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Articles 67381 - 67410 of 75086

Full-Text Articles in Engineering

Management Of Feedlot Runoff Control Systems, Elbert C. Dickey, Gerald R. Bodman Jan 1992

Management Of Feedlot Runoff Control Systems, Elbert C. Dickey, Gerald R. Bodman

Department of Agricultural and Biological Systems Engineering: Faculty Publications

During recent years, most open feedlot operators have found it desirable and, in some cases, necessary to install runoff control facilities. Even though the primary purpose of feedlot runoff control systems is the prevention of water pollution, many producers have found that good management of these systems also offers limited economic benefits in the form of fertilizer nutrients and supplemental irrigation water. Well managed runoff control systems also reduce weeds, odors, insects and muddy areas at or near feedlot edges. The runoff control system that has proved most satisfactory for all areas of the country is one consisting of clean …

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Kinetic Analysis Of Competing Intramolecular And Intermolecular Polymerization Reactions, Hossein Noureddini, Delmar C. Timm Jan 1992

Kinetic Analysis Of Competing Intramolecular And Intermolecular Polymerization Reactions, Hossein Noureddini, Delmar C. Timm

Papers in Molecular Chemistry

ABSTRACT: Kinetic reaction theory was used to model a step-growth, thermoset polymerization of a monomer of even functionality/. Intermolecular additions were represented by second-order and intramolecular reactions were expressed by first-order rate expressions. All functional groups were assumed to react with equal reactivity. Independent variables are degree of polymerization i, extent of cross-linking j, and conversion p. The normalized rate constant for intramolecular reactions is c. The solution for the normalized population density distribution............ subj Formulae for the number-, mass-, and cross-link-average molecular weights were derived.

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Parameter Sensitivity And Optimization Predictions Of A Hydrogen/Oxygen Alkaline Fuel Cell Model, Michael C. Kimble, Ralph E. White Jan 1992

Parameter Sensitivity And Optimization Predictions Of A Hydrogen/Oxygen Alkaline Fuel Cell Model, Michael C. Kimble, Ralph E. White

Faculty Publications

A mathematical model is used to predict parameter sensitivities and optimal design parameters for a hydrogen/oxygen alkaline fuel cell. A sensitivity analysis of the various transport and electrode kinetic parameters indicates which parameters have the most influence on the predicted current density and over which range of potentials these parameters affect the fuel-cell performance the most. This information can be used to decide which parameters should be optimized or determined more accurately through further modeling or experimental studies. The effect of various design parameters on the limiting current density are investigated to determine if optimal values exist for the parameters. …

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The Self-Discharge Of The Niooh/Ni(Oh)2 Electrode Constant Potential Study, Z. Mao, Ralph E. White Jan 1992

The Self-Discharge Of The Niooh/Ni(Oh)2 Electrode Constant Potential Study, Z. Mao, Ralph E. White

Faculty Publications

Hydrogen oxidation currents at a NiOOH/Ni(OH)2 electrode were measured directly at constant potentials for various hydrogen pressures and states of charge. It was found that the hydrogen oxidation current is linearly proportional to the hydrogen pressure at all electrode potentials and that the logarithm of the anodic current is a linear function of electrode potential. It was also found that hydrogen oxidation on the nickel substrate material was strongly inhibited by the presence of nickel hydroxide on the substrate surface. By comparing the currents for hydrogen oxidation and oxygen evolution on the NiOOH/Ni(OH)2 electrode and on a nickel …

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Mathematical Modeling Of Cathodic Protection Using The Boundary Element Method With A Nonlinear Polarization Curve, J. F. Fan, S. N. R Pakalapati, T. V. Nguyen, Ralph E. White, R. B. Griffin Jan 1992

Mathematical Modeling Of Cathodic Protection Using The Boundary Element Method With A Nonlinear Polarization Curve, J. F. Fan, S. N. R Pakalapati, T. V. Nguyen, Ralph E. White, R. B. Griffin

Faculty Publications

The distributions of potential and current density around a cathodically protected pipeline in seawater were determined using the boundary element technique. A nonlinear polarization curve for a low carbon steel in artificial sea water was obtained from dc-potentiodynamic measurements and was fitted for use as the boundary condition on the pipe. The program was used to evaluate cases in which one or two aluminum sacrificial anodes are used to protect a low carbon steelpipe in seawater. The results show that the number of anodes, the sizes of the anodes, and the distance between the anodes and the cathode are of …

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Hydrogen Diffusion, Solubility, And Water Uptake In Dow's Short-Side-Chain Perfluorocarbon Membranes, Yu-Min Tsou, M. C. Kimble, Ralph E. White Jan 1992

Hydrogen Diffusion, Solubility, And Water Uptake In Dow's Short-Side-Chain Perfluorocarbon Membranes, Yu-Min Tsou, M. C. Kimble, Ralph E. White

Faculty Publications

Hydrogen gas diffusion coefficients and solubilities as well as water uptake values are reported for Dow's short-side-chain perfluoro-sulfonic and -carboxylic membranes of different equivalent weight (EW). The diffusion coefficients and solubilities were determined with an electrochemical test cell. Hydrogen solubility decreases with increasing EW in the lower EW range and tends to level off at higher EWs for both types of membranes. Both hydrogen solubility and diffusion coefficients of a sulfonic membrane with EW higher than 800 are higher than the corresponding values of a carboxylic membrane of similar EW. An unusual maximum is observed in the diffusion coefficient-EW plot …

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Calorimetric Determination Of The Thermoneutral Potential Of Li/Bcx And Li/Socl2 Cells, E. E. Kalu, Ralph E. White, E. C. Darcy Jan 1992

Calorimetric Determination Of The Thermoneutral Potential Of Li/Bcx And Li/Socl2 Cells, E. E. Kalu, Ralph E. White, E. C. Darcy

Faculty Publications

Through a continuous recording of the cell voltage, heat flow, and current, the effective thermoneutral potential, Eetpof Li/BCX and Li/SOCl2 cells were determined in the temperature range, 0–60°C. The depth of discharge (DOD), temperature (T), and cell type (cell chemistry) affect the effective thermoneutral potential. The effective thermoneutral potential, Eetp differs from the classical thermoneutral potential of a cell because it takes into account the heat flow due to non-faradaic processes. The average effective thermoneutral potential at 25°C (determined by selecting the most constant region of Eetp vs. time of discharge) was 4.0 …

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Comparing Electrochemical Impedance Spectroscopy Methods For Estimating The Degree Of Delamination Of Organic Coatings On Steel, S. A. Mccluney, S. N. Popova, Branko N. Popov, Ralph E. White, R. B. Griffin Jan 1992

Comparing Electrochemical Impedance Spectroscopy Methods For Estimating The Degree Of Delamination Of Organic Coatings On Steel, S. A. Mccluney, S. N. Popova, Branko N. Popov, Ralph E. White, R. B. Griffin

Faculty Publications

Electrochemical impedance spectroscopy (EIS) was used to evaluate the degree of delamination of the epoxy primer Uniprime ED-41 electrocoated on phosphate-treated cold-rolled steel in 3.5% NaCl exposed to air. Specimens with coating thicknesses of 20.3 and 20.8 µm and surface areas of 78.5 cm2 were used. Coating parameters were obtained using a circuit-analog model. The area of delamination was estimated using several EIS parameters, including the pore resistance and the break point frequency. These values were compared to the corroded area determined visually. All methods considered exhibited a strong correlation over some or all of the range of …

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Reduction Of Chromium (Vi) When Solar Selective Black Chromium Is Deposited In The Presence Of Organic Additive, Branko N. Popov, Ralph E. White, D. Slavkov, Z. Koneska Jan 1992

Reduction Of Chromium (Vi) When Solar Selective Black Chromium Is Deposited In The Presence Of Organic Additive, Branko N. Popov, Ralph E. White, D. Slavkov, Z. Koneska

Faculty Publications

Electrochemical dc methods were used to study the reduction of chromium (VI) in the presence of organic additives. It is shown that F–, thiourea, and citric acid are essential to enable deposition of black chrome from concentrated chromic acid solutions. A new formulation of the plating bath is defined. The optimum operating conditions under which spectrally selective surface of black chrome is deposited have been determined.

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Measurements Of The Fundamental Thermodynamic Parameters Of Li/Bcx And Li/Socl2 Cells, E. E. Kalu, Ralph E. White, E. C. Darcy Jan 1992

Measurements Of The Fundamental Thermodynamic Parameters Of Li/Bcx And Li/Socl2 Cells, E. E. Kalu, Ralph E. White, E. C. Darcy

Faculty Publications

The thermodynamic data needed to estimate the heat generation characteristics of Li/BCX and Li/SOCl2 cells were determined using two experimental techniques, equilibrium or reversible cell discharge and measurement of open circuitpotential as a function of temperature. The results obtained showed that the reversible cell potential (Er), the temperature dependence of the reversible cell potential (dEr/dT) and thermoneutral potential (Eh) of the BCX cell were respectively, Er,25oc = 3.74 V, dEr/dT = –0.857 ± 0.198 mV/K and Eh = 3.994 …

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A Mathematical Model Of A Cuo/Cu Vaporvolt Cell, Makoto Kawanami, Trung V. Nguyen, Ralph E. White Jan 1992

A Mathematical Model Of A Cuo/Cu Vaporvolt Cell, Makoto Kawanami, Trung V. Nguyen, Ralph E. White

Faculty Publications

A new battery named "Vaporvolt"b cell is in the early stage of its development. A mathematical model of a CuO/CuVaporvolt cell is presented that can be used to predict the potential and the transport behavior of the cell during discharge.A sensitivity analysis of the various transport and electrokinetic parameters indicates which parameters have the mostinfluence on the predicted energy and power density of the Vaporvolt cell. This information can be used to decide whichparameters should be optimized or determined more accurately through further modeling or experimental studies. Theoptimal thicknesses of electrodes and separator, the concentration of the electrolyte, and …

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Maximizing Sustainable Ground-Water Withdrawals: Comparing Accuracy And Computational Requirements For Steady-State And Transient Digital Modeling Approaches, Richard C. Peralta, R. R.A. Cantiller, Gary L. Mahon Jan 1992

Maximizing Sustainable Ground-Water Withdrawals: Comparing Accuracy And Computational Requirements For Steady-State And Transient Digital Modeling Approaches, Richard C. Peralta, R. R.A. Cantiller, Gary L. Mahon

Civil and Environmental Engineering Faculty Publications

Rigorous models for maximizing sustainable groundwater withdrawals may require more computer memory for their constraint set than is available. In some situations, alternative constraint formulations yield similar or identical answers resulting in great saving in computer memory requirements. In order to evaluate the efficiency of using alternative constraints1 maximum ground-water withdrawal pumping strategies were computed by three digital models for a hypothetical area for a five-decade period. Model A maximized steady ground-water withdrawal. Model B maximized unsteady ground-water mining. Model C maximized unsteady ground-water mining subject to a constraint that final pumping be sustainable after the end of the 50-year …

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Optimal Linear/Nonlinear, Quantity/Quality Management Of Complex Multilayer Aquifers By Embedding, Ali Gharbi, Richard C. Peralta Jan 1992

Optimal Linear/Nonlinear, Quantity/Quality Management Of Complex Multilayer Aquifers By Embedding, Ali Gharbi, Richard C. Peralta

Civil and Environmental Engineering Faculty Publications

The embedding optimization modelling approach is adapted to aid long-term groundwater quality and quantity management of complex nonlinear multilayer aquifers. Implicit block-centered finite-difference approximations of the quasi-three-dimensional unsteady flow equation, and Galerkin finite-element approximations of the twodimensional advection-dispersion transport equation are embedded as constraints in the model. Other hydrological processes are also included as constraints. Cyclical linear differencing permits representation of nonlinear transport, even when contaminant is extracted by unsteady pumping (a decision variable). Also used are nonlinear (discontinuous derivative) constraints describing drainage, stream-aquifer interflow and evapotranspiration. The use of both linear and nonlinear formulations of the entire flow and …

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Evaluation Of Mechanisms Of Alteration And Humification Of Pahs For Water Quality Management, Ronald C. Sims, Carolyn K. Abbott Jan 1992

Evaluation Of Mechanisms Of Alteration And Humification Of Pahs For Water Quality Management, Ronald C. Sims, Carolyn K. Abbott

Reports

Introduction: Creosote-pentachlorophenol (PCP) is a mixture commonly used as a wood preservative in the U.S. (1). A 1988 survey (2) indicated that 1,397 wood preserving waste contaminated sites exist in the United States consisting of 555 active wood treatment plants and 842 inactive plants. Stinson (3) indentifed 58 wood preserving sites on the National Priorities List, of which 51 have PCP and/or creosote or polycyclic aromatic hydrocarbon (PAH) contamination. Principal classes of organic constituents present in creosote waste are PAHs (~85% by weight) and phenolics. PAHs with less than three fused benzene rings comprise 69% (i.e., naphthalene, anthracene and phenanthrene); …

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Bioengineering For Water Cleanup: State-Of-The-Art Assessment, Judith L. Sims, Ronald C. Sims, Jon S. Ginn Jan 1992

Bioengineering For Water Cleanup: State-Of-The-Art Assessment, Judith L. Sims, Ronald C. Sims, Jon S. Ginn

Reports

No abstract provided.

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A Spatially Distributed Water Balance Based On Physical, Isotropic And Airborne Remotely Sensed Data, C. M.U. Neale, David G. Tarboton, J. J. Mcdonnell Jan 1992

A Spatially Distributed Water Balance Based On Physical, Isotropic And Airborne Remotely Sensed Data, C. M.U. Neale, David G. Tarboton, J. J. Mcdonnell

Reports

Introduction: The objective of this research to develop a spatially distributed water balance model based on the integration of spatially distributed data. Progress this year has consisted of model development, instrument acquisition, installation and development of experimental procedures, and baseline data collection. The original research plan called for detailed observations related to the water balance over the year September 1991 to August 1992. The detailed measurements were to start with accumulation of the snowpack followed by melt and evapotranspiration measurements from March to August. The objective was to measure the energy balance parameters starting with the peak accumulation, through the …

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Composting Of Explosives Contaminated Soil Using The White Rot Fungus Phanerochaete Chrysosporium, Michael J. Mcfarland, Shashi Kalaskar, Eric Baiden Jan 1992

Composting Of Explosives Contaminated Soil Using The White Rot Fungus Phanerochaete Chrysosporium, Michael J. Mcfarland, Shashi Kalaskar, Eric Baiden

Reports

Bioaugmentation using the white rot fungus Phanerochaete chrysosporium was found to be effective in enhancing TNT removal in lightly (i.e., below 100 mg/kg) contaminated soil. The percent reduction in TNT increased from 15% to 53% when soils were treated with fungal inoculated organic material. Maximum removal rates improved from 0.33 mg TNT/kg-day to 0.76 mg TNT/kg-day during the same treatment. Neither fungal inoculation nor organic amendment addition resulted in improving TNT removal kinetics in highly contaminated soils (i.e., above 1000 mg/kg). Executive Summary: Laboratory scale compost studies were conducted to evaluate the effect of bioaugmentation with the white rot fungus,

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Nonparametric Stratigraphic Interpretation From Drill Log Data, Upmanu Lall, A. I. Ali Jan 1992

Nonparametric Stratigraphic Interpretation From Drill Log Data, Upmanu Lall, A. I. Ali

Reports

Near surface groundwater contamination is a widespread problem. The potential for contamination of deep aquifers in such areas depends on the vertical hydraulic gradient as well as the extent and location of interconnection between the upper and lower aquifers. In alluvial, sedimentary environment, the geologic units are typically weakly connected lenses or layers of high or low conductivity with variable size, geometry and orientation. Drill logs provide qualitative, local information on such aquifer heterogeneities. A binary (high or low conductivity) indicator function is used to describe the aquifer system. A nonparametric statistical methodology for assessing the probability that a particular …

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Fate And Transport Of Tce-Petroleum Hydrocarbon Mixture At Uttr, G. Nash Quashiga, Richard C. Peralta Jan 1992

Fate And Transport Of Tce-Petroleum Hydrocarbon Mixture At Uttr, G. Nash Quashiga, Richard C. Peralta

Civil and Environmental Engineering Faculty Publications

In 1988 a preliminary assessment (PA) study was conducted at Chemical Disposal Pit No. 4 to address several concerns of Hill Air Force Base (HAFB), the facility operators. The objectives of the PA were; i) to assess the potential for organic chemical releases to the subsurface environment, and ii) to determine the need for any immediate control measures, if the subsurface environment were threatened.

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Optimizing Perennial Groundwater Yield Planning For Nonlinear Systems: Approach Comparison, Shu Takahashi, Richard C. Peralta Jan 1992

Optimizing Perennial Groundwater Yield Planning For Nonlinear Systems: Approach Comparison, Shu Takahashi, Richard C. Peralta

Civil and Environmental Engineering Faculty Publications

Four alternative simulation/optimization models useful for computing optimal sustained-yield (steady-state) groundwater pumping strategies are compared in terms of formulation, solution procedure, accuracy, and computational efficiency. The different models require different computer processing time and memory. For the aquifer tested system, if more than 10% of the cells have pumping as a decision variable, a fully linearized embedding model will require less computer memory than any other model. All the models address linear and nonlinear steady-state flow in multilayer, unconfined/confined aquifers. They also address several types of nonsmooth external flows. Newly presented are a response matrix model solving external flows described …

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Optimizing Ground Water Planning And Management, Richard C. Peralta, L. S. Willardson Jan 1992

Optimizing Ground Water Planning And Management, Richard C. Peralta, L. S. Willardson

Civil and Environmental Engineering Faculty Publications

Simulation/optimization (S/0) models can be used to speed the process of computing long term groundwater pumping strategies. These combined models can also greatly ease the planning tasks of water management agencies. They make the process of computing optimal perennial yield groundwater management strategies fairly straightforward. S/0 models dramatically improve conjunctive water management and can help minimize the cost of groundwater contaminant clean-up. The differences between S/0 models and the simulation (S) models currently used by over 98 % of practitioners are illustrated with recent applications of S/0 models in regional planning.

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Best Management Practices (Bmps) To Minimize Nitrate Leaching From Irrigated Potatoes, Ahmad Yar Ranjha, Richard C. Peralta, Robert W. Hill Jan 1992

Best Management Practices (Bmps) To Minimize Nitrate Leaching From Irrigated Potatoes, Ahmad Yar Ranjha, Richard C. Peralta, Robert W. Hill

Civil and Environmental Engineering Faculty Publications

Numerous preliminary simulations are again performed to determine the smallest fertilizer amount, applied througii sprinkler irrigations (chemigation), that should still yield 15.3 tons of potatoes per acre. Applying only 68 lbs/ac of ammonium nitrate fertilizer in the first irrigation on June 28, should be sufficient. Again, total crop N uptake equals potential crop N uptake throughout the growing season. Except for the net income and applied fertilizer N uptake efficiency, all the other results computed by NLEAP (Figure 4 and Table 1) are very similar to results of scenario II. Applied fertilizer N uptake efficiency is the highest (91%) in …

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Optimal Groundwater Quantity/Quality Planning For Salt Lake Valley, Ali Gharbi, Richard C. Peralta Jan 1992

Optimal Groundwater Quantity/Quality Planning For Salt Lake Valley, Ali Gharbi, Richard C. Peralta

Civil and Environmental Engineering Faculty Publications

Generally, the embedding technique for optimizing groundwater management has been limited to small scale or steady-state groundwater flow management cases. The embedding approach causes sparse, highly structured constraint matrices which have been sometimes difficult to solve. Embedding applications have been limited by lack of: optimization algorithms able to easily address such matrices for large scale problems, and efficient methods for addressing common nonlinearities and converging to a solution. Computer software, USUEM, addresses these issues by: creation of alternative linear, nonlinear, combined and partitioned formulations of the same problem, implemention of an efficient cycling procedure, and good selection of optimization algorithm …

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Pluman, Decision Support System For Groundwater Contaminant Plume Simulation/Optimization Management Model, Herminio H. Suguino, Richard C. Peralta Jan 1992

Pluman, Decision Support System For Groundwater Contaminant Plume Simulation/Optimization Management Model, Herminio H. Suguino, Richard C. Peralta

Civil and Environmental Engineering Faculty Publications

No abstract provided.

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Optimal Management Of Irrigation And Vadose Zone Pesticide Transport, M. A. Hegazy, Richard C. Peralta Jan 1992

Optimal Management Of Irrigation And Vadose Zone Pesticide Transport, M. A. Hegazy, Richard C. Peralta

Civil and Environmental Engineering Faculty Publications

A management model is developed for maximizing crop yield while avoiding unacceptable pesticide leaching. Utilized constraint equations: maintain a soil moisture volume balance, describe downward pesticide transport, and limit the amount of pesticide reaching groundwater. The reported optimization model is the first which includes unsaturated zone pesticide transport. It is designed to help prevent nonpoint-source contamination of shallow groundwater aquifers. The model computes optimal irrigation amounts for given soil, crop, chemical, and climate data and irrigation frequencies. The model is tested for different irrigation scenarios. The modeling approach is promising as a tool to aid developing environmentally sound agricultural production …

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Optimal Perennial Groundwater Yield Planning For The East Shore Area, Utah, Shu Takahashi, Richard C. Peralta Jan 1992

Optimal Perennial Groundwater Yield Planning For The East Shore Area, Utah, Shu Takahashi, Richard C. Peralta

Civil and Environmental Engineering Faculty Publications

Computer models are developed for computing optimal perennial groundwater withdrawal strategies for the East Shore Area of Utah's Great Salt Lake. The underlying aquifer has three confined or unconfined layers. Both embedding and response matrix (RM) approaches are tested and compared. Historically, it has been difficult to incorporate simulation of an unconfined aquifer and many external flow equations described by nonsmooth functions within linear programming models. RM models normally assume system linearity. The presented RM model overcomes this difficulty using cycling and influence coefficients generated with a modified MODFLOW model. In this groundwater flow simulation model, the above nonlinear terms …

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Chemical Structure Of Char In The Transition From Devolatilization To Combustion, Thomas H. Fletcher, Mark S. Solum, David M. Grant, Ronald J. Pugmire Jan 1992

Chemical Structure Of Char In The Transition From Devolatilization To Combustion, Thomas H. Fletcher, Mark S. Solum, David M. Grant, Ronald J. Pugmire

Faculty Publications

Coal devolatilization experiments are generally conducted separately from char oxidation experiments, and the relationship between the chars generated in the two types of research is often ignored. However, char is one of the most important products of coal devolatilization and must be characterized as a function of temperature and heating rate in a manner similar to that for gaseous devolatilization products. The chemical structure of the parent coal directly affects devolatilization behavior. In this work, the chemical structure of chars from five coals of different rank are examined, and implications on char reactivity are discussed. Chars were obtained as a …

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Triallylphosphine Plasma Polymerization And Reaction Of The Product With Volatile Transition Metal Compounds, S. D. Clymer, Nicholas C. Morosoff, A. L. Crumbliss Jan 1992

Triallylphosphine Plasma Polymerization And Reaction Of The Product With Volatile Transition Metal Compounds, S. D. Clymer, Nicholas C. Morosoff, A. L. Crumbliss

Chemical and Biochemical Engineering Faculty Research & Creative Works

The plasma polymerization of triallyl phosphine in order to form a crosslinked polymer thin film is described. The plasma polymer thin film has been characterized and shown to contain a high proporation of C=C and P groups conserved from the monomer. The accessibility of the phosphine groups has been demonstrated by reaction with O2, NO, Ni(CO)4, and Fe(CO)5. Reaction with O2, and NO results in a P=O moiety formation. Reaction with the gaseous metal carbonyls results in fixation of the metal via complexation by the P groups as a result of exchange …

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Tensile Fatigue Behaviour Of Tightly Woven Carbon/Carbon Composites, A. Ozturk, Robert E. Moore Jan 1992

Tensile Fatigue Behaviour Of Tightly Woven Carbon/Carbon Composites, A. Ozturk, Robert E. Moore

Materials Science and Engineering Faculty Research & Creative Works

The tensile fatigue behavior of a tightly woven carbon/carbon composite was investigated as a function of stress level. Load-controlled fatigue tests were performed in tension-tension mode with a stress ratio, R, of 0.1 under ambient laboratory conditions. Results of composite behavior are discussed in terms of the relationship of the stress/strain behavior to the fatigue life of these composites as well as the effects of applied stress levels. It is shown that these composites exhibit good resistance to cyclic loading. No fatigue failures were obtained after 106 cycles when the maximum tensile load in the fatigue cycle is less than …

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Chemical Percolation Model For Devolatilization: Ii. Temperature And Heating Rate Effects On Product Yields, Thomas H. Fletcher, Alan R. Kerstein, Ronald J. Pugmire, David M. Grant Jan 1992

Chemical Percolation Model For Devolatilization: Ii. Temperature And Heating Rate Effects On Product Yields, Thomas H. Fletcher, Alan R. Kerstein, Ronald J. Pugmire, David M. Grant

Faculty Publications

The chemical percolation devolatilization (CPD) model describes the devolatilization behavior of rapidly heated coal based on the chemical structure of the parent coal. Percolation lattice statistics are employed to describe the generation of tar precursors of finite size based on the number of cleaved labile bonds in the infinite lattice. The chemical percolation devolatilization model described here includes treatment of vapor-liquid equilibrium and a cross-linking mechanism. The cross-linking mechanism permits reattachment of metaplast to the infinite char matrix. A generalized vapor pressure correlation for high molecular weight hydrocarbons, such as coal tar, is proposed based on data from coal liquids. …

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