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Articles 2131 - 2160 of 2359

Full-Text Articles in Engineering

Modeling The Effect Of Plasticizer On The Viscoelastic Response Of Crosslinked Polymers Using The Tube-Junction Model, P. P. Simon, Harry J. Ploehn Jan 2000

Modeling The Effect Of Plasticizer On The Viscoelastic Response Of Crosslinked Polymers Using The Tube-Junction Model, P. P. Simon, Harry J. Ploehn

Faculty Publications

Plasticizers modify the mechanical properties of polymericmaterials. The effects of plasticizers on glass transition temperatures can be most clearly observed in isochronal temperature sweep profiles of viscoelastic dynamic moduli. However, no simple mathematical models of plasticization are available to those who wish to design and employ plasticized materials in specific applications. We extend a phenomenological, molecular-level model (known as the tube–junction model) for crosslinked polymers to describe the effect of plasticizers on dynamic moduli. We show that the increase in free volume fraction due to the presence of the plasticizer can account for the shift in the glass transition in …

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Diffusion Of Water In Nafion 115 Membranes, Sathya Motupally, Aaron J. Becker, John W. Weidner Jan 2000

Diffusion Of Water In Nafion 115 Membranes, Sathya Motupally, Aaron J. Becker, John W. Weidner

Faculty Publications

In this paper, experimental and simulated data for the diffusion of water across Nafion membranes as a function of the water activity gradient are presented. The gradient in the activity of water across the membrane was varied by changing the flow rate and pressure of nitrogen gas on one side of the membrane. The other side of the membrane was equilibrated with liquid water. It was found that the model predictions are very sensitive to the value of the diffusion coefficient of water in Nafion. Using the Fickian diffusion coefficient extracted from self-diffusion measurements reported in the literature, the model …

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Modeling The Effects Of Ion Association On Direct-Current Polarization Of Solid Polymer Electrolytes, Changqing Lin, Ralph E. White, Harry J. Ploehn Jan 2000

Modeling The Effects Of Ion Association On Direct-Current Polarization Of Solid Polymer Electrolytes, Changqing Lin, Ralph E. White, Harry J. Ploehn

Faculty Publications

Considerable experimental evidence indicates that ion association occurs in solid polymer electrolytes. This work provides a thorough theoretical analysis of the effect of ion association on the conductivity, general current-potential behavior, and limiting current density in a solid polymer electrolyte. The model employs dilute solution theory to describe the fluxes of cations, anions, and ion pairs in a motionless continuum but neglects higher order association. The predictions of the model highlight the effects of the relative diffusion coefficients and dimensionless association constant on concentration distributions of simple ions and ion pairs, the limiting current density, and the potential drop required …

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Oxygen Diffusion Coefficient And Solubility In A New Proton Exchange Membrane, Andrew T. Haug, Ralph E. White Jan 2000

Oxygen Diffusion Coefficient And Solubility In A New Proton Exchange Membrane, Andrew T. Haug, Ralph E. White

Faculty Publications

No abstract provided.

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Self‐Discharge Model Of A Nickel‐Hydrogen Cell, B. Wu, Ralph E. White Jan 2000

Self‐Discharge Model Of A Nickel‐Hydrogen Cell, B. Wu, Ralph E. White

Faculty Publications

No abstract provided.

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An Agent-Based Global Economy, Michael N. Huhns Jan 2000

An Agent-Based Global Economy, Michael N. Huhns

Faculty Publications

Many people are buying music CDs over the Web, but with multiple retail sites offering the same CDs, how do you decide which retailer to buy from? Typically, you visit a few sites and choose the one with the lowest price. Shopbotsshopping agents that automatically search the Internet to obtain information about prices and other attributes of goods and servicesare ideal helpers for such a task.1 The better ones can visit hundreds of sites, giving price-conscious consumers a powerful tool that could work to the detriment of some retailers.

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The Emergence Of Language Among Autonomous Agents, Piotr Gmytrasiewicz, Michael N. Huhns Jan 2000

The Emergence Of Language Among Autonomous Agents, Piotr Gmytrasiewicz, Michael N. Huhns

Faculty Publications

Suppose some autonomous shopbot agents had been representing us by dealing with a vendor's pricebot, and suppose they didn't share an agent communication language (ACL). What should they know at a fundamental level, what could each point to, and how could they establish a common language? Recent research at the University of Texas at Arlington has shown that agents first establish a common vocabulary, progress to a primitive language similar to human pidgin, then enrich the language's grammar to develop a creole, and eventually arrive at a full-blown ACL. During this process, the vocabulary and grammatical structures most important to …

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Sensors + Agents + Networks = Aware Agents, Michael N. Huhns, Sreenath Seshadri Jan 2000

Sensors + Agents + Networks = Aware Agents, Michael N. Huhns, Sreenath Seshadri

Faculty Publications

Software agents are being deployed in increasing numbers to help users find and manage information, particularly in open environments such as the Internet. For the most part, they operate independently and are typically designed to be aware only of their users and the environment in which they perform their tasks. Thus, they fail to take advantage of each other's abilities or results. For example, a shopping agent might periodically access several online databases to find the best price for a music CD and then purchase it if the price falls below its user's threshold. Other agents might be tracking prices …

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Agent Teams: Building And Implementing Software, Michael N. Huhns Jan 2000

Agent Teams: Building And Implementing Software, Michael N. Huhns

Faculty Publications

Agents will become fundamental building blocks for general-purpose Internet-based software. The software may not display any explicitly agent-like characteristics, but it will exhibit the benefits of tolerance to errors, ease of maintenance, adaptability to change, and speed of construction that agents provide. Moreover, an agent-based approach to software development can lead to new types of software solutions that might not otherwise be obvious. The author considers how an approach based on teams of active, cooperative, and persistent software components, that is agents, shows special promise in enabling the rapid construction of robust and reusable software.

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Studies On The Capacitance Of Nickel Oxide Films: Effect Of Heating Temperature And Electrolyte Concentration, Venkat Srinivasan, John W. Weidner Jan 2000

Studies On The Capacitance Of Nickel Oxide Films: Effect Of Heating Temperature And Electrolyte Concentration, Venkat Srinivasan, John W. Weidner

Faculty Publications

Nickel oxide films were prepared by electrochemically precipitating the hydroxide and heating it in air to form the oxide. The resulting oxide films behave as a capacitor. The capacitance of the oxide depends on the heating temperature, showing a maximum at 300°C. The mechanism of charge storage was studied by measuring the capacitance and surface area as a function of heating temperature, and the capacitance in different electrolytes and potential windows. The charge-storage mechanism is believed to be a surface redox reaction involving adsorbed hydroxyl ions.

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Development Of A New Electrodeposition Process For Plating Of Zn-Ni-X (X = Cd, P) Alloys: I. Corrosion Characteristics Of Zn-Ni-Cd Ternary Alloys, Anand Durairajan, Bala S. Haran, Ralph E. White, Branko N. Popov Jan 2000

Development Of A New Electrodeposition Process For Plating Of Zn-Ni-X (X = Cd, P) Alloys: I. Corrosion Characteristics Of Zn-Ni-Cd Ternary Alloys, Anand Durairajan, Bala S. Haran, Ralph E. White, Branko N. Popov

Faculty Publications

A new Zn-Ni-Cd plating process was developed which offers a unique way of controlling and optimizing the Ni and Cd contents in the final deposit. Zinc-nickel-cadmium alloy was deposited from a 0.5 M NiSO4 + 0.2 M ZnSO4 bath in the presence of 0.015 M CdSO4 and 1 g/L nonyl phenyl polyethylene oxide. Using this process a Zn-Ni-Cd ternary alloy, with a higher nickel content as compared to that obtained from conventional Zn-Ni baths, was synthesized. The Zn-Ni-Cd alloy coatings deposited from an electrolyte containing 0.015 M (0.3%) CdSO4 has a Zn to Ni ratio of …

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Ni-Composite Microencapsulated Graphite As The Negative Electrode In Lithium-Ion Batteries Ii: Electrochemical Impedance And Self-Discharge Studies, P. Yu, James A. Ritter, Ralph E. White, Branko N. Popov Jan 2000

Ni-Composite Microencapsulated Graphite As The Negative Electrode In Lithium-Ion Batteries Ii: Electrochemical Impedance And Self-Discharge Studies, P. Yu, James A. Ritter, Ralph E. White, Branko N. Popov

Faculty Publications

Electrochemical impedance and self-discharge studies were carried out to investigate lithium intercalation into bare and Ni-coated KS10 graphite. Values of the charge-transfer resistances, exchange current densities, surface film resistances, and lithium-ion diffusion coefficients as functions of the state of charge (SOC) all favored the 10 wt % Ni composite KS10 graphite over bare KS10 graphite when these materials were used as the negative electrode in a Li-ion cell with mixed organic electrolyte. The charge-transfer resistances were always lower and gave rise to between 26 and 27% larger exchange current densities, which increased from 137 to 614 mA/g as the SOC …

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Structural And Electrical Characterization Of A Novel Mixed Conductor: Ceo2 - Sm2O3 - Zro2 Solid Solution, W. Huang, P. Shuk, M. Greenblatt, M. Croft, Fanglin Chen, M. Liu Jan 2000

Structural And Electrical Characterization Of A Novel Mixed Conductor: Ceo2 - Sm2O3 - Zro2 Solid Solution, W. Huang, P. Shuk, M. Greenblatt, M. Croft, Fanglin Chen, M. Liu

Faculty Publications

solid solutions were synthesized for the first time by the hydrothermal method. The electrical properties of the solid solutions have been studied in air and under reducing conditions. Solid solutions with the fluorite structure were formed in all of the studied range of substitution after calcination at 1500°C. With increasing substitution up to 30 mol %, the electronic conductivity increases under a reducing atmosphere. The solid solution has good mixed electronic and ionic conductivity; the total conductivity is 0.42 S/cm at and 700°C with an estimated ionic conductivity of ca. .

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A Semianalytical Method For Predicting Primary And Secondary Current Density Distributions: Linear And Nonlinear Boundary Conditions, Dhanwa Thirumalai, Ralph E. White Jan 2000

A Semianalytical Method For Predicting Primary And Secondary Current Density Distributions: Linear And Nonlinear Boundary Conditions, Dhanwa Thirumalai, Ralph E. White

Faculty Publications

No abstract provided.

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Development Of A New Electrodeposition Process For Plating Of Zn‐Ni‐X (X = Cd, P) Alloys: I. Corrosion Characteristics Of Zn‐Ni‐Cd Ternary Alloys, Anand Durairajan, Bala S. Haran, Ralph E. White, Branko Popov Jan 2000

Development Of A New Electrodeposition Process For Plating Of Zn‐Ni‐X (X = Cd, P) Alloys: I. Corrosion Characteristics Of Zn‐Ni‐Cd Ternary Alloys, Anand Durairajan, Bala S. Haran, Ralph E. White, Branko Popov

Faculty Publications

No abstract provided.

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Computational Fluid Dynamics Modeling Of A Lithium/Thionyl Chloride Battery With Electrolyte Flow, W. B. Gu, C. Y. Wang, John W. Weidner, Rudolph G. Jungst, Ganesan Nagasubramanian Jan 2000

Computational Fluid Dynamics Modeling Of A Lithium/Thionyl Chloride Battery With Electrolyte Flow, W. B. Gu, C. Y. Wang, John W. Weidner, Rudolph G. Jungst, Ganesan Nagasubramanian

Faculty Publications

A two-dimensional model is developed to simulate discharge of a lithium/thionyl chloride primary battery. As in earlier one-dimensional models, the model accounts for transport of species and charge, and electrode porosity variations and electrolyte flow induced by the volume reduction caused by electrochemical reactions. Numerical simulations are performed using a finite volume method of computational fluid dynamics. The predicted discharge curves for various temperatures show good agreement with published experimental data, and are essentially identical to results published for one-dimensional models. The detailed two-dimensional flow simulations show that the electrolyte is replenished from the cell head space predominantly through the …

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Development Of A New Electrodeposition Process For Plating Of Zn-Ni-X (X = Cd, P) Alloys: Permeation Characteristics Of Zn-Ni-Cd Ternary Alloys, A. Durairajan, B. S. Haran, Ralph E. White, Branko N. Popov Jan 2000

Development Of A New Electrodeposition Process For Plating Of Zn-Ni-X (X = Cd, P) Alloys: Permeation Characteristics Of Zn-Ni-Cd Ternary Alloys, A. Durairajan, B. S. Haran, Ralph E. White, Branko N. Popov

Faculty Publications

It is shown that an electrodeposited Zn-Ni-Cd alloy coating produced from sulfate electrolyte inhibits the discharge of hydrogen on carbon steel. The newly developed ternary alloys have approximately ten times higher corrosion resistance when compared to a Zn-Ni alloy. Hydrogen permeation characteristics of Zn-Ni-Cd alloy coatings were studied and compared with those of a bare and a Zn-Ni alloy coated steel. The transfer coefficient, a, exchange current density, io, thickness dependent adsorption-absorption rate constant, k0, recombination rate constant, k3, surface hydrogen coverage, θH, were obtained by applying a mathematical model to experimental results. Alloys obtained from baths containing higher concentration …

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Modeling Lithium Intercalation Of A Single Spinel Particle Under Potentiodynamic Control, Dong Zhang, Branko N. Popov, Ralph E. White Jan 2000

Modeling Lithium Intercalation Of A Single Spinel Particle Under Potentiodynamic Control, Dong Zhang, Branko N. Popov, Ralph E. White

Faculty Publications

A mathematical model is presented for the lithium intercalation of a single spinel particle as a microelectrode under the stimulus of a cyclic linear potential sweep. The model includes both lithium diffusion within the particle and kinetics at the particle/electrolyte interface. The model is used to predict that peak current densities depend linearly on the scan rate to a certain power with a constant term, which is different from the predicted peak current density for a conventional redox system.

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Shrinking Core Model For The Discharge Of A Metal Hydride Electrode, Venkat R. Subramanian, Harry J. Ploehn, Ralph E. White Jan 2000

Shrinking Core Model For The Discharge Of A Metal Hydride Electrode, Venkat R. Subramanian, Harry J. Ploehn, Ralph E. White

Faculty Publications

A shrinking core model is presented for the galvanostatic discharge of a metal hydride particle. A quantitative criterion for when the shrinking core can be completely neglected or approximated by a pseudosteady-state solution is presented. The effect of shrinking of the core on the discharge behavior of a metal hydride particle is also studied.

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Piezoelectric Doping In Alingan/Gan Heterostructures, M. Asif Khan, J. W. Yang, Grigory Simin, R. Gaska, M. S. Shur, A. D. Bykovski Nov 1999

Piezoelectric Doping In Alingan/Gan Heterostructures, M. Asif Khan, J. W. Yang, Grigory Simin, R. Gaska, M. S. Shur, A. D. Bykovski

Faculty Publications

We report on the piezoelectricdoping and two-dimensional (2D) electron mobility in AlInGaN/GaN heterostructures grown on 6H–SiC substrates. The contribution of piezoelectricdoping to the sheet electron density was determined using an In-controlled built-in strain-modulation technique. Our results demonstrate that in strained AlGaN/GaN heterostructures, the piezoelectric field generates at least 50% of the 2D electrons. The strain modulation changes the potential distribution at the heterointerface, which, in turn, strongly affects the 2D electron mobility, especially at cryogenic temperatures. The obtained results demonstrate the potential of strain engineering and piezoelectricdoping for GaN-based electronics.

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Low-Frequency Noise In N-Gan With High Electron Mobility, M. E. Levinshtein, S. L. Rumyantsev, D. C. Look, R. J. Molnar, M. Asif Khan, Grigory Simin, V. Adivarahan, M. S. Shur Nov 1999

Low-Frequency Noise In N-Gan With High Electron Mobility, M. E. Levinshtein, S. L. Rumyantsev, D. C. Look, R. J. Molnar, M. Asif Khan, Grigory Simin, V. Adivarahan, M. S. Shur

Faculty Publications

We report on the results of measurements of low frequency noise in n-type gallium nitride (GaN) grown on sapphire with 300 K electron mobility of 790 cm2/V s. The noise spectra have the form of 1/f noise with a Hooge parameter α of approximately 5×10−2. This value of α is two orders of magnitude smaller than that observed before in n-GaN. The obtained results show that the level of flicker noise in GaN, just like that in GaAs and Si, strongly depends on the structural perfection of the material (the amplitude of the 1/f …

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Oxygen Permeation Through Composite Oxide-Ion And Electronic Conductors, Kevin Huang, Michael Schroeder, John B. Goodenough May 1999

Oxygen Permeation Through Composite Oxide-Ion And Electronic Conductors, Kevin Huang, Michael Schroeder, John B. Goodenough

Faculty Publications

Oxygen permeation through composites consisting of four well-known oxide-ion conductors and a noble metal, Pd or Ag, is reported. The oxides were Zr0.9Y0.1O1.95 (YSZ), (Bi1.75Y0.25O3)0.95(CeO2)0.05 (BYC5), Ce0.8Sm0.2O1.9 (SSC), and La0.8Sr0.2Ga0.83Mg0.17O2.815 (LSGM). The results show that (BYC5 + Ag) yields the highest oxygen permeation flux, but the composite deteriorates with time. The composites (SSC + Pd), (LSGM + Pd), and (YSZ + Pd) give stable, but relatively lower oxygen permeation flux …

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Online Auctions, Michael N. Huhns, José M. Vidal May 1999

Online Auctions, Michael N. Huhns, José M. Vidal

Faculty Publications

Auctions on the Internet can involve not only consumers, but also businesses. They can form dynamically and enable the exchange of goods much as stock exchanges manage the buying and selling of securities. But because auctions have a wide scope and a short lifetime, the opportunistic behavior needed for successful interaction requires agents to both participate in and manage auctions. The article focuses on the use of software agents in such Internet based auctions

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Preparation Of Mesoporous Tin Oxide For Electrochemical Applications, Fanglin Chen, Meilin Liu Jan 1999

Preparation Of Mesoporous Tin Oxide For Electrochemical Applications, Fanglin Chen, Meilin Liu

Faculty Publications

Mesoporous tin oxide stable up to 500 °C has been prepared for the first time using both cationic and neutral surfactants.

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Analysis Of A Lithium/Thionyl Chloride Battery Under Moderate-Rate Discharge, Mukul Jain, Ganesan Nagasubramanian, Rudolph G. Jungst, John W. Weidner Jan 1999

Analysis Of A Lithium/Thionyl Chloride Battery Under Moderate-Rate Discharge, Mukul Jain, Ganesan Nagasubramanian, Rudolph G. Jungst, John W. Weidner

Faculty Publications

A one-dimensional mathematical model of a spirally wound lithium/thionyl chloride primary battery is developed and used for parameter estimation and design studies. The model formulation is based on the fundamental conservation laws using porous electrode theory and concentrated solution theory. The model is used to estimate the transference number, the diffusion coefficient, and the kinetic parameters for the reactions at the anode and the cathode as a function of temperature. These parameters are obtained by fitting the simulated capacity and average cell voltage to experimental data over a wide range of temperatures (–55 to 49°C) and discharge loads (10-250 ). …

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Determination Of The Lithium Ion Diffusion Coefficient In Graphite, Ping Yu, Branko N. Popov, James A. Ritter, Ralph E. White Jan 1999

Determination Of The Lithium Ion Diffusion Coefficient In Graphite, Ping Yu, Branko N. Popov, James A. Ritter, Ralph E. White

Faculty Publications

A complex impedance model for spherical particles was used to determine the lithium ion diffusion coefficient in graphite as a function of the state of charge (SOC) and temperature. The values obtained range from of 1.12 × 10–10 to 6.51 × 10–11 cm2/s at 25°C for 0 and 30% SOC, respectively, and for 0% SOC, the value at 55°C was 1.35 × 10–10 cm2/s. The conventional potentiostatic intermittent titration technique (PITT) and Warburg impedance approaches were also evaluated, and the advantages and disadvantages of these techniques were exposed

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Exploiting Expertise Through Knowledge Networks, Michael N. Huhns, Larry M. Stevens Jan 1999

Exploiting Expertise Through Knowledge Networks, Michael N. Huhns, Larry M. Stevens

Faculty Publications

The paper discusses the necessary capabilities of knowledge networks: categorizing (the ability to classify Web pages and other unstructured data automatically); hyperlinking (the ability to add to each item of information appropriate pointers to other relevant items of information); alerting (the automatic notification of users and agents to new information that might be of interest to them); and profiling (the construction of models of users and agents to describe their interests and expertise).

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Personal Ontologies, Michael N. Huhns, Larry M. Stevens Jan 1999

Personal Ontologies, Michael N. Huhns, Larry M. Stevens

Faculty Publications

Corporations can suffer from too much information, and it is often inaccessible, inconsistent, and incomprehensible. The corporate solution entails knowledge management techniques and data warehouses. The paper discusses the use of the personal ontology. The promising approach is an organization scheme based on a model of an office and its information, an ontology, coupled with the proper tools for using it.

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Benevolent Agents, Michael N. Huhns, Abdulla Mohamed Jan 1999

Benevolent Agents, Michael N. Huhns, Abdulla Mohamed

Faculty Publications

Some agents roaming the Web these days are benevolent-for example, they may clean up stalled or failed database transactions, or share query results that may have cost substantial resources to acquire and might consume more to share. The Agent Behavior Testbed is a tool for studying the economics of agent altruism. As more agents hit the Internet, benevolence and cooperation will help with overall efficiency and productivity. The paper discusses benevolent agents on the Web.

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Networking Embedded Agents, Michael N. Huhns Jan 1999

Networking Embedded Agents, Michael N. Huhns

Faculty Publications

Most of us will soon be managing an intranet in our homes, though we might not realize it. We might also be surprised at the devices that will be networked together. Just about every electrical device now contains one or more microprocessors. Designers typically find this a cost-effective way to provide device functionality, even when much of a processor's power is unnecessary or unused. For example, my coffee maker contains a processor, even though the appliance needn't be very smart and wastes most of its CPU cycles. Nevertheless, it is cheaper to include a general-purpose microprocessor than to incorporate custom …

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