials. However, the key challenge is that electrode materials suffer from degradation, which include transition metal dissolution, solid electrolyte interphase (SEI) layer formation, and mechanical fracture. To address these issues, applying an ultrathin coating onto active materials via Atomic Layer Deposition (ALD) is an efficient way. Although numerious works have been done for active material performance improvement via ALD technology, the fundamental enhancement mechanisms of ALD coating on battery performance improvement are not yet known. Therefore, this dissertation consists of four papers, which focused on the …

Biofuel Supply Chain Restructuring -- An Economic Viability And Environmental Sustainability Investigation For Enhancing Second Generation Biofuel Adoption, Rajkamal Kesharwani

Doctoral Dissertations

"Biofuel is a promising clean alternative to fossil fuels. Currently, first generation biofuels are commercially produced by using corn grain as biomass feedstock. However, the use of edible matter of crops, may lead to a competition between food and fuel. Therefore, there is a significant push in both industry and academia to commercialize second generation biofuel manufacturing technology, which uses non-edible matter from crops. Most research focuses on individual manufacturing processes for producing second generation biofuel, but the economic and environmental impacts of a large-scale adoption of second generation biofuel manufacturing have been less widely reported.

This work investigates the …

The Mechanics Of Precision Presplitting, Anthony Joseph Konya

Doctoral Dissertations

"Precision Presplitting is a widely used method of presplit blasting for the mining and construction industries. In recent years considerable effort has gone into the development of empirical equations based on field data to be able to better design the Precision Presplit for various rock types and structural environments. However, the most widely discussed theory about the mechanics of the presplit formation, that of shockwave collisions, does not appear to be applicable for this method of presplitting.

This research has disproven this theory based on insufficient magnitude of the shockwave from modeling with basic wave mechanics. Other authors have suggested …

Application Of Computational Intelligence To Explore And Analyze System Architecture And Design Alternatives, Gene Lesinski

Doctoral Dissertations

"Systems Engineering involves the development or improvement of a system or process from effective need to a final value-added solution. Rapid advances in technology have led to development of sophisticated and complex sensor-enabled, remote, and highly networked cyber-technical systems. These complex modern systems present several challenges for systems engineers including: increased complexity associated with integration and emergent behavior, multiple and competing design metrics, and an expansive design parameter solution space. This research extends the existing knowledge base on multi-objective system design through the creation of a framework to explore and analyze system design alternatives employing computational intelligence. The first research …

Multi-Body Dynamic And Finite Element Modeling Of Ultra-Large Dump Truck - Haul Road Interactions For Machine Health And Haul Road Structural Integrity, Bruno Ayaga Kansake

Doctoral Dissertations

"Haul truck capacities have increased due to their economies of scale in large-scale surface mine production systems. Ultra-large trucks impose high dynamic loads on haul roads. The dynamic loads are exacerbated by road surface roughness and truck over-loading. The dynamic forces also subject trucks to high torsional stresses, which affect truck health. Current haul road response models are 2D and use static truckloads for low capacity trucks. Existing 3D models consider the road as a two-layer system. No models capture the truck dynamic effects on haul roads and predict strut pressures during haulage.

Lagrangian mechanics was used to formulate the …

Insights Into Well Performance And Completion Optimization Using A Coupled Fracfocus And Drillinginfo Database, Mustafa A. Al-Alwani

Doctoral Dissertations

“The hydraulic fracturing designs, drilling, and completion trends are undergoing continuous change as the oil and gas industry pushing the boundaries of the traditional designs to increase wells productivity and meet the energy demand. The lateral length in addition to the amount of proppant and water used in well stimulation have witnessed a paradigm shift over the past few years. The motivation for this work began with a desire to better understand well performance as a function of the type of fracturing fluid treatment applied. An early objective was to compare whether East Texas Cotton Valley wells stimulated with water …

Design And Performance Of Fiber-Reinforced Concrete With Adapted Rheology For Construction And Repair Of Bridge Structures, Ahmed Abdelrazik

Doctoral Dissertations

“The objective of this document is to design high-performance fiber-reinforced self-consolidating concrete (FR-SCC) for infrastructure repair and fiber-reinforced super-workable concrete (FR-SWC) for bridge construction. The investigated fibers included propylene synthetic fibers, hooked steel fibers, double and triple hooked steel fibers, hybrid crimped steel fiber and polypropylene multifilament fibers, and micro-macro steel fibers. The fiber volume varied between 0 and 0.75%. An expansive agent (EA) was incorporated to compensate for shrinkage and induce compression in the concrete at early age. Two types of EA (G and K) were employed at 0 to 8%, by mass of binder. The investigated FRSCC and …

Feasibility And Assessment Of Using Recycled Rubber For Infrastructure Applications, Ahmed A. Gheni

Doctoral Dissertations

“The United States needs to mine billions of tons of raw natural aggregate each year. At the same time, millions of scrap tires are stockpiled every year. Therefore, replacing natural aggregate with recycled crumb rubber aggregate will be beneficial to the construction industry and environment. This research aimed to investigate the feasibility of using recycled rubber in new construction applications. Based on size, recycled rubber was selected to match its natural counterpart. Different ratios of recycled crumb rubber were used as a fine aggregate replacement in concrete masonry units (CMUs) where the rubberized units showed a lower unit weight, higher …

Design, Fabrication, And Characterization Of Functionally Graded Materials, Sreekar Karnati

Doctoral Dissertations

“The aim of this research was to investigate the feasibility of fabricating custom designed, graded materials using Laser Metal Deposition (LMD) that will cater for functionality and unconventional repair. The ultimate goal of the project is to establish the versatility of LMD for fabricating advanced materials and tackling problems that have been conventionally difficult or in cases infeasible. In order to accomplish these goals, this research involved investigations into, the feasibility of using elemental powders as modular feedstocks, the feasibility of fabricating tailored gradients with these custom compositions, and finally leveraging the advantages of grading materials using LMD to successfully …

Designing Bifunctional Materials For In-Situ Capture And Conversion Of Volatile Organic Compounds, Anirudh Krishnamurthy

Doctoral Dissertations

”Volatile organic compounds (VOCs) are a class of organic liquid compounds with low vapor pressures, which enables them to vaporize at ambient conditions. VOCs are largely toxic, carcinogenic, and mutagenic, and have profound adverse effects on human health and the ecological environment. Many VOCs cause ruinous health effects even at very low concentrations (ppm) and therefore control of these organic compounds is essential for ensuring good air quality. A large portion of VOCs cause catastrophic health effects such as cancer or liver damage even at very low concentrations (ppm), and the control of these compounds is vital in ensuring good …

Three-Dimensional Nanotube Arrays For Solar Energy Harvesting And Production Of Solar Fuels, Wipula P. R. Liyanage

Doctoral Dissertations

"Over the past decade extensive research has been carried out on photovoltaic semiconductors to provide a solution towards a renewable energy future. Fabricating high-efficiency photovoltaic devices largely rely on nanostructuring the photoabsorber layers due to the ability of improving photoabsorption, photocurrent generation and transport in nanometer scale. Vertically aligned, highly uniform nanorods and nanowire arrays for solar energy conversion have been explored as potential candidates for solar energy conversion and solar-fuel generation owing to their enhanced photoconversion efficiencies.

However, controlled fabrication of nanorod and especially nanotube arrays with uniform size and shape and a pre-determined distribution density is still a …

Nanoscale Solidification Of Metals By Atomistic Simulations: From Nucleation To Nanostructural Evolution, Avik Mahata

Doctoral Dissertations

"Homogeneous nucleation during solidification in Al (fcc), Fe (bcc) and Mg (hcp) is studied by million-atom molecular dynamics (MD) utilizing the second nearest neighbor modified embedded atom method (2NN-MEAM) potentials. Spontaneous homogenous nucleation from the melt was produced without any influence of pressure, free surface effects and impurities. We also study the effect on the simulation size on homogenous nucleation and the heterogeneity in homogenous nucleation. The heterogeneity in homogenous nucleation originates from the twins, grain boundaries and short range order in the liquid during the initial stages of solidification.

To study the solid-liquid coexistence in binary Al alloys, interatomic …

Use Of Wicking Geotextile To Dehydrate Road Embankments, Chuang Lin

Doctoral Dissertations

“Excess water within a pavement structure is the major cause of pavement deteriorations. A roadway is often constructed with soils compacted at the optimum water contents to achieve the best performance. After construction, the soil water content variation is controlled by the ambient environment. The base course aggregate is very sensitive to water content variations. Unfortunately, conventional drainage system can only drain gravity water, but not capillary water, and it cannot work under unsaturated conditions. Consequently, no matter how well the road is constructed, the water content is expected to increase with time and the excess water will inevitably accelerate …

Plasmonic Metamaterial For Structural Color Printing And Spontaneous Emission Control, Wei Wang

Doctoral Dissertations

”Plasmon polaritons or plasmons are a collective oscillation movement of free electrons in metal at optical frequencies. The frequency-dependent complex dielectric function makes the metal property at optical frequencies behave totally different with that at other spectral ranges with lower frequency such as infrared and microwaves. This novel property makes the so called plasmonics or nanoplasmonics a rapid growing research field over the past few years. Many innovative concepts and applications have been developed such as perfect absorber, structural color printing, and quantum emitter spontaneous emission enhancement.

In this dissertation two of the most important applications will be addressed. The …

Intelligent Data-Driven Decision-Making To Mitigate Or Stop Lost Circulation, Husam Hasan Alkinani

Doctoral Dissertations

”Lost circulation is a challenging problem in the oil and gas industry. Each year, millions of dollars are spent to mitigate or stop this problem. The aim of this work is to utilize machine learning and other intelligent solutions to help to make better decision to mitigate or stop lost circulation. A detailed literature review on the applications of decision tree analysis, expected monetary value, and artificial neural networks in the oil and gas industry was provided. Data for more than 3000 wells were gathered from many sources around the world. Detailed economics and probability analyses for lost circulation treatments’ …

Plenum-To-Plenum Heat Transfer Characteristics Under Natural Circulation In A Scaled-Down Prismatic Modular Reactor, Salman Mohammed Alshehri

Doctoral Dissertations

“Gas-cooled reactor (GCR) is being developed under the Next Generation Nuclear Plant Program (NGNP) in nuclear engineering studies. As the world searches for an energy source with high energy density, clean, abundant, and storable nature to avoid global warming issues, GCR seems to be a promising solution, particularly the possibility of producing hydrogen. Studying and developing the safety analysis and GCR technologies are required for the optimum design and safety of GCR system. Multiphase Reactors Engineering and Applications Laboratory (mReal) at Missouri University of Science and Technology (S&T) has developed a natural convection heat transfer test facility with one riser …

Design And Characterization Of A Strong Positron Source At The Mstr Beam Port, Raed Atiah Alsulami

Doctoral Dissertations

“For many years, slow positron sources have found uses in diverse fields including medical physics, nuclear physics, biology, surface science, exotic atom research and space science. The purpose of this work is to design and optimize a reactor-based positron source at the Missouri University of Science and Technology Reactor (MSTR) beam port and quantify its intensity. Monte Carlo simulations using the MCNP6 code were used to model the positron production and moderation processes at the MSTR beam port. The thermal neutron flux at the beam port was determined experimentally and used in the source definition of the radiation transport simulations. …

Characterization Of Aerosols In An Underground Mine, Arash A. Habibi

Doctoral Dissertations

“Diesel-powered engines are a common source of submicron carbon-rich particles. Characterizing morphological and physical attributes of diesel agglomerates is therefore of great importance to be able to identify the source and improve removal technology. Size-segregated sampling was conducted in two phases of underground experiments. Scanning transmission electron microscopy and fast mobility particle sizers were used to determine the size distribution of agglomerates based on particle mobility and projected area diameter. Controlled zone sampling test results were used to determine the morphological characteristics of agglomerates for specific types of diesel equipment both with and without removal strategies. Changes in fractal dimension, …

Volumetric Error Compensation For Industrial Robots And Machine Tools, Le Ma

Doctoral Dissertations

“A more efficient and increasingly popular volumetric error compensation method for machine tools is to compute compensation tables in axis space with tool tip volumetric measurements. However, machine tools have high-order geometric errors and some workspace is not reachable by measurement devices, the compensation method suffers a curve-fitting challenge, overfitting measurements in measured space and losing accuracy around and out of the measured space. Paper I presents a novel method that aims to uniformly interpolate and extrapolate the compensation tables throughout the entire workspace. By using a uniform constraint to bound the tool tip error slopes, an optimal model with …

Scaleable Nanomanufacturing Of Metasurfaces Using Microsphere Photolithography, Chuang Qu

Doctoral Dissertations

“The cost-effective manufacturing of metasurfaces over large areas is a critical issue that limits their implementations. Microsphere photolithography (MPL) uses a scalable self-assembled microsphere array as an optical element to focus collimated light to nanoscale photonic jets in a photoresist layer. This dissertation investigates the fabrication capabilities, process control, and potential applications of MPL. First, the MPL concept is applied to the fabrication of metasurfaces with engineered IR absorption (e.g. perfect absorption with multiband/broadband and wavelength/polarization dependences). Improving the patterning of the photoresist requires a fundamental understanding the photochemical photonic jet interactions. The dissertation presents a model of the MPL …

On Developing A Graphitic White Iron For Metal-To-Metal Wear Systems, Jie Wan

Doctoral Dissertations

"This research addressed heat dissipation issues related to the adhesive wear observed in metal-to-metal wear systems, by developing a graphitic white iron to increase thermal diffusivity of the wear components. One of the premium materials commonly used in current metal-to-metal wear systems is Fe15Mo18Cr and field returned parts were characterized as part of this study. Failure analysis showed that white layers were formed on the wearing surface due to frictional heating and surface deformation. These white layers were extremely brittle and could be fractured easily during use, which in turn led to micro-galling defects that caused parts leakage. Increasing thermal …

Fundamental Mechanism Of Time Dependent Failure In Shale, Neel Gupta

Graduate Theses, Dissertations, and Problem Reports (ETD)

In underground coal mines, mining activity disturbs the natural equilibrium state of in-situ stresses. The induced and in-situ stresses deform the rockmass surrounding the mine openings. Primary roof supports impede the deformation of the rockmass overlying the entries. However, failure can occur in the bolted rockmass, causing fatalities and injuries. The rockmass failure is erratic, and its occurrence often varies from a few days to months and years after the opening of the entry. One of the often-neglected factors in this process is the effect of time on the stability of mine openings, which can often be observed in the …