Engineering Commons^™

Confluence Of Density Currents Over An Erodible Bed, Hassan Ismail

Theses and Dissertations

Results from laboratory experiments on conservative density current confluence are reported. Hydraulic characteristics and morphodynamic consequences of the confluence of two continuous release density currents in a horizontal, 45 degree asymmetrical junction are examined and compared to those of terrestrial river junctions. It was observed that density current confluence is markedly different than those in river junctions primarily due to the ease of the dense fluid to convect into the ambient fluid in the junction zone. Upward convection in the junction resulted in low horizontal velocity and shear stresses on the bed of the junction zone, followed by re-plunging to …

Tool Material Degradation Due To Friction Stir Welding Of Aluminum Alloys, Corbin T. Collier

Theses and Dissertations

The purpose of this study is to investigate the friction stir welding (FSW) tool material degradation factors due variation in tool material properties and the effect of an aluminum diffusion wear mechanism on three different FSW tool material when exposed to various welding temperatures and times. The degradation factors are essential to FSW tool design due to the effect of the tool pin and shoulders on the heat generation and material flow which directly correlated to the weld quality created during the FSW process. For this investigation the three materials used are H13, TSP1, and MP159. To determine degradation factors …

Preparation And Characterization Of Pt-Ru Bimetallic Catalysts Using Electroless Deposition Methods And Mechanistic Study Of Re And Cs Promoters For Ag-Based, High Selectivity Ethylene Oxide Catalysts, Weijian Diao

Theses and Dissertations

Pt-Ru bimetallic catalysts are widely used for direct methanol fuel cells, biomass upgrading and hydrocarbon refining and offer unique properties compared to Pt or Ru monometallic catalysts due to ensemble effects, electronic effects, and/or bifunctional effects. To achieve better performance, strong metal-metal interactions and true bimetallic surface are needed. Electroless deposition (ED) methods are used in our laboratory to synthesize such bimetallic catalysts. In this study, two series of Ru@Pt/C (Pt deposited on Ru surfaces) and Pt@Ru/C (Ru deposited on Pt surfaces) catalysts have been synthesized. Characterization data from temperature programmed reduction (TPR), selective chemisorption, X-ray photoelectron spectroscopy (XPS), and …

Impact Of Formulation And Processing Parameters On Mechanical Properties Of Magadiite/Elastomer Composites, Yating Mao

Theses and Dissertations

This work seeks a better understanding of mechanical reinforcement and energy dissipation in elastomer composites containing the layered silicate magadiite (MGD, Na2Si14O29·nH2O). We characterized the elastomer’s accessibility into MGD interlayer spaces and studied the factors that influence the composite mechanical properties. We also compare the mechanical reinforcement of MGD with montmorillonite (MMT, a layered aluminosilicate clay mineral), which is widely used as filler in other kinds of nanocomposites. The study explores the grafting chemistry, vulcanization, and reinforcement mechanism in MGD/elastomer composites, which may help us to formulate the platelet/elastomer composites with superior mechanical properties and performance in the future. We …

Bio-Inspired Design Of Mechanical Band Pass Sensor With The Ability To Scavenge Energy, Md Riaz Uddin Ahmed

Theses and Dissertations

Primary objective of this work is to introduce the multi-scale computational model for the bio-inspired acousto-ultrasonic band pass sensor that are capable of mechanically sense and/or filter wide range user defined frequencies. Selecting a particular and/or a distinct band of frequencies is essential for many applications in science engineering and technologies. For example design of sensors in chemical, biomedical and biological applications; device application for acoustic modulation by breaking the acoustic reciprocity and the sensors used in precision manufacturing applications requires sensing and/or filtering of wide range of acousto-ultrasonic frequencies. Presently, electronic devices are widely employed in commercial applications for …

Dielectric Characteristics Of Microstructural Changes And Property Evolution In Engineered Materials, Jallisa Janet Clifford

Theses and Dissertations

Heterogeneous materials are increasingly used in a wide range of applications such as aerospace, civil infrastructure, fuel cells and many others. The ability to take properties from two or more materials to create a material with properties engineered to specific needs is always very attractive. Hence engineered materials are evolving into more complex formulations or heterogeneities in multiple disciplines. Design of microstructure at multiple scales controls the global functional properties of these materials and their structures. However, local microstructural changes do not directly cause a proportional change to the global properties (such as strength and stiffness). Instead, local changes follow …

In Situ Ir Spectroscopic Investigation Of Noble Metal Catalysts Related To The Reduction Of Automotive Exhaust Emissions, Zhiyong Wang

Theses and Dissertations

The reduction of automotive exhaust emissions has been one of the hottest topics in catalysis community since 1970s. Thanks to the development of three-way catalysts, main auto-exhaust pollutants, such as carbon monoxide, nitrogen oxides and unburned hydrocarbons, can be removed simultaneously. Nowadays, diesel engines and lean-engines become more and more popular due to their high fuel-efficiency and low CO2 emissions. Unfortunately, conventional three-way catalysts are not effective at reducing the NOx emissions from these engines due to the excess oxygen in the exhaust stream. Platinum catalysts were found to be highly active for selective NO reduction with hydrocarbons in excess …

A Multiphysics Modeling Of Solid Oxide Metal-Air Redox Battery, Md Ahsan Uddin

Theses and Dissertations

Cost-effective and large scale energy storage is essential for the growth of the future’s ‘‘green energy’’ infrastructure. Among the energy storage technologies currently being used, rechargeable batteries represent a class of advanced electrical energy storage (EES) mechanisms that can be valuable for the future renewable integration and smart grid. Rechargeable batteries have innumerous advantages over the conventional pumped hydro and compressed-air energy storage system. Now days, There are various types of rechargeable batteries available to work as an energy storage device in a smart grid but it still needs many breakthroughs to become commercially viable for stationary energy storage. First …

Surface Modification Of Nanodiamond And Its Incorporation In Nanodiamond/Peek Nanocomposites, Zahidul Wahab

Theses and Dissertations

The continued miniaturization of electronic device components requires new lightweight polymers with high thermal stability, high thermal conductivity, low electrical conductivity, and low dielectric constant. Composites of nanodiamond (ND) and poly(ether ether ketone) (PEEK) are candidates for these applications due their unique combination of properties. The objectives of this research are to explore new routes for surface functionalization of nanodiamond (ND), develop methods for maximizing dispersion of ND as a nano-scale filler in PEEK, and characterize the effect of dispersed ND on the mechanical, thermal and dielectric properties of ND/PEEK composites. Initial attempts to disperse different kinds of commercially available, …

Guided Wave Based Integrated Structural Health Monitoring And Nondestructive Evaluation, Zhenhua Tian

Theses and Dissertations

Damage detection and health monitoring are critical for ensuring the structural safety in various fields, such as aerospace, civil and nuclear engineering. Structural health monitoring (SHM) performs online nondestructive evaluation (NDE) and can predict the structural remaining life through appropriate diagnosis and prognosis technologies. Among various SHM/NDE technologies, guided ultrasonic waves have shown great potential for fast and large area SHM/NDE, due to their sensitivity to small defects and capability to propagate long distances. Recent advances in guided wave based SHM/NDE technologies have demonstrated the feasibility of detecting damage in simple structures such as metallic plates and pipes. However, there …

Nd − Pdpa: N Dimensional Probability Density Profile Analysis, Arjang Fahim

Theses and Dissertations

Proteins are often referred as working molecule of a cell, performing many structural, functional and regulatory processes. Revealing the function of proteins still remains a challenging problem. Advancement in genomics sequence projects produces large protein sequence repository, but due to technical difficulty and cost related to structure determination, the number of identified protein structure is far behind. Novel structures identification are particularly important for a number of reasons: they generate models of similar proteins for comparison; identify evolutionary relationships; further contribute to our understanding of protein function and mechanism; and allow for the fold of other family members to be …

Size-Controlled Large-Diameter And Few-Walled Carbon Nanotube Catalysts For Oxygen Reduction, Xianliang Wang, Qing Li, Hengyu Pan, Ye Lin, Yujie Ke, Haiyang Sheng, Mark T. Swihart, Gang Wu

Faculty Publications

We demonstrate a new strategy for tuning the size of large-diameter and few-walled nitrogen-doped carbon nanotubes (N-CNTs) from 50 to 150 nm by varying the transition metal (TM = Fe, Co, Ni or Mn) used to catalyze graphitization of dicyandiamide. Fe yielded the largest tubes, followed by Co and Ni, while Mn produced a clot-like carbon morphology. We show that morphology is correlated with electrocatalytic activity for the oxygen reduction reaction (ORR). A clear trend of Fe > Co > Ni > Mn for the ORR catalytic activity was observed, in both alkaline media and more demanding acidic media. The Fe-derived N-CNTs exhibited …

Application Of A Coated Film Catalyst Layer Model To A High Temperature Polymer Electrolyte Membrane Fuel Cell With Low Catalyst Loading Produced By Reactive Spray Deposition Technology, Timothy D. Myles, Siwon Kim, Radenka Maric, William E. Mustain

Faculty Publications

In this study, a semi-empirical model is presented that correlates to previously obtained experimental overpotential data for a high temperature polymer electrolyte membrane fuel cell (HT-PEMFC). The goal is to reinforce the understanding of the performance of the cell from a modeling perspective. The HT-PEMFC membrane electrode assemblies (MEAs) were constructed utilizing an 85 wt. % phosphoric acid doped Advent TPS® membranes for the electrolyte and gas diffusion electrodes (GDEs) manufactured by Reactive Spray Deposition Technology (RSDT). MEAs with varying ratios of PTFE binder to carbon support material (I/C ratio) were manufactured and their performance at various operating temperatures was …

Optimum 3d Matrix Stiffness For Maintenance Of Cancer Stem Cells Is Dependent On Tissue Origin Of Cancer Cells, Esmaiel Jabbari, Samaneh K. Sarvestani, Leily Daneshian, Seyedsina Moeinzadeh

Faculty Publications

Introduction

The growth and expression of cancer stem cells (CSCs) depend on many factors in the tumor microenvironment. The objective of this work was to investigate the effect of cancer cells’ tissue origin on the optimum matrix stiffness for CSC growth and marker expression in a model polyethylene glycol diacrylate (PEGDA) hydrogel without the interference of other factors in the microenvironment.

Methods

Human MCF7 and MDA-MB-231 breast carcinoma, HCT116 colorectal and AGS gastric carcinoma, and U2OS osteosarcoma cells were used. The cells were encapsulated in PEGDA gels with compressive moduli in the 2-70 kPa range and optimized cell seeding density …

Impacts Of Large-Scale Stormwater Green Infrastructure Implementation And Climate Variability On Receiving Water Response In The Salt Lake City Area, Chris York, Erfan Goharian, Steven J. Burian

Faculty Publications

This study evaluated impacts of Green Infrastructure (GI) as a stormwater management practice on return flows and the further Implications of climate variability. The goal was to create a model to explore the impacts that bioretention and Rainwater Harvesting (RWH) representing GI had using goldsim and Stormwater Management Modeling (SWMM) software. The software was used to represent impacts that climate variability individually and combined, may have on downstream stakeholders and receiving water systems in Salt Lake city, Utah, USA. Primary stakeholders included downstream water rights users, Farmington Bay waterfowl management area and the migratory birds that rely on Farmington Bay …

Unmanned Aircraft Systems: Air-Ground Channel Characterization For Future Applications, David W. Matolak, Ruoyu Sun

Faculty Publications

Unmanned aircraft systems (UASs) are being used increasingly worldwide. These systems will operate in conditions that differ from conventional piloted aircraft, and this implies that the airground (AG) channel for UASs can differ significantly from the traditional, simple, AG channel models. After providing some background and motivation, we describe the AG channel features and our efforts in measuring and modeling the AG channel. Some example measurement and model results-for the path loss and the Ricean K-factor-are provided to illustrate some of the interesting AG channel characteristics that are still being investigated.

High-Throughput Screening Using Fourier-Transform Infrared Imaging, Erdem Sasmaz, Kathleen Mingle, Jochen A. Lauterbach

Faculty Publications

Efficient parallel screening of combinatorial lib­ra ries is one of the most challenging aspects of the high­throughput (HT) heterogeneous catalysis workflow. Today, a number of methods have been used in HT catalyst studies, including various optical, mass­spectrometry, and gas­chromatography techniques. Of these, rapid­scanning Fourier­transform infrared (FTIR) imaging is one of the fastest and most versatile screening techniques. Here, the new design of the 16­channel HT reactor is presented and test results for its accuracy and reproducibility are shown. The performance of the system was evaluated through the oxidation of CO over commercial Pd/Al2O3 and cobalt oxide nanoparticles synthesized with different …

Photosynthetic Performance And Anti-Oxidative Response Of Cornus Controversa Seedlings Under Cadmium And Lead Stress, Xinyu Huang, Yonglei Jiang, Xiaomao Cheng, Lilan Deng, Xuncheng Liu

Faculty Publications

The photosynthetic efficiency of Cornus controversa leaves was decreased significantly under Cd treatment while it was not affected by Pb exposure. Cd decreased while Pb treatment increased the chlorophyll contents of Cornus controversa leaves. Furthermore, the peroxidase (GPX) activities were decreased after Cd treatment while elevated by Pb exposure in Cornus controvera seedlings. In addition, both Cd and Pb exposures increased the malondialdehyde (MDA) and proline contents and elevated the superoxide dismutase (SOD) activities of Cornus controvera seedlings. Collectively, these results indicated that Cornus controversa may be more tolerant to Pb than Cd toxicity. This finding will contribute to the …

Thin Film Based Biocompatible Sensors For Physiological Monitoring, Yihao Zhu

Theses and Dissertations

The development and evolution of physiological sensors, from wearable to implantable, has enabled long term continuous physiological monitoring, making possible for the out-of-clinic treatment and management of many chronic illnesses, mental health issues and post-surgery recovery. This technology advance is gradually changing the definition of health care and the way it is delivered, from clinic/emergency room to patient’s own environment. In this dissertation, three general types of sensors have been proposed for physiological monitoring of blood pressure, oxygen content and electrolyte ion concentration level in human body, respectively. The study proved the device concepts and shows promising results with the …

New Design Of Nasogastric Decompression Tube That Incorporates A Self-Cleaning Brushing Mechanism, Nichole Abla, Lindsay Rucker, Paige Schroder

Senior Theses

Many hospitalized patients require the removal of secretions that accumulate in the stomach and must be removed by a nasogastric tube, which unfortunately clogs often. This project outlines the redesign of the nasogastric tube that will ideally prevent nasogastric tube clogging by incorporating a brush mechanism and a contracting tip mechanism, to act as preventative measures against clogging.

Project Labyrinth: Exploration Of Modulating Guitar Signals, Joseph Andrews, Andrew Patterson

Senior Theses

The overall objective of this project is to create a guitar pre-amplifier in the casing of an effects pedal. The pedal must be able to modulate amplitude and pitch. More specifically, the design for this pedal will include floating frequency filtering, phase shifting, and amplitude modulation.

Evoking History Through Sound: A Soundscape Concept For Ghosts Of The Horseshoe, Connor Patrick Bain

Senior Theses

Sound has always been treated as a second citizen in our society. Our society places so much emphasis on the visual that hearing, a sense that we cannot ever shut out from our minds, is taken for granted. This thesis argues that you can never ignore sound and proposes a design cycle for creating a soundscape for a critical interactive, then implementing that cycle for "Ghosts of the Horseshoe."

Heat Integration Of An Aniline Production Process To Optimize Cost Savings And Reduce Energy Usage, Dillon Ashby

Senior Theses

The purpose of this project was to individually complete a heat integration optimization for my group’s senior design project, a process for the large-scale production of aniline.

On The Influence Of Ionic Strength On Radium And Strontium Sorption To Sandy Loam Soils, Brian A. Powell, Todd Miller, Daniel I. Kaplan

Journal of the South Carolina Academy of Science

Models which can estimate environmental transport of radioactive contaminants in natural and engineered systems are required to 1) deploy effective remediation strategies for contaminated sites, 2) design waste repositories for future waste streams, and 3) ensure protection of human and environmental health in all cases. These models require accurate transport parameters in order to correctly predict how these contaminants will move in the subsurface. This work aimed to determine more accurately the distribution coefficients for radium and strontium sorption to Savannah River Site (SRS) soils. Radium and strontium sorption to the soils was found to be highly dependent upon ionic …

Towards The Perfect Optical Fiber, John Ballato

Journal of the South Carolina Academy of Science

Optical fibers are being used in an ever more diverse array of applications today. Many of these modern applications are in high-power and, particularly, high power-per-unit-bandwidth systems where optical nonlinearities historically have not limited overall performance. Today, however, nominally weak effects, such as stimulated Brillouin scattering (SBS), are restricting continued scaling to higher optical powers. To address these limitations, the optical fiber industry has focused on fiber geometry-related solutions such as large mode area (LMA) designs. However, since all linear and nonlinear optical phenomena are fundamentally materials-based in origin, this paper identifies material solutions to present and future performance limitations …

Enhancing Grain Boundary Ionic Conductivity In Mixed Ionic–Electronic Conductors, Ye Lin, Shumin Fang, Dong Su, Kyle S. Brinkman, Fanglin Chen

Faculty Publications

Mixed ionic–electronic conductors are widely used in devices for energy conversion and storage. Grain boundaries in these materials have nanoscale spatial dimensions, which can generate substantial resistance to ionic transport due to dopant segregation. Here, we report the concept of targeted phase formation in a Ce0.8Gd0.2O2−δ–CoFe2O4 composite that serves to enhance the grain boundary ionic conductivity. Using transmission electron microscopy and spectroscopy approaches, we probe the grain boundary charge distribution and chemical environments altered by the phase reaction between the two constituents. The formation of an emergent phase successfully avoids segregation of the Gd dopant and depletion of oxygen vacancies …

Experimental Characterization And Correlation Analysis Of Indoor Channels At 15 Ghz, Xin Zhou, Zhangdui Zhong, Bei Zhang, Ruisi He, Ke Guan, Qi Wang, David W. Matolak

Faculty Publications

The indoor radio channels at 15 GHz are investigated based on measurements. The large- and small-scale fading behaviors as well as the delay dispersion characteristics are discussed. It is found that the large-scale fading, Ricean -factor, and delay spread can be described by log-normal distributions. Furthermore, both autocorrelation and cross correlation properties of the above parameters are analyzed and modeled. These parameters characterize fading and delay behaviors as well as their mutual dependency and can be used as empirical values for future wireless system design and simulation in 15 GHz short-range indoor channels.

Electrochemical Capture Of Co2 From Natural Gas Using A High-Temperature Ceramic-Carbonate Membrane, Jingjing Tong, Lingling Zhan, Jie Fang, Minfang Han, Kevin Huang

Faculty Publications

This study reports the first investigation of using a ceramic-carbonate dual-phase membrane to electrochemically separate CO₂ from a simulated natural gas. The CO₂ permeation flux density was systematically studied as a function of temperature, CO₂ partial pressure and time. As expected, the flux density was observed to increase with temperature and CO₂ partial pressure. Long-term stability test showed that flux density experienced an initial performance-improving “break-in” period followed by a slow decay. Post-test microstructural analysis suggested that a gradual loss of carbonate during the test could be the cause of the flux-time behavior observed.

Cameron Decomposition Applied To Polarimetric Synthetic Aperture Radar Signature Detection, Sean Wininger

Theses and Dissertations

Cameron et al, have developed a method of decomposing scatterer scattering matrices based on Huynen’s scattering matrix decomposition parameters. Huynen’s decomposition parameters are not unique, in that certain transformation properties, such as the angle of symmetry itself, may misidentify a scattering matriix and therefore misidentify a particular geometric shape. Cameron decomposition derives these parameters by direct calculations from the scatterer itself so that they may not be inferred or interpreted. A detailed explanation of the foundations and method of Cameron decomposition is presented here. A description of how Cameron decomposition is implemented in Polarimetric Synthetic Aperture Radar (PolSAR) signature detection …

Quantification Of The Effect Of Tool Geometric Features On Aspects Of Friction Stir Welding, Md. Reza-E-Rabby

Theses and Dissertations

In the friction stir welding (FSW) process, tool stirring and synchronized movement of the weld materials along a pre-existing seam line causes thermal gradients and severe plastic deformation resulting in the bonding of the adjacent materials. For a given set of welding parameters, tool pin geometries (dimensions, shape) and vertical/helical features that dictate the material motion also have significant effects on process response variables during FSW. Among the primary process controlling parameters in FSW, tool pin geometry and feature vary multifariously in terms of shape, dimensions, feature insertion technique depending on the weld material and application of joint. The current …