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Articles 2161 - 2190 of 2359

Full-Text Articles in Engineering

Negotiating For Goods And Services, Michael N. Huhns, Anuj K. Malhotra Jan 1999

Negotiating For Goods And Services, Michael N. Huhns, Anuj K. Malhotra

Faculty Publications

Can a negotiation protocol be both fair and “envy-free” when more than two agents are involved? The authors consider how envy-free apportioning is more difficult than fair apportioning, but both can help to manage critical resources. They discuss an envy-free protocol and agent-based Web auctions.

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Integrated Computational Chemistry System For Catalysts Design, Salai Cheettu Ammal, S. Takami, M. Kubo, A. Miyamoto Jan 1999

Integrated Computational Chemistry System For Catalysts Design, Salai Cheettu Ammal, S. Takami, M. Kubo, A. Miyamoto

Faculty Publications

The understanding of valuable catalytic and adsorptive properties of heterogeneous catalysts at atomic and electronic levels is essential for the design of novel catalysts. Computer simulation studies can significantly contribute to provide a rational interpretation of the observed experimental results and suggest modification of new catalysts. Our recent work on the application of integrated computer simulation methods to investigate the structure and catalytic properties of solid surfaces including zeolites, transition metals and their oxides have been reviewed in this paper. We have emphasized the effectivity and applicability of integrated computer simulation system to solve the problems in a variety of …

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Material Balance Modification In One-Dimensional Modeling Of Porous Electrodes, Mukul Jain, John W. Weidner Jan 1999

Material Balance Modification In One-Dimensional Modeling Of Porous Electrodes, Mukul Jain, John W. Weidner

Faculty Publications

The material balance used previously in one-dimensional mathematical models of porous electrodes is invalid when there is a non-zero volume change associated with the reaction. It is shown here how the material balance should be modified either to account for a loss in volume, or to account for an inflow of electrolyte from the header into the active pores. A one-dimensional mathematical model is used to illustrate the effect of this correction on the prediction of the delivered capacity and the electrolyte concentration in a lithium/thionyl chloride primary battery.

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Correlation Of Double-Layer Capacitance With The Pore Structure Of Sol-Gel Derived Carbon Xerogels, Chuan Lin, James A. Ritter, Branko N. Popov Jan 1999

Correlation Of Double-Layer Capacitance With The Pore Structure Of Sol-Gel Derived Carbon Xerogels, Chuan Lin, James A. Ritter, Branko N. Popov

Faculty Publications

Nine different sol-gel derived carbon xerogels were prepared with different pore structures by varying the carbonization temperature (in flowing N2) and activation time (in 5% CO2 in N2). For each of these carbon xerogels, mesopore and micropore size distributions and cumulative surface areas were extracted from a density functional theory analysis. Increasing the carbonization temperature caused a decrease in the number of micropores in the 6 Å range but had little effect on the mesopore size distribution and thus mesopore cumulative surface area. Increasing the CO2 activation time caused an increase in the number …

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A Mathematical Model Of An Electrochemical Capacitor With Double-Layer And Faradaic Processes, Chuan Lin, James A. Ritter, Branko N. Popov, Ralph E. White Jan 1999

A Mathematical Model Of An Electrochemical Capacitor With Double-Layer And Faradaic Processes, Chuan Lin, James A. Ritter, Branko N. Popov, Ralph E. White

Faculty Publications

A mathematical model of an electrochemical capacitor with hydrous ruthenium oxide (RuO2·xH2O) electrodes including both double-layer and surface faradaic processes is developed to predict the behavior of the capacitor under conditions of galvanostatic charge and discharge. The effect of RuO2·xH2O particle size is studied and shows that the smaller the particles the better the performance because of the increased surface area per unit volume or mass. The model also predicts that the faradaic process increases significantly the energy per unit volume of the capacitor for power densities of …

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Development Of Carbon-Metal Oxide Supercapacitors From Sol-Gel Derived Carbon-Ruthenium Xerogels, Chuan Lin, James A. Ritter, Branko N. Popov Jan 1999

Development Of Carbon-Metal Oxide Supercapacitors From Sol-Gel Derived Carbon-Ruthenium Xerogels, Chuan Lin, James A. Ritter, Branko N. Popov

Faculty Publications

Sol-gel derived high surface area carbon-ruthenium xerogels were prepared from carbonized resorcinol-formaldehyde resins containing an electrochemically active form of ruthenium oxide. The electrochemical capacitance of these materials increased with an increase in the ruthenium content indicating the presence of pseudocapacitance associated with the ruthenium oxide undergoing reversible faradaic redox reactions. A specific capacitance of 256 F/g (single electrode) was obtained from a carbon xerogel containing 14 wt % Ru, which corresponded to more than 50% utilization of the ruthenium. The double layer accounted for 40% of this capacitance. This material was also electrochemically stable, showing no change in a cyclic …

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A Mathematical Model For Electroless Copper Deposition On Planar Substrates, M. Ramasubramanian, Branko N. Popov, Ralph E. White, K. S. Chen Jan 1999

A Mathematical Model For Electroless Copper Deposition On Planar Substrates, M. Ramasubramanian, Branko N. Popov, Ralph E. White, K. S. Chen

Faculty Publications

A mathematical model for the electroless deposition of copper on a planar electrode is presented and used to make time-dependent predictions on the various quantities in the system. The model takes into account mass transport by diffusion and migration, Butler-Volmer kinetics at the electrode surface, and mixed potential theory. A finite difference approach is used to solve the equations, and the resultant model is used to predict the concentration profiles, potential response, and plating rate as a function of time and concentration of various reactive components.

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Mathematical Modeling Of The Lithium Deposition Overcharge Reaction In Lithium‐Ion Batteries Using Carbon‐Based Negative Electrodes, Pankaj Arora, Marc Doyle, Ralph E. White Jan 1999

Mathematical Modeling Of The Lithium Deposition Overcharge Reaction In Lithium‐Ion Batteries Using Carbon‐Based Negative Electrodes, Pankaj Arora, Marc Doyle, Ralph E. White

Faculty Publications

No abstract provided.

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Influence Of Some Design Variables On The Thermal Behavior Of A Lithium‐Ion Cell, Gerardine G. Botte, Bradley A. Johnson, Ralph E. White Jan 1999

Influence Of Some Design Variables On The Thermal Behavior Of A Lithium‐Ion Cell, Gerardine G. Botte, Bradley A. Johnson, Ralph E. White

Faculty Publications

No abstract provided.

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A Simple Method For Determining Differential Diffusion Coefficients From Aqueous Electrolyte Diaphragm Cell Data At Temperatures Below 0°C, D. M. See, Ralph E. White Jan 1999

A Simple Method For Determining Differential Diffusion Coefficients From Aqueous Electrolyte Diaphragm Cell Data At Temperatures Below 0°C, D. M. See, Ralph E. White

Faculty Publications

No abstract provided.

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Methanol Fuel Cell Model: Anode, S. F. Baxter, V. S. Battaglia, Ralph E. White Jan 1999

Methanol Fuel Cell Model: Anode, S. F. Baxter, V. S. Battaglia, Ralph E. White

Faculty Publications

No abstract provided.

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Mathematical Modeling Of Electrochemical Capacitors, Venkat Srinivasan, John W. Weidner Jan 1999

Mathematical Modeling Of Electrochemical Capacitors, Venkat Srinivasan, John W. Weidner

Faculty Publications

Analytic solutions to the mathematical model of an electrochemical capacitor (EC) are used to study cell performance under two types of operating conditions: (i) constant current and (ii) electrochemical impedance spectroscopy. The analytic solution under constant-current operation is used to investigate the relative importance of ionic resistance in the separator, and ionic and electronic resistances in the porous electrode in the design and operation of an EC. Model results are presented that show the trade-off between energy and power density, as the physical properties of the cell components are varied (e.g., electrode thickness). The analytic solution …

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Deriving Of Single Intensive Picosecond Optical Pulses From A High-Power Gain-Switched Laser Diode By Spectral Filtering, S. N. Vainshtein, Grigory Simin, J. T. Kostamovaara Oct 1998

Deriving Of Single Intensive Picosecond Optical Pulses From A High-Power Gain-Switched Laser Diode By Spectral Filtering, S. N. Vainshtein, Grigory Simin, J. T. Kostamovaara

Faculty Publications

Single 25 ps/16 W optical pulses were achieved by spectral filtering from a multiheterostructure gain-switched laser diode with its quasisteady-state modes suppressed by a factor of 103 as compared with the peak power. A significant transient spectrum broadening makes this possible provided that a very high dI/dt rate of the pumping current pulse is used. A simple numerical model is suggested which describes adequately both the spectral and transient features of the observed phenomenon. It follows from the model that single picosecond optical pulses can be obtained from any type of high power semiconductor laser.

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Chromium Oxides And Lithiated Chromium Oxides. Promising Cathode Materials For Secondary Lithium Batteries, Pankaj Arora, Dong Zhang, Branko N. Popov, Ralph E. White Sep 1998

Chromium Oxides And Lithiated Chromium Oxides. Promising Cathode Materials For Secondary Lithium Batteries, Pankaj Arora, Dong Zhang, Branko N. Popov, Ralph E. White

Faculty Publications

Chromiumoxides and lithiated chromium oxides were synthesized by thermal decompositionof chromium trioxide (CrO3) at high temperatures and oxygen pressures.Synthesis temperature and pressure markedly affect the performance of thesecathode materials. Higher pressures lead to a higher O/Cr ratioand fewer impurities in the final product. These materials arestable intercalation hosts for lithium, and exhibit a higher capacitythan any of the prominent positive electrodes used in secondarylithium batteries. m-CrOx has a capacity of 255 mAh/g, while m-LiCrOxhas a capacity of 210 mAh/g, during the first discharge. Theaverage voltage of these cells is 3.0 V vs. Li/Li …

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Cryptococcus Neoformans Chemotyping By Quantitative Analysis Of H-1 Nuclear Magnetic Resonance Spectra Of Glucuronoxylomannans With A Computer-Simulated Artificial Neural Network, Robert Cherniak, Homayoun Valafar, Laura C. Morris, Faramarz Valafar Mar 1998

Cryptococcus Neoformans Chemotyping By Quantitative Analysis Of H-1 Nuclear Magnetic Resonance Spectra Of Glucuronoxylomannans With A Computer-Simulated Artificial Neural Network, Robert Cherniak, Homayoun Valafar, Laura C. Morris, Faramarz Valafar

Faculty Publications

The complete assignment of the proton chemical shifts obtained by nuclear magnetic resonance (NMR) spectroscopy of de-O-acetylated glucuronoxylomannans (GXMs) from Cryptococcus neoformanspermitted the high-resolution determination of the total structure of any GXM. Six structural motifs based on an α-(1→3)-mannotriose substituted with variable quantities of 2-O-β- and 4-O-β-xylopyranosyl and 2-O-β-glucopyranosyluronic acid were identified. The chemical shifts of only the anomeric protons of the mannosyl residues served as structure reporter groups (SRG) for the identification and quantitation of the six triads present in any GXM. The assigned protons for the mannosyl residues resonated at clearly …

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Sr‐ And Ni‐Doped Lacoo3 And Lafeo3 Perovskites: New Cathode Materials For Solid‐Oxide Fuel Cells, Kevin Huang, Hee Y. Lee, John B. Goodenough Jan 1998

Sr‐ And Ni‐Doped Lacoo3 And Lafeo3 Perovskites: New Cathode Materials For Solid‐Oxide Fuel Cells, Kevin Huang, Hee Y. Lee, John B. Goodenough

Faculty Publications

An improved cathode material for a solid‐oxide fuel cell would be a mixed electronic and oxide‐ion conductor with a good catalytic activity for oxygen reduction at an operating temperature T op ≥ 700°C and a thermal expansion matched to that of the electrolyte and interconnect. We report on the properties of Sr‐ and Ni‐doped LaCoO3 and LaFeO3 perovskites that meet these criteria. Single‐phase regions were determined by X‐ray diffraction, and thermogravimetric analysis measurements were used to obtain the temperatures above which oxygen loss, and hence oxide‐ion conductivity, occurs. The conductivity and Seebeck measurements indicate the coexistence of both …

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Proton Diffusion In Nickel Hydroxide: Prediction Of Active Material Utilization, Sathya Motupally, Christopher C. Streinz, John W. Weidner Jan 1998

Proton Diffusion In Nickel Hydroxide: Prediction Of Active Material Utilization, Sathya Motupally, Christopher C. Streinz, John W. Weidner

Faculty Publications

Galvanostatic charge and discharge experiments reveal that the active material in nickel electrodes cannot be fully accessed at high currents or for thick films. It has been proposed that the utilization of the active material is controlled by the diffusion rate of protons through the film. This hypothesis is supported by the good agreement between mathematical simulations of material utilization and experimental data over a range of charge and discharge currents and film thicknesses. Furthermore, the fraction of material utilized is larger on charge than on discharge. The asymmetry on charge and discharge is due to a diffusion coefficient that …

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Chromium Oxides And Lithiated Chromium Oxides. Promising Cathode Materials For Secondary Lithium Batteries, Pankaj Arora, Dong Zhang, Branko N. Popov, Ralph E. White Jan 1998

Chromium Oxides And Lithiated Chromium Oxides. Promising Cathode Materials For Secondary Lithium Batteries, Pankaj Arora, Dong Zhang, Branko N. Popov, Ralph E. White

Faculty Publications

Chromium oxides and lithiated chromium oxides were synthesized by thermal decomposition of chromium trioxide (CrO3) at high temperatures and oxygen pressures. Synthesis temperature and pressure markedly affect the performance of these cathode materials. Higher pressures lead to a higher O/Cr ratio and fewer impurities in the final product. These materials are stable intercalation hosts for lithium, and exhibit a higher capacity than any of the prominent positive electrodes used in secondary lithium batteries. m-CrOx has a capacity of 255 mAh/g, while m-LiCrOx has a capacity of 210 mAh/g, during the first discharge. The average …

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Cognitive Agents, Michael N. Huhns, Munindar P. Singh Jan 1998

Cognitive Agents, Michael N. Huhns, Munindar P. Singh

Faculty Publications

Several researchers have proposed using cognitive concepts as a semantic basis for agent communications (M.N. Huhns and M.P. Singh, 1997). One of the leading candidates for such a semantics is based on Arcol, the communication language used within Artimis. Interestingly, this application (not only of Arcol, but also in general) appears extremely misguided. The intentional concepts are well suited to designing agents, but are not suited to giving a basis to a public, standardizable view of communication. A challenge for using the cognitive concepts is that although they are natural in several respects and can guide implementations, full blown implementations …

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Personal Assistants, Michael N. Huhns, Munindar P. Singh Jan 1998

Personal Assistants, Michael N. Huhns, Munindar P. Singh

Faculty Publications

Already there are simple personal agents to help with some of our shopping. There are agents to track stocks in our portfolios, advise us on how to use particular software products, and arrange meetings within corporate workgroups. However, none of these agents takes more than one aspect of our activities into account, nor do they adapt easily to our preferences. Personal assistants, on the other hand, are agents that can represent individuals on the Web. They help users in their day-to-day activities, especially those involving information retrieval, negotiation, or coordination. A personal assistant might schedule a meeting and then, based …

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Workflow Agents, Michael N. Huhns, Munindar P. Singh Jan 1998

Workflow Agents, Michael N. Huhns, Munindar P. Singh

Faculty Publications

Software agents as user agents, resource agents, and brokers may be able to enhance usefulness of workflow applications. Workflow technology is important to network computing because workflows exist naturally wherever distributed resources are interrelated. The problem with current workflow technology is that it is often too rigid. The lack of freedom accorded to human participants causes workflow management systems to appear unfriendly. As a result, they are often ignored or circumvented. This rigidity also causes productivity losses by making it harder to accommodate the flexible, ad hoc reasoning of human intelligence. Another challenge is that system requirements are rarely static. …

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All Agents Are Not Created Equal, Michael N. Huhns, Munindar P. Singh Jan 1998

All Agents Are Not Created Equal, Michael N. Huhns, Munindar P. Singh

Faculty Publications

As the technology advances, we can expect the development of specialized agents to be used as standardized building blocks for information systems. Two trends lend credence to such a prediction. First, software systems in general are being constructed with larger components, such as ActiveX and JavaBeans, which are becoming closer to being agents themselves. They have more functionality than simple objects, respond to events autonomously, and, most importantly, respond to system builders at development time, as well as to events at runtime. Moreover, there is a move toward more cooperative information systems, in which the architecture itself plays an important …

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Anthropoid Agents, Michael N. Huhns, Munindar P. Singh Jan 1998

Anthropoid Agents, Michael N. Huhns, Munindar P. Singh

Faculty Publications

In the study of agents on the Internet, we often ascribe to them human qualities, such as beliefs and intentions. These qualities are best understood as metaphors that give developers a way to talk about and design the capabilities and applications of agents. Despite all the progress in computing, users have been slow to accept the technology. They have often accepted what was thrown at them, but only under economic duress. Bringing the technology closer to their emotional needs might ease this resistance. So how can we put a human face on computing? Maybe by putting an animated face on …

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Electrochemical Investigations Of Cobalt-Doped Limn2O4 As Cathode Material For Lithium-Ion Batteries, P. Arora, Branko Popov, Ralph E. White Jan 1998

Electrochemical Investigations Of Cobalt-Doped Limn2O4 As Cathode Material For Lithium-Ion Batteries, P. Arora, Branko Popov, Ralph E. White

Faculty Publications

A wide range (y = 0.05–0.33) of Co-doped LiCoyMn2–yO4 spinels were synthesized and electrochemically characterized. These Co-doped spinels showed improved specific capacity and capacity retention over pure spinels. Electrochemical impedance spectroscopy and the linear polarization resistance technique were used to determine the transport and electrochemical kinetic parameters of Co-doped spinels. The presence of Co in the spinel inhibits the passivation process occurring on the surface of the cathode. Also, Co increases the exchange current density and facilitates the charge-transfer reaction of the active material. The lower self-discharge observed for Co-doped spinels was attributed …

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Characterization Of Hydrogen Permeation Through Zinc-Nickel Alloys Under Corroding Conditions: Mathematical Model And Experimental Study, M. Ramasubramanian, Branko N. Popov, Ralph E. White Jan 1998

Characterization Of Hydrogen Permeation Through Zinc-Nickel Alloys Under Corroding Conditions: Mathematical Model And Experimental Study, M. Ramasubramanian, Branko N. Popov, Ralph E. White

Faculty Publications

A mathematical model was developed for the characterization of hydrogen permeation into metals and alloys under corroding conditions. The model requires a knowledge of the corrosion rate of the given metal or alloy in solutions of various H+ concentrations. It provides quantitative values of rate constants of the hydrogen discharge, recombination, and adsorption reactions. This model can serve as a diagnostic criterion for determining the effectiveness of various metals and alloys as hydrogen permeation inhibitors and can be used for evaluation of hydrogen entry inhibition efficiency. Experiments were carried out to study the effectiveness of thin layers of electrodeposited …

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Characterization Of Sol-Gel-Derived Cobalt Oxide Xerogels As Electrochemical Capacitors, Chuan Lin, James A. Ritter, Branko N. Popov Jan 1998

Characterization Of Sol-Gel-Derived Cobalt Oxide Xerogels As Electrochemical Capacitors, Chuan Lin, James A. Ritter, Branko N. Popov

Faculty Publications

Very fine cobalt oxide xerogel powders were prepared using a unique solution chemistry associated with the sol-gel process. The effect of thermal treatment on the surface area, pore volume, crystallinity, particle structure, and corresponding electrochemical properties of the resulting xerogels was investigated and found to have significant effects on all of these properties. The xerogel remained amorphous as Co(OH)2 up to 160°C, and exhibited maxima in both the surface area and pore volume at this temperature. With an increase in the temperature above 200°C, both the surface area and pore volume decreased sharply, because the amorphous Co(OH)2 decomposed …

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Studies On Electroless Cobalt Coatings For Microencapsulation Of Hydrogen Storage Alloys, Bala S. Haran, Branko N. Popov, Ralph E. White Jan 1998

Studies On Electroless Cobalt Coatings For Microencapsulation Of Hydrogen Storage Alloys, Bala S. Haran, Branko N. Popov, Ralph E. White

Faculty Publications

LaNi4.27Sn0.24 alloy was microencapsulated with cobalt by electroless deposition from an alkaline hypophosphite bath. Discharge curves of the encapsulated alloy indicate an additional contribution to the capacity arising from the cobalt on the surface. Studies on cobalt thin films reveal the presence of adsorbed hydrogen in cobalt. The amount of hydrogen adsorbed was observed to increase with time of cathodic polarization and to reach a maximum. Polarization techniques have been used to characterize the cobalt-plated alloy as a function of state of charge. The equilibrium potential of the microencapsulated electrode at low hydrogen concentration is determined by …

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Theoretical Analysis Of Metal Hydride Electrodes: Studies On Equilibrium Potential And Exchange Current Density, Bala S. Haran, Branko N. Popov, Ralph E. White Jan 1998

Theoretical Analysis Of Metal Hydride Electrodes: Studies On Equilibrium Potential And Exchange Current Density, Bala S. Haran, Branko N. Popov, Ralph E. White

Faculty Publications

A theoretical model for the metal hydride electrode has been developed assuming that hydrogen diffusion in the alloy and charge-transfer at the surface control the discharge process. Theoretical equations for the dependence of equilibrium potential and exchange current density on the surface hydrogen concentration have been derived. These parameters have been used to correlate experimental data with the theoretical electrode discharge model. Analysis of both the experimental and theoretical discharge curves reveals a potential plateau determined by the magnitude of the interactions between the hydrogen in the alloy and the unhydrided metal. Neglecting these hydrogen-metal site interactions results in simulations …

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A Nonisothermal Nickel‐Hydrogen Cell Model, Pauline De Vidts, Javier Delgado, B. Wu, D. M. See, K. Kosanovich, Ralph E. White Jan 1998

A Nonisothermal Nickel‐Hydrogen Cell Model, Pauline De Vidts, Javier Delgado, B. Wu, D. M. See, K. Kosanovich, Ralph E. White

Faculty Publications

No abstract provided.

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The Role Of Oxygen At The Second Discharge Plateau Of Nickel Hydroxide, Sathya Motupally, Mukul Jain, Venkat Srinivasan, John W. Weidner Jan 1998

The Role Of Oxygen At The Second Discharge Plateau Of Nickel Hydroxide, Sathya Motupally, Mukul Jain, Venkat Srinivasan, John W. Weidner

Faculty Publications

It was shown that the appearance of a secondary discharge plateau approximately 400 mV below the primary plateau can result from the reduction of oxygen. During the galvanostatic discharge of planar nickel-hydroxide films at room temperature and in 3 weight percent KOH solutions, the second discharge plateau was observed only in the presence of dissolved oxygen in the electrolyte. When the solution was deoxygenated, no residual capacity could be extracted from the films even at low discharge rates or from overcharged films. In addition, the duration of the second plateau is inversely proportional to the square of the discharge current, …

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